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Recent Advances in Energy Storage Systems: From Materials Innovation to Practical Applications

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Dear Colleagues,

This Special Issue of Molecules, entitled "Recent Advances in Energy Storage Systems: From Materials Innovation to Practical Applications", centers on the molecular and materials chemistry foundations that underpin high-performance energy storage technologies, aligning closely with the journal’s core chemistry focus. It highlights fundamental chemical insights—including molecular design, synthetic methodologies, interfacial redox chemistry, ion transport mechanisms, and structure–property relationships—across advanced storage systems such as rechargeable batteries, supercapacitors, and hybrid storage devices. Contributions will bridge chemical innovation at the molecular level with scalable material synthesis and real-world device translation, covering topics like functional electrode materials, electrolyte chemistry, interface engineering, and degradation mitigation from a chemical perspective. We welcome original research, communications, and reviews that advance chemical understanding of energy storage materials, fostering cross-disciplinary dialog between chemists, materials scientists, and engineers to drive sustainable, high-efficiency energy storage solutions.

Prof. Dr. Dezhi Chen
Prof. Dr. Junfei Liang
Dr. Hongying Quan
Guest Editors

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21 pages, 2370 KB

Open AccessPerspective

History Matters in Solid-State Hydrogen Storage: Hidden State Variables and Pathway-Dependent Reactivity in Mg-Based Hydrides

by Chen Chen, Quanhui Hou, Liangjuan Gao and Zhao Ding

Molecules 2026, 31(11), 1982; https://doi.org/10.3390/molecules31111982 (registering DOI) - 5 Jun 2026

Abstract

Magnesium-based hydrides remain among the most intensively studied solid-state hydrogen storage materials because they combine high theoretical hydrogen capacity, elemental abundance, and relatively low cost. Yet their practical behavior often varies far more strongly than nominal composition alone would suggest. Materials described under similar chemical labels may show markedly different activation profiles, sorption kinetics, reversible capacities, and cycling responses, even when they appear compositionally comparable. This Perspective argues that such discrepancies are best understood by recognizing that Mg-based hydrogen storage materials are not fully defined by composition, catalyst identity, and equilibrium thermodynamics alone. Instead, they react from historically written states produced by synthesis, activation, and cycling. These histories generate hidden state variables, including defects, residual strain, metastable structural motifs, interfacial topology, and catalyst transformation states, that reshape the operative hydrogen sorption pathway. The discussion therefore moves from a conventional composition-centered view toward a pathway-centered interpretation of reactivity. First, it examines how hidden state variables are written into Mg-based materials through processing, activation, and repeated use. It then shows how metastability serves as the structural bridge that allows these variables to persist into the reaction window. On that basis, the article argues that hydrogen sorption in Mg-based hydrides is fundamentally pathway-dependent, with history influencing hydrogen entry, transport-network selection, interfacial route construction, and pathway evolution during cycling. This perspective also provides a more coherent explanation for the long-standing reproducibility problem in the field, which is reinterpreted here as a pathway-mismatch problem arising from comparisons among historically different reactive states. Finally, a metadata-aware, pathway-aware, and boundary-aware design framework is proposed as a more realistic basis for cumulative materials development. From this viewpoint, the future of Mg-based solid-state hydrogen storage depends not only on better compositions, but on better-defined, better-constructed, and better-preserved reactive pathways under clearly specified internal and external constraints. Full article

(This article belongs to the Special Issue Recent Advances in Energy Storage Systems: From Materials Innovation to Practical Applications)

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