The 15th Anniversary of Minerals: Bubble–Particle Interactions in Flotation Processes

A Special Issue of Minerals (ISSN 2075-163X) belonging to the section "Mineral Processing and Extractive Metallurgy".

Deadline for manuscript submissions: closed (31 August 2026) | Viewed by 1654

Editors


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Guest Editor
Department of Mineral Processing Engineering, Faculty of Mines, Istanbul Technical University, 34469 Istanbul, Turkey
Interests: flotation; adsorption; industrial minerals; waste treatment

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Guest Editor
Department of Mining Engineering, Faculty of Engineering, Afyon Kocatepe University, 03200 Afyonkarahisar, Turkey
Interests: flotation; coal preparation; mineral processing; chemical and physical wastewater treatment processes; industrial minerals; clays and their technological applications

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Guest Editor
Maelgwyn Mineral Services Ltd, Ty Maelgwyn, 1A Gower Street, Cathays, Cardiff CF24 4PA, UK
Interests: particle-bubble interaction; flotation hydrodynamics; pneumatic flotation cells; surface chemistry; micro-nano bubble generation; ultrafine grinding mills; hydrogen reduction
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Special Issue Information

Dear Colleagues,

The fundamental mechanisms governing bubble–particle interactions in froth flotation continue to present great challenges and opportunities for new developments. Bubble–particle interactions lie at the very heart of mineral flotation and continue to fundamentally control recovery, grade, and process efficiency across a wide range of ores and operating conditions.

From the initial thinning of the intervening liquid film to the complexities of collision, attachment, detachment, and the influence of hydrodynamic forces, these micro-scale phenomena dictate the success of mineral recovery operations. Despite more than a century of industrial practice, the fundamental mechanisms controlling the stability of bubble–particle aggregates remain only partially understood, particularly under the complex hydrodynamic, physicochemical, and surface heterogeneity conditions encountered in current flotation systems.

Recent advances in interfacial science, high-speed and micro-scale visualization, atomic force microscopy, molecular dynamics, numerical modeling, and data-driven approaches have created new opportunities to revisit and refine classical flotation theories and develop more predictive, physically grounded descriptions of bubble–particle interactions.

This call invites original research and critical reviews that advance fundamental understanding, experimental methodologies, modeling approaches, and industrial implications of bubble–particle interactions in mineral flotation with the aim of bridging the gap between theory, laboratory studies, and full-scale practice.

Topics of interest include (but are not limited to):

  • Fundamental mechanisms of bubble–particle collision, probability of attachment, detachment, and aggregate stability under turbulent environments.
  • Bubble size distribution, deformation, and dynamics in quiescent and turbulent flotation environments.
  • Hydrophobic, electrostatic, capillary, and non-DLVO interaction forces governing bubble–particle adhesion.
  • Adsorption of flotation reagents (collectors, frothers, modifiers) on minerals and its role in bubble-particle interactions.
  • Effects of water chemistry, dissolved ions, seawater, and process recycling water on bubble–particle interactions.
  • Bubble-particle interactions in fine and ultrafine particle flotation, including slime coatings, aggregation, and entrainment.
  • Role of frother and bubble size on coarse particle flotation, including detachment mechanisms, hydrodynamic constraints, and equipment innovations.
  • Nano- and microbubble generation, stability, and their role in enhancing fine and ultrafine particle recovery.
  • Influence of particle morphology, i.e., size, shape, roughness, and mineralogical complexity, on bubble attachment probability and flotation kinetics.
  • Mechanism of bubble–particle interactions governing froth phase behavior in various flotation cells, columns, etc.
  • Advanced experimental and in situ techniques, e.g., high-speed imaging, AFM, microfluidics, X-ray, and optical and spectroscopic methods in identifying bubble-particle interactions.
  • Numerical and theoretical approaches, including CFD, CFD–DEM, population balance models, and molecular simulations multiphase modeling, machine learning, and digital twins for predicting and optimizing flotation performance.
  • Bubble–particle interactions under high salinity/seawater.

Prof. Dr. Mehmet Sabri Celik
Prof. Dr. Eyüp Sabah
Dr. Ahmad Hassanzadeh
Guest Editors

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-anonymized peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Minerals is an international peer-reviewed open access monthly journal published by MDPI.

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Keywords

  • flotation reagents
  • bubble–particle collision
  • hydrodynamic of flotation
  • flotation machinery
  • nano- and microbubble generation
  • particle morphology
  • flotation kinetics
  • froth phase behavior

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Published Papers (2 papers)

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Research

16 pages, 3741 KB  
Article
Modelling and Simulation of a Coarse Particle Flotation Technology
by Juan Yianatos, Paulina Vallejos, Francisco Flores, Marly Carvalho, Cagri Emer and Ian Sherrell
Minerals 2026, 16(9), 883; https://doi.org/10.3390/min16090883 - 28 Aug 2026
Viewed by 416
Abstract
Coarse particle flotation technologies have emerged to overcome the limitations of conventional flotation circuits, whose performance decreases for coarse fractions. Metso’s Coarse Particle Flotation (CPF) technology takes an approach based on feeding directly into the froth zone, where particle collection and froth transport [...] Read more.
Coarse particle flotation technologies have emerged to overcome the limitations of conventional flotation circuits, whose performance decreases for coarse fractions. Metso’s Coarse Particle Flotation (CPF) technology takes an approach based on feeding directly into the froth zone, where particle collection and froth transport processes occur. Currently, there are no models that link operating variables with the metallurgical performance of this technology. This work presents a model for the Metso’s CPF cell based on the two phenomena that occur simultaneously in the froth zone: particle collection and the transport of particle–bubble aggregates by the froth. The collection process is modelled using a rectangular distribution for flotation kinetics and a residence time distribution based on three perfectly mixed reactors in series: two small reactors and one large. The transport of the froth is represented as a function of froth stability, froth transport distance, and gas residence time. The model was calibrated using laboratory experimental data from copper ore, showing a maximum absolute error in Cu recovery of 2.9%. The main results showed recoveries of approximately 70% for the 300–425 μm class and approximately 50% for the +425 μm class. The size analysis showed a systematic decrease in recovery with particle size, with critical behavior at low froth depths and low superficial gas velocity. A sensitivity analysis confirmed consistent model responses to changes in the main operating variables. Full article
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24 pages, 2933 KB  
Article
Flotation of a Copper Oxide–Sulfide Ore Using NaHS-Assisted Sulfidization and 2,5-Dimercapto-1,3,4-Thiadiazole (DMTD) as a Collector: Experimental and DFT Insights
by Isa Nozari, Asghar Azizi, Hamed Dehghani, Deniz Karataş and Ahmad Hassanzadeh
Minerals 2026, 16(8), 821; https://doi.org/10.3390/min16080821 - 8 Aug 2026
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Abstract
Flotation of mixed copper oxide–sulfide ores remains challenging due to low natural floatability of oxide minerals and complex interplay between sulfidization and collector adsorption. This study investigated the combined effect of NaHS-assisted sulfidization and 2,5-dimercapto-1,3,4-thiadiazole (DMTD), an azole-based collector, in terms of enhancing [...] Read more.
Flotation of mixed copper oxide–sulfide ores remains challenging due to low natural floatability of oxide minerals and complex interplay between sulfidization and collector adsorption. This study investigated the combined effect of NaHS-assisted sulfidization and 2,5-dimercapto-1,3,4-thiadiazole (DMTD), an azole-based collector, in terms of enhancing copper recovery from a mixed oxide–sulfide ore. The effects of pulp pH, DMTD, NaHS, and sodium metasilicate dosages, together with pulp solid concentration, were evaluated using response surface methodology. The quadratic model showed high predictive capability (R2 = 0.9361), identifying NaHS dosage as the most influential factor. Optimum operating conditions (pH 9.50, DMTD 200 g/t, NaHS 750 g/t, sodium metasilicate 500 g/t, and 25% solids) yielded 64.03% copper recovery. Compared with the plant collector (PAX, Potassium Amyl Xanthate), DMTD increased recovery by 12.6% for highly oxidized ore while producing a higher concentrate grade. Density Functional Theory (DFT) calculations provided molecular insights into the experimental observations, confirming DMTD’s high affinity for sulfidized surfaces. Hybrid solvation models revealed greater thermodynamic stability (ΔEads = −6.74 eV) than PAX due to hydrogen bonding with explicit water molecules, while the smaller HOMO–LUMO gap (ΔEgap = 0.86 eV) supported its superior electron transfer capability and reactivity. These findings demonstrate that NaHS-assisted sulfidization with DMTD is an effective strategy for improving flotation of copper oxide–sulfide ores. Full article
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