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Mass Spectrometry in Materials Science

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Materials Characterization".

Deadline for manuscript submissions: closed (10 January 2024) | Viewed by 23932

Special Issue Editor

Dr. Rafał Frański

E-Mail Website
Guest Editor
Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland
Interests: mass spectrometry; natural compounds; antioxidants; food contaminants, analytical chemistry; supramolecular chemistry
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear colleagues,

Mass spectrometry (MS) has become an important tool for scientists working on the development of modern materials. The main mass spectrometry techniques which have advanced our knowledge in the field of material science are secondary ion mass spectrometry (SIMS), inductively coupled plasma mass spectrometry (ICP-MS), and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The mass spectrometry techniques that are usually dedicated to the analysis of organic compounds, namely, electrospray ionization mass spectrometry (ESI-MS) and matrix-assisted laser desorption ionization (MALDI), have also found application in the analysis of materials, mainly in the analysis of polymers. This Special Issue of Materials, “Mass Spectrometry in Materials Science”, will focus on the application of mass spectrometry to the ultra-trace analysis, micro and nanodistribution analysis, surface analysis, as well as three-dimensional analysis of different kinds of advanced materials, e.g., semiconductors, superconductors, glass, metals and their oxides, biomaterials, ceramic materials, stainless steels, and others. Authors are invited to submit manuscripts that use mass spectrometry as an important tool in high-resolution material analysis and characterization.

Dr. Rafał Frański
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • high-purity materials
  • polymers
  • mass spectrometry
  • trace analysis
  • surface analysis

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Published Papers (6 papers)

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Research

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15 pages, 6239 KiB  
Article
Mammalian Oocyte Analysis by MALDI MSI with Wet-Interface Matrix Deposition Technique
by Anna Bodzon-Kulakowska, Wiesława Młodawska, Przemyslaw Mielczarek, Dorota Lachowicz, Piotr Suder and Marek Smoluch
Materials 2023, 16(4), 1479; https://doi.org/10.3390/ma16041479 - 9 Feb 2023
Cited by 3 | Viewed by 2188
Abstract
Oocytes are a special kind of biological material. Here, the individual variability of a single cell is important. It means that the opportunity to obtain information about the lipid content from the analysis of a single cell is significant. In our study, we [...] Read more.
Oocytes are a special kind of biological material. Here, the individual variability of a single cell is important. It means that the opportunity to obtain information about the lipid content from the analysis of a single cell is significant. In our study, we present a method for lipid analysis based on the MALDI-based mass spectrometry imaging (MSI) approach. Our attention was paid to the sample preparation optimization with the aid of a wet-interface matrix deposition system (matrix spraying). Technical considerations of the sample preparation process, such as the number of matrix layers and the position of the spraying nozzle during the matrix deposition, are presented in the article. Additionally, we checked if changing the 2,5-dihydroxybenzoic acid (DHB) and 9-Aminoacridine (9AA) matrix concentration and their solvent composition may improve the analysis. Moreover, the comparison of paraformaldehyde-fixed versus nonfixed cell analysis was performed. We hope that our approach will be helpful for those working on lipid analyses in extraordinary material such as a single oocyte. Our study may also offer clues for anybody interested in single-cell analysis with the aid of MALDI mass spectrometry imaging and the wet-interface matrix deposition method. Full article
(This article belongs to the Special Issue Mass Spectrometry in Materials Science)
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16 pages, 3110 KiB  
Article
Polyethylene Glycol-Isophorone Diisocyanate Polyurethane Prepolymers Tailored Using MALDI MS
by Diana-Andreea Blaj, Alexandra-Diana Diaconu, Valeria Harabagiu and Cristian Peptu
Materials 2023, 16(2), 821; https://doi.org/10.3390/ma16020821 - 14 Jan 2023
Cited by 6 | Viewed by 4966
Abstract
The reaction of diols with isocyanates, leading to mono-functional and di-functional prepolymers may be investigated using various characterization methods which show the overall conversion of isocyanate monomers. On the other hand, matrix-assisted laser desorption ionization mass spectrometry (MALDI MS) polymer characterization can be [...] Read more.
The reaction of diols with isocyanates, leading to mono-functional and di-functional prepolymers may be investigated using various characterization methods which show the overall conversion of isocyanate monomers. On the other hand, matrix-assisted laser desorption ionization mass spectrometry (MALDI MS) polymer characterization can be employed to identify the monomer units, the end-group functionalities, molecular weight averages, and to determine the copolymer sequence. Herein, we focus on prepolymer synthesis using isophorone diisocyanate (IPDI), a widely used diisocyanate for prepolymers preparation, especially in waterborne polyurethane materials. Thus, the reaction between polyethylene glycol diol and IPDI was in-depth investigated by mass spectrometry to determine the influence of the reaction parameters on the prepolymer’s structure. The relative content of the different functional oligomer species at given reaction times was determined in the reaction mixture. More specifically, the offline analysis revealed the influence of reaction parameters such as reaction temperature, the concentration of reactants, and the amount of dibutyltin dilaurate catalyst. The established MALDI MS analysis involved measurements of samples, first, directly collected from the reaction mixture and secondly, following derivatization with methanol. The obtained results revealed the effects of reaction parameters on the functionalization reaction with isocyanates, allowing to achieve a better reaction control. Full article
(This article belongs to the Special Issue Mass Spectrometry in Materials Science)
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10 pages, 1823 KiB  
Article
Investigation of the Ligand Exchange Process on Gold Nanorods by Using Laser Desorption/Ionization Time-of-Flight Mass Spectrometry
by Seung-Woo Kim, Young Won Kim, Tae Hoon Seo and Young-Kwan Kim
Materials 2022, 15(13), 4406; https://doi.org/10.3390/ma15134406 - 22 Jun 2022
Viewed by 2801
Abstract
The ligand exchange process on gold nanorods (Au NRs) was explored by using laser desorption/ionization time-of-flight mass spectrometry (LDI-TOF-MS). Cetyltrimethylammonium bromide (CTAB) adsorbed on Au NRs was replaced with alkanethiol derivatives presenting different functional groups. The ligand exchange process was investigated under various [...] Read more.
The ligand exchange process on gold nanorods (Au NRs) was explored by using laser desorption/ionization time-of-flight mass spectrometry (LDI-TOF-MS). Cetyltrimethylammonium bromide (CTAB) adsorbed on Au NRs was replaced with alkanethiol derivatives presenting different functional groups. The ligand exchange process was investigated under various conditions, such as in the presence of different functional groups in the ligands and with different concentrations of CTAB. The ligand-exchanged Au NRs were characterized by using a combination of UV–Vis spectroscopy and LDI-TOF-MS. Based on the results, it was revealed that LDI-TOF-MS analysis can provide crucial and distinct information about the degree of ligand exchange on Au NRs. Full article
(This article belongs to the Special Issue Mass Spectrometry in Materials Science)
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7 pages, 815 KiB  
Communication
Ethoxylated Butoxyethanol-BADGE Adducts—New Potential Migrants from Epoxy Resin Can Coating Material
by Monika Beszterda, Małgorzata Kasperkowiak, Magdalena Frańska, Sandra Jęziołowska and Rafał Frański
Materials 2021, 14(13), 3682; https://doi.org/10.3390/ma14133682 - 1 Jul 2021
Cited by 8 | Viewed by 3923
Abstract
The acetonitrile extracts of can-coating materials have been analyzed by using high-pressure liquid chromatography/electrospray ionization-mass spectrometry (HPLC/ESI-MS). On the basis of detected ions [M + H]+, [M + NH4]+, [M + Na]+ and product ions, the [...] Read more.
The acetonitrile extracts of can-coating materials have been analyzed by using high-pressure liquid chromatography/electrospray ionization-mass spectrometry (HPLC/ESI-MS). On the basis of detected ions [M + H]+, [M + NH4]+, [M + Na]+ and product ions, the ethoxylated butoxyethanol-bisphenol A diglycidyl ether adducts were identified in two of the analyzed extracts. Although the oxyethylene unit-containing compounds are widely used for the production of different kinds of materials, the ethoxylated species have not been earlier detected in epoxy resin can-coatings. Full article
(This article belongs to the Special Issue Mass Spectrometry in Materials Science)
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19 pages, 22977 KiB  
Article
Multi-Technique Investigation of Grave Robes from 17th and 18th Century Crypts Using Combined Spectroscopic, Spectrometric Techniques, and New-Generation Sequencing
by Magdalena Śliwka-Kaszyńska, Marek Ślebioda, Anna Brillowska-Dąbrowska, Martyna Mroczyńska, Jakub Karczewski, Anna Marzec, Przemysław Rybiński and Anna Drążkowska
Materials 2021, 14(13), 3535; https://doi.org/10.3390/ma14133535 - 24 Jun 2021
Cited by 7 | Viewed by 2429
Abstract
The textile fragments of the funeral clothes found in the 17th and 18th century crypts were subjected to spectroscopic, spectrometric, and microbial investigation. The next-generation sequencing enabled DNA identification of microorganisms at the genus and in five cases to the species level. The [...] Read more.
The textile fragments of the funeral clothes found in the 17th and 18th century crypts were subjected to spectroscopic, spectrometric, and microbial investigation. The next-generation sequencing enabled DNA identification of microorganisms at the genus and in five cases to the species level. The soft hydrofluoric acid extraction method was optimized to isolate different classes of dyes from samples that had direct contact with human remains. High-performance liquid chromatography coupled with diode matrix and tandem mass spectrometry detectors with electrospray ionization (HPLC-DAD-ESI-MS/MS) enabled the detection and identification of 34 colourants that are present in historical textiles. Some of them are thus far unknown and uncommon dyes. Indigo, madder, cochineal, turmeric, tannin-producing plant, and young fustic were identified as sources of dyes in textiles. Scanning electron microscopy with energy-dispersive X-ray detector (SEM-EDS) and Fourier transform infrared spectroscopy (FT-IR) were used to identify and characterize fibres and mordants in funeral gowns. Of the 23 textile samples tested, 19 were silk while the remaining four were recognized as wool. The presence of iron, aluminium, sodium, and calcium suggests that they were used as mordants. Traces of copper, silica, and magnesium might originate from the contaminants. The large amount of silver indicated the presence of metal wire in one of the dyed silk textiles. SEM images showed that textile fibres were highly degraded. Full article
(This article belongs to the Special Issue Mass Spectrometry in Materials Science)
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Review

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37 pages, 6911 KiB  
Review
Secondary Ion Mass Spectral Imaging of Metals and Alloys
by Yanjie Shen, Logan Howard and Xiao-Ying Yu
Materials 2024, 17(2), 528; https://doi.org/10.3390/ma17020528 - 22 Jan 2024
Cited by 7 | Viewed by 3983
Abstract
Secondary Ion Mass Spectrometry (SIMS) is an outstanding technique for Mass Spectral Imaging (MSI) due to its notable advantages, including high sensitivity, selectivity, and high dynamic range. As a result, SIMS has been employed across many domains of science. In this review, we [...] Read more.
Secondary Ion Mass Spectrometry (SIMS) is an outstanding technique for Mass Spectral Imaging (MSI) due to its notable advantages, including high sensitivity, selectivity, and high dynamic range. As a result, SIMS has been employed across many domains of science. In this review, we provide an in-depth overview of the fundamental principles underlying SIMS, followed by an account of the recent development of SIMS instruments. The review encompasses various applications of specific SIMS instruments, notably static SIMS with time-of-flight SIMS (ToF-SIMS) as a widely used platform and dynamic SIMS with Nano SIMS and large geometry SIMS as successful instruments. We particularly focus on SIMS utility in microanalysis and imaging of metals and alloys as materials of interest. Additionally, we discuss the challenges in big SIMS data analysis and give examples of machine leaning (ML) and Artificial Intelligence (AI) for effective MSI data analysis. Finally, we recommend the outlook of SIMS development. It is anticipated that in situ and operando SIMS has the potential to significantly enhance the investigation of metals and alloys by enabling real-time examinations of material surfaces and interfaces during dynamic transformations. Full article
(This article belongs to the Special Issue Mass Spectrometry in Materials Science)
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