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Applications, Optimization, and Comprehensive Characterization of Hydrogen Storage Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Materials Characterization".

Deadline for manuscript submissions: closed (10 March 2022) | Viewed by 4911

Special Issue Editor


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Guest Editor
Department of Systems for Materials Technology, Helmholtz-Zentrum Geesthacht, Geesthacht, Germany
Interests: hydrogen storage; hydrides; hydrogen technology; system integration; system simulation; FEM simulation

Special Issue Information

Dear Colleagues,

Hydrogen storage materials have long been a matter of interest toward the application of hydrogen as an energy vector. In particular, the compact size of hydrogen stores based on hydrides and the low pressures involved in this type of storage are an attractive selling point, especially regarding safety and in regions subject to stringent regulations regarding pressure vessels, such as Japan.

The field of hydrogen storage materials is a very diverse one, and therefore, many different types of materials can be considered for application in a variety of cases—solid (as in hydrides), liquid (such as LOHCs), and gaseous (for instance, NH3).

I am writing to invite you to participate in a Special Issue of the journal Materials on “Applications, Optimization, and Comprehensive Characterization of Hydrogen Storage Materials”. This title has been selected to include both application- and characterization-oriented studies, since they complement each other. Full papers, communications, and reviews are all welcome.

Dr. José M. Bellosta von Colbe
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

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Keywords

  • hydrogen
  • hydrogen storage
  • hydrogen compression
  • hydride
  • hydrogen applications
  • heat storage
  • tank simulation
  • systems integration
  • system simulation
  • materials characterization
  • X-ray diffraction (XRD)
  • novel characterization techniques

Published Papers (2 papers)

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Research

16 pages, 11988 KiB  
Article
Hydrogen Sorption Behavior of Cast Ag-Mg Alloys
by Adam Dębski, Sylwia Terlicka, Anna Sypien, Władysław Gąsior, Magda Pęska and Marek Polański
Materials 2022, 15(1), 270; https://doi.org/10.3390/ma15010270 - 30 Dec 2021
Cited by 5 | Viewed by 1542
Abstract
In this paper, the hydrogen sorption properties of casted Ag-Mg alloys were investigated. The obtained alloys were structurally analyzed by X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The study was carried out for four alloys from the two-phase region (Mg) [...] Read more.
In this paper, the hydrogen sorption properties of casted Ag-Mg alloys were investigated. The obtained alloys were structurally analyzed by X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The study was carried out for four alloys from the two-phase region (Mg) + γ′ (AgMg4) with nominal concentrations of 5 wt. %, 10 wt. %, 15 wt. %, and 20 wt. % Ag, four alloys with nominal compositions equivalent to intermetallic phases: AgMg4, AgMg3, AgMg, and Ag3Mg, one alloy from the two-phase region AgMg + Ag3Mg (Ag60Mg40), and one alloy from the two-phase region AgMg + AgMg3 (Ag40Mg60). The hydrogenation process was performed using a Sievert-type sorption analyzer. The hydride decomposition temperature and kinetic properties of the synthesized hydrides were investigated by differential scanning calorimetry (DSC) coupled with thermogravimetric analysis (TGA). Samples with high magnesium content were found to readily absorb significant amounts of hydrogen, while hydrogen absorption was not observed for samples with silver concentrations higher than 50 at. % (AgMg intermetallic phase). Full article
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13 pages, 5176 KiB  
Article
Design of V-Substituted TiFe-Based Alloy for Target Pressure Range and Easy Activation
by Mohammad Faisal, June-Hyung Kim, Young Whan Cho, Jae-il Jang, Jin-Yoo Suh, Jae-Hyeok Shim and Young-Su Lee
Materials 2021, 14(17), 4829; https://doi.org/10.3390/ma14174829 - 25 Aug 2021
Cited by 6 | Viewed by 2699
Abstract
Titanium iron (TiFe) alloy is a room-temperature hydrogen-storage material, and it absorbs hydrogen via a two-step process to form TiFeH and then TiFeH2. The effect of V addition in TiFe alloy was recently elucidated. The V substitution for Ti sublattice lowers [...] Read more.
Titanium iron (TiFe) alloy is a room-temperature hydrogen-storage material, and it absorbs hydrogen via a two-step process to form TiFeH and then TiFeH2. The effect of V addition in TiFe alloy was recently elucidated. The V substitution for Ti sublattice lowers P2/P1 ratio, where P1 and P2 are the equilibrium plateau pressure for TiFe/TiFeH and TiFeH/TiFeH2, respectively, and thus restricts the two-step hydrogenation within a narrow pressure range. The focus of the present investigation was to optimize the V content such that maximum usable storage capacity can be achieved for the target pressure range: 1 MPa for absorption and 0.1 MPa for desorption. The effect of V substitution at selective Ti or Fe sublattices was closely analyzed, and the alloy composition Ti46Fe47.5V6.5 displayed the best performance with ca. 1.5 wt.% of usable capacity within the target pressure range. At the same time, another issue in TiFe-based alloys, which is a difficulty in activation at room temperature, was solved by Ce addition. It was shown that 3 wt.% Ce dispersion in TiFe alloy imparted to it easy room-temperature (RT) activation properties. Full article
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