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Carbon- and Graphene-Based Composites for Energy Storage

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Carbon Materials".

Deadline for manuscript submissions: closed (30 September 2020) | Viewed by 3597

Special Issue Editors

Instituto de Ciencia y Tecnología del Carbono (INCAR), CSIC, Francisco Pintado Fe 26, 33011 Oviedo, Spain
Interests: porous carbons; porous carbons; electrochemical energy storage; supercapacitors; Li-S batteries; hybrid capacitors
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Guest Editor
CIC Energigune, Vitoria, Spain
Interests: carbons with tailored porosity; carbon-metal oxide composites; graphene; electrochemical capacitors; rechargeable batteries

Special Issue Information

Adam Moyseowicz, Krzysztof Pająk, Grażyna Gryglewicz

Department of Polymer and Carbonaceous Materials, Faculty of Chemistry, Wrocław University of Science and Technology, Gdańska 7/9, 50-344 Wrocław, Poland

A facile and environmentally friendly approach for the synthesis of polypyrrole/reduced graphene oxide hybrids via hydrothermal treatment is proposed. A series of hybrid materials with different components mass ratio of conductive polymer to graphene oxide was prepared. Morphology, chemical composition and porous structure of the synthesized materials were determined. The synthesized hybrids were investigated as electrode materials for supercapacitors. Their electrochemical performance was studied in a three-electrode system operating in 1M H2SO4. Nitrogen sorption analysis at 77K revealed significant changes in the textural development of the hybrid materials, presenting specific surface areas from 24 to 199 m2/g. Moreover, the combination of the pseudocapacitive polypyrrole and robust carbon nanomaterial (rGO) resulted in the hybrids with excellent electrochemical properties, which achieve specific capacitances as high as 198 F/g at a current density of 20 A/g and maintain up to 92 % of the initial capacitance after 3000 charge-discharge cycles.

Keywords

  • new carbon composites
  • graphene composites
  • electrochemical energy storage
  • rechargeable battery
  • supercapacitor
  • redox flow battery
  • flexible energy storage systems
  • metal air battery
  • aqueous battery

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13 pages, 4011 KiB  
Article
Synthesis of Polypyrrole/Reduced Graphene Oxide Hybrids via Hydrothermal Treatment for Energy Storage Applications
by Adam Moyseowicz, Krzysztof Pająk, Katarzyna Gajewska and Grażyna Gryglewicz
Materials 2020, 13(10), 2273; https://doi.org/10.3390/ma13102273 - 15 May 2020
Cited by 25 | Viewed by 3187
Abstract
Herein, we propose hydrothermal treatment as a facile and environmentally friendly approach for the synthesis of polypyrrole/reduced graphene oxide hybrids. A series of self-assembled hybrid materials with different component mass ratios of conductive polymer to graphene oxide was prepared. The morphology, porous structure, [...] Read more.
Herein, we propose hydrothermal treatment as a facile and environmentally friendly approach for the synthesis of polypyrrole/reduced graphene oxide hybrids. A series of self-assembled hybrid materials with different component mass ratios of conductive polymer to graphene oxide was prepared. The morphology, porous structure, chemical composition and electrochemical performance of the synthesized hybrids as electrode materials for supercapacitors were investigated. Nitrogen sorption analysis at 77 K revealed significant changes in the textural development of the synthesized materials, presenting specific surface areas ranging from 25 to 199 m2 g−1. The combination of the pseudocapacitive polypyrrole and robust graphene material resulted in hybrids with excellent electrochemical properties, which achieved specific capacitances as high as 198 F g−1 at a current density of 20 A g−1 and retained up to 92% of their initial capacitance after 3000 charge–discharge cycles. We found that a suitable morphology and chemical composition are key factors that determine the electrochemical properties of polypyrrole/reduced graphene oxide hybrid materials. Full article
(This article belongs to the Special Issue Carbon- and Graphene-Based Composites for Energy Storage)
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