Heavy Metals, Metalloids & Organic Pollutants in Soil: Effects, Sources, and Remediation Techniques. The Use of Machine Learning Approaches for the Assessment of Soil Pollution

A special issue of Land (ISSN 2073-445X). This special issue belongs to the section "Soil-Sediment-Water Systems".

Deadline for manuscript submissions: closed (23 February 2024) | Viewed by 4744

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Laboratory of Soil Science, School of Agriculture, Aristotle University of Thessaloniki, 541 24 Thessaloniki, Greece
Interests: soil science; soil chemistry; environmental analysis; environmental monitoring; GIS; heavy metal(oid)s; trace elements; contamination monitoring; urban and agricultural soil pollution; physicochemical behavior of metals in environment

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School of Electrical & ComSchool of Electrical and Computer Engineering, Technical University of Crete, 731 00 Chania, Greece
Interests: speech recognition; speech synthesis; language modelling; signal processing including speech processing; machine learning; pattern recognition and stochastic modeling; natural language processing
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Guest Editor
School of Agricultural Sciences, University of Thessaly, Fytokou Street, 38446 Nea Ionia Magnisias, Greece
Interests: environmental analytical chemistry; pollution chemistry; chromatographic techniques; development; validation of analytical methods for determination of organic micropollutants; transportation of pesticides in environmental compartments; degradation, adsorption–desorption studies; agricultural soil pollution natural language processing
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Special Issue Information

Dear Colleagues,

We are pleased to announce the Special Issue of Land on “Heavy Metals, Metalloids & Organic Pollutants in Soil: Effects, Sources, and Remediation Techniques. The Use of Machine Learning Approaches for the Assessment of Soil Pollution”.

Heavy Metals (ΗΜs) are defined as a group of metallic elements having atomic densities higher than 5 g/cm3. Recently, the term heavy metals have often been replaced by the term Potentially Toxic Elements (PTEs) since some of the elements of this category can be toxic to plants, animals and humans in high concentrations. On the other hand, these elements, in small quantities, are of paramount importance for the proper functioning and development of the flora and fauna, known as nutrients or trace elements. The group of potentially toxic elements (PTEs) also includes elements that are not metals but have many properties of metals. These elements are called metalloids. Arsenic is a representative example of a PTE. Heavy metals contaminate the environment and its living organisms in different ways. Growth reduction, protein content and adverse effects on a plant’s physiology start when the metal(oid) concentration increases. The main sources of metal enrichment in soils are lithogenic and anthropogenic. There are many different anthropogenic sources of heavy metal(oid) contamination, affecting both agricultural and urban soils, such as mining and industrial waste, the use of fertilizers, pesticides and sewage sludge in agriculture soils, transportation, forest fires, volcanic eruptions, fossil fuel combustion, urban waste, and chemical industries.

The occurrence and fate of organic compounds in soils have been the subject of numerous studies in recent decades, mostly due to the urgent need to answer the challenge of better managing soil quality and prevent soil and water pollution. This Special Issue welcomes articles that describe soil pollution caused by organic compounds, their determination and monitoring, their interaction with soil and water, their mitigation along their impact on the agricultural production, the environment, ecosystems and humans as well.

Several remediation techniques, such as extraction, stabilization, solidification, vitrification, phytoremediation, and bioremediation, have been developed to restore the heavy metal-and organics contaminated soils. These recovery techniques use containment, extraction, removal and immobilization mechanisms to reduce the effects of contamination. Phytoremediation techniques depend on the ability of certain plants to tolerate high concentrations of metal(oid)s in their environment. Exclusion, inclusion, and bioaccumulation are the three functions responsible for this ability. A successful remediation often requires early and accurate assessment of the soil pollution.

Towards this goal, a recent trend has been to use machine learning techniques such as regression, clustering and classification to obtain a better characterization and quantification of the soil contamination. This trend is enhanced from the increasing availability of soil contamination data.

This Special Issue aims at publishing original research on the following general topics:

  • monitoring soil contamination by heavy metals and/or organic pollutants;
  • contamination and health risk indexes;
  • mapping and risk assessment;
  • prevention and mitigation approaches;
  • use of machine learning techniques including deep learning, regression, classification and clustering for the characterization and quantification of soil contamination.

Dr. Evangelia Golia
Dr. Vassilios Diakoloukas
Prof. Dr. Nikolaos Tsiropoulos
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Land is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • heavy metals (ΗΜs)
  • potentially toxic elements (PTEs)
  • contaminated soils
  • recovery techniques
  • machine learning
  • deep learning
  • soil spectroscopy
  • computer vision
  • pollution mitigation, phytoremediation
  • bioremediation
  • fate and behavior of organic pollutants

Related Special Issue

Published Papers (2 papers)

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Research

15 pages, 2793 KiB  
Article
Distribution, Risk Assessment and Source Identification of Potentially Toxic Elements in Coal Mining Contaminated Soils of Makarwal, Pakistan: Environmental and Human Health Outcomes
by Liaqat Ali, Shehzad Ali, Seema Anjum Khattak, Hammad Tariq Janjuhah, George Kontakiotis, Rahib Hussain, Shah Rukh, Mohammad Tahir Shah, George D. Bathrellos and Hariklia D. Skilodimou
Land 2023, 12(4), 821; https://doi.org/10.3390/land12040821 - 3 Apr 2023
Cited by 2 | Viewed by 1801
Abstract
The present research was carried out to examine the health and environmental impacts associated with coal mining activities in the Makarwal coal mining area in Pakistan. To achieve the objectives, 41 soil samples were collected from the coalmine-affected areas and analyzed for major [...] Read more.
The present research was carried out to examine the health and environmental impacts associated with coal mining activities in the Makarwal coal mining area in Pakistan. To achieve the objectives, 41 soil samples were collected from the coalmine-affected areas and analyzed for major and toxic trace elements (TTEs) using atomic absorption spectroscopy. Most of the soil samples have extremely high concentrations of toxic metals such as Ni, Cd, Cr, Cu, Zn, and Pb. The positive correlations and high concentration of trace elements in the Makarwal coalmine-affected region suggest an analogous origin of soil contamination. The factor analysis (FA) showed two components, i.e., F1 (53.4%) and F (74.21%), of total variability for soil. The F2 was loaded with Pb, Zn, Ni, and Cr, which was similar to cluster 2, while the F1 was loaded with Cu and Cr, having a similar pattern to cluster 1. This proves that the contamination in the surrounding area is mostly associated with geological ore strata existing in the Makarwal coalfield. Based on geoaccumulation (Igeo), the elemental concentration in the studied soil sample could be categorized as follows: (1) Pb, Ni, and Zn are moderate to severely polluted and (2) Cr and Cu are in the moderately polluted category. The ecological risk indices (ERIs) of the single trace element contamination index highlighted that Cd, Pb, Ni, and Cr pose a high risk to humans and the ecosystem. Based on different statistical tools performed for the source identification and distribution of metal contamination, it seems that the exposed sedimentary rocks, including limestone, dolomite, sandstone, and coal, are responsible for the toxic metal contamination in the study area. Full article
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20 pages, 1281 KiB  
Article
The Use of biochar in the Remediation of Pb, Cd, and Cu-Contaminated Soils. The Impact of biochar Feedstock and Preparation Conditions on Its Remediation Capacity
by Theodora Bousdra, Sotiria G. Papadimou and Evangelia E. Golia
Land 2023, 12(2), 383; https://doi.org/10.3390/land12020383 - 31 Jan 2023
Cited by 9 | Viewed by 2330
Abstract
Soil constitutes an important part of terrestrial ecosystems, prone to be adversely impacted by human activities. During the last decades, several methods have been developed aiming at its remediation, including the use of biochar as a soil amendment. In the present work, we [...] Read more.
Soil constitutes an important part of terrestrial ecosystems, prone to be adversely impacted by human activities. During the last decades, several methods have been developed aiming at its remediation, including the use of biochar as a soil amendment. In the present work, we have assessed the reduction of Pb, Cd, and Cu soil concentrations as a function of the mixing ratio of biochar added to soil, as well as the source of biochar employed. Furthermore, we have investigated the effects of biochar addition relating to the chemical forms of heavy metals (HMs) related to their bioavailability and mobility. The concentrations of HMs were determined by the BCR (European Community Bureau of Reference) sequential extraction procedure before and after biochar addition to the soils. Five types of biochar were used, obtained as by-products of sugarcane bagasse (Β), bamboo (ΒΒ), rice straw (RSB), garden waste (GB), and paulownia (PB) treatment, respectively. Biochar derived from sugarcane (B) reduced the availability of metals, as it decreased their concentration in the acid extractable fraction, by 40.5, 66.6, and 50% for Pb, Cd, and Cu, respectively. In addition, (B) application increased the residual fraction of Cu and Pb by 9% and 24.8%, respectively. Biochar derived from garden residues (GB) and paulownia plant (PB) dramatically increased the residual fraction of Cd over 97%, minimizing its availability. Sugarcane-derived biochar appeared to significantly increase Cu and Pb residual fraction concentrations and decrease available Cd concentration. Similar changes are caused by the types of biochar in the following order: biochar from sugarcane > paulownia > garden wastes > bamboo > rice straw. The redistribution of HM concentrations causes a significant improvement of environmental quality in polluted soils, as it limits the mobility and availability of toxic metals to the soil ecosystem. The use of biochar is a low-cost and eco-friendly method for the remediation of contaminated with HMs soils in the framework of a circular economy. Full article
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