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Photochemistry in Molecular Clusters

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Physical Chemistry and Chemical Physics".

Deadline for manuscript submissions: 30 August 2024 | Viewed by 959

Special Issue Editor


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Guest Editor
National Institute for Research and Development of Isotopic and Molecular Technologies, Donat Street, No. 67-103, 400283 Cluj-Napoca, Romania
Interests: intermolecular interactions; self-assembled supramolecular systems; laser-molecule interaction; molecular excited states; biopolymers
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Special Issue Information

Dear Colleagues,

The photochemistry of single-molecule systems is already a well-established field of research, where both experimental methods based on laser spectroscopy and theoretical methods derived from advanced quantum chemical models provide exhaustive descriptions of photochemical phenomena. At the same time, much less is known about the photochemistry of systems where multiple molecules in cluster or aggregate forms are collectively involved in the light-induced electronic excitation and relaxation processes. Phenomena such as thermally activated delayed fluorescence, formation of excimer or exciplex structures, light-induced charge transfer in donor–acceptor complexes, fluorescence resonance energy transfer, and triplet–triplet annihilation upconversion still require specially designed experimental setups and a carefully established theoretical methodology, and involve entities with multi-molecular characters.

This Special Issue is intended to provide a common platform for experimental and modelling science in order to obtain a more comprehensive picture of these photochemical processes. Both original research articles and reviews in the fields of photochemistry, laser spectroscopy, light-induced molecular processes, molecular self-assembly, and photochemistry of molecular ensembles adsorbed on a surface or interface are highly welcome.

Dr. Attila Bende
Guest Editor

Manuscript Submission Information

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Keywords

  • photochemistry
  • fluorescence
  • phosphorescence
  • laser spectroscopy
  • electronic excited states
  • excited state relaxation
  • time-dependent density functional theory
  • molecular switches

Published Papers (1 paper)

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Research

15 pages, 9875 KiB  
Article
The Brown Sugar Mediated Carbon Quantum Dots as a Novel Fluorescence Sensor for Sensitive Detection of Gentamicin and Its Application in Foods
by Xinran Guo, Yanxin Guo and Xinyue Chen
Int. J. Mol. Sci. 2024, 25(4), 2143; https://doi.org/10.3390/ijms25042143 - 10 Feb 2024
Viewed by 658
Abstract
In this work, a novel fluorescence sensing strategy was proposed for the detection of gentamicin based on fluorescent carbon quantum dots (CQDs) and gold nanoparticles (AuNPs). Herein, the CQDs were green-synthesized for the first time via a one-step hydrothermal method utilizing brown sugar [...] Read more.
In this work, a novel fluorescence sensing strategy was proposed for the detection of gentamicin based on fluorescent carbon quantum dots (CQDs) and gold nanoparticles (AuNPs). Herein, the CQDs were green-synthesized for the first time via a one-step hydrothermal method utilizing brown sugar as the precursor. In the presence of citrate-stabilized AuNPs, the fluorescence of CQDs was quenched efficiently. Gentamicin, on the other hand, had a higher affinity for AuNPs and was able to compete with CQDs for a preferential binding to AuNPs, which ultimately led to the aggregation of AuNPs and freeing of CQDs in solution, causing the fluorescence recovery of CQDs. Based on the above phenomenon, the concentrations of gentamicin could be ascertained by detecting the variations in fluorescence intensity of CQDs. This sensing strategy exhibited excellent selectivity in various antibiotics. At the same time, the method displayed outstanding sensitivity for gentamicin, which was successfully applied to real samples detection. Full article
(This article belongs to the Special Issue Photochemistry in Molecular Clusters)
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