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Industrial Waste Water Treatment and Reuse

A special issue of International Journal of Environmental Research and Public Health (ISSN 1660-4601). This special issue belongs to the section "Water Science and Technology".

Deadline for manuscript submissions: closed (30 November 2022) | Viewed by 9624

Special Issue Editors


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Guest Editor
Environmental Energy Engineering (E3) workgroup, School of Environment Science and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, China
Interests: industrial wastewater treatment; environmental electrochemistry; environment functional materials; electrochemical hydrometallurgy; environmental energy engineering

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Guest Editor
School of Environment Science and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, China
Interests: chemical effect of particulate pollutants; wastewater treatment

Special Issue Information

Dear Colleagues,

Large quantities of  industrial wastewater are discharged from various chemical plants, e.g., pharmaceutical, insecticide, mining, and metallurgical factories, etc. There are kinds of pollutants in these wastewaters that can cause serious global or regional environmental disasters if they cannot be controlled properly. Generally, such discharges contain highly concentrated organic compounds and salts, and sometimes heavy metal ions or organometallics are involved. In this sense, to deal with them via energy and cost efficient technologies is very important. Therefore, researches on biological processes with functional bacteria, advanced oxidation processes (not limited to elecro, ultrasonic-, reagent-, photo- and thermal-oxidation), and other processes for pre-/post- treatment of industrial wastewaters should be conducted to help solving these environmental issues. On the other hand, we would also like to focus on the water shortage in some regions of the world. Prior to the reuse of industrial wastewaters, salt contents, heavy metal ions, and organometallics must be reduced to low levels in order to meet the standards for agricultural irrigation, municipal greening, and other industries. In the past decade or so, research approaches linking wastewater treatment and resource recovery have emerged; for example, capacitive deionization and hydrogen production from water electrolysis. All these techniques are associated with cation and anion removal, which are beneficial to the high value-added reuse of industrial wastewaters. Papers addressing these topics are invited for this Special Issue, especially those with high academic standards coupled with outstanding treatment effects and resource recycling.

Prof. Dr. Lizhang Wang
Dr. Ping Luo
Guest Editors

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Keywords

  • industrial wastewater treatment
  • industrial wastewater reuse
  • effective pollutants removal
  • cost-effective wastewater desalting
  • resource/energy utilization of pollutants

Published Papers (6 papers)

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Research

13 pages, 3267 KiB  
Article
Degradation of Dye Wastewater by a Novel mBT-MPR Visible Light Photocatalytic System
by Miaomiao Cheng, Chunxia Zhao, Zefeng Wu, Ling Liu and Hongjie Wang
Int. J. Environ. Res. Public Health 2023, 20(1), 571; https://doi.org/10.3390/ijerph20010571 - 29 Dec 2022
Cited by 2 | Viewed by 1244
Abstract
The high efficiency and low consumption green wastewater treatment technology has important practical significance for the recycling of printing and dyeing wastewater. The efficiency of visible light catalytic degradation of organics is greatly affected by the performance of the catalyst and the photo [...] Read more.
The high efficiency and low consumption green wastewater treatment technology has important practical significance for the recycling of printing and dyeing wastewater. The efficiency of visible light catalytic degradation of organics is greatly affected by the performance of the catalyst and the photo reactor. Therefore, Bi2WO6/TiO2/Fe3O4 (mBT) visible light photocatalyst was accurately prepared by the ammonia iron double drop method. In order to improve the photodegradation efficiency, a tubular magnetic field-controlled photocatalytic reactor (MPR) was developed. The novel mBT-MPR visible light photocatalytic system was proposed to treat RhB simulated wastewater. The experimental results showed that when the dosage of mBT catalyst was 1 g/L and visible light was irradiated for 60 min, the average removal rate of rhodamine B (RhB) with initial an concentration of 10 mg/L in the simulated wastewater for four times was 91.7%. The mBT-MPR visible light photocatalysis system is a green and efficient treatment technology for organic pollutants in water with simple operation, low energy consumption, and no need for catalyst separation. Full article
(This article belongs to the Special Issue Industrial Waste Water Treatment and Reuse)
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15 pages, 3790 KiB  
Article
Carbothermal Synthesis of Sludge Biochar Supported Nanoscale Zero-Valent Iron for the Removal of Cd2+ and Cu2+: Preparation, Performance, and Safety Risks
by Yingying Shao, Chao Tian, Yanfeng Yang, Yanqiu Shao, Tao Zhang, Xinhua Shi, Weiyi Zhang and Ying Zhu
Int. J. Environ. Res. Public Health 2022, 19(23), 16041; https://doi.org/10.3390/ijerph192316041 - 30 Nov 2022
Cited by 2 | Viewed by 1131
Abstract
The practical application of nanoscale zero-valent iron (NZVI) is restricted by its easy oxidation and aggregation. Here, sludge biochar (SB) was used as a carrier to stabilize NZVI for Cd2+ and Cu2+ removal. SB supported NZVI (SB-NZVI) was synthesized using the [...] Read more.
The practical application of nanoscale zero-valent iron (NZVI) is restricted by its easy oxidation and aggregation. Here, sludge biochar (SB) was used as a carrier to stabilize NZVI for Cd2+ and Cu2+ removal. SB supported NZVI (SB-NZVI) was synthesized using the carbothermic method. The superior preparation conditions, structural characteristics, and performance and mechanisms of the SB-NZVI composites for the removal of Cd2+ and Cu2+ were investigated via batch experiments and characterization analysis. The optimal removal capacities of 55.94 mg/g for Cd2+ and 97.68 mg/g for Cu2+ were achieved at a Fe/sludge mass ratio of 1:4 and pyrolysis temperature of 900 °C. Batch experiments showed that the SB-NZVI (1:4-900) composite had an excellent elimination capacity over a broad pH range, and that weakly acidic to neutral solutions were optimal for removal. The XPS results indicated that the Cd2+ removal was mainly dependent on the adsorption and precipitation/coprecipitation, while reduction and adsorption were the mechanisms that play a decisive role in Cu2+ removal. The presence of Cd2+ had an opposite effect on the Cu2+ removal. Moreover, the SB-NZVI composites made of municipal sludge greatly reduces the leaching toxicity and bio-availability of heavy metals in the municipal sludge, which can be identified as an environmentally-friendly material. Full article
(This article belongs to the Special Issue Industrial Waste Water Treatment and Reuse)
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10 pages, 1610 KiB  
Article
Peroxymonosulfate Activation by Palladium(II) for Pollutants Degradation: A Study on Reaction Mechanism and Molecular Structural Characteristics
by Bowen Yang, Qiang Ma, Jiming Hao and Xiaojie Sun
Int. J. Environ. Res. Public Health 2022, 19(20), 13036; https://doi.org/10.3390/ijerph192013036 - 11 Oct 2022
Viewed by 1123
Abstract
Compared with certain transition metals (e.g., iron, cobalt, and manganese), noble metals are less frequently applied in peroxymonosulfate (PMS)-based advanced oxidation processes (AOPs). Palladium (Pd), as one of noble metals, has been reported to possess the possibility of both radical mechanisms and electron [...] Read more.
Compared with certain transition metals (e.g., iron, cobalt, and manganese), noble metals are less frequently applied in peroxymonosulfate (PMS)-based advanced oxidation processes (AOPs). Palladium (Pd), as one of noble metals, has been reported to possess the possibility of both radical mechanisms and electron transfer mechanisms in a heterogeneous Pd/PMS system, however, data are still sparse on the homogeneous Pd/PMS system. Therefore, this work aims to explore the homogeneous reactivity of PMS by Pd(II) ions from the aspects of reaction parameters, radical or non-radical oxidation mechanisms, and the relationship between pollutants’ degradation rate and their molecular descriptors based on both experimental data and density functional theory (DFT) calculation results. As a result, the reaction mechanism of Pd(II)/PMS followed a radical-driven oxidation process, where sulfate radicals (SO4•−), rather than hydroxyl radicals (HO•), were the primary reactive oxidant species. BOx and EHOMO played significant roles in pollutant degradation during the Pd(II)/PMS system. It turned out that the bond’s stability and electron donation ability of the target compound was responsible for its degradation performance. This finding provides an insight into PMS activation by a noble metal, which has significant implications for scientific research and technical development. Full article
(This article belongs to the Special Issue Industrial Waste Water Treatment and Reuse)
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17 pages, 12136 KiB  
Article
The Aggregation and Dissolution of Citrate−Coated AgNPs in High Ammonia Nitrogen Wastewater and Sludge from UASB−Anammox Reactor
by Jiachao Jiang, Xin Wang, Yuanyuan Zhang, Jiageng Zhang, Xiujun Gu, Shilong He, Shuo Duan, Jianli Ma, Lizhang Wang and Ping Luo
Int. J. Environ. Res. Public Health 2022, 19(15), 9502; https://doi.org/10.3390/ijerph19159502 - 2 Aug 2022
Cited by 1 | Viewed by 1857
Abstract
Silver nanoparticles (AgNPs) are released into the sewage pipes and ultimately wastewater treatment plants during manufacturing, use, and end–life disposal. AgNPs in wastewater treatment plants aggregate or dissolve, and may affect the microbial community and subsequent pollutant removal efficiency. This study aims to [...] Read more.
Silver nanoparticles (AgNPs) are released into the sewage pipes and ultimately wastewater treatment plants during manufacturing, use, and end–life disposal. AgNPs in wastewater treatment plants aggregate or dissolve, and may affect the microbial community and subsequent pollutant removal efficiency. This study aims to quantitatively investigate the fate of AgNPs in synthetic high ammonia nitrogen wastewater (SW) and sludge from an up–flow anaerobic sludge blanket (UASB) anammox reactor using a nanoparticle tracking analysis (NTA), dynamic light scattering (DLS), transmission electron microscope (TEM), and atomic absorption spectroscopy (AAS). Results showed that 18.1 mM NH4+, 2.11 mM Mg2+ in SW caused less negative zeta potential (ζ−potential, −18.4 vs. −37.4 mV), aggregation (388.8 vs. 21.5 nm), and settlement (80%) of citrate−coated AgNPs (cit−AgNPs) in 220 min. The presence of 18.5 mM Cl in SW formed AgCl2, AgCl(aq) and eventually promoted the dissolution (9.3%) of cit−AgNPs. Further exposure of SW−diluted AgNPs to sludge (42 mg L−1 humic acid) and induced a more negative ζ−potential (−22.2 vs. −18.4 mV) and smaller aggregates (313.4 vs. 388.8 nm) due to the steric and hindrance effect. The promoted Ag dissolution (34.4% vs. 9.3%) was also observed after the addition of sludge and the possible reason may be the production of Ag(NH3)2+ by the coexistence of HA from sludge and NH4+ from SW. These findings on the fate of AgNPs can be used to explain why AgNPs had limited effects on the sludge−retained bacteria which are responsible for the anammox process. Full article
(This article belongs to the Special Issue Industrial Waste Water Treatment and Reuse)
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13 pages, 5158 KiB  
Article
Optimization of PNP Degradation by UV-Activated Granular Activated Carbon Supported Nano-Zero-Valent-Iron-Cobalt Activated Persulfate by Response Surface Method
by Jiankun Zhang, Huifang Zhang, Lei Chen, Xiulei Fan and Yangyang Yang
Int. J. Environ. Res. Public Health 2022, 19(13), 8169; https://doi.org/10.3390/ijerph19138169 - 4 Jul 2022
Cited by 4 | Viewed by 1619
Abstract
Nitrophenols are toxic substances that present humans and animals with the risk of deformities, mutations, or cancer when ingested or inhaled. Traditional water treatment technologies have high costs and low p-nitrophenol (PNP) removal efficiency. Therefore, an ultraviolet (UV)-activated granular activated carbon supported nano-zero-valent-iron-cobalt [...] Read more.
Nitrophenols are toxic substances that present humans and animals with the risk of deformities, mutations, or cancer when ingested or inhaled. Traditional water treatment technologies have high costs and low p-nitrophenol (PNP) removal efficiency. Therefore, an ultraviolet (UV)-activated granular activated carbon supported nano-zero-valent-iron-cobalt (Co-nZVI/GAC) activated persulfate (PS) system was constructed to efficiently degrade PNP with Co-nZVI/GAC dosage, PS concentration, UV power, and pH as dependent variables and PNP removal rate as response values. A mathematical model between the factors and response values was developed using a central composite design (CCD) model. The model-fitting results showed that the PNP degradation rate was 96.7%, close to the predicted value of 98.05 when validation tests were performed under Co-nZVI/GAC injection conditions of 0.827 g/L, PS concentration of 3.811 mmol/L, UV power of 39.496 W, and pH of 2.838. This study demonstrates the feasibility of the response surface methodology for optimizing the UV-activated Co-nZVI/GAC-activated PS degradation of PNP. Full article
(This article belongs to the Special Issue Industrial Waste Water Treatment and Reuse)
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12 pages, 2350 KiB  
Article
Electrochemical Oxidation of Methyl Orange in an Active Carbon Packed Electrode Reactor (ACPER): Degradation Performance and Kinetic Simulation
by Jing Hou, Xue Li, Yuting Yan and Lizhang Wang
Int. J. Environ. Res. Public Health 2022, 19(8), 4775; https://doi.org/10.3390/ijerph19084775 - 14 Apr 2022
Cited by 4 | Viewed by 1719
Abstract
The efficient removal and kinetic modelling of methyl orange (MO) degradation using an electrocatalytic oxidation method in an activated carbon (AC) packed electrode reactor (ACPER) were conducted. A significantly high (81.2%) chemical oxygen demand (COD) and 100.0% MO decolorization efficiency were observed under [...] Read more.
The efficient removal and kinetic modelling of methyl orange (MO) degradation using an electrocatalytic oxidation method in an activated carbon (AC) packed electrode reactor (ACPER) were conducted. A significantly high (81.2%) chemical oxygen demand (COD) and 100.0% MO decolorization efficiency were observed under the experimental conditions of current density of 3.0 mA·cm−2, flow velocity of 0.3 L·h−1, and treatment duration of 1.68 h using a β-PbO2/Ti anode. The high removal efficiency is ascribed to the anode expansion effect after AC packing. The anode expansion coefficient (λ) of the ACPER was calculated to be 0.63 from the cyclic voltammetry (CV) measurement, which means the further current utilization for MO oxidation. Based on the current utilization efficiency on anodic and particle electrode surfaces, a phase-reaction kinetics model was proposed for the simulation of MO COD removal efficiency. Our simulation results showed that the newly established average current efficiency (ACE) and energy consumption (Esp) model well matched the MO experimental degradation data. Our work broadens the scope of the application of ACPER in the treatment industry wastewater containing organics and provides a new strategy for the energy utilization evaluation during the removal of organic matter by electrocatalytic oxidation. Full article
(This article belongs to the Special Issue Industrial Waste Water Treatment and Reuse)
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