Functionalization and Modification of Polymers, Polymeric Recyclates and Films

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Functional Polymer Coatings and Films".

Deadline for manuscript submissions: 31 December 2025 | Viewed by 1378

Special Issue Editors


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Guest Editor
Mechanical Engineering and Energy Department, Koszalin University of Technology, Raclawicka 15-17, 75-620 Koszalin, Poland
Interests: polymer processing; recycling; composites; biocomposites; nanoparticles; packaging systems
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Guest Editor
Chemical Engineering Department, University of Bradford, Richmond Rd, Bradford, UK
Interests: polymer processing; coatings; chemical engineering; nanocomposites; water; biodiesel and metal production; energy

Special Issue Information

Dear Colleagues,

The dynamic development of technology, increasing customer demands, and environmental limitations pose significant challenges for science and engineering. We expect the materials we use to have increasingly better and more complex properties. On the other hand, the growing awareness of humanity and the constraints associated with sustainable development limit our possibilities.

The current knowledge and state of technology allow us to make various modifications to materials and their surfaces. We apply a range of less or more complex layers, create intricate composites, add various nanoparticles, irradiate plastics, and subject them to other physicochemical actions. As a result, we achieve many highly attractive features, which sometimes weaken other functions and, unfortunately, can be problematic in the recycling processes after the product reaches the end of its life cycle.

Creating multilayer composites for the construction or packaging industries (especially for the food and medical applications) enables us to develop materials with sophisticated properties, but this usually comes at the expense of their ecological friendliness. Therefore, we are looking for alternative solutions, and in packaging, there is a return to monofilms. Monomaterial films, which are intended to replace multilayer films, will need to be functionalized in various ways to achieve necessary functionalities, such as barrier properties or biostatic qualities.

We are developing material management, ensuring that our materials are eco-friendly and recyclable. A circular economy is one of the fundamental goals, and we are thus paying more attention to biomaterials and their degradation processes. There is a vast scope for research in this area.

In this Special Issue, we would like to present articles on modern materials and composites, technologies for their production, and property modifications. We aim to discuss the functionalization of their surfaces and the related successes as well as challenges. In the era of environmental crisis, an important issue is the recycling and disposal of plastic waste, which is a very significant topic. Recycling is a very interesting process, but it is not without problems, especially concerning composites. The waste from functionalized materials will undoubtedly lead to changes in the properties of recovered materials, which is a very interesting topic. For example, although the addition of nanoparticles in polymers is very popular at present, it does affect the properties of recyclates; this is a fascinating research area that is not yet fully understood.

We invite you to contribute to this publication.

Prof. Dr. Tomasz Rydzkowski
Prof. Dr. Rajnikant Patel
Guest Editors

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Keywords

  • polymer processing and modification
  • film modification and applications
  • thin films
  • chemical engineering
  • nanocomposites
  • adhesion
  • surface modification
  • surface energy sfe
  • developed interfacial area ratio sdr
  • packaging systems
  • biodegradadation
  • permeability for water vapour and gases
  • composites and biocompostes
  • recycling issues

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Published Papers (2 papers)

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Research

12 pages, 2341 KiB  
Article
Correlations Between Crystallinity, Rheological Behavior, and Short-Term Biodegradation for LDPE/Cellulose Composites with Potential as Packaging Films
by Nizar Jawad Hadi, Tomasz Rydzkowski, Zahraa Saleem Ali and Q. A. Al-Jarwany
Coatings 2025, 15(4), 397; https://doi.org/10.3390/coatings15040397 - 27 Mar 2025
Viewed by 215
Abstract
The need for renewable and biodegradable materials for packaging applications has grown significantly in recent years. Growing environmental worries over the widespread use of synthetic and non-biodegradable polymeric packaging, particularly polyethylene, are linked to this increase in demand. This study investigated the degradation [...] Read more.
The need for renewable and biodegradable materials for packaging applications has grown significantly in recent years. Growing environmental worries over the widespread use of synthetic and non-biodegradable polymeric packaging, particularly polyethylene, are linked to this increase in demand. This study investigated the degradation properties of low-density polyethylene (LDPE), a material commonly used in packaging, after incorporating various natural fillers that are sustainable, compatible, and biodegradable. The LDPE was mixed with 2.5, 5, and 10 wt.% of sawdust, cellulose powder, and Nanocrystalline cellulose (CNC). The composites were melted and mixed using a twin-screw extruder machine with a screw speed of 50 rpm at 190 °C to produce sheets using a specific die. These sheets were used to prepare samples for rheological tests that measured the viscosity curve, the flow curve, and a non-Newtonian mathematical model using a capillary rheometer at 170, 190, and 210 °C. X-ray diffraction analysis was carried out on the 5 wt.% samples, and a short-term degradation test was conducted in soil with a pH of 6.5, 50% humidity, and a temperature of 27 °C. The results revealed that the composite melts exhibited non-Newtonian behavior, with shear thinning being the dominant characteristic in the viscosity curves. The shear viscosity increased as the different cellulose additives increased. The 5% ratio had a higher viscosity for all composite melts, and the LDPE/CNC melts showed higher viscosities at different temperatures. The curve fitting results confirmed that the power-law model best described the flow behavior of all composite melts. The LDPE/sawdust and cellulose powder melts showed higher flow index (n) and lower viscosity consistency (k) values compared with LDPE/CNC melted at different temperatures. The sawdust and powder composites had greater weight loss compared with the LD vbbPE/CNC composites; digital images supported these results after 30 days. The degradation test and weight loss illustrated stronger relations with the viscosity values at low shear rates. The higher the shear viscosity, the lower the degradation and vice versa. Full article
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18 pages, 2294 KiB  
Article
Effect of Graphene and Graphene Oxide Addition to Polyethylene Film on Lipid Quality of African Catfish (Clarias gariepinus) Fillets During Refrigerated Storage
by Zdzisław Domiszewski, Sylwia Mierzejewska, Iwona Michalska-Pożoga, Klaudia Rybka and Tomasz Rydzkowski
Coatings 2024, 14(12), 1506; https://doi.org/10.3390/coatings14121506 - 29 Nov 2024
Viewed by 876
Abstract
The purpose of this study was to investigate the effect of the addition of graphene (G) and graphene oxide (GO) to polyethylene film on the lipid oxidation level and sensory quality of African catfish fillets during refrigerated storage. The study was conducted on [...] Read more.
The purpose of this study was to investigate the effect of the addition of graphene (G) and graphene oxide (GO) to polyethylene film on the lipid oxidation level and sensory quality of African catfish fillets during refrigerated storage. The study was conducted on de-skinned fillets from a local farm. A composite film with 0.1%, 0.6%, and 1% G nanoplatelets and 0.1% GO nanoplatelets was used to package the fillets. The film was obtained using the free-blowing vertical upward method. The fillets were stored in polyethylene bags at 4 °C, and tests were conducted on the day of packaging and after 3, 7, 10, and 14 days of refrigerated storage. The peroxide number, anisidine number, and Totox index were determined in the extracted lipids using the Bligh and Dyer method. Sensory analysis of the fillets was carried out using the spot method and sensory profiling. Global migration for the film was also investigated. After 14 days, fillets packaged in the plain film exhibited, on average, 50%–100% higher lipid oxidation indices than those packaged in the film with G and GO. The film with 1% G and 0.1% GO additive showed the best properties for retarding the formation of aldehydes and ketones in lipids during fillet storage. There was no significant effect of the addition of nanomaterials to the film on the sensory quality of the fillets. The global migration did not exceed the allowed limit of 10 mg/dm2 for any of the films. Composite films with nanomaterials have great potential as packaging in slowing down oxidation processes in foods. Full article
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