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J. Compos. Sci., Volume 8, Issue 6 (June 2024) – 41 articles

Cover Story (view full-size image): Lightweight composite metal foam (CMF) is composed of hollow metal spheres filled with air embedded in a metallic matrix. CMF is a novel metallic material in which still air inside its hollow spheres prevents thermal transmission and acts like a heavy-duty Styrofoam. In the meantime, the airtight hollow spheres act like a heavy-duty bubble wrap and protect against impact. A combination of the two properties can offer a single-layer lightweight alternative for the protection of tank cars carrying hazardous materials (HAZMAT) against puncture, extreme heat and fire resulting from a potential derailment. CMF is a single-layer lightweight material offering protection against multiple threats. View this paper
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11 pages, 1663 KiB  
Article
Selected Mechanical Properties of Dental Hybrid Composite with Fluorine, Hydroxyapatite and Silver Fillers
by Zofia Kula, Leszek Klimek, Katarzyna Dąbrowska, Cristina Bettencourt Neves and João Carlos Roque
J. Compos. Sci. 2024, 8(6), 232; https://doi.org/10.3390/jcs8060232 - 20 Jun 2024
Cited by 1 | Viewed by 1781
Abstract
In recent years, hydroxyapatite, as a ceramic material, has been a subject of growing interest due to its optimal biological properties, which are useful especially in medical and dental applications. It has been increasingly used in dentistry as a filler in composites. Nevertheless, [...] Read more.
In recent years, hydroxyapatite, as a ceramic material, has been a subject of growing interest due to its optimal biological properties, which are useful especially in medical and dental applications. It has been increasingly used in dentistry as a filler in composites. Nevertheless, research has shown a deterioration of their mechanical properties. The aim of this study was to investigate the influence of the content of hydroxyapatite together with fluorine and silver on the mechanical properties of a hybrid composite used in conservative dentistry. The authors compared specimens of commercial hybrid composite with specimens of experimental hybrid composite containing 2 wt% and 5 wt% of hydroxyapatite powder with fluorine and silver. The composite specimens were subjected to hardness and impact strength measurements, as well as bending, compression, and tribological wear tests. The research results indicate that the mechanical properties of composites are influenced by the type and amount of filler used. Composite containing 2 wt% of hydroxyapatite powder along with calcium fluoride and silver provided acceptable results. Full article
(This article belongs to the Special Issue Innovations in Direct and Indirect Dental Composite Restorations)
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17 pages, 10296 KiB  
Article
Low Magnetic Field Induced Extrinsic Strains in Multifunctional Particulate Composites: An Interrupted Mechanical Strengthening in 3D-Printed Nanocomposites
by Andiol Mucolli, Alden Midmer, Marinos Manolesos, Salem Aldosari, Cristian Lira and Hamed Yazdani Nezhad
J. Compos. Sci. 2024, 8(6), 231; https://doi.org/10.3390/jcs8060231 - 20 Jun 2024
Cited by 1 | Viewed by 2134
Abstract
The current paper reports on the quantification of the effect of magnetic fields on the mechanical performance of ferromagnetic nanocomposites in situ during basic standard tensile testing. The research investigates altering the basic mechanical properties (modulus and strength) via the application of a [...] Read more.
The current paper reports on the quantification of the effect of magnetic fields on the mechanical performance of ferromagnetic nanocomposites in situ during basic standard tensile testing. The research investigates altering the basic mechanical properties (modulus and strength) via the application of a contact-less magnetic field as a primary attempt for a future composites strengthening mechanism. The nanocomposite specimens were fabricated using filament-based 3D printing and were comprised of ferromagnetic nanoparticle-embedded thermoplastic polymers. The nanoparticles were iron particles dispersed at 21 wt.% (10.2 Vol.%) inside a polylactic acid (PLA) polymer, characterised utilising optical microscopy and 3D X-ray computed tomography. The magnetic field was stationary and produced using permanent neodymium round-shaped magnets available at two field strengths below 1 Tesla. The 3D printing was a MakerBot Replicator machine operating based upon a fused deposition method, which utilised 1.75 mm-diameter filaments made of iron particle-based PLA composites. The magnetic field-equipped tensile tests were accompanied by a real-time digital image correlation technique for localized strain measurements across the specimens at a 10-micron pixel resolution. It was observed that the lateral magnetic field induces a slight Poisson effect on the development of extrinsic strain across the length of the tensile specimens. However, the effect reasonably interferes with the evolution of strain fields via the introduction of localised compressive strains attributed to accumulated magnetic polarisation at the magnetic particles on an extrinsic scale. The theory overestimated the moduli by a factor of approximately 3.1. To enhance the accuracy of its solutions for 3D-printed specimens, it is necessary to incorporate pore considerations into the theoretical derivations. Additionally, a modest 10% increase in ultimate tensile strength was observed during tensile loading. This finding suggests that field-assisted strengthening can be effective for as-received 3D-printed magnetic composites in their solidified state, provided that the material and field are optimally designed and implemented. This approach could propose a viable method for remote field tailoring to strengthen the material by mitigating defects induced during the 3D printing process. Full article
(This article belongs to the Special Issue 3D Printing Composites)
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28 pages, 5591 KiB  
Review
Keratinous Natural Fibres as Sustainable Flame Retardants and Reinforcements in Polymer Composites
by Avishek Mishra, Nam Kyeun Kim and Debes Bhattacharyya
J. Compos. Sci. 2024, 8(6), 230; https://doi.org/10.3390/jcs8060230 - 17 Jun 2024
Cited by 3 | Viewed by 2331
Abstract
Natural fibres have been used as fibre reinforcements in composites as they offer eco-friendly and economic advantages, but their susceptibility to deterioration when exposed to heat and flames has limited their practical application in fibre-reinforced polymeric composites. Fire-reaction properties have been explored in [...] Read more.
Natural fibres have been used as fibre reinforcements in composites as they offer eco-friendly and economic advantages, but their susceptibility to deterioration when exposed to heat and flames has limited their practical application in fibre-reinforced polymeric composites. Fire-reaction properties have been explored in reasonable detail for plant fibres, but a gap exists in the understanding of animal fibre-reinforced composites. Understanding the thermal and fire reactions of these keratin-rich animal fibres is crucial for material selection and advancing composite product development. The current paper critically discusses the existing research landscape and suggests future research directions. The use of keratinous fibres in composites can definitely improve their thermal stability and fire performance, but it also appears to adversely affect the composite’s mechanical performance. The main part of this paper focuses on the flame-retardant treatment of keratinous fibres and polymer composites, and their behaviour under fire conditions. The final part of this paper includes a brief look at the environmental impact of the treatment methods; the overall processing of keratinous fibre-reinforced composites is also presented to gain further insight. Full article
(This article belongs to the Special Issue Polymer Composites and Fibers, Volume II)
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29 pages, 11029 KiB  
Article
The Use of Externally Bonded Fibre Reinforced Polymer Composites to Enhance the Seismic Resilience of Single Shear Walls: A Nonlinear Time History Assessment
by Ali Abbaszadeh and Omar Chaallal
J. Compos. Sci. 2024, 8(6), 229; https://doi.org/10.3390/jcs8060229 - 17 Jun 2024
Viewed by 992
Abstract
In medium- to high-rise buildings, single shear walls (SSWs) are often used to resist lateral force due to wind and earthquakes. They are designed to dissipate seismic energy mainly through plastic hinge zones at the base. However, they often display large post-earthquake deformations [...] Read more.
In medium- to high-rise buildings, single shear walls (SSWs) are often used to resist lateral force due to wind and earthquakes. They are designed to dissipate seismic energy mainly through plastic hinge zones at the base. However, they often display large post-earthquake deformations that can give rise to many economic and safety concerns within buildings. Hence, the primary objective of this research study is to minimize residual deformations in existing SSWs located in the Western and Eastern seismic zones of Canada, thereby enhancing their resilience and self-centering capacity. To that end, four SSWs of 20 and 15 stories, located in Vancouver and Montreal, were meticulously designed and detailed per the latest Canadian standards and codes. The study assessed the impact of three innovative strengthening schemes on the seismic response of these SSWs through 2D nonlinear time history (NLTH) analysis. All three strengthening schemes involved the application of Externally Bonded Fiber Reinforced Polymer (EB-FRP) to the shear walls. Accordingly, a total of 208 NLTH analyses were conducted to assess the effectiveness of all strengthening configurations. The findings unveiled that the most efficient technique for reducing residual drift in SSWs involved applying three layers of vertical FRP sheets to the extreme edges of the wall, full FRP wrapping the walls, and full FRP wrapping of the plastic hinge zone. Nevertheless, it is noteworthy that implementing these strengthening schemes may lead to an increase in bending moment and base shear force demands within the walls. Full article
(This article belongs to the Special Issue Polymer Composites and Fibers, Volume II)
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17 pages, 4719 KiB  
Article
Bio-Inspired Helicoidal Composite Structure Featuring Graded Variable Ply Pitch under Transverse Tensile Loading
by Hossein Malekinejad, Ricardo J. C. Carbas, Alireza Akhavan-Safar, Eduardo A. S. Marques, Maria Ferreira and Lucas F. M. da Silva
J. Compos. Sci. 2024, 8(6), 228; https://doi.org/10.3390/jcs8060228 - 16 Jun 2024
Cited by 3 | Viewed by 2060
Abstract
Biostructures found in nature exhibit remarkable strength, toughness, and damage resistance, achieved over millions of years. Observing nature closely might help develop laminates that resemble natural structures more closely, potentially improving strength and mimicking natural principles. Bio-inspired Carbon Fiber-Reinforced Polymers (CFRP) investigated thus [...] Read more.
Biostructures found in nature exhibit remarkable strength, toughness, and damage resistance, achieved over millions of years. Observing nature closely might help develop laminates that resemble natural structures more closely, potentially improving strength and mimicking natural principles. Bio-inspired Carbon Fiber-Reinforced Polymers (CFRP) investigated thus far exhibit consistent pitch angles between layers, whereas natural structures display gradual variations in pitch angle rather than consistency. Therefore, this study explores helicoidal CFRP laminates, focusing on the Non-Linear Rotation Angle (NLRA) or gradual variation to enhance composite material performance. In addition, it compares the strength and failure mechanisms of the gradual configuration with conventional helicoidal and unidirectional (UD) laminates, serving as references while conducting transverse tensile tests (out-of-plane tensile). The findings highlight the potential of conventional and gradual helicoidal structures in reinforcing CFRP laminates, increasing the failure load compared to unidirectional CFRP laminate by about 5% and 17%, respectively. In addition, utilizing bio-inspired configurations has shown promising improvements in toughness compared to traditional unidirectional laminates, as evidenced by the increased displacement at failure. The numerical and experimental analyses revealed a shift in crack path when utilizing the bio-inspired helicoidal stacking sequence. Validated by experimental data, this alteration demonstrates longer and more intricate crack propagation, ultimately leading to increased transverse strength. Full article
(This article belongs to the Special Issue Sustainable Biocomposites, Volume II)
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21 pages, 5671 KiB  
Article
Competitive Adsorption of Aqueous Cd(II) and Pb(II) Solutions onto Silicas Synthesized with Saponin as Template Agent
by Claudia-Maria Simonescu, Florina Dumitru, Bianca Zărnescu, Daniela Cristina Culiţă, Anca Răzvan, Ovidiu Oprea, Roxana Truşcă and Eugeniu Vasile
J. Compos. Sci. 2024, 8(6), 227; https://doi.org/10.3390/jcs8060227 - 16 Jun 2024
Cited by 1 | Viewed by 1371
Abstract
The aim of the research was to prepare silica adsorbents using an environmentally friendly pathway, a template synthesis with saponin biosurfactant as a structure-directing agent. The adsorbents prepared in this way exhibit improved adsorption properties while maintaining environmental innocuousness. For the preparation of [...] Read more.
The aim of the research was to prepare silica adsorbents using an environmentally friendly pathway, a template synthesis with saponin biosurfactant as a structure-directing agent. The adsorbents prepared in this way exhibit improved adsorption properties while maintaining environmental innocuousness. For the preparation of porous silica, the biosurfactant template sol–gel method was used with tetraethoxysilane as a silica precursor. The silica adsorbents were analyzed by FTIR spectroscopy, nitrogen adsorption–desorption and SEM/EDX microscopy, TEM/HRTEM microscopy, and thermogravimetric analyses. Batch tests were carried out to remediate Pb(II)/Cd(II) ions in single/binary aqueous solutions, and the effect of the surfactant on the adsorption properties was assessed. The optimal adsorption parameters (pH, contact time, initial concentration of metal ions) have been determined. The adsorption was fitted using Langmuir and Freundlich adsorption isotherms and kinetic models. Mathematical modeling of the retention process of Pb(II) and Cd(II) ions from binary solutions indicated a competitive effect of each of the two adsorbed metal ions. The experimental results demonstrated that saponin has the effect of modifying the silica structure through the formation of pores, which are involved in the retention of metal ions from aqueous solutions and wastewater. Full article
(This article belongs to the Special Issue Metal Composites, Volume II)
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16 pages, 11971 KiB  
Article
Development and Evaluation of 3D-Printed PLA/PHA/PHB/HA Composite Scaffolds for Enhanced Tissue-Engineering Applications
by Motahareh Sadat Raziyan, Arvydas Palevicius, Dariusz Perkowski, Sigita Urbaite and Giedrius Janusas
J. Compos. Sci. 2024, 8(6), 226; https://doi.org/10.3390/jcs8060226 - 16 Jun 2024
Cited by 6 | Viewed by 2635
Abstract
Recently, tissue engineering has been revolutionised by the development of 3D-printed scaffolds, which allow one to construct a precise architecture with tailored properties. In this study, three different composite materials were synthesised using a combination of polylactic acid (PLA), polyhydroxyalkanoates (PHA), poly(3-hydroxybutyrate) (PHB) [...] Read more.
Recently, tissue engineering has been revolutionised by the development of 3D-printed scaffolds, which allow one to construct a precise architecture with tailored properties. In this study, three different composite materials were synthesised using a combination of polylactic acid (PLA), polyhydroxyalkanoates (PHA), poly(3-hydroxybutyrate) (PHB) and hydroxyapatite (HA) in varying weight percentages. Morphological properties were evaluated by scanning electron microscopy showing a uniform distribution of HA particles throughout the matrix, indicating good compatibility between the materials. Furthermore, the printed scaffolds were tested under pressure using a load cell to examine mechanical strength. Scanning electron microscopy (SEM) analysis showed favorable dispersion, biological compatibility together with enhanced bioactivity within the PHB/PHA/PLA/HA composite matrixes. Thus, this paper demonstrates the successful design and implementation of these composite structures for tissue-engineering applications and highlights the effective development of biocompatible scaffold designs with improved functionality. Full article
(This article belongs to the Special Issue Progress in Polymer Composites, Volume III)
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16 pages, 5626 KiB  
Article
Development, Dielectric Response, and Functionality of ZnTiO3/BaTiO3/Epoxy Resin Hybrid Nanocomposites
by Anastasios C. Patsidis, Eleftherios I. Koufakis, Georgios N. Mathioudakis, Orestis Vryonis and Georgios C. Psarras
J. Compos. Sci. 2024, 8(6), 225; https://doi.org/10.3390/jcs8060225 - 15 Jun 2024
Cited by 2 | Viewed by 1468
Abstract
In the present work, hybrid nanocomposites of an epoxy resin reinforced with ZnTiO3 and BaTiO3 nanoparticles, at various filler contents, were fabricated and studied. The successful integration of ceramic nanofillers and the fine distribution of nanoparticles were confirmed via X-ray Diffraction [...] Read more.
In the present work, hybrid nanocomposites of an epoxy resin reinforced with ZnTiO3 and BaTiO3 nanoparticles, at various filler contents, were fabricated and studied. The successful integration of ceramic nanofillers and the fine distribution of nanoparticles were confirmed via X-ray Diffraction patterns and Scanning Electron Microscopy images, respectively. Dielectric properties and related relaxation phenomena were investigated via Broadband Dielectric Spectroscopy in a wide range of frequencies and temperatures. Data analysis showed that dielectric permittivity increases with filler content, although optimum performance does not correspond to the maximum ZnTiO3 content. Four relaxation processes were observed and attributed to interfacial polarization (IP) (at low frequencies and high temperatures), glass-to-rubber transition (α-relaxation) of the epoxy matrix (at intermediate frequencies and temperatures), and local rearrangements of polar side groups of the macromolecules (β-relaxation) and small flexible groups of the main polymer chain (γ-relaxation) occurring at low temperatures and high frequencies. The ability of hybrid nanocomposites to store and retrieve energy was studied under dc conditions by employing a charging/discharging sequence. The stored and retrieved energy increases with filler content and charging voltage. The optimum ability of energy recovering, shown by the epoxy/7 phr ZnTiO3/7 phr BaTiO3 nanocomposite, ranges between 30 and 50 times more than the matrix, depending on the time instant. The employed nanoparticles induce piezoelectric properties in the nanocomposites, as found by the increase in the piezoelectric coefficient with filler content. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
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18 pages, 22798 KiB  
Article
Design of a Lightweight Origami Composite Crash Box: Experimental and Numerical Study on the Absorbed Energy in Frontal Impacts
by Alberto Ciampaglia, Luca Patruno and Raffaele Ciardiello
J. Compos. Sci. 2024, 8(6), 224; https://doi.org/10.3390/jcs8060224 - 14 Jun 2024
Cited by 4 | Viewed by 1862
Abstract
Origami-shaped composite structures are currently being explored for their ability to absorb energy in a progressive and controlled manner. In vehicle passive safety applications, this prevents the occurrence of peak forces that could potentially cause injuries to vehicle passengers. The work presents the [...] Read more.
Origami-shaped composite structures are currently being explored for their ability to absorb energy in a progressive and controlled manner. In vehicle passive safety applications, this prevents the occurrence of peak forces that could potentially cause injuries to vehicle passengers. The work presents the design of a carbon fiber-reinforced polymer (CFRP) crash box for a Formula Student race car, using a numerical model validated by experimental tests. An initial characterization of the material is conducted according to the standards. Following, six origami samples are manufactured and subjected to crash tests to gather accurate experimental data. The numerical model is validated on the tests and used for the design of the race car’s impact attenuator. The designed crash box meets the Formula Student requirements while reducing the total mass by 14% and the maximum deceleration of 21% compared with the previous design. The study confirms the potential use of origami structures to improve crashworthiness while reducing vehicle weight. Full article
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15 pages, 6369 KiB  
Article
Does the Layer Configuration of Loofah (Luffa cylindrica) Affect the Mechanical Properties of Polymeric Composites?
by Edgley Alves de Oliveira Paula, Rafael Rodolfo de Melo, Felipe Bento de Albuquerque, Fernanda Monique da Silva, Mário Vanoli Scatolino, Alexandre Santos Pimenta, Edjane Alves de Oliveira Paula, Talita Dantas Pedrosa, Ricardo Alan da Silva Vieira and Francisco Rodolfo Junior
J. Compos. Sci. 2024, 8(6), 223; https://doi.org/10.3390/jcs8060223 - 14 Jun 2024
Cited by 2 | Viewed by 1267
Abstract
The arrangement of layers of natural long fibers that compose a polymeric composite can result in a final material with greater mechanical strength, in addition to replacing synthetic glass and carbon fibers. This study proposed different configurations of layers of loofah fibers ( [...] Read more.
The arrangement of layers of natural long fibers that compose a polymeric composite can result in a final material with greater mechanical strength, in addition to replacing synthetic glass and carbon fibers. This study proposed different configurations of layers of loofah fibers (Luffa cylindrica) to produce reinforced polymeric–polyester composites, determining their potential mechanical properties such as flexural strength and Rockwell hardness. The layers were arranged by varying parallel and perpendicularly the direction of the loofah fibers pieces. The reinforcement decreased the density of all composites, with the lowest value, 1.03 g cm−3, indicated by the configuration 90°/0°/90°. The composites in the configuration 0°/90°/0° presented the highest value among the reinforced compositions (10.8 MPa), in addition to the highest rigidity value during bending tests (774.8 MPa). In the Rockwell hardness tests, the treatment reinforced with fibers in the configuration 90°/90°/90° had the highest value among all experimental treatments with a value of 86.9 HHR. The configuration angle of the loofah layers has a significant impact on the mechanical performance of the composites and should be taken into account in their confection. Furthermore, composites reinforced with loofah fibers in different configurations have physical–mechanical properties that qualify them for non-structural applications in indoor environments. Full article
(This article belongs to the Section Biocomposites)
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24 pages, 3744 KiB  
Article
Comparing Degradation Mechanisms, Quality, and Energy Usage for Pellet- and Filament-Based Material Extrusion for Short Carbon Fiber-Reinforced Composites with Recycled Polymer Matrices
by Marah Baddour, Chiara Fiorillo, Lynn Trossaert, Annabelle Verberckmoes, Arthur Ghekiere, Dagmar R. D’hooge, Ludwig Cardon and Mariya Edeleva
J. Compos. Sci. 2024, 8(6), 222; https://doi.org/10.3390/jcs8060222 - 12 Jun 2024
Cited by 2 | Viewed by 1650
Abstract
Short carbon fiber (sCF)-based polymer composite parts enable one to increase in the material property range for additive manufacturing (AM) applications. However, room for technical and material improvement is still possible, bearing in mind that the commonly used fused filament fabrication (FFF) technique [...] Read more.
Short carbon fiber (sCF)-based polymer composite parts enable one to increase in the material property range for additive manufacturing (AM) applications. However, room for technical and material improvement is still possible, bearing in mind that the commonly used fused filament fabrication (FFF) technique is prone to an extra filament-making step. Here, we compare FFF with direct pellet additive manufacturing (DPAM) for sCF-based composites, taking into account degradation reactions, print quality, and energy usage. On top of that, the matrix is based on industrial waste polymers (recycled polycarbonate blended with acrylonitrile butadiene styrene polymer and recycled propylene), additives are explored, and the printing settings are optimized, benefiting from molecular, rheological, thermal, morphological, and material property analyses. Despite this, DPAM resulted in a rougher surface finish compared to FFF and can be seen as a faster printing technique that reduces energy consumption and molecular degradation. The findings help formulate guidelines for the successful DPAM and FFF of sCF-based composite materials in view of better market appreciation. Full article
(This article belongs to the Special Issue Recycled Polymer Composites: Futuristic Sustainable Material)
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11 pages, 2286 KiB  
Article
Mechanical Properties and Thermal Conductivity of Y-Si and Gd-Si Silicides: First-Principles Calculations
by Kexue Peng, Panxin Huang, Guifang Han, Huan Liu, Weibin Zhang, Weili Wang and Jingde Zhang
J. Compos. Sci. 2024, 8(6), 221; https://doi.org/10.3390/jcs8060221 - 12 Jun 2024
Viewed by 945
Abstract
The traditional Si bonding layer in environmental barrier coatings has a low melting point (1414 °C), which is a significant challenge in meeting the requirements of the next generation higher thrust-to-weight ratio aero-engines. To seek new bonding layer materials with higher melting points, [...] Read more.
The traditional Si bonding layer in environmental barrier coatings has a low melting point (1414 °C), which is a significant challenge in meeting the requirements of the next generation higher thrust-to-weight ratio aero-engines. To seek new bonding layer materials with higher melting points, the mechanical properties of Y-Si and Gd-Si silicides were calculated by the first-principles method. Subsequently, empirical formulae were employed to compute the sound velocities, Debye temperatures, and the minimum coefficients of thermal conductivity for the YSi, Y5Si4, Y5Si3, GdSi, and Gd5Si4. The results showed that Y5Si4 has the best plasticity and ductility among all these materials. In addition, Gd5Si4 has the minimum Debye temperature (267 K) and thermal conductivity (0.43 W m−1 K−1) compared with others. The theoretical calculation results indicate that some silicides in the Y-Si and Gd-Si systems possess potential application value in high-temperature bonding layers for thermal and/or environmental barrier coating. Full article
(This article belongs to the Special Issue Characterization and Modelling of Composites, Volume III)
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25 pages, 1639 KiB  
Review
Biochar Production and Its Potential Application for Biocomposite Materials: A Comprehensive Review
by Guillermina Feliz Florian, Mohamed Ragoubi, Nathalie Leblanc, Bechara Taouk and Lokmane Abdelouahed
J. Compos. Sci. 2024, 8(6), 220; https://doi.org/10.3390/jcs8060220 - 9 Jun 2024
Cited by 5 | Viewed by 5269
Abstract
Biochar, an organic, porous, and carbon-rich material originating from biomass via pyrolysis, showcases compelling attributes and intrinsic performances. Its appeal as a reinforcement material for biocomposites, as well as its auspicious electrical properties, has gained more attention, and makes biochar a versatile candidate [...] Read more.
Biochar, an organic, porous, and carbon-rich material originating from biomass via pyrolysis, showcases compelling attributes and intrinsic performances. Its appeal as a reinforcement material for biocomposites, as well as its auspicious electrical properties, has gained more attention, and makes biochar a versatile candidate for applications ranging from energy storage to catalytic devices. This scientific review undertakes a comprehensive exploration of biochar, spanning production methodologies, physicochemical intricacies, and critical process parameters. The focus of this paper extends to optimization strategies for biochar properties tailored to specific applications, with a dedicated inquiry into diverse production methods and activation strategies. This review’s second phase delves into a meticulous analysis of key properties within biochar-based composites, emphasizing limitations and unique performance characteristics crucial for diverse applications. By synthesizing a substantial body of research, this review aims to catalyze future investigations by pinpointing areas that demand attention in upcoming experiments, ultimately emphasizing the profound potential of biochar-based materials across technical and scientific domains. Full article
(This article belongs to the Special Issue Sustainable Biocomposites, Volume II)
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19 pages, 5071 KiB  
Article
Conditioning Influence of Kaolinite Matrices on Flexural Strength of Raw Pressed Slurry Collected from Ceramic Tile Production Wastewater
by Simona Elena Avram, Lucian Barbu Tudoran, Stanca Cuc, Gheorghe Borodi, Bianca Violeta Birle and Ioan Petean
J. Compos. Sci. 2024, 8(6), 219; https://doi.org/10.3390/jcs8060219 - 9 Jun 2024
Cited by 6 | Viewed by 1085
Abstract
Kaolinite is able to assure the high binding affinity of the filler particles of raw ceramic bodies. It acts as a matrix that strongly holds the other constituents’ particles in a compact structure. The slurry samples were characterized by XRD, mineralogical microscopy and [...] Read more.
Kaolinite is able to assure the high binding affinity of the filler particles of raw ceramic bodies. It acts as a matrix that strongly holds the other constituents’ particles in a compact structure. The slurry samples were characterized by XRD, mineralogical microscopy and SEM coupled with an EDX elemental analysis. The slurry collected from the ceramic tile production wastewaters had a significant amount of kaolinite (36%), mostly fine particles of 3 µm, less surrounding quartz (37%) and mullite (19%) particles of 5–100 µm in diameter and traces of lepidocrocite (8%). It is a dense paste with a relative moisture of 25%. The square bar of the slurry as received, pressed at a load of 350 N, had a flexural strength of 0.61 MPa. Increasing the moisture to 33% using regular water, followed by mechanical attrition at 2000 rpm for 5 min, resulted in a porous bar with a flexural strength of 0.09 MPa; by increasing the attrition speed to 6000 rpm, the microstructural homogenization was improved and the flexural strength was about 0.68 MPa. It seems that regular water does not assure an optimal moisture for the kaolinite matrix conditioning. Therefore, we used technological water at pH = 10, a moisture of 33% and attrition at 6000 rpm for 5 min, and the bar pressed at a load of 350 N had a flexural strength of 1.17 MPa. The results demonstrate that the bar moistened with technological water and an attrition regime assured a proper conditioning for the kaolinite matrix, achieving the optimal binding of the quartz and mullite particles under the pressing load. Bars with the optimal mixture were pressed at several loads, including 70, 140, 210 and 350 N, and the flexural strength was progressively increased from 0.56 MPa to 1.17 MPa. SEM fractography coupled with atomic force microscopy (AFM) revealed that the optimal moisture facilitated a proper kaolinite particle disposal regarding the quartz and mullite filler particles, and the progressive load assured the strong binding of the finest kaolinite platelets onto their surface. Full article
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108 pages, 6586 KiB  
Review
Calcium Orthophosphate (CaPO4) Containing Composites for Biomedical Applications: Formulations, Properties, and Applications
by Sergey V. Dorozhkin
J. Compos. Sci. 2024, 8(6), 218; https://doi.org/10.3390/jcs8060218 - 8 Jun 2024
Cited by 7 | Viewed by 3844
Abstract
The goal of this review is to present a wide range of hybrid formulations and composites containing calcium orthophosphates (abbreviated as CaPO4) that are suitable for use in biomedical applications and currently on the market. The bioactive, biocompatible, and osteoconductive properties [...] Read more.
The goal of this review is to present a wide range of hybrid formulations and composites containing calcium orthophosphates (abbreviated as CaPO4) that are suitable for use in biomedical applications and currently on the market. The bioactive, biocompatible, and osteoconductive properties of various CaPO4-based formulations make them valuable in the rapidly developing field of biomedical research, both in vitro and in vivo. Due to the brittleness of CaPO4, it is essential to combine the desired osteologic properties of ceramic CaPO4 with those of other compounds to create novel, multifunctional bone graft biomaterials. Consequently, this analysis offers a thorough overview of the hybrid formulations and CaPO4-based composites that are currently known. To do this, a comprehensive search of the literature on the subject was carried out in all significant databases to extract pertinent papers. There have been many formulations found with different material compositions, production methods, structural and bioactive features, and in vitro and in vivo properties. When these formulations contain additional biofunctional ingredients, such as drugs, proteins, enzymes, or antibacterial agents, they offer improved biomedical applications. Moreover, a lot of these formulations allow cell loading and promote the development of smart formulations based on CaPO4. This evaluation also discusses basic problems and scientific difficulties that call for more investigation and advancements. It also indicates perspectives for the future. Full article
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17 pages, 4110 KiB  
Article
Electrochemical Enrichment of Biocharcoal Modified on Carbon Electrodes for the Detection of Nitrite and Paraxon Ethyl Pesticide
by Anurag Adiraju, Amina Brahem, Tianqi Lu, Ammar Al-Hamry, Yu Zhou, Leixin Wei, Aditya Jalasutram, Christoph Tegenkamp, Kamel Halouani and Olfa Kanoun
J. Compos. Sci. 2024, 8(6), 217; https://doi.org/10.3390/jcs8060217 - 8 Jun 2024
Cited by 4 | Viewed by 1791
Abstract
Biocharcoal (BioC), a cost-effective, eco-friendly, and sustainable material can be derived from various organic sources including agricultural waste. However, to date, complex chemical treatments using harsh solvents or physical processes at elevated temperatures have been used to activate and enhance the functional groups [...] Read more.
Biocharcoal (BioC), a cost-effective, eco-friendly, and sustainable material can be derived from various organic sources including agricultural waste. However, to date, complex chemical treatments using harsh solvents or physical processes at elevated temperatures have been used to activate and enhance the functional groups of biochar. In this paper, we propose a novel easy and cost-effective activation method based on electrochemical cycling in buffer solutions to enhance the electrochemical performance of biocharcoal derived from almond shells (AS-BioC). The novel electrochemical activation method enhanced the functional groups and porosity on the surface of AS-BioC, as confirmed by microscopic, spectroscopic characterizations. Electrochemical characterization indicated an increase in the conductivity and surface area. A modified SPCE with activated AS-BioC (A.AS-BioC/SPCE), shows enhanced electrochemical performance towards oxidation and reduction of nitrite and paraxon ethyl pesticide, respectively. For both target analytes, the activated electrode demonstrates high electrocatalytic activity and achieves a very LOD of 0.38 µM for nitrite and 1.35 nM for ethyl paraxon with a broad linear range. The sensor was validated in real samples for both contaminants. Overall, the research demonstrates an innovative technique to improve the performance of AS-BioC to use as a modifier material for electrochemical sensors. Full article
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18 pages, 18979 KiB  
Article
Friction Stir Processed AA5754-Al2O3 Nanocomposite: A Study on Tribological Characteristics
by M. Nafea M. Rohim, Mahmoud E. Abdullah, Moustafa M. Mohammed, Andrzej Kubit and Hamed Aghajani Derazkola
J. Compos. Sci. 2024, 8(6), 216; https://doi.org/10.3390/jcs8060216 - 7 Jun 2024
Cited by 3 | Viewed by 1320
Abstract
This study investigates the tribological properties of an AA 5754 aluminum alloy composite reinforced with the nanopowder of Al2O3, fabricated using the friction stir processing (FSP) technique with blind holes. The aim is to analyze the effects of varying [...] Read more.
This study investigates the tribological properties of an AA 5754 aluminum alloy composite reinforced with the nanopowder of Al2O3, fabricated using the friction stir processing (FSP) technique with blind holes. The aim is to analyze the effects of varying the tool rotational speed (rpm) and blind hole diameter on the wear and friction behavior of the produced composite. A pin-on disk test is conducted under dry conditions and room temperature to assess the tribological properties against steel. Scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS) is employed to examine the worn and wear surfaces of the produced composites post test. The results indicate that increasing the applied load results in a decrease in the coefficient of friction (COF), with values ranging from 0.775 to 0.852 for 10 N and 0.607 to 0.652 for 20 N. Moreover, the wear rate diminishes with higher Al2O3 content and optimal FSP tool rotation (1280 rpm). Hardness analysis reveals variations between 33–42 HV and 35–39 HV, influenced by nanoparticle distribution. The composite demonstrates superior wear resistance compared to raw AA5754 aluminum due to its reinforced nature. However, high FSP tool rotation rates lead to abrasive wear and surface cracks. These findings offer insights into optimizing FSP parameters to enhance the tribological performance of nano-reinforced aluminum alloys. Full article
(This article belongs to the Special Issue Metal Composites, Volume II)
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28 pages, 5234 KiB  
Review
Mechanical Performance of Recycled 3D Printed Sustainable Polymer-Based Composites: A Literature Review
by Ioannis Filippos Kyriakidis, Nikolaos Kladovasilakis, Eleftheria Maria Pechlivani and Konstantinos Tsongas
J. Compos. Sci. 2024, 8(6), 215; https://doi.org/10.3390/jcs8060215 - 7 Jun 2024
Cited by 8 | Viewed by 4050
Abstract
The development of efficient waste valorization strategies has emerged as an important field in the overall efforts for alignment with the environmental goals that have been set by the European Union (EU) Green Deal regarding the development of sustainable circular economy models. Additive [...] Read more.
The development of efficient waste valorization strategies has emerged as an important field in the overall efforts for alignment with the environmental goals that have been set by the European Union (EU) Green Deal regarding the development of sustainable circular economy models. Additive manufacturing has emerged as a sustainable method for secondary life product development with the main advantages of it being a form of net-zero waste production and having the ability to successfully transport complex design to actual products finding applications in the industry for rapid prototyping or for tailored products. The insertion of eco-friendly sustainable materials in these processes can lead to significant reduction in material footprints and lower energy demands for the manufacturing process, helping achieve Sustainable Development Goal 12 (SDG12) set by the EU for responsible production and consumption. The aim of this comprehensive review is to state the existing progress regarding the incorporation of sustainable polymeric composite materials in additive manufacturing (AM) processes and identify possible gaps for further research. In this context, a comprehensive presentation of the reacquired materials coming from urban and industrial waste valorization processes and that are used to produce sustainable composites is made. Then, an assessment of the printability and the mechanical response of the constructed composites is made, by taking into consideration some key thermal, rheological and mechanical properties (e.g., viscosity, melting and degradation temperature, tensile and impact strength). Finally, existing life cycle analysis results are presented regarding overall energy demands and environmental footprint during the waste-to-feedstock and the manufacturing processes. A lack of scientific research was observed, regarding the manifestation of novel evaluation techniques such as dynamic mechanical analysis and impact testing. Assessing the dynamic response is vital for evaluating whether these types of composites are adequate for upscaling and use in real life applications. Full article
(This article belongs to the Special Issue Recycled Polymer Composites: Futuristic Sustainable Material)
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18 pages, 2970 KiB  
Article
A Study of the Moisture Absorption Characteristics of Vinyl Ester Polymer and Unidirectional Glass Fibre Vinyl Ester Laminates
by James Thomason and Georgios Xypolias
J. Compos. Sci. 2024, 8(6), 214; https://doi.org/10.3390/jcs8060214 - 7 Jun 2024
Cited by 1 | Viewed by 1645
Abstract
Vinyl esters are increasingly being used as the matrix polymer in fibre-reinforced composites for demanding large applications which experience long-term exposure to moist and wet conditions. This paper presents the results of a study of ageing due to moisture absorption in vinyl ester [...] Read more.
Vinyl esters are increasingly being used as the matrix polymer in fibre-reinforced composites for demanding large applications which experience long-term exposure to moist and wet conditions. This paper presents the results of a study of ageing due to moisture absorption in vinyl ester polymer and glass fibre–vinyl ester laminates. The moisture uptake kinetics of the two neat VE polymers, cured at different conditions, and their glass-reinforced composites has been characterised by gravimetric methods. These studies have been carried out using submersion in water at 23 °C and 50 °C and exposure to high relative humidity moisture conditions at room temperature. A dynamic mechanical analysis characterisation of the glass transition temperatures of both the aged matrix and the composite is also presented. Full article
(This article belongs to the Special Issue Polymer Composites and Fibers, Volume II)
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14 pages, 27807 KiB  
Article
Development of High-Sensitivity Thermoplastic Polyurethane/Single-Walled Carbon Nanotube Strain Sensors through Solution Electrospinning Process Technique
by Athanasios Kotrotsos, Nikolaos Syrmpopoulos, Prokopios Gavathas, Sorina Moica and Vassilis Kostopoulos
J. Compos. Sci. 2024, 8(6), 213; https://doi.org/10.3390/jcs8060213 - 6 Jun 2024
Cited by 2 | Viewed by 2197
Abstract
In this study, nanofibers obtained through the electrospinning process are explored for strain-sensing applications. Thermoplastic polyurethane (TPU) flexible structures were fabricated using the solution electrospinning process (SEP) technique. Subsequently, these structures were nanomodified with single-walled carbon nanotubes (SWCNTs) through immersion into an ultrasonicated [...] Read more.
In this study, nanofibers obtained through the electrospinning process are explored for strain-sensing applications. Thermoplastic polyurethane (TPU) flexible structures were fabricated using the solution electrospinning process (SEP) technique. Subsequently, these structures were nanomodified with single-walled carbon nanotubes (SWCNTs) through immersion into an ultrasonicated suspension containing 0.3 wt% SWCNTs. The nanomodification aimed to impart an electrically conductive network to the structures. Micro-tensile tests and electrical resistance measurements were conducted to characterize the apparent mechanical and electrical properties, respectively. The fabricated structures demonstrated potential as wearable strain sensors for monitoring changes in strain across various applications. The samples exhibited excellent performance, high sensitivity, outstanding mechanical properties, and a broad stretching range. Scanning electron microscopy (SEM) observations provided qualitative insights into the activated conductive pathways during operation. Full article
(This article belongs to the Special Issue Progress in Polymer Composites, Volume III)
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18 pages, 8257 KiB  
Article
Gypsum–Cement–Pozzolan Composites for 3D Printing: Properties and Life Cycle Assessment
by Genadijs Sahmenko, Liga Puzule, Alise Sapata, Peteris Slosbergs, Girts Bumanis, Maris Sinka and Diana Bajare
J. Compos. Sci. 2024, 8(6), 212; https://doi.org/10.3390/jcs8060212 - 6 Jun 2024
Cited by 2 | Viewed by 1981
Abstract
Over the past decade, 3D printing with concrete has been widely adopted worldwide. The primary drivers for this innovation are the reduction in manual labor and the more efficient use of natural resources. New materials that are suitable for 3D printing are developed, [...] Read more.
Over the past decade, 3D printing with concrete has been widely adopted worldwide. The primary drivers for this innovation are the reduction in manual labor and the more efficient use of natural resources. New materials that are suitable for 3D printing are developed, which are characterized by rapid setting and robust physical and mechanical properties. In this study, for the first time, ternary gypsum–cement–pozzolanic (GCP) composites were developed and evaluated for use in 3D printing. These composites are associated with durability in water as Portland cement (PC) while maintaining the rapid hardening properties of gypsum. Two types of secondary gypsum—recycled plasterboard gypsum (RG) and phosphogypsum (PG)—were used as the calcium hemihydrate component. The compressive strength test showed that 37 MPa can be achieved, which is comparable to that of traditional PC-based 3D printable mixtures. For the first time in a 3D print test, it was experimentally proved that GCP mixtures have good stability and buildability up to 35 layers. According to Life Cycle Analysis, elaborated material gives a carbon footprint reduction of up to 40%, compared to traditional PC mortar, thus supporting the sustainable use of this innovative composite. Full article
(This article belongs to the Special Issue 3D Printing Composites)
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16 pages, 7979 KiB  
Article
Physical, Mechanical and Microstructural Characteristics of Perlite-Based Geopolymers Modified with Mineral Additives
by Natalia I. Kozhukhova, Roman A. Glazkov, Marina S. Ageeva, Marina I. Kozhukhova, Ivan S. Nikulin and Irina V. Zhernovskaya
J. Compos. Sci. 2024, 8(6), 211; https://doi.org/10.3390/jcs8060211 - 4 Jun 2024
Cited by 2 | Viewed by 1307
Abstract
One of the promising raw materials for the synthesis of geopolymers is perlite, which is a natural low-calcium aluminosilicate. This research studied the physical, mechanical and microstructural characteristics of perlite-based geopolymers modified with different mineral additives that were prepared using different methods of [...] Read more.
One of the promising raw materials for the synthesis of geopolymers is perlite, which is a natural low-calcium aluminosilicate. This research studied the physical, mechanical and microstructural characteristics of perlite-based geopolymers modified with different mineral additives that were prepared using different methods of introducing the alkali components and curing conditions. The experimental results of the consolidated perlite-based geopolymer pastes showed that curing conditions and the method of introducing the alkali component into the geopolymer matrix had a minimal effect on the average density while demonstrating a significant boost in compressive strength. So, after thermal treatment, the compressive strength increased by 0.63 to 11.4 times for the mixes when fresh alkali solution was used and by 0.72 to 12.8 times for the mixes with the 24 h conditioned alkali solution. Maximum-strength spikes from 1.1 MPa to 13.2 MPa and from 0.7 MPa to 9.7 MPa were observed for the mixes with kaolin when prepared with fresh and conditioned alkali solutions, respectively. It was also observed that thermal treatment facilitates the compaction of the matrix structure by 18% and 1% for the non-modified mix and the mix modified with Portland cement. Perlite-based geopolymers modified with Portland cement and citrogypsum demonstrated a significant reduction in the initial and final setting times with both methods of introducing the alkali solution. On the surface of mixes modified with citrogypsum, regardless of the curing conditions and method of introducing the alkali component, an efflorescence substance was observed. The microstructural analysis of the consolidated geopolymer perlite-based pastes containing citrogypsum demonstrated a loose structure and the presence of efflorescence, which can be associated with a retardation in interaction processes between alkali cations and the aluminosilicate component. EDS analysis demonstrated that the presence of such elements as oxygen, sodium and sulfur may indicate the efflorescence of unreacted sodium hydroxide (NaOH), citrogypsum (CaSO4) and the products of their interaction in the form of crystalline hydrates of sodium sulfate (Na2SO4). Full article
(This article belongs to the Special Issue Characterization and Modelling of Composites, Volume III)
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13 pages, 5291 KiB  
Article
Multi-Objective Optimization of Novel Aluminum Welding Fillers Reinforced with Niobium Diboride Nanoparticles
by Andrés F. Calle-Hoyos, Norman A. Burgos-León, Luisa I. Feliciano-Cruz, David Florián-Algarín, Christian Vázquez Rivera, Jorge D. De Jesús-Silva and Oscar Marcelo Suárez
J. Compos. Sci. 2024, 8(6), 210; https://doi.org/10.3390/jcs8060210 - 4 Jun 2024
Cited by 1 | Viewed by 1368
Abstract
New and innovative technologies have expanded the quality and applications of aluminum welding in the maritime, aerospace, and automotive industries. One such technology is the addition of nanoparticles to aluminum matrices, resulting in improved strength, operating temperature, and stiffness. Furthermore, researchers continue to [...] Read more.
New and innovative technologies have expanded the quality and applications of aluminum welding in the maritime, aerospace, and automotive industries. One such technology is the addition of nanoparticles to aluminum matrices, resulting in improved strength, operating temperature, and stiffness. Furthermore, researchers continue to assess pertinent factors that improve the microstructure and mechanical characteristics of aluminum welding by enabling the optimization of the manufacturing process. Hence, this research explores alternatives, namely cost-effective aluminum welding fillers reinforced with niobium diboride nanoparticles. The goal has been to improve weld quality by employing multi-objective optimization, attained through a central composite design with a response surface model. The model considered three factors: the amount (weight percent) of nanoparticles, melt stirring speed, and melt stirring time. Filler hardness and porosity percentage served as response variables. The optimal parameters for manufacturing this novel filler for the processing conditions studied are 2% nanoparticles present in a melt stirred at 750 rpm for 35.2 s. The resulting filler possessed a 687.4 MPA Brinell hardness and low porosity, i.e., 3.9%. Overall, the results prove that the proposed experimental design successfully identified the optimal processing factors for manufacturing novel nanoparticle-reinforced fillers with improved mechanical properties for potential innovative applications across diverse industries. Full article
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12 pages, 2192 KiB  
Article
Effects of Nanofillers and Synergistic Action of Carbon Black/Nanoclay Hybrid Fillers in Chlorobutyl Rubber
by Tomy Muringayil Joseph, Hanna J. Maria, Martin George Thomas, Józef T. Haponiuk and Sabu Thomas
J. Compos. Sci. 2024, 8(6), 209; https://doi.org/10.3390/jcs8060209 - 3 Jun 2024
Viewed by 1669
Abstract
Nanocomposites based on chlorobutyl rubber (CIIR) have been made using a variety of nanofillers such as carbon black (CB), nanoclay (NC), graphene oxide (GO), and carbon black/nanoclay hybrid filler systems. The hybrid combinations of CB/nanoclay are being employed in the research to examine [...] Read more.
Nanocomposites based on chlorobutyl rubber (CIIR) have been made using a variety of nanofillers such as carbon black (CB), nanoclay (NC), graphene oxide (GO), and carbon black/nanoclay hybrid filler systems. The hybrid combinations of CB/nanoclay are being employed in the research to examine the additive impacts on the final characteristics of nanocomposites. Atomic force microscopy (AFM), together with resistivity values and mechanical property measurements, have been used to characterise the structural composition of CIIR-based nanocomposites. AFM results indicate that the addition of nanoclay into CIIR increased the surface roughness of the material, which made the material more adhesive. The study found a significant decrease in resistivity in CIIR–nanoclay-based composites and hybrid compositions with nanoclay and CB. The higher resistivity in CB composites, compared to CB/nanoclay, suggests that nanoclay enhances the conductive network of carbon black. However, GO-incorporated composites failed to create conductive networks, which this may have been due to the agglomeration. The study also found that the modulus values at 100%, 200%, and 300% elongation are the highest for clay and CB/clay systems. The findings show that nanocomposites, particularly clay and clay/CB hybrid nanocomposites, may produce polymer nanocomposites with high electrical conductivity. Mechanical properties correlated well with the reinforcement provided by nanoclay. Hybrid nanocomposites with clay/CB had increased mechanical properties because of their enhanced compatibility and higher filler–rubber interaction. Nano-dispersed clay helps prevent fracture growth and enhances mechanical properties even more so than CB. Full article
(This article belongs to the Special Issue Characterization of Polymer Nanocomposites)
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21 pages, 3120 KiB  
Review
Anthranilic Acid: A Versatile Monomer for the Design of Functional Conducting Polymer Composites
by Rachel McCormick, Emily Buckley, Paul J. Donnelly, Victoria Gilpin, Regan McMath, Robert B. Smith, Pagona Papakonstantinou and James Davis
J. Compos. Sci. 2024, 8(6), 208; https://doi.org/10.3390/jcs8060208 - 3 Jun 2024
Cited by 1 | Viewed by 1740
Abstract
Polyaniline has been utilized in various applications, yet its widespread adoption has often been impeded by challenges. Composite systems have been proposed as a means of mitigating some of these limitations, and anthranilic acid (2-aminobenzoic acid) has emerged as a possible moderator for [...] Read more.
Polyaniline has been utilized in various applications, yet its widespread adoption has often been impeded by challenges. Composite systems have been proposed as a means of mitigating some of these limitations, and anthranilic acid (2-aminobenzoic acid) has emerged as a possible moderator for use in co-polymer systems. It offers improved solubility and retention of electroactivity in neutral and alkaline media, and, significantly, it can also bestow chemical functionality through its carboxylic acid substituent, which can greatly ease post-polymer modification. The benefits of using anthranilic acid (as a homopolymer or copolymer) have been demonstrated in applications including corrosion protection, memory devices, photovoltaics, and biosensors. Moreover, this polymer has been used as a versatile framework for the sequestration of metal ions for water treatment, and, critically, these same mechanisms serve as a facile route for the production of catalytic metallic nanoparticles. However, the widespread adoption of polyanthranilic acid has been limited, and the aim of the present narrative review is to revisit the early promise of anthranilic acid and assess its potential future use within modern smart materials. A critical evaluation of its properties is presented, and its versatility as both a monomer and a polymer across a spectrum of applications is highlighted. Full article
(This article belongs to the Special Issue Advanced Conductive Polymer Composites, Volume II)
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19 pages, 28912 KiB  
Article
Multifunctional Anatase–Silica Photocatalytic Material for Cements and Concretes
by Valeria Strokova, Yulia Ogurtsova, Ekaterina Gubareva, Sofya Nerovnaya and Marina Antonenko
J. Compos. Sci. 2024, 8(6), 207; https://doi.org/10.3390/jcs8060207 - 31 May 2024
Viewed by 963
Abstract
The purpose of this research was to study the influence of multifunctional anatase–silica photocatalytic materials (ASPMs) with various photocatalytic and pozzolanic activities on the properties of white portland cement and fine-grained concrete. ASPMs were synthesized by a sol–gel method, during which the levels [...] Read more.
The purpose of this research was to study the influence of multifunctional anatase–silica photocatalytic materials (ASPMs) with various photocatalytic and pozzolanic activities on the properties of white portland cement and fine-grained concrete. ASPMs were synthesized by a sol–gel method, during which the levels of photocatalytic and pozzolanic activity were regulated by a certain amount of solvent. ASPMb, obtained with the use of a smaller amount of solvent, was characterized by increased pozzolanic activity due to the lower degree of coating of the surface of diatomite particles with titanium dioxide and the higher content of an opal–cristobalite–tridymite-phase and Bronsted acid sites. They promoted the reaction of diatomite with portlandite of cement stone and allowed significant decreases in the strength of cement–sand mortar to be avoided when replacing 15% of the cement with ASPMs. This allowed self-cleaning fine-grained concrete to be produced, which, after forced carbonization, simulating the natural aging of the product during operation, retained the ability of self-cleaning without changes. ASPMc, produced with the use of a larger amount of solvent with a more uniform distribution of titanium dioxide on the surface of diatomite, allowed fine-grained concrete with a high self-cleaning ability to be obtained, but with a lesser manifestation of the pozzolanic effect. Full article
(This article belongs to the Special Issue Functional Composites: Fabrication and Application)
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17 pages, 5541 KiB  
Article
Experimental Characterization of Fabric-Reinforced Cementitious Matrix (FRCM) Systems Applied on Calcarenite Stone: Adoption of Non-Standard Setup for Double-Shear Bond Tests
by Maria Concetta Oddo, Liborio Cavaleri, Catherine Papanicolaou and Lidia La Mendola
J. Compos. Sci. 2024, 8(6), 206; https://doi.org/10.3390/jcs8060206 - 31 May 2024
Cited by 2 | Viewed by 1029
Abstract
The use of Fabric-Reinforced Cementitious Matrix (FRCM) systems is an innovative method for strengthening structures, particularly masonry, while addressing environmental and economic concerns. Despite their widespread use, characterizing FRCM composites poses challenges due to their complex mechanical behavior and considerable variability in properties. [...] Read more.
The use of Fabric-Reinforced Cementitious Matrix (FRCM) systems is an innovative method for strengthening structures, particularly masonry, while addressing environmental and economic concerns. Despite their widespread use, characterizing FRCM composites poses challenges due to their complex mechanical behavior and considerable variability in properties. The available standardized testing methods exhibit some inconsistencies, underscoring the need for reliable characterization procedures. This paper presents an experimental study on the bond behavior between FRCM materials and calcarenite stone using a non-standard setup for double shear bond tests. Different FRCM systems are considered, varying the matrix composition and fabric nature. The experimental results are evaluated in terms of maximum stress, slip and data dispersion, alongside comparisons with double shear tests on larger samples and single-lap shear. These findings provide insights into how the mortar nature influences the stress-slip curves, strength, ductility and failure modes. The experimental study demonstrates the repeatability and robustness, particularly in terms of peak strength, of the non-standard setup configuration utilized in the study. The study highlights the importance of reliable characterization procedures for FRCM materials, especially in bond behavior assessments, emphasizing the need for further research to enhance our understanding of their application in structural reinforcement. Full article
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26 pages, 5470 KiB  
Article
Metaheuristic Optimization of Functionally Graded 2D and 3D Discrete Structures Using the Red Fox Algorithm
by J. S. D. Gaspar, M. A. R. Loja and J. I. Barbosa
J. Compos. Sci. 2024, 8(6), 205; https://doi.org/10.3390/jcs8060205 - 30 May 2024
Cited by 2 | Viewed by 853
Abstract
The growing applicability of functionally graded materials is justified by their ability to contribute to the development of advanced solutions characterized by the material customization, through the selection of the best parameters that will confer the best mechanical behaviour for a given structure [...] Read more.
The growing applicability of functionally graded materials is justified by their ability to contribute to the development of advanced solutions characterized by the material customization, through the selection of the best parameters that will confer the best mechanical behaviour for a given structure under specific operating conditions. The present work aims to attain the optimal design solutions for a set of illustrative 2D and 3D discrete structures built from functionally graded materials using the Red Fox Optimization Algorithm, where the design variables are material parameters. From the results achieved one concludes that the optimal selection and distribution of the different materials’ mixture and the different exponents associated with the volume fraction law significantly influence the optimal responses found. To note additionally the good performance of the coupling between this optimization technique and the finite element method used for the linear static and free vibration analyses. Full article
(This article belongs to the Special Issue Characterization and Modelling of Composites, Volume III)
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44 pages, 9217 KiB  
Article
Mechanisms of Component Degradation and Multi-Scale Strategies for Predicting Composite Durability: Present and Future Perspectives
by Paulo Ricardo Ferreira Rocha, Guilherme Fonseca Gonçalves, Guillaume dos Reis and Rui Miranda Guedes
J. Compos. Sci. 2024, 8(6), 204; https://doi.org/10.3390/jcs8060204 - 30 May 2024
Cited by 2 | Viewed by 2687
Abstract
Composite materials, valued for their adaptability, face challenges associated with degradation over time. Characterising their durability through traditional experimental methods has shown limitations, highlighting the need for accelerated testing and computational modelling to reduce time and costs. This study presents an overview of [...] Read more.
Composite materials, valued for their adaptability, face challenges associated with degradation over time. Characterising their durability through traditional experimental methods has shown limitations, highlighting the need for accelerated testing and computational modelling to reduce time and costs. This study presents an overview of the current landscape and future prospects of multi-scale modelling for predicting the long-term durability of composite materials under different environmental conditions. These models offer detailed insights into complex degradation phenomena, including hydrolytic, thermo-oxidative, and mechano-chemical processes. Recent research trends indicate a focus on hygromechanical models across various materials, with future directions aiming to explore less-studied environmental factors, integrate multiple stressors, investigate emerging materials, and advance computational techniques for improved predictive capabilities. The importance of the synergistic relationship between experimental testing and modelling is emphasised as essential for a comprehensive understanding of composite material behaviour in diverse environments. Ultimately, multi-scale modelling is seen as a vital contributor to accurate predictions of environmental effects on composite materials, offering valuable insights for sustainable development across industries. Full article
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33 pages, 3395 KiB  
Review
Enhancing Hydrogels with Quantum Dots
by Hossein Omidian and Renae L. Wilson
J. Compos. Sci. 2024, 8(6), 203; https://doi.org/10.3390/jcs8060203 - 29 May 2024
Cited by 6 | Viewed by 3654
Abstract
This manuscript explores the interdisciplinary integration of quantum dot–hydrogel composites and smart materials and their applications across a spectrum of fields, including biomedical engineering, environmental sensing, and energy harvesting. It covers the synthesis of novel materials like fluorescent hydrogel nanocomposites that display enhanced [...] Read more.
This manuscript explores the interdisciplinary integration of quantum dot–hydrogel composites and smart materials and their applications across a spectrum of fields, including biomedical engineering, environmental sensing, and energy harvesting. It covers the synthesis of novel materials like fluorescent hydrogel nanocomposites that display enhanced chemical stability, mechanical strength, and thermal resistance, highlighting their utility in environmental monitoring and catalysis. In the biomedical sector, innovations include hydrogel composites for targeted drug delivery and advanced therapies such as photothermal DNA hydrogels for tumor treatment. This review also discusses the application of these materials in imaging, diagnostics, and the development of smart sensors capable of detecting various biological and environmental changes. Its scope further extends to optoelectronics and the design of energy-efficient systems, underscoring the versatile functionalities of hydrogels in modern technological applications. Challenges remain in scaling up these technologies for commercial use and ensuring their long-term stability and safety, necessitating future research focused on sustainable, scalable solutions that can be integrated into existing systems. Full article
(This article belongs to the Special Issue Hydrogel and Biomaterials)
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