High-resolution TEM (HRTEM) is a powerful tool for structure characterization. However, methylammonium lead iodide (MAPbI
3) perovskite is highly sensitive to electron beams and easily decomposes into lead iodide (PbI
2). Misidentifications, such as PbI
2 being incorrectly labeled as perovskite,
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High-resolution TEM (HRTEM) is a powerful tool for structure characterization. However, methylammonium lead iodide (MAPbI
3) perovskite is highly sensitive to electron beams and easily decomposes into lead iodide (PbI
2). Misidentifications, such as PbI
2 being incorrectly labeled as perovskite, are widely present in HRTEM characterization and would negatively affect the development of perovskite research field. Here misidentifications in MAPbI
3 perovskite are summarized, classified, and corrected based on low-dose imaging and electron diffraction (ED) simulations. Corresponding crystallographic parameters of intrinsic tetragonal MAPbI
3 and the confusable hexagonal PbI
2 are presented unambiguously. Finally, the method of proper phase identification and some strategies to control the radiation damage in HRTEM are provided. This warning paves the way to avoid future misinterpretations in HRTEM characterization of perovskite and other electron beam-sensitive materials.
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