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Review

An Overview of Electrochemical Advanced Oxidation Processes for Pesticide Removal

by
Maiara A. P. Frigulio
,
Alexandre S. Valério
and
Juliane C. Forti
*
School of Sciences and Engineering, São Paulo State University (UNESP), Tupã 17602-496, SP, Brazil
*
Author to whom correspondence should be addressed.
Processes 2025, 13(7), 2227; https://doi.org/10.3390/pr13072227
Submission received: 10 June 2025 / Revised: 4 July 2025 / Accepted: 8 July 2025 / Published: 11 July 2025
(This article belongs to the Special Issue Green Separation and Purification Processes)

Abstract

This article provides an overview of the use of electrochemical advanced oxidation processes (EAOPs) applied to the treatment of water contaminated by pesticides. Given the global increase in the use of pesticides and the ineffectiveness of conventional treatment methods, EAOPs emerge as promising alternatives. They stand out for their efficiency in the degradation of organic compounds, minimal reliance on additional chemical reagents, and minimal generation of waste. The main methods addressed include anodic oxidation, photoelectro-oxidation, electro-Fenton and photoelectro-Fenton, which use hydroxyl radicals, a potent non-selective oxidant, to mineralize pollutants. A total of 165 studies were reviewed, with emphasis on the contributions of countries such as China, Spain, Brazil, and India. Factors such as electrode type, presence of catalysts, pH, and current density influence the effectiveness of treatments. Combined processes, especially those integrating UV light and renewable sources, have proven to be more efficient. Despite challenges related to electrode cost and durability, recent advances highlight the sustainability and scalability of EAOPs for the treatment of agricultural and industrial effluents contaminated with pesticides.
Keywords: anodic oxidation; electro-Fenton; photo-electro-oxidation; photoelectro-Fenton; wastewater treatment anodic oxidation; electro-Fenton; photo-electro-oxidation; photoelectro-Fenton; wastewater treatment

Share and Cite

MDPI and ACS Style

Frigulio, M.A.P.; Valério, A.S.; Forti, J.C. An Overview of Electrochemical Advanced Oxidation Processes for Pesticide Removal. Processes 2025, 13, 2227. https://doi.org/10.3390/pr13072227

AMA Style

Frigulio MAP, Valério AS, Forti JC. An Overview of Electrochemical Advanced Oxidation Processes for Pesticide Removal. Processes. 2025; 13(7):2227. https://doi.org/10.3390/pr13072227

Chicago/Turabian Style

Frigulio, Maiara A. P., Alexandre S. Valério, and Juliane C. Forti. 2025. "An Overview of Electrochemical Advanced Oxidation Processes for Pesticide Removal" Processes 13, no. 7: 2227. https://doi.org/10.3390/pr13072227

APA Style

Frigulio, M. A. P., Valério, A. S., & Forti, J. C. (2025). An Overview of Electrochemical Advanced Oxidation Processes for Pesticide Removal. Processes, 13(7), 2227. https://doi.org/10.3390/pr13072227

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