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Article

Fractal Characteristics of Multi-Scale Pore Structure of Coal Measure Shales in the Wuxiang Block, Qinshui Basin

1
School of Ocean Sciences, China University of Geosciences (Beijing), Beijing 100083, China
2
School of Resources and Environment, Henan Polytechnic University, Jiaozuo 454003, China
*
Author to whom correspondence should be addressed.
Processes 2025, 13(10), 3214; https://doi.org/10.3390/pr13103214
Submission received: 15 September 2025 / Revised: 27 September 2025 / Accepted: 30 September 2025 / Published: 9 October 2025

Abstract

Due to the diverse origins of shale reservoirs, the coal measure shales of the Wuxiang block, Qinshui Basin typically exhibit fractal pore structures, which significantly influence shale gas occurrence and migration. Clarifying the fractal nature of pore structures is significant for the efficient development and utilization of shale gas. In this study, mercury intrusion porosimetry and liquid nitrogen adsorption experiments were conducted to develop a method that integrates pore compressibility correction and nitrogen adsorption for pore structure characterization. On this basis, this study analyzed the fractal characteristics of coal measure shale pore structures across multiple scales. The results reveal that coal measure shale pores exhibit a three-stage fractal pattern, consisting of three regions with pore diameters >65 nm (seepage pores), 6–65 nm (transition pores), and <6 nm (micropores). Samples with fractal dimensions of seepage pores (Da) exceeding 2.9 and transition pores (D1) exceeding 2.5 tend to have larger specific surface areas and more complex pore structures; this is indicated by the increased surface roughness of large-scale pores, which hinders gas seepage. Samples with lower fractal dimension of micropores (D2)—in the range of 2.2–2.8—exhibit higher micropore development, larger specific surface area, and simpler pore structures, as demonstrated by a greater number of micropores and a more uniform pore distribution, which promotes gas adsorption.
Keywords: coal measure shale; pore structure; fractal dimension; mercury intrusion porosimetry; liquid nitrogen adsorption method coal measure shale; pore structure; fractal dimension; mercury intrusion porosimetry; liquid nitrogen adsorption method

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MDPI and ACS Style

Wang, R.; Zhao, M. Fractal Characteristics of Multi-Scale Pore Structure of Coal Measure Shales in the Wuxiang Block, Qinshui Basin. Processes 2025, 13, 3214. https://doi.org/10.3390/pr13103214

AMA Style

Wang R, Zhao M. Fractal Characteristics of Multi-Scale Pore Structure of Coal Measure Shales in the Wuxiang Block, Qinshui Basin. Processes. 2025; 13(10):3214. https://doi.org/10.3390/pr13103214

Chicago/Turabian Style

Wang, Rui, and Mengyu Zhao. 2025. "Fractal Characteristics of Multi-Scale Pore Structure of Coal Measure Shales in the Wuxiang Block, Qinshui Basin" Processes 13, no. 10: 3214. https://doi.org/10.3390/pr13103214

APA Style

Wang, R., & Zhao, M. (2025). Fractal Characteristics of Multi-Scale Pore Structure of Coal Measure Shales in the Wuxiang Block, Qinshui Basin. Processes, 13(10), 3214. https://doi.org/10.3390/pr13103214

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