Hollow MFI Zeolite Supported Pt Catalysts for Highly Selective and Stable Hydrodeoxygenation of Guaiacol to Cycloalkanes
Abstract
:1. Introduction
2. Experimental Section
2.1. Catalyst Preparation
2.2. Catalyst Characterization
2.3. Catalytic Evaluation
3. Results and Discussion
3.1. Catalyst Properties
3.2. Hydrodeoxygenation of Guaiacol
4. Conclusions
Supplementary Materials
Author Contributions
Acknowledgments
Conflicts of Interest
References
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Samples | Specific Surface Area (m2·g−1) | Pore Volume (cm3·g−1) | ||||
---|---|---|---|---|---|---|
SBET a | Smicro. b | Sext. c | Vtotal d | Vmicro. b | Vmeso. e | |
cZSM-5 | 332.04 | 218.34 | 113.70 | 0.1920 | 0.1366 | 0.0554 |
S-1 | 408.85 | 289.98 | 118.87 | 0.2411 | 0.1421 | 0.0990 |
hS-1 | 372.22 | 142.03 | 230.19 | 0.2483 | 0.0715 | 0.1768 |
hZSM-5 | 386.96 | 157.88 | 229.08 | 0.2585 | 0.0804 | 0.1781 |
Samples | Si/Al a | Peak Temperature (°C) | Amount of Acid Sites (μmol·g−1) | CO Uptake (μmol·g−1) | Dispersion b (%) | |||||
---|---|---|---|---|---|---|---|---|---|---|
Peak I | Peak II | Peak III | Weak | Medium | Strong | Total | ||||
Pt/cZSM-5 | 80 | 172 | 232 | 364 | 208.03 | 72.61 | 144.1 | 424.74 | 7.98 | 15.56 |
Pt/S-1 | — | 147 | — | 329 | 32.44 | — | 19.15 | 51.59 | 6.79 | 13.24 |
Pt/hS-1 | — | 150 | — | — | 7.08 | — | — | 7.08 | 14.01 | 27.32 |
Pt/hZSM-5 | 175 | 177 | 285 | 380 | 128.37 | 43.8 | 87.75 | 259.93 | 17.36 | 33.86 |
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Niu, X.; Feng, F.; Yuan, G.; Zhang, X.; Wang, Q. Hollow MFI Zeolite Supported Pt Catalysts for Highly Selective and Stable Hydrodeoxygenation of Guaiacol to Cycloalkanes. Nanomaterials 2019, 9, 362. https://doi.org/10.3390/nano9030362
Niu X, Feng F, Yuan G, Zhang X, Wang Q. Hollow MFI Zeolite Supported Pt Catalysts for Highly Selective and Stable Hydrodeoxygenation of Guaiacol to Cycloalkanes. Nanomaterials. 2019; 9(3):362. https://doi.org/10.3390/nano9030362
Chicago/Turabian StyleNiu, Xiaopo, Fuxiang Feng, Gang Yuan, Xiangwen Zhang, and Qingfa Wang. 2019. "Hollow MFI Zeolite Supported Pt Catalysts for Highly Selective and Stable Hydrodeoxygenation of Guaiacol to Cycloalkanes" Nanomaterials 9, no. 3: 362. https://doi.org/10.3390/nano9030362