Abstract
Micro-nanobubbles have emerged as a transformative technology in mineral flotation, offering superior performance in the recovery of fine-grained minerals. Conventional flotation processes often struggle with low recovery rates due to inefficient particle–bubble interactions and the formation of slimes, which increase pulp viscosity and reduce selectivity. Micro-nanobubbles, characterized by their smaller size, larger specific surface area, and high stability, overcome these limitations by enhancing collision efficiency, promoting particle aggregation through the “bubble bridge” effect, and improving flotation recovery rates and concentrate quality. This review systematically examines the generation mechanisms of micro-nanobubbles, critically appraises their laboratory and industrial applications through specific case studies, and elucidates their fundamental roles in enhancing fine-grained mineral recovery by increasing collision-attachment efficiency and promoting hydrophobic aggregation. Additionally, the study highlights real-world application cases and discusses future directions for optimizing micro-nanobubbles flotation technology through equipment improvements, process integration, and synergies with emerging techniques. The findings underscore the potential of micro-nanobubbles to revolutionize mineral processing by increasing recovery efficiency, reducing reagent usage, and enhancing sustainability.