Petrogenesis and Tectonic Setting of the Highly Fractionated Junye Granitic Intrusion in the Yiliu Tungsten Polymetallic Deposit, Guangdong Province, South China: Constraints from Geochemistry and Sr-Nd-Pb-Hf Isotopes
Abstract
:1. Introduction
2. Geological Background
3. Sampling and Analytical Methods
3.1. Sampling
3.2. Major and Trace Elements Analyses
3.3. Bulk-Rock Sr-Nd-Pb-Hf Isotope Analyses
4. Analytical Results
4.1. Major Elements
4.2. Trace Elements
4.3. Whole-Rock Sr-Nd-Pb-Hf Isotope Compositions
5. Discussion
5.1. Genetic Type of Granites
5.2. Magma Source
5.3. Fractional Crystallization
5.4. Implications for Tectonic Setting and W-Polymetallic Mineralization
6. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample No. | JY-60-B2 | JY-60-B3 | JY-60-B5 | JY-60-B6 | JY-B6 | JY-B10 |
---|---|---|---|---|---|---|
SiO2 | 76.44 | 75.74 | 76.12 | 75.68 | 76.13 | 76.15 |
TiO2 | 0.03 | 0.05 | 0.05 | 0.05 | 0.04 | 0.06 |
Al2O3 | 12.76 | 12.80 | 12.80 | 13.00 | 12.62 | 12.62 |
Fe2O3 | 1.01 | 1.04 | 1.06 | 1.07 | 0.93 | 1.07 |
MnO | 0.04 | 0.05 | 0.06 | 0.05 | 0.04 | 0.05 |
MgO | 0.02 | 0.02 | 0.03 | 0.04 | 0.03 | 0.04 |
CaO | 0.89 | 0.92 | 0.89 | 0.95 | 0.78 | 0.95 |
Na2O | 3.48 | 3.65 | 3.56 | 3.97 | 3.70 | 3.56 |
K2O | 4.93 | 4.53 | 4.89 | 4.46 | 4.60 | 4.50 |
P2O5 | <0.01 | <0.01 | <0.01 | <0.01 | <0.01 | <0.01 |
LOI | 0.60 | 0.41 | 0.48 | 0.87 | 0.37 | 0.31 |
Total | 100.20 | 99.23 | 99.95 | 100.14 | 99.27 | 99.33 |
K2O/Na2O | 1.42 | 1.24 | 1.37 | 1.12 | 1.24 | 1.26 |
A/CNK | 1.01 | 1.02 | 1.00 | 0.99 | 1.01 | 1.01 |
DI | 94.15 | 93.76 | 94.07 | 93.89 | 94.68 | 93.58 |
Sc | 3.38 | 3.18 | 4.51 | 4.00 | 3.29 | 3.34 |
Ti | 241 | 296 | 343 | 330 | 293 | 393 |
P | 9.51 | 15.7 | 21.9 | 19.7 | 18.2 | 26.7 |
V | 0.35 | 0.65 | 0.88 | 0.98 | 0.56 | 0.68 |
Cr | 2.51 | 1.67 | 2.00 | 2.08 | 2.76 | 3.66 |
Mn | 254 | 338 | 376 | 413 | 300 | 391 |
Co | 180 | 140 | 140 | 158 | 168 | 225 |
Ni | 16.6 | 13.5 | 13.6 | 16.0 | 16.0 | 24.0 |
Cu | 1.63 | 0.54 | 0.64 | 4.29 | 0.75 | 0.86 |
Zn | 12.6 | 16.6 | 19.1 | 23.7 | 12.8 | 17.0 |
Ga | 17.6 | 18.2 | 18.1 | 19.4 | 18.0 | 17.2 |
Rb | 578 | 481 | 761 | 860 | 521 | 521 |
Sr | 23.4 | 11.1 | 18.8 | 22.0 | 20.3 | 20.0 |
Y | 73.4 | 34.1 | 63.8 | 57.1 | 34.8 | 61.8 |
Zr | 74.2 | 41.3 | 152 | 37.4 | 39.8 | 80.8 |
Nb | 22.4 | 16.2 | 22.9 | 17.6 | 13.4 | 15.9 |
Mo | 0.35 | 0.28 | 1.90 | 1.03 | 0.36 | 0.57 |
Cd | 0.02 | 0.02 | 0.05 | 0.08 | 0.02 | 0.03 |
Sn | 7.47 | 14.7 | 15.8 | 16.4 | 12.0 | 18.4 |
Sb | 0.35 | 0.74 | 0.72 | 0.82 | 1.09 | 0.80 |
Cs | 18.5 | 54.9 | 69.3 | 77.7 | 44.2 | 77.5 |
Ba | 5.08 | 1.01 | 5.69 | 5.79 | 2.40 | 2.39 |
La | 4.52 | 11.1 | 10.1 | 8.24 | 6.74 | 19.0 |
Ce | 11.0 | 25.0 | 25.4 | 20.7 | 16.2 | 48.0 |
Pr | 1.52 | 3.03 | 3.34 | 2.88 | 2.12 | 6.77 |
Nd | 6.08 | 10.5 | 12.6 | 11.0 | 7.92 | 26.8 |
Sm | 2.56 | 2.92 | 3.68 | 3.66 | 2.60 | 8.38 |
Eu | 0.09 | 0.12 | 0.23 | 0.17 | 0.10 | 0.27 |
Gd | 3.92 | 3.02 | 4.21 | 4.23 | 2.93 | 7.95 |
Tb | 0.92 | 0.59 | 0.83 | 0.85 | 0.61 | 1.45 |
Dy | 6.84 | 3.98 | 5.66 | 5.66 | 4.15 | 9.10 |
Ho | 1.70 | 0.93 | 1.32 | 1.28 | 0.96 | 1.92 |
Er | 5.85 | 3.16 | 4.35 | 4.17 | 3.14 | 5.93 |
Tm | 1.09 | 0.58 | 0.77 | 0.75 | 0.58 | 1.04 |
Yb | 8.27 | 4.41 | 5.55 | 5.38 | 4.41 | 7.48 |
Lu | 1.38 | 0.73 | 0.93 | 0.85 | 0.72 | 1.16 |
Hf | 4.13 | 2.47 | 8.20 | 2.34 | 2.50 | 3.99 |
Ta | 1.18 | 1.35 | 1.81 | 2.33 | 1.14 | 1.78 |
W | 587 | 533 | 549 | 582 | 566 | 781 |
Tl | 2.39 | 2.14 | 3.62 | 3.72 | 2.00 | 2.01 |
Pb | 64.4 | 54.5 | 62.8 | 58.3 | 56.9 | 49 |
Th | 16.2 | 30.5 | 41.3 | 33.5 | 17.6 | 46.1 |
U | 40.6 | 40.8 | 33.4 | 25.4 | 38.6 | 32.7 |
ΣREE | 55.7 | 70.1 | 79.0 | 69.8 | 53.2 | 145.3 |
LREE/HREE | 0.86 | 3.03 | 2.34 | 2.01 | 2.04 | 3.03 |
LaN/YbN | 0.39 | 1.81 | 1.31 | 1.10 | 1.10 | 1.82 |
δEu | 0.09 | 0.12 | 0.17 | 0.13 | 0.11 | 0.10 |
10,000 Ga/Al | 2.60 | 2.68 | 2.67 | 2.82 | 2.69 | 2.57 |
Sample No. | JY-60-B2 | JY-60-B3 | JY-60-B5 | JY-60-B6 | JY-B6 | JY-B10 |
---|---|---|---|---|---|---|
Rb(ppm) | 578 | 481 | 761 | 860 | 521 | 521 |
Sr(ppm) | 23.4 | 11.1 | 18.8 | 22 | 20 | 20 |
87Sr/86Sr | 0.845472 | 0.941059 | 0.946419 | 0.902160 | 0.844373 | 0.863345 |
±2σ | 0.000016 | 0.000015 | 0.000018 | 0.000011 | 0.000014 | 0.000012 |
87Rb/86Sr | 69.7185 | 122.3090 | 114.2518 | 110.3347 | 72.4399 | 73.5265 |
(87Sr/86Sr )i | 0.696814 | 0.680263 | 0.702803 | 0.666897 | 0.689912 | 0.706566 |
Sm(ppm) | 2.6 | 2.9 | 3.7 | 3.7 | 2.6 | 8.4 |
Nd(ppm) | 6.1 | 10.5 | 12.6 | 11.0 | 7.92 | 26.8 |
143Nd/144Nd | 0.512272 | 0.512192 | 0.512169 | 0.512222 | 0.512206 | 0.512182 |
±2σ | 0.000005 | 0.000005 | 0.000005 | 0.000005 | 0.000006 | 0.000005 |
147Sm/144Nd | 0.2646 | 0.1748 | 0.1836 | 0.2091 | 0.2063 | 0.1965 |
(143Nd/144Nd)i | 0.512013 | 0.512021 | 0.511988 | 0.512016 | 0.512004 | 0.511989 |
εNd(t)a | −8.44 | −8.28 | −8.91 | −8.36 | −8.61 | −8.90 |
TDM2/Ma | 1659 | 1645 | 1698 | 1652 | 1673 | 1697 |
U(ppm) | 40.6 | 40.8 | 33.4 | 25.4 | 38.6 | 32.7 |
Th(ppm) | 16.2 | 30.5 | 41.3 | 33.5 | 17.6 | 46.1 |
Pb(ppm) | 64.4 | 54.5 | 62.8 | 58.3 | 56.9 | 49.0 |
208Pb/204Pb | 39.280 | 39.431 | 39.446 | 39.432 | 39.311 | 39.640 |
±2σ | 0.0021 | 0.0019 | 0.0025 | 0.0020 | 0.0027 | 0.0055 |
207Pb/204Pb | 15.814 | 15.842 | 15.810 | 15.813 | 15.827 | 15.837 |
±2σ | 0.0007 | 0.0007 | 0.0008 | 0.0008 | 0.0007 | 0.0013 |
206Pb/204Pb | 19.617 | 20.174 | 19.614 | 19.598 | 19.902 | 20.039 |
±2σ | 0.0007 | 0.0008 | 0.0008 | 0.0009 | 0.0008 | 0.0022 |
(208Pb/204Pb)i | 39.152 | 39.145 | 39.113 | 39.141 | 39.154 | 39.159 |
(207Pb/204Pb)i | 15.767 | 15.785 | 15.770 | 15.780 | 15.776 | 15.786 |
(206Pb/204Pb)i | 18.646 | 19.010 | 18.793 | 18.926 | 18.852 | 19.000 |
176Lu/177Hf | 0.015 | 0.046 | 0.041 | 0.032 | 0.016 | 0.050 |
176Yb/177Hf | 0.439 | 1.374 | 1.225 | 1.000 | 0.464 | 1.577 |
176Hf/177Hf | 0.282565 | 0.282524 | 0.282507 | 0.282583 | 0.282598 | 0.282530 |
±2σ | 0.000003 | 0.000003 | 0.000004 | 0.000004 | 0.000004 | 0.000004 |
(176Hf/177Hf)i | 0.282435 | 0.282410 | 0.282463 | 0.282442 | 0.282485 | 0.282417 |
εHf(0) | −7.3 | −8.8 | −9.4 | −6.7 | −6.2 | −8.6 |
εHf(t)b | −8.6 | −9.5 | −7.6 | −8.4 | −6.9 | −9.3 |
TDM2/Ma | 1841 | 2153 | 1680 | 1799 | 2062 | 2214 |
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Wu, T.; Huang, Z.; Yang, M.; Zhang, D.; Zhang, J.; Wei, C. Petrogenesis and Tectonic Setting of the Highly Fractionated Junye Granitic Intrusion in the Yiliu Tungsten Polymetallic Deposit, Guangdong Province, South China: Constraints from Geochemistry and Sr-Nd-Pb-Hf Isotopes. Minerals 2020, 10, 631. https://doi.org/10.3390/min10070631
Wu T, Huang Z, Yang M, Zhang D, Zhang J, Wei C. Petrogenesis and Tectonic Setting of the Highly Fractionated Junye Granitic Intrusion in the Yiliu Tungsten Polymetallic Deposit, Guangdong Province, South China: Constraints from Geochemistry and Sr-Nd-Pb-Hf Isotopes. Minerals. 2020; 10(7):631. https://doi.org/10.3390/min10070631
Chicago/Turabian StyleWu, Tao, Zhilong Huang, Mu Yang, Dexian Zhang, Jiawei Zhang, and Chen Wei. 2020. "Petrogenesis and Tectonic Setting of the Highly Fractionated Junye Granitic Intrusion in the Yiliu Tungsten Polymetallic Deposit, Guangdong Province, South China: Constraints from Geochemistry and Sr-Nd-Pb-Hf Isotopes" Minerals 10, no. 7: 631. https://doi.org/10.3390/min10070631