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Paper Electrodes Coated with Partially-Exfoliated Graphite and Polypyrrole for High-Performance Flexible Supercapacitors

State Key Laboratory for Hubei New Textile Materials and Advanced Processing Technology, School of Materials Science & Engineering, Wuhan Textile University, Wuhan 430200, China
School of Textile Science & Engineering, Wuhan Textile University, Wuhan 430200, China
Authors to whom correspondence should be addressed.
Polymers 2018, 10(2), 135;
Received: 11 December 2017 / Revised: 25 January 2018 / Accepted: 25 January 2018 / Published: 31 January 2018
(This article belongs to the Special Issue Soft Materials and Systems)
PDF [5374 KB, uploaded 31 January 2018]


Flexible paper electrodes for supercapacitors were prepared with partially-exfoliated graphite and polypyrrole as the active materials. Graphite was coated on paper with pencil drawing and then electrochemically exfoliated using the cyclic voltammetry (CV) technique to obtain the exfoliated graphite (EG)-coated paper (EG-paper). Polypyrrole (PPy) doped with β-naphthalene sulfonate anions was deposited on EG-paper through in-situ polymerization, leading to the formation of PPy-EG-paper. The as-prepared PPy-EG-paper showed a high electrical conductivity of 10.0 S·cm−1 and could be directly used as supercapacitor electrodes. The PPy-EG-paper electrodes gave a remarkably larger specific capacitance of 2148 F∙g−1 at a current density of 0.8 mA∙cm−2, compared to PPy-graphite-paper (848 F∙g−1). The capacitance value of PPy-EG-paper could be preserved by 80.4% after 1000 charge/discharge cycles. In addition, the PPy-EG-paper electrodes demonstrated a good rate capability and a high energy density of 110.3 Wh∙kg−1 at a power density of 121.9 W∙kg−1. This work will pave the way for the discovery of efficient paper-based electrode materials. View Full-Text
Keywords: paper; polypyrrole; partially-exfoliated graphite; supercapacitor paper; polypyrrole; partially-exfoliated graphite; supercapacitor

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Huang, L.; Rao, W.; Fan, L.; Xu, J.; Bai, Z.; Xu, W.; Bao, H. Paper Electrodes Coated with Partially-Exfoliated Graphite and Polypyrrole for High-Performance Flexible Supercapacitors. Polymers 2018, 10, 135.

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