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Polymers 2018, 10(12), 1311; https://doi.org/10.3390/polym10121311

Fluorinated and Bio-Based Polyamides with High Transparencies and Low Yellowness Index

1
Graduate School of Advanced Science and Technology, Energy and Environment Area, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Nomi, Ishikawa 923-1292, Japan
2
Japan Science and Technology, JST ALCA, Tokyo 102-0076, Japan
*
Author to whom correspondence should be addressed.
Received: 31 October 2018 / Revised: 22 November 2018 / Accepted: 22 November 2018 / Published: 27 November 2018
(This article belongs to the Special Issue Aromatic Polymers)
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Abstract

Bio-based polyamides with high transparency and low yellowness were synthesized using 4,4′-bis(trifluoroacetamido)-α-truxillic acid (ATA-F1) and 4,4′-bis(pentafluoropropionamido)-α-truxillic acid (ATA-F2) as a fluoroalkylated aromatic dicarboxylic acid, and various aromatic diamines. The introduction of fluorine side chains improved the transparency of the polyamide film, and suppressed its yellowness. On the other hand, water repellency, which should be a general characteristic of the fluorinated polymers, was not observed. By using ATA-F1 and various aromatic diamines, aromatic and fluorinated polyamides were obtained. In addition, these also demonstrated a high transparency and a low yellowness index. The heat resistance properties of all the obtained polyamides was over 250 °C, and the characteristics of the bio-based polyamides from 4-aminocinnamic acid derivatives were retained. View Full-Text
Keywords: bio-based polymer; polyamides; fluorinated polymer; transparent materials bio-based polymer; polyamides; fluorinated polymer; transparent materials
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Takada, K.; Mae, Y.; Kaneko, T. Fluorinated and Bio-Based Polyamides with High Transparencies and Low Yellowness Index. Polymers 2018, 10, 1311.

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