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N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia
Nanotechnology Education and Research Center, South Ural State University, 454080 Chelyabinsk, Russia
Author to whom correspondence should be addressed.
Academic Editor: Bartolo Gabriele
Molbank 2021, 2021(4), M1290;
Received: 12 October 2021 / Revised: 18 October 2021 / Accepted: 19 October 2021 / Published: 21 October 2021
(This article belongs to the Special Issue Metal-Catalyzed Synthesis)
N,N-Diarylthiophen-2-amine units are of great interest for the synthesis of optoelectronic devices. In this communication, N,N-bis (4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)thiophen-2-amine was obtained by means of a Buchwald–Hartwig cross-coupling reaction of bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine and 2-bromothiophene in the presence of tris(dibenzylideneacetone)dipalladium(0), tri-tert-butyl phosphine and sodium tert-butanolate. The structure of newly synthesized compounds was established by means of elemental analysis, high-resolution mass spectrometry, 1H, 13C NMR, IR and UV spectroscopy and mass-spectrometry. View Full-Text
Keywords: donor building blocks; Buchwald–Hartwig cross-coupling reaction; triarylamines; biphenyls; 2-bromothiophene donor building blocks; Buchwald–Hartwig cross-coupling reaction; triarylamines; biphenyls; 2-bromothiophene
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MDPI and ACS Style

Chmovzh, T.N.; Rakitin, O.A. N,N-Bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)thiophen-2-amine. Molbank 2021, 2021, M1290.

AMA Style

Chmovzh TN, Rakitin OA. N,N-Bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)thiophen-2-amine. Molbank. 2021; 2021(4):M1290.

Chicago/Turabian Style

Chmovzh, Timofey N., and Oleg A. Rakitin 2021. "N,N-Bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)thiophen-2-amine" Molbank 2021, no. 4: M1290.

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