Mass Spectrometry Reveals Complexing Properties of Modified PNP-Lariat Ether Containing Benzyl Derivative of (S)–Prolinamine
Abstract
:1. Introduction
2. Results and Discussion
2.1. Investigations of Silver Ions Complexes with the Ligand
2.2. Mass Spectrometry Investigations of Ligand and Its Complexes with Ag+ Cu2+, Co2+, Ni2+, and Zn2+ Ions
3. Materials and Methods
3.1. Materials
3.1.1. For the Synthesis
3.1.2. For the NMR Measurements
3.1.3. For the Potentiometric Measurement
3.1.4. For the MS Measurements
3.2. Characterization Techniques
3.2.1. NMR Measurements
3.2.2. Elemental Analysis
3.2.3. Potentiometric Measurements
3.2.4. ESI-MSn Analyses
3.2.5. TLC Analyses
3.3. Synthesis
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Sample Availability: Samples of the compound L. are available from the authors. |
Complex Form | L | |
---|---|---|
log β in Acetonitrile | log β in Methanol | |
Ag+ + L → AgL+ | 7.12 ± 0.01 | 8.61 ± 0.01 |
AgL+ + Ag+ → Ag2L2+ | 5.94 ± 0.01 | 3.83 ± 0.01 |
Ag2L2+ + Ag+ → Ag3L3+ | 4.28 ± 0.01 | 3.41 ± 0.01 |
Ag3L3+ + Ag+ → Ag4L4+ | 3.06 ± 0.01 | 1.99 ± 0.01 |
L + M | L + 2M | L + 3M | L + 4M | L + M + NO3 | |
---|---|---|---|---|---|
Ag+ | [Ag(I)L]+ 1192.388 | [Ag(I)2L]2+ 648.966 | [Ag(I)3L]3+ 468.395 | [Ag(I)4L]4+ 378.340 | --- |
Co2+ | --- | --- | --- | --- | [Co(II)L + NO3]+ 1204.090 |
Cu2+ | --- | --- | --- | --- | [Cu(II)L + NO3]+ 1208.414 |
Ni2+ | --- | --- | --- | --- | [Ni(II)L + NO3]+ 1203.062 |
Zn2+ | --- | --- | --- | --- | [Zn(II)L + NO3]+ 1209.260 |
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Gutowska, N.; Seliger, P.; Romański, J.; Zięba, M.; Adamus, G.; Kowalczuk, M. Mass Spectrometry Reveals Complexing Properties of Modified PNP-Lariat Ether Containing Benzyl Derivative of (S)–Prolinamine. Molecules 2020, 25, 136. https://doi.org/10.3390/molecules25010136
Gutowska N, Seliger P, Romański J, Zięba M, Adamus G, Kowalczuk M. Mass Spectrometry Reveals Complexing Properties of Modified PNP-Lariat Ether Containing Benzyl Derivative of (S)–Prolinamine. Molecules. 2020; 25(1):136. https://doi.org/10.3390/molecules25010136
Chicago/Turabian StyleGutowska, Natalia, Piotr Seliger, Jarosław Romański, Magdalena Zięba, Grazyna Adamus, and Marek Kowalczuk. 2020. "Mass Spectrometry Reveals Complexing Properties of Modified PNP-Lariat Ether Containing Benzyl Derivative of (S)–Prolinamine" Molecules 25, no. 1: 136. https://doi.org/10.3390/molecules25010136