Next Article in Journal
10-Undecenoic Acid, an Inexpensive Source for the Synthesis of the Pheromones of Cotton Pests, Peach Tree Borer and Cherry Tree Borer
Previous Article in Journal
Synthesis and Reactions of Furo[2,3-b]pyrroles
Open AccessArticle

The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format

1
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, USA
2
Department of Chemistry, University of Wisconsin - River Falls 410 S. Third St., River Falls, WI 54022, USA
*
Author to whom correspondence should be addressed.
Molecules 1997, 2(5), 80-86; https://doi.org/10.3390/20500080
Received: 8 April 1997 / Accepted: 18 April 1997 / Published: 15 May 1997
Two 1,3,8,10-undecatetraenes were synthesized to test the viability of the intramolecular radical cation induced Diels-Alder reaction in the diene - diene format. Cyclization was successful only for the substituted tetraene with the lower oxidation potential. The major hexahydroindene product possessed a trans ring juncture demonstrating a selectivity for the endo stereochemistry. View Full-Text
Keywords: Radical cation; Diels-Alder reaction; intramolecular cyclization Radical cation; Diels-Alder reaction; intramolecular cyclization
Show Figures

Scheme 1

MDPI and ACS Style

Rusterholz, D.B.; Gorman, D.B.; Gassman, P.G. The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format. Molecules 1997, 2, 80-86.

Show more citation formats Show less citations formats

Article Access Map by Country/Region

1
Only visits after 24 November 2015 are recorded.
Search more from Scilit
 
Search
Back to TopTop