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Ring Expansion of Vinylaziridines through the Strain-Release Pericyclic Reaction: Recent Developments and Applications

College of Pharmacy and Research Institute of Pharmaceutical Sciences, Gyeongsang National University, Jinju daero, Jinju, Gyeongnam 660-751, Korea
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Molecules 2013, 18(8), 9650-9662; https://doi.org/10.3390/molecules18089650
Received: 23 July 2013 / Revised: 1 August 2013 / Accepted: 7 August 2013 / Published: 12 August 2013
(This article belongs to the Special Issue Bioorthogonal Chemistry)
Recent syntheses of azetidines, pyrrolidines, piperidines and azepines through cycloaddition or sigmatropic rearrangements of vinylaziridines are described. Applications to natural product synthesis and mechanistic investigations are also summarized. View Full-Text
Keywords: vinylaziridines; cycloaddition; rearrangement; ring expansion vinylaziridines; cycloaddition; rearrangement; ring expansion
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Heo, Y.M.; Paek, S.-M. Ring Expansion of Vinylaziridines through the Strain-Release Pericyclic Reaction: Recent Developments and Applications. Molecules 2013, 18, 9650-9662.

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