Search Results (286)

Ecosystem restoration represents a promising solution for enhancing ecosystem services and environmental sustainability. However, border regions—characterized by ecological fragility and geopolitical complexity—remain underrepresented in ecosystem service and restoration research. To fill this gap, we coupled spatially explicit models (e.g., InVEST and RUSLE) with scenario analysis to quantify the ecosystem service potential that could be achieved in China’s Tibetan borderlands under two interacting agendas: ecological restoration and border-strengthening policies. Restoration feasibility was evaluated through combining local biophysical constraints, economic viability (via restoration-induced carbon gains vs. opportunity costs), operational practicality, and simulated infrastructure expansion. The results showed that per-unit-area ecosystem services in border counties (particularly Medog, Cona, and Zayu) exceed that of interior Tibet by a factor of two to four. Combining these various constraints, approximately 4–17% of the border zone remains cost-effective for grassland or forest restoration. Under low carbon pricing (US$10 t⁻¹ CO₂), the carbon revenue generated through restoration is insufficient to offset the opportunity cost of agricultural production, constituting a major constraint. Habitat quality, soil conservation, and carbon sequestration increase modestly when induced by restoration, but a pronounced carbon–water trade-off emerges. Planned infrastructure reduces restoration benefits only slightly, whereas raising the carbon price to about US$50 t⁻¹ CO₂ substantially expands such benefits. These findings highlight both the opportunities and limits of ecosystem restoration in border regions and point to carbon pricing as the key policy lever for unlocking cost-effective restoration. Full article

This study optimizes the production of activated carbons from hydrothermally carbonized (HTC) biomass using potassium hydroxide (KOH) and phosphoric acid (H₃PO₄) as activating agents. A 2³ factorial experimental design evaluated the effects of agent-to-precursor ratio, dry impregnation time, and activation duration on mass yield and iodine adsorption capacity. KOH-activated carbons achieved superior iodine numbers (up to 1289 mg/g) but lower mass yields (18–35%), reflecting enhanced porosity at the cost of material loss. Conversely, H₃PO₄ activation yielded higher mass retention (up to 54.86%) with moderate iodine numbers (up to 1117.3 mg/g), balancing porosity and yield. HTC pretreatment at 190 °C reduced the ash content, thereby enhancing the stability of hydrochar. These findings highlight the trade-offs between adsorption performance and process efficiency, with KOH suited for high-porosity applications (e.g., water purification) and H₃PO₄ for industrial scalability. The study advances biomass waste valorization, aligning with circular economy principles and offering sustainable solutions for environmental and industrial applications, such as water purification and energy storage. Full article

An in-depth understanding of the spatiotemporal heterogeneity of ecosystem service (ES) trade-offs and synergies, along with their driving factors, is crucial for formulating key ecological restoration strategies and effectively allocating ecological environmental resources in the Hulunbuir region. This study employed an integrated analytical approach combining the InVEST model, ArcGIS geospatial processing, R software environment, and Optimal Parameter Geographical Detector (OPGD). The spatiotemporal patterns and driving factors of the interaction of four major ES functions in Hulunbuir area from 2000 to 2020 were studied. The research findings are as follows: (1) carbon storage (CS) and soil conservation (SC) services in the Hulunbuir region mainly show a distribution pattern of high values in the central and northeast areas, with low values in the west and southeast. Water yield (WY) exhibits a distribution pattern characterized by high values in the central–western transition zone and southeast and low values in the west. For forage supply (FS), the overall pattern is higher in the west and lower in the east. (2) The trade-off relationships between CS and WY, CS and SC, and SC and WY are primarily concentrated in the western part of Hulunbuir, while the synergistic relationships are mainly observed in the central and eastern regions. In contrast, the trade-off relationships between CS and FS, as well as FS and WY, are predominantly located in the central and eastern parts of Hulunbuir, with the intensity of these trade-offs steadily increasing. The trade-off relationship between SC and FS is almost widespread throughout HulunBuir. (3) Fractional vegetation cover, mean annual precipitation, and land use type were the primary drivers affecting ESs. Among these factors, fractional vegetation cover demonstrates the highest explanatory power, with a q-value between 0.6 and 0.9. The slope and population density exhibit relatively weak explanatory power, with q-values ranging from 0.001 to 0.2. (4) The interactions between factors have a greater impact on the inter-relationships of ESs in the Hulunbuir region than individual factors alone. The research findings have facilitated the optimization and sustainable development of regional ES, providing a foundation for ecological conservation and restoration in Hulunbuir. Full article

The spatial variation of forest ecosystem services at regional scales remains poorly understood, and few studies have explicitly analyzed how ecosystem services are distributed across different forest management types. This study assessed the spatial overlap between forest management types and ecosystem service hotspots in the Southeastern United States (SEUS) and the Pacific Northwest (PNW) forests. We used the InVEST suite of tools and GIS to quantify carbon storage and water yield. Carbon storage was estimated, stratified by forest group and age class, and literature-based biomass pool values were applied. Average annual water yield and its temporal changes (2001–2020) were modeled using the annual water yield model, incorporating precipitation, potential evapotranspiration, vegetation type, and soil characteristics. Ecosystem service outputs were classified to identify hotspot zones (top 20%) and to evaluate the synergies and tradeoffs between these services. Hotspots were then overlaid with forest management maps to examine their distribution across management types. We found that only 2% of the SEUS and 11% of the PNW region were simultaneous hotspots for both services. In the SEUS, ecological and preservation forest management types showed higher efficiency in hotspot allocation, while in PNW, production forestry contributed relatively more to hotspot areas. These findings offer valuable insights for decision-makers and forest managers seeking to preserve the multiple benefits that forests provide at regional scales. Full article

Situated in the southern hilly-mountain belt of China’s “Three Zones and Four Belts Strategy”, Gannan region is a critical ecological shelter belt for the Ganjiang River. Decades of intensive mineral extraction and irrational agricultural development have rendered it into an ecologically fragile area. Consequently, multiple restoration initiatives have been implemented in the region over recent decades. However, it remains unclear how relationships among ecosystem services have evolved under these interventions and how future ecosystem management should be optimized based on these changes. Thus, in this study, we simulated and assessed the spatiotemporal dynamics of five key ESs in Gannan region from 1990 to 2020. Through integrated correlation, clustering, and redundancy analyses, we quantified ES interactions, tracked the evolution of ecosystem service bundles (ESBs), and identified their socio-ecological drivers. Despite a 31% decline in water yield, ecological restoration initiatives drove substantial improvements in key regulating services: carbon storage increased by 6.9 × 10¹² gC while soil conservation rose by 4.8 × 10⁸ t. Concurrently, regional habitat quality surged by 45% in mean scores, and food production increased by 2.1 × 10⁵ t. Critically, synergistic relationships between habitat quality, soil retention, and carbon storage were progressively strengthened, whereas trade-offs between food production and habitat quality intensified. Further analysis revealed that four distinct ESBs—the Agricultural Production Bundle (APB), Urban Development Bundle (UDB), Eco-Agriculture Transition Bundle (ETB), and Ecological Protection Bundle (EPB)—were shaped by slope, forest cover ratio, population density, and GDP. Notably, 38% of the ETB transformed into the EPB, with frequent spatial interactions observed between the APB and UDB. These findings underscore that future ecological restoration and conservation efforts should implement coordinated, multi-service management mechanisms. Full article

Hydrogen production is increasingly vital for global decarbonization but remains a water- and energy-intensive process, especially in arid regions. Despite growing attention to its climate benefits, limited research has addressed the environmental impacts of water sourcing. This study employs a life cycle assessment (LCA) approach to evaluate three water supply strategies for hydrogen production: (1) seawater desalination without brine treatment (BT), (2) desalination with partial BT, and (3) freshwater purification. Scenarios are modeled for the United Arab Emirates (UAE), Australia, and Spain, representing diverse electricity mixes and water stress conditions. Both electrolysis and steam methane reforming (SMR) are evaluated as hydrogen production methods. Results show that desalination scenarios contribute substantially to human health and ecosystem impacts due to high energy use and brine discharge. Although partial BT aims to reduce direct marine discharge impacts, its substantial energy demand can offset these benefits by increasing other environmental burdens, such as marine eutrophication, especially in regions reliant on carbon-intensive electricity grids. Freshwater scenarios offer lower environmental impact overall but raise water availability concerns. Across all regions, feedwater for SMR shows nearly 50% lower impacts than for electrolysis. This study focuses solely on the environmental impacts associated with water sourcing and treatment for hydrogen production, excluding the downstream impacts of the hydrogen generation process itself. This study highlights the trade-offs between water sourcing, brine treatment, and freshwater purification for hydrogen production, offering insights for optimizing sustainable hydrogen systems in water-stressed regions. Full article

This study utilises the Open Source Energy Modelling System (OSeMOSYS) in conjunction with the Climate, Land, Energy, and Water systems (CLEWs) framework to investigate Thailand’s energy transition, which is designed to achieve carbon neutrality by 2050. Two scenarios have been devised to evaluate the long-term trade-offs among energy, water, and land systems. Data were sourced from esteemed international organisations (e.g., the IEA, FAO, and OECD) and national agencies and organised into a tailored OSeMOSYS Starter Data Kit for Thailand, comprising a baseline and a carbon neutral trajectory. The baseline scenario, primarily reliant on fossil fuels, is projected to generate annual CO₂ emissions exceeding 400 million tons and water consumption surpassing 85 billion cubic meters by 2025. By the mid-century, the carbon neutral scenario will have approximately 40% lower water use and a 90% reduction in power sector emissions. Under the carbon neutral path, renewable energy takes the front stage; the share of renewable electricity goes from under 20% in the baseline scenario to almost 80% by 2050. This transition and large reforestation initiatives call for consistent investment in solar energy (solar energy expenditures exceeding 20 billion USD annually by 2025). Still, it provides notable co-benefits, including greater resource sustainability and better alignment with international climate targets. The results provide strategic insights aligned with Thailand’s National Energy Plan (NEP) and offer modelling evidence toward achieving international climate goals under COP29. Full article

(1) Background: Wetlands are ecologically significant ecosystems that support biodiversity and contribute to essential environmental functions such as water purification, carbon storage and flood regulation. However, these ecosystems face increasing pressures from land-use change and degradation, prompting the need for scalable and accurate classification methods to support conservation and policy efforts. In this research, our motivation was to test whether high-spatial-resolution PlanetScope imagery can be used with pixel-based machine learning to support the mapping and monitoring of wetlands at a national scale. (2) Methods: This study compared four machine learning classification models—Random Forest (RF), XGBoost (XGB), Histogram-Based Gradient Boosting (HGB) and a Multi-Layer Perceptron Classifier (MLPC)—to detect and map wetland areas across New Zealand. All models were trained using eight-band SuperDove satellite imagery from PlanetScope, with a spatial resolution of ~3 m, and ancillary geospatial datasets representing topography and soil drainage characteristics, each of which is available globally. (3) Results: All four machine learning models performed well in detecting wetlands from SuperDove imagery and environmental covariates, with varying strengths. The highest accuracy was achieved using all eight image bands alongside features created from supporting geospatial data. For binary wetland classification, the highest F1 scores were recorded by XGB (0.73) and RF/HGB (both 0.72) when including all covariates. MLPC also showed competitive performance (wetland F1 score of 0.71), despite its relatively lower spatial consistency. However, each model over-predicts total wetland area at a national level, an issue which was able to be reduced by increasing the classification probability threshold and spatial filtering. (4) Conclusions: The comparative analysis highlights the strengths and trade-offs of RF, XGB, HGB and MLPC models for wetland classification. While all four methods are viable, RF offers some key advantages, including ease of deployment and transferability, positioning it as a promising candidate for scalable, high-resolution wetland monitoring across diverse ecological settings. Further work is required for verification of small-scale wetlands (<~0.5 ha) and the addition of fine-spatial-scale covariates. Full article

Elucidating the trade-offs and synergies among ecosystem services is crucial for effective ecosystem management and the promotion of sustainable development in specific regions. The Hexi Corridor, a vital agricultural hub in Northwest China, is instrumental in both ecological conservation and socioeconomic advancement throughout the area. Utilizing an integrated “water–soil–carbon–grain” framework, this study conducted a quantitative assessment of four essential ecosystem services within the Hexi Corridor from 2000 to 2020: water yield, soil conservation, vegetation carbon sequestration, and grain production. Our research thoroughly explores the equilibrium and synergistic interactions between grain production and other ecosystem services, while also exploring potential strategies to boost grain yields through the precise management of these services. The insights garnered are invaluable for strategic regional development and will contribute to the revitalization efforts in Northwest China. Key findings include the following: (1) between 2000 and 2020, grain production exhibited a steady increase, alongside rising trends in water yields, soil conservation, and carbon sequestration, all of which demonstrated significant synergies with agricultural productivity; (2) in areas identified as grain production hotspots, there were stronger positive correlations between grain output and carbon sequestration services, soil conservation, and water yields than the regional averages, suggesting more pronounced mutual benefits; (3) the implementation of strategic initiatives such as controlling soil erosion, expanding afforestation efforts, and enhancing water-saving irrigation infrastructure could simultaneously boost ecological services and agricultural productivity. These results significantly enhance our comprehension of the interplay between ecosystem services in the Hexi Corridor and present practical approaches for the optimization of regional agricultural systems. Full article

The growing mismatch between ecosystem service (ES) supply and demand underscores the importance of thoroughly understanding their spatiotemporal patterns and key drivers to promote ecological civilization and sustainable development at the regional level in China. This study investigates six key ES indicators across mainland China—habitat quality (HQ), carbon sequestration (CS), water yield (WY), sediment delivery ratio (SDR), food production (FP), and nutrient delivery ratio (NDR)—by integrating a suite of analytical approaches. These include a spatiotemporal analysis of trade-offs and synergies in supply, demand, and their ratios; self-organizing maps (SOM) for bundle identification; and interpretable machine learning models. While prior research studies have typically examined ES at a single spatial scale, focusing on supply-side bundles or associated drivers, they have often overlooked demand dynamics and cross-scale interactions. In contrast, this study integrates SOM and SHAP-based machine learning into a dual-scale framework (grid and city levels), enabling more precise identification of scale-dependent drivers and a deeper understanding of the complex interrelationships between ES supply, demand, and their spatial mismatches. The results reveal pronounced spatiotemporal heterogeneity in ES supply and demand at both grid and city scales. Overall, the supply services display a spatial pattern of higher values in the east and south, and lower values in the west and north. High-value areas for multiple demand services are concentrated in the densely populated eastern regions. The grid scale better captures spatial clustering, enhancing the detection of trade-offs and synergies. For instance, the correlation between HQ and NDR supply increased from 0.62 (grid scale) to 0.92 (city scale), while the correlation between HQ and SDR demand decreased from −0.03 to −0.58, indicating that upscaling may highlight broader synergistic or conflicting trends missed at finer resolutions. In the spatiotemporal interaction network of supply–demand ratios, CS, WY, FP, and NDR persistently show low values (below −0.5) in western and northern regions, indicating ongoing mismatches and uneven development. Driver analysis demonstrates scale-dependent effects: at the grid scale, HQ and FP are predominantly influenced by socioeconomic factors, SDR and WY by ecological variables, and CS and NDR by climatic conditions. At the city level, socioeconomic drivers dominate most services. Based on these findings, nine distinct supply–demand bundles were identified at both scales. The largest bundle at the grid scale (B3) occupies 29.1% of the study area, while the largest city-scale bundle (B8) covers 26.5%. This study deepens the understanding of trade-offs, synergies, and driving mechanisms of ecosystem services across multiple spatial scales; reveals scale-sensitive patterns of spatial mismatch; and provides scientific support for tiered ecological compensation, integrated regional planning, and sustainable development strategies. Full article

Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO₂) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO₂ severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO₂ thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO₂, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO₂ thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO₂ technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO₂-philic groups. Rheological tests conducted under scCO₂ conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO₂ (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO₂ and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO₂ thickeners. This research lays the foundation for green CO₂-based energy extraction technologies. Full article

As a typical reforested region of the Loess Plateau, the Caijiachuan watershed plays a vital role in ecological security and resource management. This study evaluates the spatiotemporal variations in key ecosystem services—namely soil retention, water yield, carbon storage, and habitat quality—between 2002 and 2024 using the InVEST model, calibrated with field-measured rainfall, carbon density, and high-resolution land use data derived from integrated remote sensing and field surveys. Statistical analyses based on the R language reveal dynamic trade-offs and synergies among these services. The results show that: (1) soil retention, carbon storage, and habitat quality have steadily improved, while water yield shows an overall upward trend with significant spatial heterogeneity; (2) a consistent and significant trade-off exists between carbon storage and water yield (average R² ≈ 0.28), while other ecosystem service interactions are relatively weak; (3) climatic variability, topographic heterogeneity (e.g., slope and elevation), and vegetation structure are key drivers of these trade-offs. This study provides scientific evidence to support ecological management and policy formulation in reforested areas of the Loess Plateau. Full article

[Objective] To quantify key ecosystem services within the Dongting Lake region, clarify the trade-off/synergy relationships, and detect the driving factors in order to support the ecological sustainable development of the Dongting Lake region. [Methods] Using the InVEST model, taking the area around Dongting Lake as the study area, four ecosystem services including water yield, carbon storage, soil conservation, and habitat quality were quantitatively assessed. Interdependencies between ecosystem services were assessed using correlation analysis to quantify trade-offs/synergies, and the geodetector model was used to detect their driving factors. [Results] (1) From 2000 to 2020, the soil retention service and water yield service in the Dongting Lake area showed an increasing trend over time. The total water yield increased from 4.93 × 10¹⁰ m³ to 6.71 × 10¹⁰ m³, while the total soil retention increased from 4.46 × 10⁹ t to 5.77 × 10⁹ t; habitat quality and total carbon storage continued to decline, with habitat quality decreasing from 0.6906 to 0.6785 and carbon storage decreasing from 1.480 × 10⁹ t to 1.476 × 10⁹ t. (2) In the study area, significant synergistic effects existed between carbon storage and habitat quality, carbon storage and soil retention, carbon storage and water yield, habitat quality and soil retention, and soil retention and water yield. However, there was a significant trade-off relationship between habitat quality and water yield. (3) During the study period, ecosystem service trade-offs and synergy relationships in the Dongting Lake area were jointly influenced by natural factors and human activities. Ranked by the magnitude of driving factor influence, they were land use type, land use intensity, vegetation coverage, temperature, and nighttime light. [Conclusions] Synergies dominated the ecosystem services in the research region, and the influence of natural factors behind them was greater than that of human activities. These research conclusions offer a scientific foundation for the institutional construction of the ecological compensation mechanism in the Dongting Lake basin. Full article

In this study, the enhancement mechanism of the nano-dispersion of stearic acid-modified montmorillonite (SMMT) induced by carbon nanotubes (CNTs) in ethylene-butene terpolymer (EBT) was comprehensively investigated, and the regulation effect of composite fillers on EBT properties was revealed. Scanning electron microscopy (SEM) confirmed that SMMT achieved homogeneous nanoscale dispersion after CNT addition, and the size of aggregates was greatly reduced. Four-cycle strain-scanning analysis revealed a 200% increase in rubber–filler (R-F) interaction strength due to CNT incorporation. At the optimal CNT/SMMT ratio of 1:5, the EBT composites exhibited a 40.4% increase in Young’s modulus, 71.4% enhancement in tensile strength, and maintained 250% elongation at break, effectively addressing the strength–toughness trade-off of traditional rigid fillers. Thermogravimetric analysis (TGA) showed near 20 °C elevation in EBT composites’ maximum decomposition temperature, while water contact angle measurements indicated a hydrophobicity increase to 117.5° and water absorption rate below 0.2%. The quantitative improvement in thermal oxidation stability and hydrophobic barrier performance was achieved simultaneously. Full article

Given the worsening global climate change that drives drought frequency and irrigation water shortages, implementing water-conserving practices like alternate wetting and drying (AWD) is now critically urgent. Biochar is widely used for soil carbon sequestration. However, there is limited information on the effects of biochar on soil organic carbon (SOC) and its labile fractions in paddy fields, especially under AWD. A two-year field experiment was conducted with two irrigation regimes (CF: continuous flooding irrigation; AWD) as the main plots and 0 (B₀) and 20 t ha⁻¹ (B₁) biochar as sub-plots. AWD had no effect on the SOC and particulate organic carbon (POC) content, but increased the dissolved organic carbon (DOC), microbial biomass carbon (MBC), easily oxidizable organic carbon (EOC), light fraction organic carbon (LFOC), and carbon pool management index (CPMI) at 0–10 cm depths, by 24.4–56.4%, 12.6–17.7%, 9.2–16.8%, 25.6–28.1%, and 11.3–18.6%, respectively. Biochar increased SOC while also increasing DOC, MBC, EOC, LFOC, POC, and CPMI at 0–20 cm depths, by 18.4–53.3%, 14.7–70.2%, 17.4–22.3%, 10.2–27.6%, 95.2–188.3%, 46.6–224%, and 5.6–27.2, respectively, making SOC more labile under AWD. Our results highlight that biochar still holds great potential for improving soil quality and carbon sequestration under AWD, and the combination of biochar and AWD can achieve the synergistic optimization of the food–water–carbon sequestration trade-off, which is beneficial to sustainable agricultural production. Full article