Search Results (14,631)

With the rapid development of the shipping industry, the collision risk among ships in open waters has been steadily increasing, making effective multi-ship collision avoidance decision-making a critical issue for ensuring navigational safety. This paper proposes a multi-ship collision avoidance decision-making method based on the COLREGs. First, a fuzzy comprehensive evaluation method is used to construct a collision risk index model. Then, considering navigational safety, COLREG compliance, turning amplitude, and path economy, an objective function for ship collision avoidance is formulated. Next, the AVOA is improved by incorporating SA to simulate the foraging and navigation behavior of vultures. The Metropolis acceptance criterion is applied to help the algorithm escape local optima and enhance global search capabilities. Experiments conducted in the VSC simulation environment show that the proposed method significantly improves decision-making performance in multi-ship encounter scenarios compared to the standard AVOA. Full article

The use of white-rot fungi Pleurotus spp. and Trametes versicolor in continuous-flow fixed-bed systems has emerged as a promising and sustainable approach for the removal of different pollutants from aqueous media. This overview presents the most important design and operating parameters, the efficiency of fixed-bed systems using these fungi and their spent substrate, and the effect of operating parameters on changes in removal efficiency. After a literature screening based on the Scopus database, the overview focuses specifically on 55 studies that present the results of several hundred tests, meeting the criteria for continuous-flow fixed-bed systems, which include ensuring uninterrupted flow, constant adsorbent mass, and continuous interaction between the stationary and mobile phases. Results reported in the literature show the varying importance of biodegradation and biosorption processes in the removal of metals and organic pollutants (e.g., dyes, pharmaceuticals, pesticides, volatile compounds). The overview highlights the impact of operational parameters on removal efficiency, including bed depth, flow rate, type of polluted water, and initial concentration. It also determines that these fixed-bed systems using Pleurotus spp. and Trametes versicolor are primarily suitable for modelling the adsorption-based removal of given pollutants and the bioremediation of smaller amounts of municipal, industrial, or agricultural wastewater. Full article

Assessment of water resource spatial equilibrium (WRSE) is crucial for regional sustainable development, yet traditional methods always face difficulties in quantifying systemic differences and resolving their internal uncertainties. Accordingly, this study proposes a novel multi-attribute decision-making (MADM) model that integrates symmetric interaction entropy (SIE) with connection numbers (CNs) within a variable-weight framework. Firstly, information differences between alternatives and an ideal state were quantified by SIE, then these differences were decomposed into certain and uncertain components through the “identity–difference–opposition” (IDO) idea of CNs. In addition, a variable-weight mechanism was incorporated to enhance the model’s adaptability to regional characteristics. Applied to evaluate the WRSE in the Beijing–Tianjin–Hebei (BTH) region from 2014 to 2023, the model reveals that Hebei maintains the most favorable equilibrium state, with a partial identity potential or equal potential, followed by Beijing, while Tianjin predominantly exhibits partial opposite potential due to pronounced conflicts between its resource endowment and industrial structure. The proposed model not only enhances the sensitivity and interpretability of evaluation results but also facilitates the identification of key vulnerable indicators, thereby providing a scientific basis for formulating differentiated regional water governance strategies. Full article

Declining recovery factors from mature oil fields, coupled with the technical challenges of recovering residual oil under harsh reservoir conditions, necessitate the development of advanced enhanced oil recovery (EOR) techniques. While promising, chemical EOR often faces economic and technical hurdles in high-salinity, high-temperature environments where conventional polymers like hydrolyzed polyacrylamide (HPAM) degrade and fail. This study presents a comprehensive numerical investigation that addresses this critical industry challenge by applying a rigorously calibrated simulation framework to evaluate a novel hybrid EOR process that synergistically combines an ionic liquid (IL) with HPAM polymer. Utilizing core-flooding data from a prior study that employed the same Berea sandstone core plug and Saudi medium crude oil, supplemented by independently measured interfacial tension and contact angle data for the same chemical system, we built a core-scale model that was history-matched with RMSE < 2% OOIP. The calibrated polymer transport parameters—including a low adsorption capacity (~0.012 kg/kg-rock) and a high viscosity multiplier (4.5–5.0 at the injected concentration)—confirm favorable polymer propagation and effective in -situ mobility control. Using this validated model, we performed a systematic optimization of key process parameters, including IL slug size, HPAM concentration, salinity, temperature, and injection rate. Simulation results identify an optimal design: a 0.4 pore volume (PV) slug of IL (Ammoeng 102) reduces interfacial tension and shifts wettability toward water-wet, effectively mobilizing residual oil. This is followed by a tailored HPAM buffer in diluted formation brine (20% salinity, 500 ppm), which enhances recovery by up to 15% of the original oil in place (OOIP) over IL flooding alone by improving mobility control and enabling in-depth sweep. This excellent history match confirms the dual-displacement mechanism: microscopic oil mobilization by the IL, followed by macroscopic conformance improvement via HPAM-induced flow diversion. This integrated simulation-based approach not only validates the technical viability of the hybrid IL–HPAM flood but also delivers a predictive, field-scale-ready framework for heterogeneous reservoir systems. The work provides a robust strategy to unlock residual oil in such challenging reservoirs. Full article

Microbial proteases are fundamental towards the eco-sustainability of proteolysis at the industrial scale. A proteolytic broth was obtained from a bioreactor fermentation of a proteolytic Bacillus strain isolated from an industrial alkaline bath. Broth proteolytic activity was applied to leather tanning and to the removal of protein stains. The hide tanned with the microbial proteolytic fermentation broth showed better physical properties than the one tanned with commercial pancreatic proteases of the same activity (780 LVU). Proteinaceous stains on cotton fabric were removed more efficiently using the Bacillus proteolytic broth than water or a commercial detergent. Blood and egg yolk disappeared in less than 30 min. The removal of soya and English sauce stains was even faster. Broth proteolytic activity was characterised by caseinolytic (5200 LVU), collagenolytic (10.0 U mg⁻¹), elastolytic (3.7 U mg⁻¹), and keratinolytic (0.7 U mg⁻¹) activities, which were compared with those of a commonly used commercial protease. Alkaline protease activity in the broth was demonstrated by a 20% increase in caseinolytic activity from pH 5 to 8. Besides the demonstrated applications in the leather and detergent industries, the produced alkaline microbial proteases can also be used in the treatment of proteinaceous wastes and effluents, offering potential environmental benefits reinforcing and impacting the bioeconomy. Full article

The ceramics industry has long embraced the principles of the circular economy, with a strong focus on the reuse and recovery of raw materials essential to the production cycle. This approach reduces costs by reintroducing secondary raw materials—such as production scraps and recycled materials—into the manufacturing process after appropriate recovery treatments. This study aims to contribute to the transition of the ceramic industry toward a circular economy by incorporating industrial by-products into monoporosa ceramic bodies, thereby transforming waste materials into valuable resources. Monoporosa is a porous, single-fired ceramic wall tile characterized by a high carbonate content and low bulk density. However, the role of secondary raw materials in monoporosa formulations, as well as their influence on processing behavior (e.g., during sintering) and on key technological properties, is not yet fully understood. This work investigates a standard monoporosa formulation based on conventional raw materials (sand, calcite, feldspars, and clays) and compares it with new formulations in which industrial waste materials from local and national sources—originating from other industrial processes—are used as partial or total substitutes for some of the traditional raw materials, particularly sand and calcite. The industrial by-products examined include biomass bottom ash, foundry sand, and marble cutting and processing sludge. All materials were characterized using chemical–mineralogical, thermal, and morphological analyses and were incorporated into the ceramic bodies at different substitution levels (10%, 50%, and 100%) to replace natural raw materials. Their behavior within the mixtures was evaluated to determine ceramic suitability and acceptable replacement ratios. Furthermore, the effects of these additions on water absorption, thermal expansion coefficient, and microstructural characteristics were assessed. Based on the positive results obtained, this study demonstrates the feasibility of using, in particular, two secondary raw materials—foundry sand and marble sludge—in monoporosa body formulations, allowing for the complete replacement of the original raw materials and thereby contributing to the development of more sustainable ceramic compositions. Full article

Land degradation issues are getting complicated worldwide. Kazakhstan’s land use has sharply deteriorated over several decades, necessitating comprehensive assessment and restoration. Farmlands in Kazakhstan are grappling with multiple challenges related to climate change, intense anthropogenic disturbances, and aggressive industrial agricultural practices involving monoculture crop production. Soil depletion is widespread in Kazakhstan due to flood erosion and drought expansion, causing desertification. The land sustainability of farmland improvement, including the soil, geology, and water retention assessment, is currently under investigation through our project activities in North Kazakhstan. Nature-based methods for forest plantation along contour strips and topography-based design landscapes are rarely applied or are absent in many rural areas these days. The land use issues have resulted in the loss of the soil moisture protective functions and a reduction in agricultural efficiency. Geodesy geomatics tools were applied for a topography investigation with digital elevation, digital terrain model preparation, and potential retention ponds’ location identification for managed aquifer recharge introduction. The combination of effective water accumulation methods, considering topography, with the development of protective forest shelterbelts should enhance the land use strategies for sustainable development. This strategy is expected to reduce soil erosion, promote moisture accumulation, by improving the soil’s quality as a sponge in water collection, and increase crop yields. Alongside this, a system for developing the retention ponds with managed aquifer recharge locations for proper water collection to improve the agrolandscapes was presented. Full article

Clathrates have gained considerable attention due to their potential impact on various industries, including oil and gas production, and more recently in the fields ranging from energy storage and transportation to environmental protection and gas separation processes, opening up new technological possibilities. Overall, the attention is focused on their spontaneous and uncontrolled formation/nucleation in offshore oil and gas pipelines, which can lead to numerous and serious operational problems. Accordingly, significant research efforts have focused on understanding the mechanisms of clathrate formation and inhibition or dissociation. Different approaches are being explored; some are ambitious and innovative, whereas others seek further validation. Among these, particular interest has emerged in the coupling of Terahertz (THz) radiation with the collective low-energy and/or vibrational modes of water, and/or other molecules, as well as their clusters. In this review, we summarize recent advances and findings in this promising research field, highlighting the potential applications of THz radiation and spectroscopy, future applications in the field of clathrates, and the technological progress toward the implementation of THz-based solutions in transportation and industrial processes. Full article

The ornamental industry encompasses a wide range of species cultivated for their aesthetic value, including floriculture crops, ornamental and turf grasses, trees, and shrubs. In Italy, in particular, this sector represents a significant component of the agricultural economy, with an annual wholesale production value of approximately EUR 2.6 billion. Despite its economic importance, the industry has recently faced challenges related to the COVID-19 pandemic and increasing international competition. Moreover, ornamental production is highly water-demanding, making water availability a critical concern under climate change scenarios. The future competitiveness of ornamental sector depends on its ability to adapt to environmental and market pressures through sustainable cultivation practices, diversification with value-added crops, and improved post-production management. This study investigates the potential introduction of non-endemic wild or underutilized species as innovative ornamental crops for EU markets. While economic evaluation will be essential prior to commercialization, the current focus is on identifying promising species and outlining strategies to optimize the production chain. These approaches aim to enhance the sector’s resilience, align with sustainability goals, and foster innovation within the Italian and Mediterranean ornamental industry. Full article

Plastic microbeads, widely incorporated into personal care and cleansing products, have emerged as a pervasive contaminant in freshwater systems, including in North America. Historical estimates indicate that North American consumers alone contributed trillions of microbeads daily to municipal wastewater, with global usage reaching quadrillions per day. Regulatory actions in 2017 in Canada and the USA to ban microbeads in personal care products appear to have greatly reduced microbead contamination levels, including a decrease in microbead proportion from 2 to 5% to 0.003%, and an 86% reduction in PE microbead discharge from wastewater treatment plants. Yet these particles still persist in the environment due to their resistance to degradation and continued release from unregulated sources, including industrial abrasives and certain cleaning agents. Studies across the Great Lakes, one of the world’s largest freshwater systems, have documented widespread microbead contamination in surface waters, sediments, and shorelines, highlighting their persistence and accumulation. This review synthesizes findings from key studies conducted between 2013 and 2017 to establish a pre-ban baseline of microbead distribution in the Great Lakes, and presents new data collected from 2018 to 2021 as a post-ban contamination assessment. The review emphasizes the unique challenges posed by microbeads within the broader context of microplastic pollution. We also hope that this paper underscores the critical role of polymer chemists and engineers in developing innovative materials and removal strategies to mitigate future contamination. Full article

The global population faces increasing demands for sustainable initiatives due to industrialized agriculture. To meet the demand for protein-rich foods, innovative practices must be implemented. Conventional agricultural systems face significant challenges, including soil degradation, biodiversity loss, nutrient depletion, air pollution, and degraded water quality. Additionally, conventional agriculture affects the environment due to unsustainable farming practices utilizing chemical fertilizers, pesticides, and herbicides. These practices contribute to the accumulation of greenhouse gases and carbon emissions, which negatively affect air and water quality. Agricultural yield is declining, reducing the availability of foods, and further increasing food insecurity through increased costs. Microalgae, a unicellular organism with adaptive capabilities for carbon sequestration, offers a beneficial shift from conventional agriculture. Microalgae provide low-impact environmental alternatives to the agricultural sector, promote energy conservation, and synthesize health-promoting biomolecules, such as antioxidants, pigments, essential fatty acids, polysaccharides, and protein. This review evaluates the potentials of microalgal biomass for sustainable food applications, highlighting its role in strengthening microalgae as a biorefinery and alleviating the environmental and ecological burdens of traditional farming. Full article

The discharge of dye-contaminated effluents from textile industries into water bodies poses a severe threat to aquatic ecosystems and human health. To address this challenge, cellulose and interpenetrating polymer network (IPN) hydrogels based on cellulose and poly(vinyl alcohol) (PVA) were developed via an in situ synthesis method. The cellulose solution was obtained by cold dissolving the polysaccharide in NaOH, then dissolving PVA. The IPN hydrogels were obtained by co-cross-linking the two polymers in an alkaline medium using ECH. To optimize the hydrogels, synthesis parameters like time (4–7 h), temperature (50–80 °C), and cross-linking ratio (ECH = 50–125% w/w) were varied. Different hydrogel compositions (Cel/PVA = 90/10 to 60/40 w/w) were tested for their absorption efficiency in removing Tubantin Blue (DB 78) dye under varying initial concentrations and temperatures. Hydrogels exhibit varying adsorption capacities for DB78, depending on their IPN composition, synthesis parameters, and dye concentration. Specifically, IPN adsorption capacity ranges from 8.8 to 38.1 mg DB78/g hydrogel (7.5–36.2% efficiency). At high effluent concentrations, IPN can reach a retention capacity of 217.7 mg/g, achieving a retention efficiency of 58.4%. Cellulose and cellulose/PVA IPN hydrogels show promise as sustainable adsorbents for treating dye-contaminated wastewater. Full article

The combined challenges of water scarcity and inefficient nitrogen use pose substantial barriers to sustainable agricultural development. Optimizing the coordinated regulation of water and nitrogen resources in fruit trees is essential for promoting water-saving agriculture in drylands. To establish a water and nitrogen collaborative management model for efficient resource utilization, this study conducted a 3-year field experiment examining different irrigation amount (W1: 4500 m³·ha⁻¹, W2: 6000 m³·ha⁻¹, and W3: 7500 m³·ha⁻¹) and nitrogen application rates (N1: 200 kg·ha⁻¹, N2: 300 kg·ha⁻¹, and N3: 400 kg·ha⁻¹), coupled with ¹⁵N isotopic labeling, to evaluate the impact of water and nitrogen regulation on the following: (i) the spatial distribution patterns of water and nitrogen in the root zone soil, (ii) dynamic characteristics of water and nitrogen across organs, and (iii) ¹⁵N absorption and utilization. The findings revealed that 20–80 cm depth was the key zone for water and nitrogen absorption by roots of pear. The W2 treatment met the optimal irrigation requirement for young pear tree roots and exhibited the optimal dynamic characteristics of water and nitrogen among the newly formed organs. At the end of the growth period, N3 treatment had the highest nitrogen content and the root system was the main organ for nitrogen absorption and storage. Water-saving irrigation coupled with optimized nitrogen application synergistically enhanced the nitrogen accumulation efficiency in fragrant pear. The W2N2 treatment exhibited the highest ¹⁵N absorption and utilization rate (40.79%), effectively promoting nitrogen absorption and assimilation, reducing nitrogen losses, and offering valuable insights for advancing sustainable practices in the fruit and forestry industries. Full article

Circular economy (CE) strategies in the agri-food sector hold strong potential for reducing waste, enhancing resource efficiency, and promoting sustainable value creation. However, early-stage assessment of innovative valorisation pathways remains challenging due to limited data availability and heterogeneous sustainability trade-offs. This study presents a multi-criteria evaluation tool designed to identify sustainability hotspots and support the preliminary screening of CE solutions based on easily obtainable information. The tool combines a structured literature review with expert-based scoring across environmental (ENV), economic (EC), and social (SOC) dimensions. Its applicability was demonstrated through the following three case studies: (i) reconstitution of cheese approaching expiration, (ii) extraction of polyphenols from grape-wine residues via subcritical water extraction, and (iii) biodegradable mulching film production from grape-wine pomace. Results show that the tool successfully differentiates sustainability performance across value chain areas Residue, Final Product, and Process (RES, FP, and PRO) and reveals critical gaps requiring further investigation. Scenario 3 achieved the higher overall score (69.7%) due to fewer regulatory constraints, whereas Scenarios 1 and 2 (61.2% and 54.5%, respectively) are penalised due to the more regulations for human consumption. The proposed tool offers a practical and efficient method to support researchers and industry stakeholders in identifying CE strategies with the highest potential for sustainable development. Full article

The accumulation of municipal sewage sludge is a worldwide problem, although when properly treated, it can be utilized for various purposes in industry and agriculture. Due to its high nutrient content, one of its possible uses is the application as fertilizer on agricultural or degraded lands with the purpose of non-food plant production. In the present study, the sustainability of dehydrated sewage sludge application was tested in Szarvasi-1 energy grass (Thinopyrum obtusiflorum cv. Szarvasi-1) plantations, with special focus on the turnover of nutrients and trace elements in two experiments conducted outdoors between 2016 and 2019. Experiment 1 was conducted in 1 m³ containers, and the treatment was started on two-year old plants in 0, 15, 22.5, and 30 Mg ha⁻¹ doses per year applied in two or three portions to reveal the upper limit of sludge application. Experiment 2 was conducted in 100 m² field quadrates with 0, 7.5, 15, and 22.5 Mg ha⁻¹ doses per year applied once a year, which is in the range of the currently permitted application dose in Hungary. Soil, sludge, and plant samples, as well as physiological data, were collected. Aboveground biomass yield was measured 2–3 times per year. Increasing doses of sewage sludge significantly increased the yield compared to the controls, but the increment between the second and third doses was small. Chlorophyll content (SPAD values) increased tendentiously and partly significantly. The maximal quantum efficiency of PSII and the stomatal conductance was not improved compared to the control, whereas the relative water content of the plants was increased in Experiment 1 but not in Experiment 2 compared to the control. Malondialdehyde concentration was increased by the largest dose in Experiment 1. The concentration of macroelements, Ca, Mg, N, and S, increased in the aboveground biomass with increasing doses of sewage sludge, but even after three years, the cumulative amount removed with the harvested biomass was much smaller than the amount remaining in the soil. The total amount of K in the harvested biomass exceeded that introduced to the soil by the treatments. Micro- and trace-element concentrations did not show increasing tendency in the biomass, suggesting a slower uptake and removal rate than macroelements. The results point to the necessity to assess the real nutrient requirement and trace-element uptake by the plants as compared to the sewage sludge treatment to avoid their uncontrolled accumulation in the soil and ensure a sustainable fertilization of the plantations. Full article