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Search Results (1,321)

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Keywords = water–energy balance

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16 pages, 2576 KiB  
Article
Modeling and Spatiotemporal Analysis of Actual Evapotranspiration in a Desert Steppe Based on SEBS
by Yanlin Feng, Lixia Wang, Chunwei Liu, Baozhong Zhang, Jun Wang, Pei Zhang and Ranghui Wang
Hydrology 2025, 12(8), 205; https://doi.org/10.3390/hydrology12080205 - 6 Aug 2025
Abstract
Accurate estimation of actual evapotranspiration (ET) is critical for understanding hydrothermal cycles and ecosystem functioning in arid regions, where water scarcity governs ecological resilience. To address persistent gaps in ET quantification, this study integrates multi-source remote sensing data, energy balance modeling, and ground-based [...] Read more.
Accurate estimation of actual evapotranspiration (ET) is critical for understanding hydrothermal cycles and ecosystem functioning in arid regions, where water scarcity governs ecological resilience. To address persistent gaps in ET quantification, this study integrates multi-source remote sensing data, energy balance modeling, and ground-based validation that significantly enhances spatiotemporal ET accuracy in the vulnerable desert steppe ecosystems. The study utilized meteorological data from several national stations and Landsat-8 imagery to process monthly remote sensing images in 2019. The Surface Energy Balance System (SEBS) model, chosen for its ability to estimate ET over large areas, was applied to derive modeled daily ET values, which were validated by a large-weighted lysimeter. It was shown that ET varied seasonally, peaking in July at 6.40 mm/day, and reaching a minimum value in winter with 1.83 mm/day in December. ET was significantly higher in southern regions compared to central and northern areas. SEBS-derived ET showed strong agreement with lysimeter measurements, with a mean relative error of 4.30%, which also consistently outperformed MOD16A2 ET products in accuracy. This spatial heterogeneity was driven by greater vegetation coverage and enhanced precipitation in the southeast. The steppe ET showed a strong positive correlation with surface temperatures and vegetation density. Moreover, the precipitation gradients and land use were primary controllers of spatial ET patterns. The process-based SEBS frameworks demonstrate dual functionality as resource-optimized computational platforms while enabling multi-scale quantification of ET spatiotemporal heterogeneity; it was therefore a reliable tool for ecohydrological assessments in an arid steppe, providing critical insights for water resource management and drought monitoring. Full article
(This article belongs to the Section Hydrological and Hydrodynamic Processes and Modelling)
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13 pages, 1841 KiB  
Article
Valorizing Biomass Waste: Hydrothermal Carbonization and Chemical Activation for Activated Carbon Production
by Fidel Vallejo, Diana Yánez, Luis Díaz-Robles, Marcelo Oyaneder, Serguei Alejandro-Martín, Rasa Zalakeviciute and Tamara Romero
Biomass 2025, 5(3), 45; https://doi.org/10.3390/biomass5030045 - 5 Aug 2025
Abstract
This study optimizes the production of activated carbons from hydrothermally carbonized (HTC) biomass using potassium hydroxide (KOH) and phosphoric acid (H3PO4) as activating agents. A 23 factorial experimental design evaluated the effects of agent-to-precursor ratio, dry impregnation time, [...] Read more.
This study optimizes the production of activated carbons from hydrothermally carbonized (HTC) biomass using potassium hydroxide (KOH) and phosphoric acid (H3PO4) as activating agents. A 23 factorial experimental design evaluated the effects of agent-to-precursor ratio, dry impregnation time, and activation duration on mass yield and iodine adsorption capacity. KOH-activated carbons achieved superior iodine numbers (up to 1289 mg/g) but lower mass yields (18–35%), reflecting enhanced porosity at the cost of material loss. Conversely, H3PO4 activation yielded higher mass retention (up to 54.86%) with moderate iodine numbers (up to 1117.3 mg/g), balancing porosity and yield. HTC pretreatment at 190 °C reduced the ash content, thereby enhancing the stability of hydrochar. These findings highlight the trade-offs between adsorption performance and process efficiency, with KOH suited for high-porosity applications (e.g., water purification) and H3PO4 for industrial scalability. The study advances biomass waste valorization, aligning with circular economy principles and offering sustainable solutions for environmental and industrial applications, such as water purification and energy storage. Full article
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22 pages, 2029 KiB  
Article
A Deep Reinforcement Learning Framework for Cascade Reservoir Operations Under Runoff Uncertainty
by Jing Xu, Jiabin Qiao, Qianli Sun and Keyan Shen
Water 2025, 17(15), 2324; https://doi.org/10.3390/w17152324 - 5 Aug 2025
Abstract
Effective management of cascade reservoir systems is essential for balancing hydropower generation, flood control, and ecological sustainability, especially under increasingly uncertain runoff conditions driven by climate change. Traditional optimization methods, while widely used, often struggle with high dimensionality and fail to adequately address [...] Read more.
Effective management of cascade reservoir systems is essential for balancing hydropower generation, flood control, and ecological sustainability, especially under increasingly uncertain runoff conditions driven by climate change. Traditional optimization methods, while widely used, often struggle with high dimensionality and fail to adequately address inflow variability. This study introduces a novel deep reinforcement learning (DRL) framework that tightly couples probabilistic runoff forecasting with adaptive reservoir scheduling. We integrate a Long Short-Term Memory (LSTM) neural network to model runoff uncertainty and generate probabilistic inflow forecasts, which are then embedded into a Proximal Policy Optimization (PPO) algorithm via Monte Carlo sampling. This unified forecast–optimize architecture allows for dynamic policy adjustment in response to stochastic hydrological conditions. A case study on China’s Xiluodu–Xiangjiaba cascade system demonstrates that the proposed LSTM-PPO framework achieves superior performance compared to traditional baselines, notably improving power output, storage utilization, and spillage reduction. The results highlight the method’s robustness and scalability, suggesting strong potential for supporting resilient water–energy nexus management under complex environmental uncertainty. Full article
(This article belongs to the Section Hydrology)
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21 pages, 7111 KiB  
Article
Seasonal Variation in Energy Balance, Evapotranspiration and Net Ecosystem Production in a Desert Ecosystem of Dengkou, Inner Mongolia, China
by Muhammad Zain Ul Abidin, Huijie Xiao, Sanaullah Magsi, Fang Hongxin, Komal Muskan, Phuocthoi Hoang and Muhammad Azher Hassan
Water 2025, 17(15), 2307; https://doi.org/10.3390/w17152307 - 3 Aug 2025
Viewed by 209
Abstract
This study investigates the seasonal dynamics of energy balance, evapotranspiration (ET), and Net Ecosystem Production (NEP) in the Dengkou desert ecosystem of Inner Mongolia, China. Using eddy covariance and meteorological data from 2019 to 2022, the research focuses on understanding how these processes [...] Read more.
This study investigates the seasonal dynamics of energy balance, evapotranspiration (ET), and Net Ecosystem Production (NEP) in the Dengkou desert ecosystem of Inner Mongolia, China. Using eddy covariance and meteorological data from 2019 to 2022, the research focuses on understanding how these processes interact in one of the world’s most water-limited environments. This arid research area received an average of 109.35 mm per annum precipitation over the studied period, classifying the region as a typical arid ecosystem. Seasonal patterns were observed in daily air temperature, with extremes ranging from −20.6 °C to 29.6 °C. Temporal variations in sensible heat flux (H), latent heat flux (LE), and net radiation (Rn) peaked during summer season. The average ground heat flux (G) was mostly positive throughout the observation period, indicating heat transmission from atmosphere to soil, but showed negative values during the winter season. The energy balance ratio for the studied period was in the range of 0.61 to 0.80, indicating challenges in achieving energy closure and ecological shifts. ET exhibited two annual peaks influenced by vegetation growth and climate change, with annual ET exceeding annual precipitation, except in 2021. Net ecosystem production (NEP) from 2019 to 2020 revealed that the Dengkou desert were a net source of carbon, indicating the carbon loss from the ecosystem. In 2021, the Dengkou ecosystem shifted to become a net carbon sink, effectively sequestrating carbon. However, this was sharply reversed in 2022, resulting in a significant net release of carbon. The study findings highlight the complex interactions between energy balance components, ET, and NEP in desert ecosystems, providing insights into sustainable water management and carbon neutrality strategies in arid regions under climate change effect. Full article
(This article belongs to the Special Issue The Observation and Modeling of Surface Air Hydrological Factors)
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18 pages, 10032 KiB  
Article
Design and Efficiency Analysis of High Maneuvering Underwater Gliders for Kuroshio Observation
by Zhihao Tian, Bing He, Heng Zhang, Cunzhe Zhang, Tongrui Zhang and Runfeng Zhang
Oceans 2025, 6(3), 48; https://doi.org/10.3390/oceans6030048 - 1 Aug 2025
Viewed by 148
Abstract
The Kuroshio Current’s flow velocity imposes exacting requirements on underwater vehicle propulsive systems. Ecological preservation necessitates low-noise propeller designs to mitigate operational disturbances. As technological evolution advances toward greater intelligence and system integration, intelligent unmanned systems are positioning themselves as a critical frontier [...] Read more.
The Kuroshio Current’s flow velocity imposes exacting requirements on underwater vehicle propulsive systems. Ecological preservation necessitates low-noise propeller designs to mitigate operational disturbances. As technological evolution advances toward greater intelligence and system integration, intelligent unmanned systems are positioning themselves as a critical frontier in marine innovation. In recent years, the global research community has increased its efforts towards the development of high-maneuverability underwater vehicles. However, propeller design optimization ignores the key balance between acoustic performance and hydrodynamic efficiency, as well as the appropriate speed threshold for blade rotation. In order to solve this problem, the propeller design of the NACA 65A010 airfoil is optimized by using OpenProp v3.3.4 and XFlow 2022 software, aiming at innovating the propulsion system of shallow water agile submersibles. The study presents an integrated design framework combining lattice Boltzmann method (LBM) simulations synergized with fully Lagrangian-LES modeling, implementing rotational speed thresholds to detect cavitation inception, followed by advanced acoustic propagation analysis. Through rigorous comparative assessment of hydrodynamic metrics, we establish an optimization protocol for propeller selection tailored to littoral zone operational demands. Studies have shown that increasing the number of propeller blades can reduce the single-blade load and delay cavitation, but too many blades will aggravate the complexity of the flow field, resulting in reduced efficiency and noise rebound. It is concluded that the propeller with five blades, a diameter of 234 mm, and a speed of 500 RPM exhibits the best performance. Under these conditions, the water efficiency is 69.01%, and the noise is the lowest, which basically realizes the balance between hydrodynamic efficiency and acoustic performance. This paradigm-shifting research carries substantial implications for next-generation marine vehicles, particularly in optimizing operational stealth and energy efficiency through intelligent propulsion architecture. Full article
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18 pages, 6506 KiB  
Article
Realizing the Role of Hydrogen Energy in Ports: Evidence from Ningbo Zhoushan Port
by Xiaohui Zhong, Yuxin Li, Daogui Tang, Hamidreza Arasteh and Josep M. Guerrero
Energies 2025, 18(15), 4069; https://doi.org/10.3390/en18154069 - 31 Jul 2025
Viewed by 315
Abstract
The maritime sector’s transition to sustainable energy is critical for achieving global carbon neutrality, with container terminals representing a key focus due to their high energy consumption and emissions. This study explores the potential of hydrogen energy as a decarbonization solution for port [...] Read more.
The maritime sector’s transition to sustainable energy is critical for achieving global carbon neutrality, with container terminals representing a key focus due to their high energy consumption and emissions. This study explores the potential of hydrogen energy as a decarbonization solution for port operations, using the Chuanshan Port Area of Ningbo Zhoushan Port (CPANZP) as a case study. Through a comprehensive analysis of hydrogen production, storage, refueling, and consumption technologies, we demonstrate the feasibility and benefits of integrating hydrogen systems into port infrastructure. Our findings highlight the successful deployment of a hybrid “wind-solar-hydrogen-storage” energy system at CPANZP, which achieves 49.67% renewable energy contribution and an annual reduction of 22,000 tons in carbon emissions. Key advancements include alkaline water electrolysis with 64.48% efficiency, multi-tier hydrogen storage systems, and fuel cell applications for vehicles and power generation. Despite these achievements, challenges such as high production costs, infrastructure scalability, and data integration gaps persist. The study underscores the importance of policy support, technological innovation, and international collaboration to overcome these barriers and accelerate the adoption of hydrogen energy in ports worldwide. This research provides actionable insights for port operators and policymakers aiming to balance operational efficiency with sustainability goals. Full article
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16 pages, 2207 KiB  
Article
Mitogenomic Insights into Adaptive Evolution of African Ground Squirrels in Arid Environments
by Yamin Xing, Xibao Wang, Yao Chen, Yongquan Shang, Haotian Cai, Liangkai Wang and Xiaoyang Wu
Diversity 2025, 17(8), 538; https://doi.org/10.3390/d17080538 - 31 Jul 2025
Viewed by 212
Abstract
African ground squirrels (Xerus spp.), the inhabitants of African arid zones, face extreme heat and water scarcity driving selection for metabolic optimization. We assembled and annotated the first mitogenomes of Xerus inauris and Xerus rutilus (16,525–16,517 bp), revealing conserved vertebrate architecture with [...] Read more.
African ground squirrels (Xerus spp.), the inhabitants of African arid zones, face extreme heat and water scarcity driving selection for metabolic optimization. We assembled and annotated the first mitogenomes of Xerus inauris and Xerus rutilus (16,525–16,517 bp), revealing conserved vertebrate architecture with genus-specific traits. Key features include Xerus rutilus’s elongated ATP6 (680 vs. 605 bp), truncated ATP8ATP6 spacers (4 vs. 43 bp), and tRNA-Pro control regions with 78.1–78.3% AT content. Their nucleotide composition diverged from that of related sciurids, marked by reduced T (25.78–26.9%) and extreme GC skew (−0.361 to −0.376). Codon usage showed strong Arg-CGA bias (RSCU = 3.78–3.88) and species-specific elevations in Xerus rutilus’s UGC-Cys (RSCU = 1.83 vs. 1.17). Phylogenetics positioned Xerus as sister to Ratufa bicolor (Bayesian PP = 0.928; ML = 1.0), aligning with African biogeographic isolation. Critically, we identified significant signatures of positive selection in key mitochondrial genes linked to arid adaptation. Positive selection signals in ND4 (ω = 1.8 × background), ND1, and ATP6 (p < 0.0033) correspond to enhanced proton gradient efficiency and ATP synthesis–molecular adaptations likely crucial for optimizing energy metabolism under chronic water scarcity and thermoregulatory stress in desert environments. Distinct evolutionary rates were observed across mitochondrial genes and complexes: Genes encoding Complex I subunits (ND2, ND6) and Complex III (Cytb) exhibited accelerated evolution in arid-adapted lineages, while genes encoding Complex IV subunits (COXI) and Complex V (ATP8) remained highly conserved. These findings resolve the Xerus mitogenomic diversity, demonstrating adaptive plasticity balancing arid-energy optimization and historical diversification while filling critical genomic gaps for this xeric-adapted lineage. Full article
(This article belongs to the Section Animal Diversity)
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35 pages, 8044 KiB  
Article
Transboundary Water–Energy–Food Nexus Management in Major Rivers of the Aral Sea Basin Through System Dynamics Modelling
by Sara Pérez Pérez, Iván Ramos-Diez and Raquel López Fernández
Water 2025, 17(15), 2270; https://doi.org/10.3390/w17152270 - 30 Jul 2025
Viewed by 333
Abstract
Central Asia (CA) faces growing Water–Energy–Food (WEF) Nexus challenges, due to its complex transboundary water management, legacy Soviet-era water infrastructure, and increasing climate and socio-economic pressures. This study presents the development of a System Dynamics Model (SDM) to evaluate WEF interdependencies across the [...] Read more.
Central Asia (CA) faces growing Water–Energy–Food (WEF) Nexus challenges, due to its complex transboundary water management, legacy Soviet-era water infrastructure, and increasing climate and socio-economic pressures. This study presents the development of a System Dynamics Model (SDM) to evaluate WEF interdependencies across the Aral Sea Basin (ASB), including the Amu Darya and Syr Darya river basins and their sub-basins. Different downscaling strategies based on the area, population, or land use have been applied to process open-access databases at the national level in order to match the scope of the study. Climate and socio-economic assumptions were introduced through the integration of already defined Shared Socioeconomic Pathways (SSPs) and Representative Concentration Pathways (RCPs). The resulting SDM incorporates more than 500 variables interacting through mathematical relationships to generate comprehensive outputs to understand the WEF Nexus concerns. The SDM was successfully calibrated and validated across three key dimensions of the WEF Nexus: final water discharge to the Aral Sea (Mean Absolute Error, MAE, <5%), energy balance (MAE = 4.6%), and agricultural water demand (basin-wide MAE = 1.2%). The results underscore the human-driven variability of inflows to the Aral Sea and highlight the critical importance of transboundary coordination to enhance future resilience. Full article
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38 pages, 16643 KiB  
Article
Numerical Investigation of Inclination Effects on a Submerged Plate as Breakwater and Wave Energy Converter Under Realistic Sea State Waves
by Vitor Eduardo Motta, Gabrielle Ücker Thum, Maycon da Silveira Paiva, Rafael Adriano Alves Camargo Gonçalves, Luiz Alberto Oliveira Rocha, Elizaldo Domingues dos Santos, Bianca Neves Machado and Liércio André Isoldi
J. Mar. Sci. Eng. 2025, 13(8), 1438; https://doi.org/10.3390/jmse13081438 - 28 Jul 2025
Viewed by 220
Abstract
This study investigates the influence of inclination on a submerged plate (SP) device acting as both a breakwater (BW) and a wave energy converter (WEC) subjected to representative regular and realistic irregular waves of a sea state across 11 inclination angles. Numerical simulations [...] Read more.
This study investigates the influence of inclination on a submerged plate (SP) device acting as both a breakwater (BW) and a wave energy converter (WEC) subjected to representative regular and realistic irregular waves of a sea state across 11 inclination angles. Numerical simulations were conducted using ANSYS Fluent. Regular waves were generated by Stokes’s second-order theory, while the WaveMIMO technique was employed to generate irregular waves. Using the volume of fluid (VOF) method to model the water–air interaction, both approaches generate waves by imposing their vertical and horizontal velocity components at the inlet of the wave flume. The SP’s performance as a BW was analyzed based on the upstream and downstream free surface elevations of the device; in turn, its performance as a WEC was determined through its axial velocity beneath the plate. The results indicate that performance varies between regular and irregular wave conditions, underscoring the importance of accurately characterizing the sea state at the intended installation site. These findings demonstrate that the inclination of the SP plays a critical role in balancing its dual functionality, with certain configurations enhancing WEC efficiency by over 50% while still offering relevant BW performance, even under realistic irregular sea conditions. Full article
(This article belongs to the Section Coastal Engineering)
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14 pages, 838 KiB  
Article
Impact of Water Vapor on the Predictive Modeling of Full-Scale Indirectly Heated Biomass Torrefaction System Throughput Capacity
by Chaitanya Bhatraju, Matthew Russell and Martijn Dekker
Energies 2025, 18(15), 3978; https://doi.org/10.3390/en18153978 - 25 Jul 2025
Viewed by 227
Abstract
Biomass torrefaction must be self-sustaining and continuous to be commercially viable, eliminating dependence on additional fuels while achieving industrial-scale production. This study presents a predictive model of a full-scale continuous biomass torrefaction process that explicitly incorporates the radiation absorption properties of torrefaction gas, [...] Read more.
Biomass torrefaction must be self-sustaining and continuous to be commercially viable, eliminating dependence on additional fuels while achieving industrial-scale production. This study presents a predictive model of a full-scale continuous biomass torrefaction process that explicitly incorporates the radiation absorption properties of torrefaction gas, with a focus on water vapor. Previous research, primarily based on lab-scale batch processes, has not adequately addressed scale-up challenges or the dynamic evolution of torrefaction gas. Industrial insights from Perpetual Next confirm that water vapor significantly impacts reactor performance by absorbing heat and reducing radiative flux to the biomass. Simulations show that neglecting water vapor absorption in reactor design can lead to throughput deviations of 10–20%, affecting process stability and efficiency. Industrial-scale validation demonstrates that the model accurately predicts this effect, ensuring realistic energy demand and throughput expectations. By explicitly incorporating water vapor absorption into the radiation balance, the model provides a validated framework for optimizing reactor design and process scale-up. It demonstrates that failing to consider this effect can lead to operational instability and deviations from the intended torrefaction severity, ultimately affecting industrial-scale performance and self-sustaining operation. Full article
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29 pages, 9145 KiB  
Article
Ultra-Short-Term Forecasting-Based Optimization for Proactive Home Energy Management
by Siqi Liu, Zhiyuan Xie, Zhengwei Hu, Kaisa Zhang, Weidong Gao and Xuewen Liu
Energies 2025, 18(15), 3936; https://doi.org/10.3390/en18153936 - 23 Jul 2025
Viewed by 207
Abstract
With the increasing integration of renewable energy and smart technologies in residential energy systems, proactive household energy management (HEM) have become critical for reducing costs, enhancing grid stability, and achieving sustainability goals. This study proposes a ultra-short-term forecasting-driven proactive energy consumption optimization strategy [...] Read more.
With the increasing integration of renewable energy and smart technologies in residential energy systems, proactive household energy management (HEM) have become critical for reducing costs, enhancing grid stability, and achieving sustainability goals. This study proposes a ultra-short-term forecasting-driven proactive energy consumption optimization strategy that integrates advanced forecasting models with multi-objective scheduling algorithms. By leveraging deep learning techniques like Graph Attention Network (GAT) architectures, the system predicts ultra-short-term household load profiles with high accuracy, addressing the volatility of residential energy use. Then, based on the predicted data, a comprehensive consideration of electricity costs, user comfort, carbon emission pricing, and grid load balance indicators is undertaken. This study proposes an enhanced mixed-integer optimization algorithm to collaboratively optimize multiple objective functions, thereby refining appliance scheduling, energy storage utilization, and grid interaction. Case studies demonstrate that integrating photovoltaic (PV) power generation forecasting and load forecasting models into a home energy management system, and adjusting the original power usage schedule based on predicted PV output and water heater demand, can effectively reduce electricity costs and carbon emissions without compromising user engagement in optimization. This approach helps promote energy-saving and low-carbon electricity consumption habits among users. Full article
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17 pages, 5257 KiB  
Article
Research on Draft Control Optimization of Ship Passing a Lock Based on CFD Method
by Yuan Zhuang, Yu Ding, Jialun Liu and Song Zhang
J. Mar. Sci. Eng. 2025, 13(8), 1406; https://doi.org/10.3390/jmse13081406 - 23 Jul 2025
Viewed by 206
Abstract
Waterborne transportation serves as a critical pillar of trunk-line freight systems, offering unparalleled advantages in transport capacity, energy efficiency, and cost-effectiveness. As cargo throughput demands escalate, optimizing lock capacity becomes imperative. This study investigates ship sinkage dynamics through computational fluid dynamics (CFD) simulations [...] Read more.
Waterborne transportation serves as a critical pillar of trunk-line freight systems, offering unparalleled advantages in transport capacity, energy efficiency, and cost-effectiveness. As cargo throughput demands escalate, optimizing lock capacity becomes imperative. This study investigates ship sinkage dynamics through computational fluid dynamics (CFD) simulations for a representative inland cargo vessel navigating the Three Gorges on the Yangtze River. We develop a predictive sinkage model that integrates four key hydrodynamic parameters: ship velocity, draft, water depth, and bank clearance, applicable to both open shallow water and lockage conditions. The model enables determination of maximum safe drafts for lock transit by analyzing upstream/downstream water levels and corresponding chamber depths. Our results demonstrate the technical feasibility of enhancing single-lock cargo capacity while maintaining safety margins. These findings provide (1) a scientifically grounded framework for draft control optimization, and (2) actionable insights for lock operation management. The study establishes a methodological foundation for balancing navigational safety with growing throughput requirements in constrained waterways. Full article
(This article belongs to the Section Ocean Engineering)
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16 pages, 1188 KiB  
Article
Preparation and Performance Evaluation of Modified Amino-Silicone Supercritical CO2 Viscosity Enhancer for Shale Oil and Gas Reservoir Development
by Rongguo Yang, Lei Tang, Xuecheng Zheng, Yuanqian Zhu, Chuanjiang Zheng, Guoyu Liu and Nanjun Lai
Processes 2025, 13(8), 2337; https://doi.org/10.3390/pr13082337 - 23 Jul 2025
Viewed by 339
Abstract
Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO2) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. [...] Read more.
Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO2) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO2 severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO2 thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO2, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO2 thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO2 technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO2-philic groups. Rheological tests conducted under scCO2 conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO2 (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO2 and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO2 thickeners. This research lays the foundation for green CO2-based energy extraction technologies. Full article
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23 pages, 2364 KiB  
Review
A Comprehensive Review of Applications and Environmental Risks of Waste Plastics in Asphalt Pavements
by Ju Pan, Jue Li, Bailin Shan, Yongsheng Yao and Chao Huang
Materials 2025, 18(15), 3441; https://doi.org/10.3390/ma18153441 - 22 Jul 2025
Viewed by 246
Abstract
The global plastic crisis has generated significant interest in repurposing waste plastics as asphalt modifiers, presenting both environmental and engineering advantages. This study offers a comprehensive review of the applications of waste plastics in asphalt, focusing on their types, modification mechanisms, incorporation techniques, [...] Read more.
The global plastic crisis has generated significant interest in repurposing waste plastics as asphalt modifiers, presenting both environmental and engineering advantages. This study offers a comprehensive review of the applications of waste plastics in asphalt, focusing on their types, modification mechanisms, incorporation techniques, and environmental impacts, alongside proposed mitigation strategies. Commonly utilized plastics include polyethylene (PE), polypropylene (PP), polystyrene (PS), polyvinyl chloride (PVC), and polyethylene terephthalate (PET), each affecting asphalt performance differently—enhancing high-temperature stability and fatigue resistance while exhibiting varying levels of compatibility and environmental risks. The incorporation techniques, namely wet and dry processes, differ in terms of efficiency, cost, and environmental footprint: the wet process enhances durability but requires more energy, whereas the dry process is more cost-effective but may lead to uneven dispersion. Environmental concerns associated with these practices include toxic emissions (such as polycyclic aromatic hydrocarbons and volatile organic compounds) during production, microplastic generation through abrasion and weathering, and ecological contamination of soil and water. Mitigation strategies encompass optimizing plastic selection, improving pre-treatment and compatibilization methods, controlling high-temperature processing, and monitoring the spread of microplastics. This review highlights the need for balanced adoption of waste plastic-modified asphalt, emphasizing sustainable practices to maximize benefits while minimizing risks. Full article
(This article belongs to the Section Construction and Building Materials)
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26 pages, 2178 KiB  
Article
Optimizing Agri-PV System: Systematic Methodology to Assess Key Design Parameters
by Kedar Mehta and Wilfried Zörner
Energies 2025, 18(14), 3877; https://doi.org/10.3390/en18143877 - 21 Jul 2025
Viewed by 414
Abstract
Agrivoltaic (Agri-PV) systems face the critical challenge of balancing photovoltaic energy generation with crop productivity, yet systematic approaches to quantifying the trade-offs between these objectives remain scarce. In this study, we identify nine essential design indicators: panel tilt angle, elevation, photovoltaic coverage ratio, [...] Read more.
Agrivoltaic (Agri-PV) systems face the critical challenge of balancing photovoltaic energy generation with crop productivity, yet systematic approaches to quantifying the trade-offs between these objectives remain scarce. In this study, we identify nine essential design indicators: panel tilt angle, elevation, photovoltaic coverage ratio, shading factor, land equivalent ratio, photosynthetically active radiation (PAR) utilization, crop yield stability index, water use efficiency, and return on investment. We introduce a novel dual matrix Analytic Hierarchy Process (AHP) to evaluate their relative significance. An international panel of eighteen Agri-PV experts, encompassing academia, industry, and policy, provided pairwise comparisons of these indicators under two objectives: maximizing annual energy yield and sustaining crop output. The high consistency observed in expert responses allowed for the derivation of normalized weight vectors, which form the basis of two Weighted Influence Matrices. Analysis of Total Weighted Influence scores from these matrices reveal distinct priority sets: panel tilt, coverage ratio, and elevation are most influential for energy optimization, while PAR utilization, yield stability, and elevation are prioritized for crop productivity. This methodology translates qualitative expert knowledge into quantitative, actionable guidance, clearly delineating both synergies, such as the mutual benefit of increased elevation for energy and crop outcomes, and trade-offs, exemplified by the negative impact of high photovoltaic coverage on crop yield despite gains in energy output. By offering a transparent, expert-driven decision-support tool, this framework enables practitioners to customize Agri-PV system configurations according to local climatic, agronomic, and economic contexts. Ultimately, this approach advances the optimization of the food energy nexus and supports integrated sustainability outcomes in Agri-PV deployment. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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