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Keywords = warm mix asphalt (WMA)

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25 pages, 3889 KB  
Article
Performance of Warm Mix Asphalt with Polymer Modified RAP Using Recycled Engine Oil and SBS Binder Modification
by Byung-Sik Ohm and Tri Ho Minh Le
Polymers 2026, 18(1), 44; https://doi.org/10.3390/polym18010044 - 23 Dec 2025
Viewed by 508
Abstract
The growing use of reclaimed asphalt pavement (RAP) in warm-mix asphalt (WMA) presents significant challenges when RAP originates from aged polymer-modified binder (PMB) pavements, where severe oxidation and polymer degradation lead to excessive stiffness and poor cracking resistance. This study presents a multi-scale [...] Read more.
The growing use of reclaimed asphalt pavement (RAP) in warm-mix asphalt (WMA) presents significant challenges when RAP originates from aged polymer-modified binder (PMB) pavements, where severe oxidation and polymer degradation lead to excessive stiffness and poor cracking resistance. This study presents a multi-scale evaluation of a hybrid modification strategy combining recycled engine oil waste (REOW, 3 wt.%) and styrene–butadiene–styrene (SBS, 1–4 wt.%) to restore aged PMB-containing RAP systems under controlled binder conditions. Three binders (control, REOW-modified, and REOW–SBS hybrid) were prepared using a fixed 70/30 virgin-to-RAP binder blend and characterized through rheological analysis, and multiple stress creep recovery (MSCR). The findings show that REOW softened the binder but reduced elastic recovery, whereas SBS modification restored elastic response. Corresponding WMA mixtures with 30 wt.% RAP and 5.0 wt.% total binder content were evaluated for moisture damage, raveling, rutting, and cracking resistance. At the mixture scale, the hybrid system achieved a TSR of 83%, reduced Hamburg rut depth by ~20%, and increased SCB fracture energy by ~30% compared with the control. These findings demonstrate that combined rejuvenation–reinforcement effectively re-mobilizes aged PMB chemistry and restores polymer elasticity, enabling high-performance WMA production with RAP derived from polymer-modified pavements. Full article
(This article belongs to the Section Polymer Chemistry)
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12 pages, 3206 KB  
Article
Flame Retardancy and Smoke Suppression of Warm-Mix Asphalt Binder Containing Various Flame Retardants
by Qiaoming Guo, Yuanbao Liu and Shengjie Liu
Coatings 2026, 16(1), 15; https://doi.org/10.3390/coatings16010015 - 22 Dec 2025
Viewed by 375
Abstract
This study investigated the synergistic mechanisms of flame retardancy and smoke suppression exhibited by a novel ternary additive in warm-mix asphalt (WMA). The ternary additive consisted of aluminum hydroxide (ATH), organic montmorillonite (OMMT), and expandable graphite (EG). A comprehensive experimental program was conducted, [...] Read more.
This study investigated the synergistic mechanisms of flame retardancy and smoke suppression exhibited by a novel ternary additive in warm-mix asphalt (WMA). The ternary additive consisted of aluminum hydroxide (ATH), organic montmorillonite (OMMT), and expandable graphite (EG). A comprehensive experimental program was conducted, encompassing limiting oxygen index (LOI) testing, cone calorimeter testing, thermogravimetric analysis (TGA), and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM–EDS). The results showed that incorporation of 6 wt% of the ternary additive (by mass of the asphalt binder) markedly improved the fire resistance of the WMA. The LOI increased from 19.8% (neat asphalt) to 25.2%. Cone calorimeter tests revealed a 23.9% increase in time to ignition, a 24.2% reduction in peak heat release rate, and a 47.5% decrease in total smoke production. These improvements are attributed to a synergistic mechanism involving the endothermic decomposition of ATH, the char-promoting effect of OMMT, and the intumescent expansion of expandable graphite (EG) forming a compact insulating barrier, which collectively inhibit combustion and smoke release. The ternary additive exhibits considerable promise as an effective flame-retardant modifier for enhancing the fire safety of warm-mix asphalt pavements, especially in high-risk scenarios such as tunnels. Full article
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23 pages, 2467 KB  
Article
New Type of Asphalt Concrete with Bitumen Emulsion in Terms of Type and Quantity of Binder
by Maciej Krasowski, Przemysław Buczyński, Grzegorz Mazurek and Matúš Kozel
Materials 2025, 18(23), 5437; https://doi.org/10.3390/ma18235437 - 2 Dec 2025
Viewed by 364
Abstract
This paper presents the effect of modifiers on the properties of a mixture of asphalt concrete with bitumen emulsion (ACBE). The mineral-asphalt mixture is the only one that can be produced using the cold-mix technology (CMA). The theoretical part of the article details [...] Read more.
This paper presents the effect of modifiers on the properties of a mixture of asphalt concrete with bitumen emulsion (ACBE). The mineral-asphalt mixture is the only one that can be produced using the cold-mix technology (CMA). The theoretical part of the article details the characteristics of the methods for producing mineral-asphalt mixtures in terms of their production temperature. Thus, hot (HMA), half-warm (H-WMA), warm (WMA) and cold (CMA) mixtures are discussed. The research section presents the design of the asphalt concrete composition with bitumen emulsion, the research methods, the experiment design and the research results. The design of the mixture of asphalt concrete with bitumen emulsion was carried out in accordance with the guidelines set out in EN 13108-31. In the experiment, Portland cement (C), bitumen emulsion (A), synthetic latex (styrene-butadiene rubber SBR) (B) and redispersible polymer powder EVA (polyethylene-co-vinyl acetate) (P) were used as modifiers. Twenty-four mixtures were designed as part of the experiment, according to the 34 experiment design. The following physical and mechanical properties were assessed in the design of the research: air void content Vm, water ab-sorption nw, indirect tensile strength ITS and IT-CY stiffness modulus. When analysing the research results, the authors observed a noticeable impact of the content of asphalt (A) and synthetic latex (B) on the air void content Vm. A significant effect was also observed for the interaction of Portland cement (C) and redispersible polymer powder (P) on the indirect tensile strength ITS. The next step was the optimisation of the ACBE mixture composition, which effect made it possible to identify the optimum amounts of modifiers in the mixture of asphalt concrete with bitumen emulsion (ACBE), which constituted recommendations for the requirements for mixtures of asphalt concrete with bitumen emulsion. Full article
(This article belongs to the Special Issue Innovative Approaches in Asphalt Binder Modification and Performance)
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25 pages, 2975 KB  
Article
Laboratory Study on the Effect of Kraft Lignin and Sasobit on Construction Temperatures, Compactability and Physical Properties of Hot and Warm Mix Asphalt
by Ali Rezazad Gohari, Sébastien Lamothe, Jean-Pascal Bilodeau, Ahmad Mansourian and Alan Carter
Infrastructures 2025, 10(12), 327; https://doi.org/10.3390/infrastructures10120327 - 1 Dec 2025
Viewed by 447
Abstract
This study investigates the feasibility of using Kraft lignin in Hot and Warm Mix Asphalt (HMA and WMA), with a particular focus on its integration alongside Sasobit®. The research aims to evaluate the impact of Kraft lignin and Sasobit, individually and [...] Read more.
This study investigates the feasibility of using Kraft lignin in Hot and Warm Mix Asphalt (HMA and WMA), with a particular focus on its integration alongside Sasobit®. The research aims to evaluate the impact of Kraft lignin and Sasobit, individually and in combination, on the construction temperatures, compactability, and physical properties of asphalt mixtures. The experimental program included a reference HMA and modified mixes with 20% Kraft lignin, 3% Sasobit, and their combinations. These mixes were designed and subjected to tests to assess their volumetric and mass properties and to determine the construction temperatures using the Superpave Gyratory Compactor (SGC). The results demonstrated that adding Kraft lignin increased construction temperatures, while Sasobit effectively reduced these temperatures by lowering binder viscosity. When used together, Sasobit offset the increase in construction temperatures caused by Kraft lignin, resulting in compaction temperatures similar to the reference HMA mix. Additionally, Kraft lignin increased air voids, leading to reduced compactability at higher gyration levels. It also exhibited indications of a dual role, functioning as both a binder replacement and a filler. In conclusion, the combination of 20% Kraft lignin with 3% Sasobit offers a promising solution for enhancing the sustainability of asphalt mixtures. Full article
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26 pages, 2107 KB  
Systematic Review
Recycled Plastics in Asphalt Mixtures: A Systematic Review of Mechanical Performance, Environmental Impact and Practical Implementation
by Julio Calderón-Ramírez, David Sepúlveda-Valdez, Leonel García, Marcelo A. Lomeli-Banda, Carlos Salazar-Briones and Marco Montoya-Alcaraz
Appl. Sci. 2025, 15(18), 9901; https://doi.org/10.3390/app15189901 - 10 Sep 2025
Cited by 2 | Viewed by 4170
Abstract
The growing environmental impact of plastic waste and the high energy consumption in traditional asphalt production have driven the search for more sustainable alternatives in road construction. This systematic review evaluates the incorporation of recycled plastics into Hot Mix Asphalt (HMA) and Warm [...] Read more.
The growing environmental impact of plastic waste and the high energy consumption in traditional asphalt production have driven the search for more sustainable alternatives in road construction. This systematic review evaluates the incorporation of recycled plastics into Hot Mix Asphalt (HMA) and Warm Mix Asphalt (WMA), focusing on their effects on mechanical performance and environmental outcomes. Using the Preferred Reporting Items for Systematic Reviews and Meta-Analyses extension for Scoping Reviews (PRISMA/ScR) methodology, 39 studies published between 2012 and 2023 were analyzed to compare plastic types, incorporation methods (dry, wet, and pyrolysis), and dosage levels. Results show that plastics such as Polyethylene Terephthalate (PET), Low-Density Polyethylene (LDPE), and Polypropylene (PP) can improve stiffness, rutting resistance, and fatigue life. WMA technologies, while less commonly applied, offer significant environmental advantages by reducing greenhouse gas emissions and energy consumption. The review highlights the critical role of plastic type, blending method, and local conditions in optimizing performance. Overall, integrating recycled plastics into asphalt mixtures presents a promising pathway toward more durable and sustainable pavement infrastructure. Full article
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18 pages, 1918 KB  
Article
Development of Low Rolling Resistance Asphalt Mixtures with RAP and WMA Technologies
by Judita Škulteckė, Ovidijus Šernas, Donatas Čygas, Igoris Kravcovas, Laura Žalimienė and Rafal Mickevič
Buildings 2025, 15(17), 3203; https://doi.org/10.3390/buildings15173203 - 5 Sep 2025
Viewed by 950
Abstract
The development of sustainable and energy-efficient asphalt pavements is essential to address the growing demand for climate-neutral transportation infrastructure. This study investigates the structural design and functional performance of low rolling resistance asphalt mixtures utilizing reclaimed asphalt pavement (RAP) and warm mix asphalt [...] Read more.
The development of sustainable and energy-efficient asphalt pavements is essential to address the growing demand for climate-neutral transportation infrastructure. This study investigates the structural design and functional performance of low rolling resistance asphalt mixtures utilizing reclaimed asphalt pavement (RAP) and warm mix asphalt (WMA) technologies. Ten mixtures with WMA additive—including asphalt concrete (AC) and stone mastic asphalt (SMA) with and without RAP—were evaluated for volumetric and mechanical performance. Laboratory results show that RAP addition did not compromise compaction nor indirect tensile strength ratio (ITSR), and in some cases improved these properties. SMA and SMA RAP-modified mixtures achieved the highest resistance to rutting (as low as 5.0% rut depth), while AC and SMA mixtures both demonstrated low rolling resistance (coefficients of energy loss 0.00604–0.00636). Resistance to low-temperature cracking was strong for all mixtures, with thermal stress restrained specimen test (TSRST) fracture temperatures ranging from −32.8 °C to −36.0 °C. SMA mixtures generally exhibited superior resistance to fatigue (up to 63 με at 1 million cycles). Overall, three asphalt mixtures with different particle size distribution containing 14% RAP and a WMA additive (SMA 8 S_1 R, SMA 8 S_3 R, and AC 11 VS_2 R) demonstrated the best balance of rolling resistance, durability, and circularity, and are recommended for field trials to support climate-neutral and sustainable road infrastructure. These results encourage broader adoption of circular practices in road infrastructure projects, contributing to lower emissions and life-cycle costs. Full article
(This article belongs to the Special Issue Carbon-Neutral Infrastructure: 2nd Edition)
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18 pages, 2760 KB  
Article
Behavioral Analysis of Rigid Pavements Utilizing Recycled Base Layers
by Elaheh TaghaviGhalehsari, Hassan Kardgar and Ali Hasanzadeh
J 2025, 8(3), 34; https://doi.org/10.3390/j8030034 - 2 Sep 2025
Viewed by 1251
Abstract
Sustainable pavement design requires a balanced consideration of economic, environmental, and social impacts. In line with Federal Highway Administration (FHWA) guidelines for sustainable roadway infrastructure, incorporating recycled materials such as reclaimed asphalt pavement (RAP), recycled pavement material (RPM), recycled asphalt shingles (RASs), and [...] Read more.
Sustainable pavement design requires a balanced consideration of economic, environmental, and social impacts. In line with Federal Highway Administration (FHWA) guidelines for sustainable roadway infrastructure, incorporating recycled materials such as reclaimed asphalt pavement (RAP), recycled pavement material (RPM), recycled asphalt shingles (RASs), and warm-mix asphalt (WMA) has been shown to reduce natural resource depletion while promoting circular construction practices. This study investigates the structural performance of Portland cement concrete (PCC) pavements constructed on RAP and RPM base layers. A series of design scenarios was modeled using site-specific laboratory and field data—particularly subgrade soil properties and climatic conditions—from El Paso and San Antonio, Texas. The analysis incorporates unsaturated soil parameters and follows the performance thresholds set by the Mechanistic-Empirical Pavement Design Guide (MEPDG). Findings indicate that concrete mixture design, pavement structure, and local weather conditions are the primary drivers of distress in jointed plain concrete pavements (JPCPs). However, subsoil characteristics have a significant impact on joint faulting in JPCP and punchout occurrences in continuously reinforced concrete pavements (CRCPs), especially in thinner sections. Notably, the use of up to 50% recycled material in the base layer had minimal adverse effects on pavement performance, underscoring its viability as a sustainable design strategy for rigid pavements. Full article
(This article belongs to the Section Engineering)
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22 pages, 3743 KB  
Article
Mechanical and Performance Characteristics of Warm Mix Asphalt Modified with Phase Change Materials and Recycled Cigarette Filters
by Zahraa Ahmed al-Mammori, Israa Mohsin Kadhim Al-Janabi, Ghadeer H. Abbas, Doaa Hazim Aziz, Fatin H. Alaaraji, Elaf Salam Abbas, Beshaer M. AL-shimmery, Tameem Mohammed Hashim, Ghanim Q. Al-Jameel, Ali Shubbar and Mohammed Salah Nasr
CivilEng 2025, 6(3), 41; https://doi.org/10.3390/civileng6030041 - 5 Aug 2025
Cited by 1 | Viewed by 1632
Abstract
With rising global temperatures and increasing sustainability demands, the need for advanced pavement solutions has never been greater. This study breaks new ground by integrating phase change materials (PCMs), including paraffin-based wax (Rubitherm RT55), hydrated salt (Climator Salt S10), and fatty acid (lauric [...] Read more.
With rising global temperatures and increasing sustainability demands, the need for advanced pavement solutions has never been greater. This study breaks new ground by integrating phase change materials (PCMs), including paraffin-based wax (Rubitherm RT55), hydrated salt (Climator Salt S10), and fatty acid (lauric acid), as binder modifiers within warm mix asphalt (WMA) mixtures. Moving beyond the traditional focus on binder-only modifications, this research utilizes recycled cigarette filters (CFs) as a dual-purpose fiber additive, directly reinforcing the asphalt mixture while simultaneously transforming a major urban waste stream into valuable infrastructure. The performance of the developed WMA mixture has been evaluated in terms of stiffness behavior using an Indirect Tensile Strength Modulus (ITSM) test, permanent deformation using a static creep strain test, and rutting resistance using the Hamburg wheel-track test. Laboratory tests demonstrated that the incorporation of PCMs and recycled CFs into WMA mixtures led to remarkable improvements in stiffness, deformation resistance, and rutting performance. Modified mixes consistently outperformed the control, achieving up to 15% higher stiffness after 7 days of curing, 36% lower creep strain after 4000 s, and 64% reduction in rut depth at 20,000 passes. Cost–benefit analysis and service life prediction show that, despite costing USD 0.71 more per square meter with 5 cm thickness, the modified WMA mixture delivers much greater durability and rutting resistance, extending service life to 19–29 years compared to 10–15 years for the control. This highlights the value of these modifications for durable, sustainable pavements. Full article
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17 pages, 2459 KB  
Article
Comparative Life Cycle Assessment of Rubberized Warm-Mix Asphalt Pavements: A Cradle-to-Gate Plus Maintenance Approach
by Ana María Rodríguez-Alloza and Daniel Garraín
Coatings 2025, 15(8), 899; https://doi.org/10.3390/coatings15080899 - 1 Aug 2025
Cited by 1 | Viewed by 1497
Abstract
In response to the escalating climate crisis, reducing greenhouse gas emissions (GHG) has become a top priority for both the public and private sectors. The pavement industry plays a key role in this transition, offering innovative technologies that minimize environmental impacts without compromising [...] Read more.
In response to the escalating climate crisis, reducing greenhouse gas emissions (GHG) has become a top priority for both the public and private sectors. The pavement industry plays a key role in this transition, offering innovative technologies that minimize environmental impacts without compromising performance. Among these, the incorporation of recycled tire rubber and warm-mix asphalt (WMA) additives represents a promising strategy to reduce energy consumption and resource depletion in road construction. This study conducts a comparative life cycle assessment (LCA) to evaluate the environmental performance of an asphalt pavement incorporating recycled rubber and a WMA additive—referred to as R-W asphalt—against a conventional hot-mix asphalt (HMA) pavement. The analysis follows the ISO 14040/44 standards, covering material production, transport, construction, and maintenance. Two service-life scenarios are considered: one assuming equivalent durability and another with a five-year extension for the R-W pavement. The results demonstrate environmental impact reductions of up to 57%, with average savings ranging from 32% to 52% across key impact categories such as climate change, land use, and resource use. These benefits are primarily attributed to lower production temperatures and extended maintenance intervals. The findings underscore the potential of R-W asphalt as a cleaner engineering solution aligned with circular economy principles and climate mitigation goals. Full article
(This article belongs to the Special Issue Surface Protection of Pavements: New Perspectives and Applications)
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24 pages, 8192 KB  
Article
Mapping the Relationship Between Diffusion Characteristics of Warm-Mix Recycled Asphalt on Molecular Dynamics (MD) and High-Low Temperature Properties of Mixtures
by Xin Jin, Shanshan Meng, Haoxuan Fu, Qi Zhao, Deli Li, Zhuolin Li, Ye Yang, Yanhai Yang, Jiupeng Zhang and Qingyue Zhou
Materials 2025, 18(12), 2740; https://doi.org/10.3390/ma18122740 - 11 Jun 2025
Cited by 1 | Viewed by 665
Abstract
Warm-mix recycled asphalt (WMA-R) technology for reclaimed asphalt pavement (RAP) significantly reduces energy consumption and environmental pollution while maintaining the performance of asphalt mixtures. Significant progress has been made at home and abroad in evaluating the impact of regenerated asphalt mixtures on the [...] Read more.
Warm-mix recycled asphalt (WMA-R) technology for reclaimed asphalt pavement (RAP) significantly reduces energy consumption and environmental pollution while maintaining the performance of asphalt mixtures. Significant progress has been made at home and abroad in evaluating the impact of regenerated asphalt mixtures on the performance of regenerated asphalt. However, the performance improvement of WMA-R depends on the effective diffusion of regenerated agents and their interaction mechanism with aged asphalt, which has not been fully studied. This paper systematically studies the diffusion characteristics of biomimetic-based warm-mix regenerant in aged asphalt and its impact on the high- and low-temperature performance of asphalt mixtures through MD and experimental verification. The results show that biomimetic-based warm-mix regenerant can significantly improve the diffusion performance of aged asphalt. Through the rutting test and low-temperature bending test, the significant improvement of the biomimetic-based warm-mix regenerant in the rutting resistance and crack resistance of asphalt mixtures was verified. Full article
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17 pages, 28066 KB  
Article
Performance Evaluation of Warm-Mix Asphalt Binders with an Emphasis on Rutting and Intermediate-Temperature Cracking Resistance
by Jiangbo Pang, Yu Chen, Longfei Jing, Haoran Song and Ziyang Liu
Materials 2025, 18(7), 1571; https://doi.org/10.3390/ma18071571 - 30 Mar 2025
Cited by 4 | Viewed by 955
Abstract
Warm-mix asphalt (WMA) technology is gaining popularity worldwide due to its benefits of considerable emissions reduction and energy savings when compared with hot-mix asphalt (HMA). Currently, there is a wide range of WMA products with considerable variability in the corresponding pavement performances. It [...] Read more.
Warm-mix asphalt (WMA) technology is gaining popularity worldwide due to its benefits of considerable emissions reduction and energy savings when compared with hot-mix asphalt (HMA). Currently, there is a wide range of WMA products with considerable variability in the corresponding pavement performances. It has also been difficult to reach a unified conclusion regarding the effects of various WMA additives on asphalt binder properties. In this study, two categories of warm-mix additives, including six organic additives and three chemical additives, were evaluated in terms of their effects on asphalt binder properties, with a focus on rutting and intermediate-temperature cracking. It was found that the viscosity-reducing effect of organic additives was more significant in comparison to chemical additives. In addition, the binders modified with the organic additives obtained enhanced rutting resistance at high temperatures but compromised cracking resistance at intermediate temperatures, as shown by the increasing complex modulus (G*) and non-recoverable creep compliance (Jnr) and decreasing binder fracture energy (BFE). Meanwhile, the very limited effect of chemical additives on rutting resistance was observed while the cracking resistance was slightly improved. The findings will assist in the selection and application of WMA additives for the production of asphalt mixture. Full article
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21 pages, 5339 KB  
Article
Contribution of Oxygen and Ultraviolet Light to the Adhesion Properties of Warm Mix Asphalt During the Light-Oxidative Coupling Ultraviolet Aging Process
by Jianbing Ma, Bo Li, Yongning Wang, Xiaomin Li, Dongna Li, Xiaoyu Ren and Mingxing Fu
Materials 2025, 18(6), 1345; https://doi.org/10.3390/ma18061345 - 18 Mar 2025
Cited by 1 | Viewed by 785
Abstract
Objective: We investigated the contribution of oxygen and UV light to the UV aging process of warm mix asphalt (WMA). Methods: In this paper, warm mix asphalt was prepared with different aging methods (RTFOT, PAV and UV) and UV aging times (50 h, [...] Read more.
Objective: We investigated the contribution of oxygen and UV light to the UV aging process of warm mix asphalt (WMA). Methods: In this paper, warm mix asphalt was prepared with different aging methods (RTFOT, PAV and UV) and UV aging times (50 h, 100 h, 150 h and 200 h). The cohesion and bonding functions of WMA were tested using surface free energy theory. In addition, the UV aging functional groups of WMA were analyzed using Fourier transform infrared spectroscopy (FTIR). On this basis, the contribution of oxygen and ultraviolet light to the UV aging of WMA was analyzed using the random forest model. Results and conclusions: The results showed that UV aging had the greatest effect on the adhesion property index and functional group index of WMA, followed by PAV aging, and RTFOT aging had the least effect. With the extension of UV aging time, the adhesion and cohesion functions of WMA showed a decreasing trend, while the carbonyl index and sulfoxide index showed an increasing trend. When the UV aging time exceeded 150 h, the adhesion function and functional group index of WMA gradually tended to stabilize. The effect of UV aging on the adhesive properties of WMA was mainly due to adhesive damage. There were significant differences in the effects of oxygen isolation and light–oxygen-coupled UV aging on the adhesive properties and functional group index of WMA. In the light–oxygen-coupled UV aging of warm mix asphalt, the contribution of UV radiation was 79.9%, and the contribution of oxygen was 20.1%. Full article
(This article belongs to the Special Issue Development of Sustainable Asphalt Materials)
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28 pages, 6455 KB  
Article
Optimizing Bitumen Performance in Warm Mix Asphalt Using Cecabase RT BIO10: A Taguchi-Based Experimental Approach
by Mustafa Çakı and Fatih İrfan Baş
Appl. Sci. 2025, 15(4), 1761; https://doi.org/10.3390/app15041761 - 9 Feb 2025
Cited by 2 | Viewed by 2639
Abstract
Flexible pavements stand out as the most commonly used worldwide, compared to rigid and composite pavements, owing to their versatility and widespread application. The use of hot mix asphalt (HMA) in flexible pavements causes significant environmental concerns due to high CO2 emissions [...] Read more.
Flexible pavements stand out as the most commonly used worldwide, compared to rigid and composite pavements, owing to their versatility and widespread application. The use of hot mix asphalt (HMA) in flexible pavements causes significant environmental concerns due to high CO2 emissions and energy consumption, whereas warm mix asphalt (WMA) technologies have gained popularity in recent decades, offering a more sustainable alternative by enabling asphalt production at lower temperatures. WMA technologies can be categorized into three main groups: foaming, organic additives, and chemical additives, with each offering distinct benefits for performance and environmental impact. One of the chemical additives used in WMA production is Cecabase RT BIO10. In this study, virgin bitumen with 50/70 penetration was modified by adding Cecabase RT BIO10 at four levels: 0%, 0.3%, 0.4%, and 0.5% by weight. The experimental design employed a Taguchi L16 orthogonal array to systematically evaluate the effects of various factors on modified bitumen performance. Binders were prepared at four temperatures (110 °C, 120 °C, 130 °C, and 140 °C), four mixing durations (15, 20, 25, and 30 min), and four mixing speeds (1000, 2000, 3000, and 4000 rpm), enabling an efficient analysis of each parameter’s impact. The prepared binders were subjected to a series of tests, including penetration, softening point, flash point, rotational thin film oven test (RTFOT), elastic recovery, Marshall stability, ultrasonic pulse velocity (UPV), and FTIR analysis. These tests were conducted to investigate the effects of various parameters and levels on the binder properties. Additionally, stiffness and seismic modules were evaluated to provide a more comprehensive understanding of the binder’s performance. The experiment results revealed that the penetration, elastic recovery percentage, and Marshall stability increased with increasing additive content while the softening point and RTFOT mass loss decreased. At a high service temperature of 40 °C, the stiffness modulus of the modified bitumen decreased slightly. At a low service temperature of −10 °C, it decreased further. Additionally, the incorporation of Cecabase RT BIO10 led to an increase in the seismic modulus. Through optimization using the Taguchi method, the optimal levels were determined to be a 0.4% Cecabase RT BIO10 ratio, 140 °C mixing temperature, 30 min mixing time, and 1000 RPM mixing speed. The optimal responses for each test were identified and integrated into a unified optimal response, resulting in a comprehensive design guide with 95% confidence level estimates for all possible level combinations. Full article
(This article belongs to the Section Civil Engineering)
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24 pages, 7247 KB  
Article
Molecular Dynamics Investigation of the Diffusion Mechanisms and Thermodynamic Behaviors in Warm Mix Recycled Asphalt Binders with and Without Rejuvenators
by Qisheng Hu, Derun Zhang and Peixin Xu
Materials 2025, 18(3), 703; https://doi.org/10.3390/ma18030703 - 5 Feb 2025
Cited by 2 | Viewed by 1582
Abstract
In recent years, the employment of rejuvenators and warm mix asphalt (WMA) additives for reclaimed asphalt pavement (RAP) has been recognized as a popular approach to increase the recycling rate of waste materials and promote the sustainable development of pavement engineering. However, the [...] Read more.
In recent years, the employment of rejuvenators and warm mix asphalt (WMA) additives for reclaimed asphalt pavement (RAP) has been recognized as a popular approach to increase the recycling rate of waste materials and promote the sustainable development of pavement engineering. However, the composition of warm mix recycled asphalt binder is complicated, and the microstructural changes brought about by the rejuvenators and WMA additives are critical in determining its macroscopic mechanical properties. This research focuses on the atomic modeling of the rejuvenators and WMA additives diffusion behavior of the warm mix recycled asphalt binder. The objective is to reveal the thermodynamic performance and diffusion mechanism of the WMA binder under the dual presence of rejuvenators and WMA additives. Three types of mutual diffusion systems (Aged and oil + virgin + wax, Aged + virgin + wax, and Aged and oil + virgin) were established, respectively, for a comparative investigation of the glass transition temperature, viscosity, thermodynamics, free volume, and diffusion behavior. The results indicate a 44.27% and 31.33% decrease in the glass transition temperature and apparent viscosity, respectively, after the incorporation of 5% oil rejuvenators in the Aged + virgin + wax asphalt binder, demonstrating the improved cracking resistance and construction workability. The presence of the RAP binder and organic WMA additives raised the cohesion of the asphalt binder and decreased self-healing ability and free volume, and these detrimental influences can be offset by the introduction of rejuvenators. The combined use of rejuvenators and organic WMA additives remarkably enhanced the de-agglomeration to asphaltenes, stimulated the activity of aged RAP macromolecular components, and ultimately improved the blending efficiency of virgin binders with the overall structure of RAP binders. Full article
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14 pages, 4669 KB  
Article
Cool Mix Asphalt—Redefining Warm Mix Asphalt with Implementations in Korea, Italy and Vietnam
by Hosin (David) Lee, Lan Ngoc Nguyen, Elena Sturlini and Young-ik Kim
Infrastructures 2025, 10(1), 24; https://doi.org/10.3390/infrastructures10010024 - 20 Jan 2025
Cited by 3 | Viewed by 2783
Abstract
During the past decades, to minimize Greenhouse Gas (GHG) emissions and asphalt fumes during the asphalt mix production and construction process, various warm mix asphalt (WMA) additives have been developed and successfully applied. Currently, as production of WMA reaches close to that of [...] Read more.
During the past decades, to minimize Greenhouse Gas (GHG) emissions and asphalt fumes during the asphalt mix production and construction process, various warm mix asphalt (WMA) additives have been developed and successfully applied. Currently, as production of WMA reaches close to that of Hot Mix Asphalt (HMA) in the US, the varied definition of WMA is questioned in this paper. Not only are the temperature reduction ranges from HMA defined by various studies too wide, but also the minimum threshold to be classified as WMA is often too small. In this paper, a new category of “Cool Mix Asphalt (CMA)” is proposed to distinguish it from the newly defined WMA based not on the reduction amount from HMA temperature but its actual production temperature. It is proposed that HMA should be defined as asphalt mixtures produced at temperatures between 140 and 160 °C (between 284 and 320 °F), WMA as production temperatures between 120 and 140 °C (between 248 and 284 °F), and CMA as production temperatures between 100 and 120 °C (212 to 248 °F). By defining their actual production temperatures rather than reduction temperatures from HMA, WMA and CMA will be clearly defined. This paper then presents a new Polymer Cool Mix Asphalt (PCMA) additive called “Zero-M”, which was developed to lower the mixing temperature to around 110 °C (203 °F). Recently, test sections using Zero-M were successfully constructed in Korea, Italy and Vietnam, and their laboratory test results of field cores and production and construction experiences are described in this paper. The chemistry and compositions of Zero-M are discussed along with its mechanism to significantly lower the production temperature of PCMA. All test sections constructed in three countries met the in-place compaction density requirements of their respective countries, which were close to or higher than those of the control HMA test sections. Full article
(This article belongs to the Special Issue Cool Mix Asphalt: Redefining Warm Mix Asphalt)
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