Search Results (212)

A comprehensive investigation is presented for cyclohexene, C₆H₁₀, via the vacuum ultraviolet (VUV) absorption spectrum in the photon energy range 4.0–10.8 eV (310–115 nm). Quantum chemical calculations (Density Functional Theory (DFT), Time Dependent Density Functional Theory (TD-DFT) and Equation of Motion Coupled-Cluster Single and Doubles (EOM-CCSD)) are combined with experiments in order to provide the most accurate and up-to-date information about the electronic state spectroscopy of cyclohexene. The spectrum reveals several new features not previously reported in the literature, with special attention to the different Rydberg series converging to (11b)⁻¹  ${\tilde{X}}^{2}B$, (10b)⁻¹  ${\tilde{A}}^{2}B$, (12a)⁻¹ ${\tilde{B}}^{2}A$, (11a)⁻¹ ${\tilde{C}}^{2}A$, and (9b)⁻¹ ${\tilde{D}}^{2}B$ ionic electronic states of cyclohexene. We also provide absolute cross-section values from high-resolution VUV photoabsorption measurements, with photolysis lifetimes in the Earth’s atmosphere from 0 to 50 km altitude being obtained, showing that solar photolysis is not an important sink mechanism at altitudes lower than 22 km, relative to ^●OH radical reactions. Full article

We present a comprehensive review of regularization schemes for magnetized dense quark matter within effective models of quantum chromodynamics, focusing on the Magnetic-Field-Independent Regularization (MFIR) and the Medium Separation Scheme (MSS) at finite chemical potential and magnetic field. In nonrenormalizable frameworks such as the Nambu–Jona-Lasinio model, the treatment of ultraviolet divergences is crucial, particularly in magnetized and dense environments where conventional regularization procedures may introduce unphysical artifacts. We show that MFIR consistently isolates divergent vacuum contributions from finite magnetic-field-dependent terms, while MSS extends this separation to the medium sector, ensuring that only vacuum quantities are regularized. Within this unified framework, we analyze the thermodynamics of cold and dense quark matter, including color-superconducting phases, and demonstrate that the superconducting gap remains finite at large chemical potentials, even in the presence of strong magnetic fields. In contrast to results obtained with traditional regularization schemes, we find no evidence for a transition to a normal phase at zero temperature, highlighting the importance of a proper separation between vacuum and medium contributions. These results eliminate spurious oscillations and other nonphysical artifacts, leading to a more robust and physically consistent description of strongly interacting matter under extreme conditions relevant to compact stars and heavy-ion collisions. Full article

The formation and stabilization of silver nanoparticles (AgNPs) in thin films of ionic liquids (ILs) based on long-chain alkylimidazolium cations are demonstrated in this work. IL films were prepared by vacuum thermal evaporation using the Knudsen effusion method onto ITO/glass substrates, leading to the formation of micro- and nanosized structures distributed across the surface. The investigated ILs were symmetrical dialkylimidazolium-based systems: [C₇C₇im][NTf₂], [C₈C₈im][NTf₂], and [C₁₀C₁₀im][NTf₂]. Increasing the alkyl side-chain length of the imidazolium cation resulted in larger droplet domains. AgNPs were subsequently deposited onto the IL films by sputtering. The formation of AgNPs was confirmed by scanning electron microscopy (SEM), ultraviolet (UV)–visible spectroscopy, and X-ray photoelectron spectroscopy (XPS). The results show that increasing the alkyl side-chain length promotes more effective confinement and stabilization of AgNPs, leading to improved nanoparticle formation and a narrower size distribution. The temporal stability of the Ag-containing IL films was evaluated under both air exposure and inert argon storage, revealing a strong influence of the surrounding atmosphere on nanoparticle evolution. Among the ILs studied, [C₁₀C₁₀im][NTf₂] exhibited the most favorable behavior for AgNP formation and stabilization, providing a more stable and homogeneous nanoparticle distribution over time. Full article

This proof-of-concept study proposes a photovoltaic transparent vacuum insulation panel (PV-TVIP) and evaluates its heat transfer and power generation characteristics with increased temperatures, and light transmission characteristics for visible light and ultraviolet wavelengths. The study was conducted with a climate-controlled chamber mimicking the common temperature range of Sapporo, Japan. The average TVIP heat flux was measured to be 65–75 W/m² with a U-value of 1.95–2.3 W/(m²∙K). Compared to earlier measurements to see the effect of seasonal atmospheric conditions to the quality of the TVIP, it was determined that the TVIP manufactured during winter conducted less heat, assumed to be caused by decreased humidity. Placing the PV between the TVIP and a glass pane increased the operating temperature by 26.06 °C and decreased power generation by 13%. Afterwards, the transparency of the TVIP and PV-TVIP were measured under a bright light therapy lamp, showing that TVIP reduced the amount of most visible light wavelengths by 50% and the PV-TVIP by 90%. UV radiation was respectively reduced by approximately 78% and 100%. The results show that while PV-TVIP shows potential as a BAPV window retrofit solution, its manufacturing requires optimized, low-humidity conditions during all phases of the manufacturing process. Full article

Ultraviolet remote sensing systems generally encounter the technical limitation of insufficient effective signal energy. Optical systems featuring a lightweight and compact layout are emerging as the mainstream research and development trend in this field. Varied-line-space (VLS) gratings can simultaneously achieve effective aberration correction and beam focusing in ultraviolet spectral imaging systems, enabling fewer system components and a simplified optical layout. On this basis, the modulation mechanisms of the groove distribution of planar VLS gratings for aberration correction and dispersion manipulation in the non-vacuum ultraviolet (non-VUV) band are thoroughly investigated. We elaborate on the theories concerning the line density function of VLS gratings based on phase distribution, and implement global optimization for the parameters of holographic gratings. The overall optical performance of the grating system is evaluated via ray tracing, which verifies the capability of VLS gratings to improve spectral resolution. We further perform optical design, device fabrication, and experimental validation using VLS gratings with a central groove density of 300 lp/mm. A spectral resolution of 0.345 nm is finally realized at the central wavelength of 300 nm. This work not only enriches the fundamental theories of VLS grating systems but also demonstrates that VLS gratings can significantly boost the aberration correction performance of ultraviolet spectrometers while adopting only a small number of optical elements. The theoretical conclusions are validated by measured data, and a complementary research framework integrating theoretical analysis and experimental testing is established. This study offers novel design ideas for hyperspectral and high-spatial-resolution spectral imaging systems. Full article

Mars Sample Return Program planning includes a series of spacecraft staged both on the Martian surface and in low-Mars-orbit (LMO). During the transfer of samples into orbit, external spacecraft surfaces might be exposed to Mars dust carried on the sample container exterior and possibly extant microbiota (if present). This study was designed to characterize the synergistic effects of LMO ultraviolet irradiation, vacuum, and solar heating on the survival of two UV-resistant and heat-tolerant bacteria, one yeast, and one fungus. The species tested were Bacillus pumilus SAFR-032 spores, Geobacillus stearothermophilus ATCC 12980 spores, Naganishia onofrii DBVPG 5303 cells, and Aspergillus fumigatus ISSFT-021-30 spores, respectively. Spores of A. fumigatus ISSFT-021-30 and B. pumilus were also exposed to LMO conditions with and without a Mojave Mars Simulant (MMS) dust layer. Based on the data, the time required to reach the desired Sterility Assurance Level (SAL; dose-defined to yield a −12 log reduction) was 2.0 h for A. fumigatus ISSFT-021-30 and 76.6 min for B. pumilus SAFR-032 if exposed directly to the solar UV beam under LMO conditions. With the MMS present, predicted times to reach one SAL were extended to 22 h and 1.72 h, respectively. Analysis of UV transmittance through cell stacks of up to 12 µm thick was performed for A. fumigatus ISSFT-021-30. Results indicated that ~4–5% of UVC photons can penetrate through 12 µm stacked aggregates of spores. These findings indicate that (1) the LMO environment can be used to attain the mandated levels of spacecraft surface bioburden reductions and (2) dust shielding and microbial aggregation attenuate UV irradiation, leading to extended orbital residence times to achieve mandated bioburden reductions. Full article

Noble liquids, notably argon and xenon, are utilised as both detector media and as the detector target for dark matter and neutrino physics experiments. When the noble liquid is excited by particles, it scintillates vacuum ultraviolet light, which sensors then detect. A major focus of the detector development community is on producing precision light sensors for noble liquid detectors. We introduce a flash lamp to test VUV-sensitive light sensors with light at wavelengths observed using noble liquid detectors. This paper discusses the design and presents results from a flash lamp prototype operated at room temperature. Full article

Microplastics (MPs), i.e., plastic particles <5 mm, and nanoplastics (NPs), i.e., plastic particles <1 µm, are widespread in the environment. MPs and NPs (MNPs) have also been detected in human tissues. Environmental MNPs exhibit diverse physicochemical properties such as size, shape, and surface degradation. However, most experimental studies have used pristine MNPs, which poorly represent real-world conditions, and only a limited number of studies have focused on preparing environmentally relevant MNPs. Therefore, we focused on the key physicochemical properties of MNPs, particularly their shape, size, and surface degradation, using polyvinyl chloride (PVC) as the model polymer. In this study, fragment and spherical PVC-MNPs were utilized, and surface degradation was introduced through exposure to vacuum ultraviolet (VUV) radiation at a wavelength of 172 nm. Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) analysis revealed the formation of additional carbonyl groups after VUV exposure. We investigated the cytotoxic effects of the degraded and non-degraded PVC-MNPs on A549, Caco-2, and THP-1 cells. The results indicated that the degraded PVC-MNP-treated groups induced higher cytotoxic effects than those in the non-degraded groups. Notably, the degraded PVC-NPs induced stronger cytotoxicity than the degraded PVC-MPs. These findings highlight the potential health risks associated with environmental MNPs. Full article

We simulate the generation of multiple harmonics up to the sixth order extending into vacuum ultraviolet. The harmonics are generated by χ⁽ⁿ⁾:χ^(m) cascades, containing second- or third-order perturbative nonlinear processes. We identify three additional phase-matching conditions beyond standard phase matching, namely when only the first step or only the second step of the cascades are phase-matched and when the non-phase-matched second or third harmonic produces quasi-phase matching for higher-order harmonics, causing an essential enhancement of the harmonic signals. Full article

Haloacetaldehydes (HALs) and haloacetonitriles (HANs) are groups of carcinogenic disinfection by products (DBPs) present in water supplies, of which trichloroacetaldehyde (TCAL) and dichloroacetonitrile (DCAN) are frequently detected. The efficiency of ultraviolet (UV) irradiation processes in the removal of DBPs depends strongly on the contribution of direct and indirect photolysis. Significant gaps exist in research regarding kinetics of photodegradation in multi-solute systems. Therefore, in this study the efficiency of vacuum UV (VUV) and UV-C processes was tested on batch photodegradation with synthetic waters containing either TCAL or DCAN and bi-solutes. A radical scavenger test was performed to determine the presence of OH radicals. The VUV (185 + 254 nm) degraded TCAL and DCAN more effectively than UV-C (254 nm), achieving absolute elimination after 30 min (>99.9%, 113 mW/cm²) for TCAL, but only an 84% reduction in DCAN after 120 min of irradiation at fluence of >450 mW/cm². The experimental results demonstrate that the main mechanism in TCAL reduction was indirect photolysis, but for DCAN it was direct photolysis by VUV photolysis. When indirect photolysis dominated, HALs and HANs in the mixture competed for OH radicals under VUV photolysis. A degradation pathway study indicated that TCAL was degraded and transformed to formic acid, while DCAN was dechlorinated by OH radicals. Overall, this study confirms that the VUV process is more effective than UV-C in photodegrading carbonaceous DBPs. Full article

Perovskite solar cells (PSCs) have quickly achieved certified energy conversion efficiency reaching a certified record of 27.3% for single-junction cells, while having a low mass, thin-film form factor and high specific power, which are attractive for space energy systems. However, their long-term reliability in extraterrestrial environments is not adequately ensured by terrestrial qualification routes, and standardized space-related test protocols remain insufficiently developed. This review critically summarizes the current understanding of the degradation of PSCs under the influence of key environmental factors in space—ionizing and non-ionizing radiation, thermal vacuum exposure and thermal cycling, and ultraviolet radiation AM0, as well as atmospheric oxygen in low orbits. The central task of the work is to develop and justify the need to create specialized PSCs test protocols for space applications, since existing ground standards do not reflect the multifactorial nature and extreme orbital loads. It has been shown that thermal vacuum accelerates ion migration, interphase reactions, and degassing, while AM0 UV and atomic oxygen introduce additional photochemical and oxidative mechanisms of destruction; at the same time, stressors often act synergistically and are not detected by single-factor tests. Next, the limitations of the current IEC and ISOS are discussed and an approach to their expansion is formulated through the ISOS-T-Space and ISOS-LC-Space protocols, which integrate high vacuum, AM0 lighting, extended temperature ranges and controlled particle irradiation. It is concluded that the development and interlaboratory validation of such space-oriented protocols is a key condition for the correct qualification of PSCs and targeted optimization of materials and interfaces to meet the requirements of space energy. Full article

Photopolymer-based additive manufacturing processes such as stereolithography (SLA) offer high precision and surface quality but generate cured thermoset waste that is typically non-recyclable. In microgravity environments, conventional recycling approaches—based on gravitational settling, open solvent handling, and buoyancy-driven degassing—are ineffective, motivating the development of fully contained, gravity-independent material recovery systems for on-orbit manufacturing. This work presents a conceptual, design-stage closed-loop system architecture for recycling photopolymer resins in microgravity. The system integrates eight subassemblies enabling mechanical fragmentation, solvent-assisted dissolution, filtration, low-pressure degassing, pressurized storage, injection molding, and ultraviolet curing. A hermetically sealed dual-screw shredder produces resin fragments of 1–3 mm, suitable for dissolution. Gas removal is achieved through low-vacuum degassing at approximately 0.1–0.3 bar, with characteristic residence times of 5–10 min, ensuring stable processing prior to injection. Material transport is governed by mechanical conveyance and controlled pressure, eliminating reliance on gravity. The architecture maintains full containment of solids, liquids, and vapors throughout the process. Supported by engineering design considerations, the system establishes a microgravity-compatible pathway for closed-loop recycling of SLA materials. Experimental validation is planned in future work. Full article

Perovskite solar cells (PSCs) have rapidly evolved into one of the most promising photovoltaic technologies, achieving power conversion efficiencies comparable to established silicon devices while offering unique advantages such as low weight, mechanical flexibility, and low-temperature, solution-based manufacturing. These attributes, combined with recently demonstrated tolerance to high-energy particle irradiation, position PSCs as compelling candidates for next-generation space power systems. This perspective work summarizes recent advances in PSC development for space environments, focusing on their behaviour under key stressors such as radiation (e.g., electrons, protons, gamma rays, and neutrons), ultraviolet exposure, extreme thermal cycling, and ultra-high vacuum. Progress in material design, device architecture, self-healing mechanisms, and encapsulation strategies is discussed, along with early in-orbit and suborbital demonstrations. Remaining challenges, including long-term stability, encapsulation reliability, large-area scalability, and the need for standardized space-qualification protocols, are also outlined. Indeed, PSCs represent a compelling opportunity for next-generation space photovoltaics, provided that targeted materials and engineering solutions address critical issues of encapsulation and durability under combined stressors to ensure reliable operation in harsh extraterrestrial conditions. Full article

Deposition of amorphous boron (a-B) onto Si substrates via chemical decomposition of B₂H₆ molecules produces a-B/Si, heterojunctions which are the core parts of photodetectors used in vacuum ultraviolet (VUV) and potentially in extreme ultraviolet (EUV) lithography. However, fundamental questions regarding the limit on the thickness of the deposited a-B thin films and the intrinsic electronic nature of the B atoms adjacent to the Si substrate remain unanswered. Here we investigated the local structural and electronic properties of atomic-thin a-B layers at the Si{001} substrates using ab initio molecular dynamics (AIMD) techniques. The investigation revealed a rich variety of local chemical bonding and consequently interfacial electronic properties. For thin a-B layer(s)/Si systems, most of the a-B atoms at the interface formed (-B-Si-B-Si-) chains on the Si{001} surface. These B atoms were found to occupy the positions of the missing Si atoms and were bonded to the surficial Si atoms. The surficial Si atoms predominantly have two B neighbors. Localized defect states at the Fermi level for the interfacial Si and B atoms were found in the pseudo-gap. These states have a major influence on the electrical properties of the device. The predicted minimum thickness of the a-B films is about 1 to 2 nm, a useful metric for the manufacturing of a-B/Si devices. The information obtained here further helps us to understand the working mechanisms of a-B/Si interfaces for photon detection and constructing new core devices for potential applications in the field of metal/semiconductor heterojunctions for photon detection, photovoltaics, Schottky diodes and semiconductor devices. Full article

The ²²⁹Th nuclear clock, based on a low-energy nuclear transition, has attracted significant interest as a next-generation time and frequency standard. It is expected to surpass current leading optical atomic clocks in performance. Because nuclear transitions are naturally isolated from external electromagnetic fields, their sensitivity to blackbody radiation and environmental noise is much lower than that of electronic transitions. This gives the nuclear clock a unique advantage in both stability and accuracy. This paper reviews the current progress in nuclear clock research, focusing on the physical properties of the ²²⁹Th isomer, the operating principles, and the primary implementation methods of the nuclear clock. Comparing key technical approaches, specifically trapped ions and thorium-doped crystals, and introducing the VUV frequency comb technology used to drive the nuclear transition. Finally, we provide an outlook on the future development of the field. Full article