Search Results (465)

To address the challenges of low density, loose structure, high utilization costs, and inadequate molding effects of corn straw char under ambient temperature and pressure conditions, this study investigated the utilization of waste soybean powder (WSP) as a binder to produce biochar pellets via ultrasonic-assisted processing. A single-factor experiment was initially conducted to assess the effects of key variables. Subsequently, a Central Composite Rotatable Design (CCRD) was employed to evaluate the individual and interactive effects of these variables, in which pellet density and durability served as response indicators. Regression models for both responses were developed and validated using analysis of variance (ANOVA). The results indicated that, at a 0.05 significance level, the mixing ratio of corn straw char to WSP and molding pressure had highly significant effects on pellet density, while pelleting time had a significant effect and ultrasonic power had no significant influence. All four factors significantly affected pellet durability, and their interactions were further analyzed. The optimal conditions were a mixing ratio of 45%, pelleting time of 33 s, an ultrasonic power of 150 W, and a molding pressure of 5 MPa, yielding pellets with a density of 1140.41 kg/m³ and a durability of 98.54%. These results demonstrate that WSP is an effective binder for the ultrasonic-assisted fabrication of biochar pellets. Full article

Micro-textures are crucial for enhancing surface performance in diverse applications, but traditional radial electrochemical micromachining (REMM) suffers from process complexity and workpiece damage. This study presents radial ultrasonic rolling electrochemical micromachining (RUREMM), an advanced technique integrating an ultrasonic field to improve electrolyte renewal, disrupt passivation layers, and optimize electrochemical reaction uniformity on SS304 surfaces. Aimed at overcoming challenges in precision machining, the research explores the synergistic effects of ultrasonic energy and flow field dynamics, offering novel insights for high-quality metal micromachining applications. The research establishes a mathematical model to analyze the interaction between the ultrasonic energy field and electrolytic machining and optimizes the flow field in the narrow electrolytic gap using Fluent software, revealing that an initial electrolyte velocity of 4 m/s and ultrasonic amplitude of 35 μm ensure optimal stability. High-speed photography is employed to capture bubble distribution and micro-pit formation dynamics, while SS304 surface experiments analyze the effects of machining parameters on micro-dimple localization and surface quality. The results show that optimized parameters significantly improve micro-texture quality, yielding micro-pits with a width of 223.4 μm, depth of 28.9 μm, aspect ratio of 0.129, and Ra of 0.205 μm, providing theoretical insights for high-precision metal micromachining. Full article

Three-dimensional (3D) concrete printing (3DCP) has gained significant attention over the last decade due to its many claimed benefits. The absence of effective real-time quality control mechanisms, however, can lead to inconsistencies in extrusion, compromising the integrity of 3D-printed structures. Although the importance of quality control in 3DCP is broadly acknowledged, research lacks systematic methods. This research investigates the feasibility of using ultrasonic pulse velocity (UPV) as a practical, in situ, real-time monitoring tool for 3DCP. Two different groups of binders were investigated: limestone calcined clay (LC³) and zeolite-based mixes in binary and ternary blends. Filaments of 200 mm were extruded every 5 min, and UPV, pocket hand vane, flow table, and viscometer tests were performed to measure pulse velocity, shear strength, relative deformation, yield stress, and plastic viscosity, respectively, in the fresh state. Once the filaments presented printing defects (e.g., filament tearing, filament width reduction), the tests were concluded, and the open time was recorded. Isothermal calorimetry tests were conducted to obtain the initial heat release and reactivity of the supplementary cementitious materials (SCMs). Results showed a strong correlation (R² = 0.93) between UPV and initial heat release, indicating that early hydration (ettringite formation) influenced UPV and determined printability across different mixes. No correlation was observed between the other tests and hydration kinetics. UPV demonstrated potential as a real-time monitoring tool, provided the mix-specific pulse velocity is established beforehand. Further research is needed to evaluate UPV performance during active printing when there is an active flow through the printer. Full article

Titanium alloy/carbon fiber-reinforced polymer (TA1/CFRP) laminates, representing the latest fourth generation of fiber metal laminates (FMLs), is a kind of high-performance composite material. However, the fragility of the fiber/resin and metal/resin interface layers in these composites directly impacts their mechanical properties. To enhance these properties, this paper investigates the preparation process of multi-walled carbon nanotube (MWCNT)-reinforced ultra-thin TA1/CFRP laminates and explores the impact of MWCNT content on the interlayer properties of these ultra-thin TA1/CFRP laminates. Initially, the challenge of dispersing carbon nanotubes using ultrasonic dispersion devices and dispersants was addressed. Vacuum-curing pressure studies revealed minimal overflow at 0.8 bar vacuum. Subsequently, the impact of MWCNT content on interlayer properties was investigated. The results indicated a significant increase in interlayer shear strength and interlayer fracture toughness with MWCNT additions at 0.5 wt% and 0.75 wt%, whereas the interlayer properties decreased at 1.0 wt% MWCNT. Fracture morphology analysis revealed that MWCNT content exceeding 0.75 wt% led to agglomeration, resulting in resin cavity formation and stress concentration. Full article

Polymer brushes (PBs) are transformative surface-modifying nanostructures, yet their synthesis via controlled methods like copper-mediated surface-initiated atom-transfer radical polymerization (Cu⁰-SI-ATRP) faces reproducibility challenges due to a lack of understanding of parameter interdependencies. This study systematically evaluates the Cu⁰-SI-ATRP process for polyacrylamide brushes (PAM-PBs), aiming to clarify key parameters that influence the synthesis process. This evaluation followed a step-by-step characterization that tracked molecular changes through infrared spectroscopy (IR) and surface development by contact angle (CA) through two different mixing methods: ultrasonic mixing and process simplification (Method A) and following literature-based parameters (Method B). Both methods, consisting of surface activation, 3-aminopropyltriethoxysilane (APTES) deposition, bromoisobutyryl bromide (BiBB) anchoring, and polymerization, were analyzed by varying parameters like concentration, temperature, and time. Results showed ultrasonication during surface activation enhanced siloxane (1139→1115 cm⁻¹) and amine (1531 cm⁻¹) group availability while reducing APTES concentration to 1 Vol% without drying sufficed for BiBB anchoring. BiBB exhibited insensitivity to concentration but benefited from premixing, evidenced by sharp C–Br (~1170 cm⁻¹) and methyl (3000–2800 cm⁻¹) bands. Additionally, it was observed that PAM-PBs improved with Method A, which had reduced variance in polymer fingerprint regions compared to Method B. Adding to the above, CA measurements gave complementary step-by-step information along the modifications of the surface, revealing distinct wettability behaviors between bulk PAM and synthesized PAM-PBs (from 51° to 37°). As such, this work identifies key parameter influence (e.g., mixing, BiBB concentration), simplifies steps (drying omission, lower APTES concentration), and demonstrates a step-by-step, systematic parameter decoupling that reduces variability. In essence, this detailed parameter analysis addresses the PAM-PBs synthesis process with better reproducibility than the previously reported synthesis method and achieves the identification of characteristic behaviors across the step-by-step process without the imperative need for higher-cost characterizations. Full article

To mitigate the adverse effects of particle agglomeration in alkali-activated coal gangue-based cementitious (AAM–CG) materials, ultrasonic treatment and fractal theory, combined with microscopic analysis techniques were employed to investigate the physical activity of coal gangue (CG) and the microscopic mechanisms of AAM–CG materials. The results indicate that ultrasonic treatment effectively enhances the mechanical properties of AAM–CG materials. With increasing ultrasonic duration, the compressive strength initially rises and then declines, whereas it shows a continuous upward trend with increasing ultrasonic power. The optimal dispersion of CG particles in AAM–CG materials was achieved under ultrasonic treatment at 840 W for 4 min, resulting in a peak compressive strength of 106 MPa. This represents a 28.8% enhancement compared to non-sonicated controls. Ultrasonic treatment effectively disperses agglomerated particles, fully activates CG reactivity, promotes the formation of cementitious phases, improves pore-filling effects, and optimizes the internal pore structure of the material. Compared to untreated samples, the fractal dimension of the pore structure increased after ultrasonic treatment, harmful pores decreased, and porosity was reduced by 32%. This study expands the application of ultrasonic technology in the preparation of alkali-activated geopolymers and provides an efficient activation method for the resource utilization of CG. Full article

Nickel-based superalloys, renowned for their exceptional high-temperature strength, oxidation resistance, and corrosion resistance, have become essential materials in the aerospace, defense, and nuclear industries. However, due to their poor machinability, common cutting processes often result in poor surface quality, difficulties in chip breaking, and significant tool wear. This study investigates the surface integrity of nickel-based superalloys during ultrasonic elliptical vibration cutting. The effects of various process parameters on the surface roughness, residual stress, and microhardness are systematically analyzed. The results indicate that under ultrasonic elliptical vibration cutting conditions, the surface roughness of the workpiece increases with the ultrasonic amplitude, cutting depth, and feed rate. It initially decreases and then increases with cutting speed, and decreases with an increase in the tool tip radius. The post-cutting residual stress in the nickel-based superalloy decreases with higher cutting speed and ultrasonic amplitude, but increases with greater cutting depth and tool tip radius. The surface microhardness increases with the cutting speed up to a point, after which it decreases, while it significantly increases with a higher ultrasonic amplitude, feed rate, and cutting depth. A comparative experiment was conducted between ultrasonic elliptical vibration and conventional cutting. The research results showed that when the cutting depth was 2 µm, the surface roughness and wear decreased by 19% and 53%, respectively, and the residual compressive stress and microhardness increased by 44% and 21%, respectively. This further verified the significant advantages of ultrasonic elliptical vibration cutting in optimizing machining performance. Full article

Compared to traditional temperature measurement methods, ultrasonic temperature measurement technology based on the principle of resonance offers advantages such as shorter section lengths, higher signal amplitude, and reduced signal attenuation. First, the type of sensor-sensitive element was determined, with a resonant design chosen to improve measurement performance; using magnetostrictive and resonant temperature measurement principles, the length, diameter, and resonator dimensions of the waveguide rod were designed, and a molybdenum–rhenium alloy (Mo-5%Re) material suitable for high-temperature environments was selected; COMSOL finite element simulation was used to simulate the propagation characteristics of acoustic signals in the waveguide rod, observing the distribution of sound pressure and energy attenuation, verifying the applicability of the model in high-temperature testing environments. Second, a resonant temperature sensor consistent with the simulation parameters was prepared using a molybdenum–rhenium alloy waveguide rod, and an ultrasonic resonant temperature-sensing system suitable for high-temperature environments up to 1800 °C was constructed using the molybdenum–rhenium alloy waveguide rod. The experiment used a tungsten–rhenium calibration furnace to perform static calibration of the sensor. The temperature range was set from room temperature to 1800 °C, with the temperature increased by 100 °C at a time, and it was maintained at each temperature point for 5 to 10 min to ensure thermal stability. This was conducted to verify the performance of the sensor and obtain the functional relationship between temperature and resonance frequency. Experimental results show that during the heating process, the average resonance frequency of the sensor decreased from 341.8 kHz to 310.37 kHz, with an average sensitivity of 17.66 Hz/°C. During the cooling process, the frequency increased from 309 kHz to 341.8 kHz, with an average sensitivity of 18.43 Hz/°C. After cooling to room temperature, the sensor’s resonant frequency returned to its initial value of 341.8 kHz, demonstrating excellent repeatability and thermal stability. This provides a reliable technical foundation for its application in actual high-temperature environments. Full article

The inspection of oil storage tanks is a critical measure to prevent the risk of oil leakage. Therefore, research has focused on magnet-type climbing robots for automated tank inspections. While existing magnet-type climbing robots have demonstrated significant improvements in climbing steel structures, their capability in terms of metal thickness measurement has not been previously evaluated. During thickness inspections, ultrasonic thickness sensors require a probe to be pressed against target surfaces. To automate metal thickness measurements, this pressing motion of the probe needs to be performed by the robot. This study introduces a novel metal thickness measurement device comprising an ultrasonic probe, a linear actuator, a gel pump, and a pressure sensor designed for a magnet-type climbing robot. The linear actuator moves the probe to its initial position, the gel pump injects a coupling gel, and then the actuator moves the probe to the surface and back. Finally, our prototype of an ultrasonic probe with a linear actuator was installed on a magnet-type climbing robot to demonstrate its functionality in a practical application regarding an oil storage tank inspection system. The prototype achieved a measurement success rate of 65.9% and an average error of 0.7% compared to a reference thickness. This article details the design and development of the ultrasonic probe with a linear actuator to enable the probe to make contact with the surface. It then details the experimental results and evaluation of metal thickness measurement performed using the prototype and the climbing robot. Full article

In this study, an orthogonal array design was employed to optimize total flavonoid extraction conditions. The results showed that the optimal conditions were an ethanol concentration of 70%, an ultrasonic power of 250 W, a solid–liquid ratio of 1:30 g/mL, and an ultrasonic time of 25 min. Under these optimal extraction conditions, the total flavonoid yield was 169.3 mg/g plant material. The purification effects of LX-38, LX-60, LS-46, LS-306, XDA-8, AB-8, and D101 macroporous resins on the total flavonoids of Eucommia ulmoides leaves were also investigated. The parameters of the process using XDA-8 macroporous resin for the purification of the crude extract of total flavonoids from Eucommia ulmoides leaves were investigated. The adsorption conditions of the XDA-8 resin consisted of an initial sample concentration of 2.0 mg/mL, a sample pH value of 5.0, an adsorption flow rate of 1.5 mL/min, and a temperature of 25 °C. The desorption conditions of the XDA-8 resin consisted of 60% ethanol used as a desorption solution and a 2.0 mL/min desorption flow rate of the eluent. The total flavonoids from the Eucommia ulmoides leaves were purified under these conditions, and, afterward, the flavonoid content was 51.5%. The main components of the purified flavonoids from the Eucommia ulmoides leaves were isolated using high-performance liquid chromatography (HPLC), and they included chlorogenic acid, rutin, isoquercetin, kaempferol-3-O-rutinoside, quercetin 3-rhamnoside, hyperoside, and quercetin. The antioxidant activities were measured, and those of the purified total flavonoids from the Eucommia ulmoides leaves were higher than those of dibutylhydroxytoluene (BHT) and lower than those of ascorbic acid (Vc). Additionally, the purified total flavonoids from the Eucommia ulmoides leaves exhibited significant antioxidant activities. Full article

Background:Cenostigma bracteosum (Tul.) Gagnon & G.P. Lewis (Fabaceae), popularly known as “catingueira”, is a plant widely distributed in the Caatinga biome, which comprises 11% of the Brazilian territory. While this species is of interest given local knowledge, formal reports are lacking in the literature, warranting targeted investigation. This study aimed to prepare and characterize a hydroethanolic extract of C. bracteosum leaves, prepare carbopol gels containing the extract, and evaluate their cytotoxicity and antibacterial activity against Staphylococcus aureus and Escherichia coli. Methods: The initial extract was prepared in an ultrasonic bath using ethanol/water (70:30, v/v). The extract (1 mg/mL) was analyzed by liquid chromatography coupled with mass spectrometry (UHPLC-MS/MS). Carbopol-based gels containing 1% and 3% of C. bracteosum extract were prepared and characterized in terms of pH, conductivity, spreadability, and rheology. The cytotoxicity was determined by the MTT method using MC3T3-E1 pre-osteoblast cells and L929-CCL1 fibroblast cells. The antibacterial activity of the extract and gels was evaluated using the agar diffusion method against S. aureus and E. coli. Results: The C. bracteosum leaves extract demonstrated antibacterial activity against S. aureus and E. coli, were not cytotoxic for the assessed cells at concentrations up to 100 μg/mL, and its analysis by UHPLC-MS/MS allowed the annotation of 18 metabolites, mainly of the phenolic acid and flavonoids glycoside classes, together with a biflavonoid. The prepared gels remained stable over the 30-day post-production analysis period. Conclusions: These findings provide a better understanding of the chemical diversity of the secondary metabolites of a common Caatinga biome species—C. bracteosum—specifically present in leaves hydroethanolic extract and gel formulation adapted for skin application with activity against S. aureus. Full article

The application of rebar reinforced ultra-high-performance concrete (R-UHPC) has been increasingly adopted in engineering structures due to its exceptional mechanical performance and durability characteristics. Nevertheless, when subjected to combined saline and stray current conditions, R-UHPC remains vulnerable to severe corrosion degradation. This investigation examined the corrosion performance and tensile behavior evolution of R-UHPC containing 2.0 vol% copper-coated steel fiber content and HRB400 steel rebar with a reinforcement ratio of 3.1%. The accelerated corrosion process was induced through an impressed current method, followed by direct tensile tests at varying exposure periods. The findings revealed that the embedding of rebar in UHPC led to the formation of fiber-to-rebar (F-R) conductive pathways, generating radial cracks besides laminar cracks. The bonding between rebar and UHPC degraded as corrosion progressed, leading to the loss of characteristic multiple-cracking behavior of R-UHPC in tension. Meanwhile, R-UHPC load-bearing capacity, transitioning from gradual to accelerated deterioration phases with prolonged corrosion, aligns with steel fibers temporally. During the initial 4 days of corrosion, the specimens displayed surface-level corrosion features with negligible steel fiber loss, showing less than 4.0% reduction in ultimate bearing capacity. At 8 days of corrosion, the steel fiber decreased by 22.6%, accompanied by an 18.3% reduction in bearing capacity. By 16 days of corrosion, the steel fiber loss reached 41.5%, with a corresponding bearing capacity reduction of 29.1%. During the corrosion process, corrosion cracks and load-bearing degradation in R-UHPC could be indicated by the ultrasonic damage factor. Full article

The aim to reduce health risks of workers related to inhalative exposure to potentially toxic dusts requires the selection of appropriate measures depending on the hazard classification of the dust-composing materials. Due to their biodurability, respirable carbon fibers and their fragments can impose such health risks but are currently lacking hazard classification. Here, a method is presented for fragmenting carbon fiber materials and enriching fibrous fragments to a level that is expected to allow differentiating between fiber and particle overload-related toxic effects. The method was applied to a commercial polyacrylonitrile-based carbon fiber. It was ground in an oscillating ball mill, homogenized in a liquid using ultrasonication and left undisturbed for gravitational settling. This way, a vertical gradient in particle size and shape formed, from which the supernatant was collected. Fragment morphologies were characterized with large ensemble statistics by semi-automated evaluation of scanning electron microscopy images employing an artificial neural network for binary semantic segmentation. The number of fibrous fragments of respirable and thus critical fiber morphology was increased from $0.36\times {10}^6$ to $6\times {10}^6$ WHO-analog fibers per mg. This corresponds to a factor of about 15 compared to the initial ground material. Since the mass percentage of non-fibrous objects was also significantly reduced, the requirements for a subsequently scheduled toxicological study with intraperitoneal application were fulfilled. Intraperitoneal testing is an accepted method for assessing the carcinogenic potential of biopersistent fibers. The developed method allows enriching fibrous fractions of concern at acceptable throughput and enables testing fiber toxicological effects of respirable fragments from disintegrated polyacrylonitrile-based carbon fibers. Full article

This investigation aimed at studying the effect of enrichment of corn oil, which was used as a model lipid, using waste orange peel (WOP), polyphenolic antioxidants, to provide effective shielding against oxidation. An initial comparison of two modes, a stirred-tank and an ultrasound-assisted one, evidenced that the latter was more efficacious in enriching corn oil with total polyphenols. However, detailed examination of the polyphenolic composition revealed that the oil enriched with the stirred-tank mode may have almost two times higher polyphenolic content, which totaled 109 mg per kg of oil. The major polyphenolic constituents identified were polymethylated flavones, but also ferulic acid and naringenin. Oil stability trials, including the monitoring of peroxide value and p-anisidin value, demonstrated that the oil enriched with WOP polyphenols using the stirred-tank mode exhibited significantly higher oxidative resilience compared to control (neat oil), but also compared to the oil enriched using ultrasonication. Furthermore, it was observed that when neat oil was ultrasonicated, it also displayed exceptional stability against oxidation. Based on the outcome of this study, it is recommended that WOP, owed to its richness in lipophilic flavonoids, might be an ideal candidate for edible oil fortification, which could provide the oil with natural powerful antioxidants. Such a process could lend oils high oxidative resilience, but also functional ingredients. Full article

Xanthan gum (XG) is a biopolymer primarily composed of polysaccharides that is increasingly employed to stabilize problematic soils. Although promising results have been obtained in clayey soils, its effect on other geomaterials remains underexplored. This study investigates the impact of XG on the mechanical strength (q_u), stiffness (Go), and microstructure of compacted mixtures of soil and reclaimed asphalt pavement (RAP). A two-part mixing method was adopted: Initially, the XG was mixed with water to form a hydrosolution before mixing in the soil and subsequently combined with the soil–RAP mixture. Xanthan gum was incorporated at dosages of 0.5%, 1.0%, 1.5%, and 2.0% relative to the dry soil weight, while RAP contents were varied at 10%, 20%, and 30% on a dry soil basis. The compaction density was adjusted between 17 and 18 kN/m³, with an optimum moisture content of 18% as determined by the Proctor test. Specimens were cured in a humid chamber for 14 and 28 days. The experimental methodology included unconfined compression tests, ultrasonic pulse velocity measurements, and characterization using scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM–EDS). The findings show that the mechanical strength of the soil–RAP mixture increased with the incorporation of up to 1% XG, which was identified as the optimal dosage. The strength values declined at higher dosages (1.5% and 2.0%). Moreover, the highest strength and stiffness were achieved with a 10% RAP content, while mixtures containing 20% and 30% RAP exhibited reduced performance. Microstructural analysis revealed that at 1% XG, there was a pronounced interaction between the XG and the soil–RAP matrix; however, as the RAP content increased, the larger voids present led only to a moderate interaction between the materials. Additionally, a correlation between the stiffness parameter (Go) and the unconfined compressive strength (q_u) was established, showing that the Go/q_u ratio was dependent on the percentage of XG yet remained independent of curing time—a finding that contrasts with previous correlations for this type of soil that were unaffected by other factors. Full article