Search Results (14)

The dielectric relaxation behavior of polymeric materials is critical to their performance in electronic, insulating, and energy storage applications. This study presents an electrical fractional model (EFM) based on fractional calculus and the complex electric modulus ($M^{*}\mathit{=}{M}^{\prime }\mathit{+}i{M}^{″}$) formalism to simultaneously describe two key relaxation phenomena: $\alpha$-relaxation and interfacial polarization (Maxwell–Wagner–Sillars effect). The model incorporates fractional elements (cap-resistors) into a modified Debye equivalent circuit to capture polymer dynamics and energy dissipation. Fractional differential equations are derived, with fractional orders taking values between 0 and 1; the frequency and temperature responses are analyzed using Fourier transform. Two temperature-dependent behaviors are considered: the Matsuoka model, applied to $\alpha$-relaxation near the glass transition, and an Arrhenius-type equation, used to describe interfacial polarization associated with thermally activated charge transport. The proposed model is validated using literature data for amorphous polymers, polyetherimide (PEI), polyvinyl chloride (PVC), and polyvinyl butyral (PVB), successfully fitting dielectric spectra and extracting meaningful physical parameters. The results demonstrate that the EFM is a robust and versatile tool for modeling complex dielectric relaxation in polymeric systems, offering improved interpretability over classical integer-order models. This approach enhances understanding of coupled relaxation mechanisms and may support the design of advanced polymer-based materials with tailored dielectric properties. Full article

Modern logistics requires effective solutions for the optimization of intermodal transportation, providing cost reduction and improvement of transport flows. This paper proposes a multi-objective optimization method for intermodal freight transportation planning within the framework of sustainable service network design. The approach aims to balance economic efficiency and environmental sustainability by minimizing both transportation costs and delivery time. A bi-criteria mathematical model is developed and solved using the Non-dominated Sorting Genetic Algorithm III (NSGA-III), which is well-suited for handling complex, large-scale optimization problems under multiple constraints. The aim of the study is to develop and implement this technology that balances economic efficiency, environmental sustainability and manageability of operational processes. The research includes the development of a two-criteria model that takes into account both temporal and economic parameters of the routes. The optimization method employs the NSGA-III, a well-known metaheuristic that generates a diverse set of near-optimal Pareto-efficient solutions. This enables the selection of trade-off alternatives depending on the decision-maker’s preferences and specific operational constraints. Simulation results show that the implementation of the proposed technology can reduce the costs of intermodal operators by an average of 8% and the duration of transportation by up to 50% compared to traditional planning methods. In addition, the automation of the process contributes to a more rational use of resources, reducing carbon emissions and increasing the sustainability of transportation networks. This approach is in line with the principles of sustainable economic development, as it improves the efficiency of logistics operations, reduces pressure on infrastructure and minimizes the environmental impact of the transport sector. Route optimization and digitalization of transport processes can increase resource efficiency, improve freight flow management and contribute to the long-term stability of transport systems. The developed technology of automated planning of intermodal transportation is oriented to application in large-scale production systems, providing effective management of cargo flows within complex logistics chains. The proposed method supports the principles of sustainable development by providing a formal decision-making framework that balances transportation cost, delivery time and environmental objectives. Instead of optimizing for a single goal, the model enables the identification of efficient trade-offs between economic performance and ecological impact. Moreover, by generating multiple routing scenarios under varying operational constraints, the approach enhances the adaptability and robustness of freight transportation systems in dynamic and uncertain environments. Full article

The study examines the process of information transfer between the sensor network end IoT device and the hub at the transport protocol level focused on using the 5G platform. The authors interpreted the researched process as a semi-Markov (focused on the dynamics of the size of the protocol sliding window) process with two nested Markov chains (the first characterizes the current size of the sliding window, and the second, the number of data blocks sent at the current value of this characteristic). As a result, a stationary distribution of the size of the sliding window was obtained both for the resulting semi-Markov process and for nested Markov chains, etc. A recursive approach to the calculation of the mentioned stationary distribution is formalized. This approach is characterized by linear computational complexity. Based on the obtained stationary distribution of the size of the sliding window, a distribution function is formulated that characterizes the bandwidth of the communication channel between the entities specified in the research object. Using the resulting mathematical apparatus, the Window Scale parameter of the TCP Westwood+ protocol was tuned. Testing has shown the superiority of the modified protocol over the basic versions of the BIC TCP, TCP Vegas, TCP NewReno, and TCP Veno protocols in conditions of data transfer between two points in the wireless sensor network environment. Full article

Electric potentials referred to as the gravielectric effect ($∆{\Psi }_S$) are generated in a double-membrane system containing identical polymer membranes set in horizontal planes and separating non-homogenous electrolyte solutions. The gravielectric effect depends on the concentration and composition of the solutions and is formed due to the gravitational field breaking the symmetry of membrane complexes/concentration boundary layers formed under concentration polarization conditions. As a part of the Kedem–Katchalsky formalism, a model of ion transport was developed, containing the transport parameters of membranes and solutions and taking into account hydrodynamic (convective) instabilities. The transition from non-convective to convective or vice versa can be controlled by a dimensionless concentration polarization factor or concentration Rayleigh number. Using the original measuring set, the time dependence of the membrane potentials was investigated. For steady states, the $∆{\Psi }_S$ was calculated and then the concentration characteristics of this effect were determined for aqueous solutions of NaCl and ethanol. The results obtained from the calculations based on the mathematical model of the gravitational effect are consistent with the experimental results within a 7% error range. It has been shown that a positive or negative gravielectric effect appeared when a density of the solution in the inter-membrane compartment was higher or lower than the density in the outer compartments. The values of the $∆{\Psi }_S$ were in a range from 0 to 27 mV. It was found that, the lower the concentration of solutions in the outer compartments of the two-membrane system ($C_0$), for the same values of $C_m/C_0$, the higher the $∆{\Psi }_S$, which indicates control properties of the double-membrane system. The considered two-membrane electrochemical system is a source of electromotive force and functions as an electrochemical gravireceptor. Full article

A novel analytical formalism based on the quantum heat transport equation is proposed for the interaction of fs-laser pulses with deoxyribonucleic acid (DNA) strands. The formalism has the intensity of the laser beam and the interaction time between the laser and the DNA as input parameters. To this end, the thermal distribution generated in the irradiated DNA strands was introduced by splitting the laser beam into transverse Hermite-Gauss modes. To achieve this goal, a new powerful mathematical model was developed and applied. Fluctuations in laser intensity were taken into account by modeling them as superpositions of Hermite-Gauss laser modes. These analyses were carried out for a laser pulse duration of 100 fs, where a tiny heat-affected zone is expected, with positive predicted effects on the stability and repeatability of this technology. The main conclusion is that the laser beam spatial distribution intensity plays an essential role in the generation of the shape and magnitude of the thermal field at the junction of the irradiated DNA strands. The model may prove useful in modeling laser beam processing under significant intensity fluctuations. There are at least two main areas of application for the present model of heat transfer from laser to DNA: (i) the study of DNA elongation without destroying the target information (for a sample temperature variation lower than 10 K; in the case of H[1,y]); and (ii) cancer treatment (especially of skin tissue), where we should obtain a temperature variation higher than 10 K (but lower than 30 K; in the case of H[2,y], H[4,y]), in order to eradicate the diseased cells. Full article

Using the Life Cycle Assessment (LCA) approach, environmental benefits in terms of CO₂ stored in chestnut wood in Italy have been calculated. Using one of the methodologies proposed under the LCA umbrella, a physical and formal balance sheet of CO₂ has been built. Chestnut forests (Castanea sativa Mill.) are one of the most critical forest types in Europe. They cover an area of 800,000 hectares in Italy, most of which are managed as coppices. Chestnut wood’s high-quality physical-chemical and mechanical characteristics and medium-long durability explains its widespread uses. In this case study a section of a public forest in Central Italy (Lazio Region) has been considered. In the section, during the rotation, two types of intervention were carried out: thinning at 19 years of age, and final cutting at the age of 32. A production of 416 and 93 m³ha⁻¹ for final cutting and thinning, respectively, was recorded. The global amount of 507 m³ is the functional unit, which has stored 547,875 kgCO₂. The combination of forest management and sawmill processing produces semi-finished chestnut timber products for 125 m³, which have a physical storage of 135,210 kgCO₂. Using the formal balance sheet of CO₂, total emissions from processing were recorded for a total of 27,766 kgCO₂. At the exit of sawmill, products stored 107,444 kgCO₂, which is the amount of Net-Carbon Dioxide Surplus (Net-CDS). Transportation from sawmill to market reduces the sequestered CO₂ by 0.77 kgCO₂/km. The Net-CDS represents a competitive advantage in the timber market. If tree species have the same physical, chemical, mechanical and price parameters, the timber consumer would prefer to buy wood with the highest Net-CDS. Full article

The Gravity Recovery and Climate Experiment (GRACE) satellite mission has provided global long-term observations of mass transport in the Earth system with applications in numerous geophysical fields. In this paper, we targeted the in-orbit performance of the GRACE key instruments, the ACCelerometers (ACC) and the MicroWave ranging Instrument (MWI). For the ACC data, we followed a transplant approach analyzing the residual accelerations from transplanted accelerations of one of the two satellites to the other. For the MWI data, we analyzed the post-fit residuals of the monthly GFZ GRACE RL06 solutions with a focus on stationarity. Based on the analyses for the two test years 2007 and 2014, we derived stochastic models for the two instruments and a combined ACC+MWI stochastic model. While all three ACC axes showed worse performance than their preflight specifications, in 2007, a better ACC performance than in 2014 was observed by a factor of 3.6 due to switched-off satellite thermal control. The GRACE MWI noise showed white noise behavior for frequencies above 10 mHz around the level of $1.5\times {10}^{-6} \mathrm{m}/\sqrt{\mathrm{Hz}}$. In the combined ACC+MWI noise model, the ACC part dominated the frequencies below 10 mHz, while the MWI part dominated above 10 mHz. We applied the combined ACC+MWI stochastic models for 2007 and 2014 to the monthly GFZ GRACE RL06 processing. This improved the formal errors and resulted in a comparable noise level of the estimated gravity field parameters. Furthermore, the need for co-estimating empirical parameters was reduced. Full article

In this work, a finite periodic superlattice is studied, analyzing the probability of electronic transmission for two types of semiconductor heterostructures, GaAs/AlGaAs and InSe/InP. The changes in the maxima of the quasistationary states for both materials are discussed, making variations in the number of periods of the superlattice and its shape by means of geometric parameters. The effect of a non-resonant intense laser field has been included in the system to analyze the changes in the electronic transport properties by means of the Landauer formalism. It is found that the highest tunneling current is given for the GaAs-based compared to the InSe-based system and that the intense laser field improves the current–voltage characteristics generating higher current peaks, maintaining a negative differential resistance (NDR) effect, both with and without laser field for both materials and this fact allows to tune the magnitude of the current peak with the external field and therefore extend the range of operation for multiple applications. Finally, the power of the system is discussed for different bias voltages as a function of the chemical potential. Full article

In this work, we perform a numerical study of magnetoresistance in a one-dimensional quantum heterostructure, where the change in electrical resistance is measured between parallel and antiparallel configurations of magnetic layers. This layered structure also incorporates a non-magnetic spacer, subjected to quasi-periodic potentials, which is centrally clamped between two ferromagnetic layers. The efficiency of the magnetoresistance is further tuned by injecting unpolarized light on top of the two sided magnetic layers. Modulating the characteristic properties of different layers, the value of magnetoresistance can be enhanced significantly. The site energies of the spacer is modified through the well-known Aubry–André and Harper (AAH) potential, and the hopping parameter of magnetic layers is renormalized due to light irradiation. We describe the Hamiltonian of the layered structure within a tight-binding (TB) framework and investigate the transport properties through this nanojunction following Green’s function formalism. The Floquet–Bloch (FB) anstaz within the minimal coupling scheme is introduced to incorporate the effect of light irradiation in TB Hamiltonian. Several interesting features of magnetotransport properties are represented considering the interplay between cosine modulated site energies of the central region and the hopping integral of the magnetic regions that are subjected to light irradiation. Finally, the effect of temperature on magnetoresistance is also investigated to make the model more realistic and suitable for device designing. Our analysis is purely a numerical one, and it leads to some fundamental prescriptions of obtaining enhanced magnetoresistance in multilayered systems. Full article

Cities demand urgent transformations in order to become more affordable, livable, sustainable, walkable and comfortable spaces. Hence, important changes have to be made in the way cities are understood, diagnosed and planned. The current paper puts urban accessibility into the centre of the public policy and planning agenda, as a transferable approach to transform cities into better living environments. To do so, a practical example of the City of Monterrey, Mexico, is presented at two planning scales: the metropolitan and local level. Both scales of analysis measure accessibility to main destinations using walking and cycling as the main transport modes. The results demonstrate that the levels of accessibility at the metropolitan level are divergent, depending on the desired destination, as well as on the planning processes (both formal and informal) from different areas of the city. At the local level, the Distrito Tec Area is diagnosed in terms of accessibility to assess to what extent it can be considered a part of a 15 minutes city. The results show that Distrito Tec lacks the desired parameters of accessibility to all destinations for being a 15 minutes city. Nevertheless, there is a considerable increase in accessibility levels when cycling is used as the main travelling mode. The current research project serves as an initial approach to understand the accessibility challenges of the city at different planning levels, by proving useful and disaggregated data. Finally, it concludes providing general recommendations to be considered in planning processes aimed to improve accessibility and sustainability. Full article

Mo disulfide overlayers with the thickness exceeding 1.77 nm were obtained on Si substrates through mechanical exfoliation. The resulting Mo disulfide flakes were then analyzed ex situ using combination of Auger electron spectroscopy (AES), elastic-peak electron spectroscopy (EPES) and scanning electron microscopy (SEM) in order to characterize their surface chemical composition, electron transport phenomena and surface morphology. Prior to EPES measurements, the Mo disulfide surface was sputter-cleaned and amorphized by 3 kV argon ions, and the resulting S/Mo atomic ratio varied in the range 1.80–1.88, as found from AES measurements. The SEM images revealed single crystalline small-area (up to 15 μm in lateral size) Mo disulfide flakes having polygonal or near-triangular shapes. Such irregular-edged flakes exhibited high crystal quality and thickness uniformity. The inelastic mean free path (IMFP), characterizing electron transport, was evaluated from the relative EPES using Au reference material for electron energies E = 0.5–2 keV. Experimental IMFPs, λ, determined for the AES-measured surface compositions were approximated by the simple function λ = kE^p, where k = 0.0289 and p = 0.946 were fitted parameters. Additionally, these IMFPs were compared with IMFPs resulting from the two methods: (i) present calculations based on the formalism of the Oswald et al. model; (ii) the predictive equation of Tanuma et al. (TPP-2M) for the measured Mo_0.293S_0.551C_0.156 surface composition (S/Mo = 1.88), and also for stoichiometric MoS₂ composition. The fitted function was found to be reasonably consistent with the measured, calculated and predicted IMFPs. We concluded that the measured IMFP value at 0.5 keV was only slightly affected by residual carbon contamination at the Mo disulfide surface. Full article

The Jurkat cell is an immortalized line of human acute lymphocyte leukemia cells that is widely used in the study of adoptive cell therapy, a novel treatment of several advanced forms of cancer. The ability to transport water and solutes across the cell membrane under different temperatures is an important factor for deciding the specific protocol for cryopreservation of the Jurkat cell. In this study we propose a comprehensive process for determination of membrane transport properties of Jurkat cell. using a novel microfluidic controlled single cell-trapping system. The osmotic behavior of an individual Jurkat cell to water and dimethyl sulfoxide (DMSO), a commonly used cryoprotective agent (CPA), under constant temperature, was recorded under a microscope utilizing the modified microfluidic system. The images of the Jurkat cell under osmotic change were processed to obtain a relationship between cell volume change and time. The experimental results were fitted using a two-parameter transport numeric model to calculate the Jurkat cell membrane permeability to water and DMSO at room temperature (22 °C). This model and the calculated parameters can help scientists optimize the cryopreservation protocol for any cell type with optimal cryoprotective agents and cooling rate for future experiments. Full article

Understanding the transport mechanisms and properties of complex networks is fundamental for the comprehension of a vast class of phenomena, from state transfer on a spin network to light-harvesting in photosynthetic complexes. It has been theoretically and experimentally demonstrated that noise can enhance transport when the system parameters are properly tuned, an effect known as noise-assisted transport (NAT). In this work we investigate the role of initial entanglement in the transfer efficiency of two walkers in a noisy network. By using the formalism of quantum walks, we define a range of small dephasing noise where initial site-entanglement provides transport enhancement and outperforms the NAT effect. Furthermore, we show two specific scenarios where entanglement-assisted transport can open faster channels for slow walkers and avoid a broken link in a communication line. These findings may be of potential interest for quantum technologies. Full article

A new formalism to describe metabolic fluxes as well as membrane transport processes was developed. The new flux equations are comparable to other phenomenological laws. Michaelis-Menten like expressions, as well as flux equations of nonequilibrium thermodynamics, can be regarded as special cases of these new equations. For metabolic network modeling, variable conductances and driving forces are required to enable pathway control and to allow a rapid response to perturbations. When applied to oxidative phosphorylation, results of simulations show that whole oxidative phosphorylation cannot be described as a two-flux-system according to nonequilibrium thermodynamics, although all coupled reactions per se fulfill the equations of this theory. Simulations show that activation of ATP-coupled load reactions plus glucose oxidation is brought about by an increase of only two different conductances: a [Ca²⁺] dependent increase of cytosolic load conductances, and an increase of phosphofructokinase conductance by [AMP], which in turn becomes increased through [ADP] generation by those load reactions. In ventricular myocytes, this feedback mechanism is sufficient to increase cellular power output and O₂ consumption several fold, without any appreciable impairment of energetic parameters. Glucose oxidation proceeds near maximal power output, since transformed input and output conductances are nearly equal, yielding an efficiency of about 0.5. This conductance matching is fulfilled also by glucose oxidation of β-cells. But, as a price for the metabolic mechanism of glucose recognition, β-cells have only a limited capability to increase their power output. Full article