Search Results (1,025)

Following the trend of food waste valorization to produce innovative bio-based materials, this study proposes the conversion of brewer’s spent grain (BSG) into added value edible, high oxygen barrier, flexible, active packaging films via an extrusion molding compression method. Gelatin (Gel) was used as both a reinforcement and barrier agent and glycerol (Gl) as a plasticizer. Eugenol was nanoencapsulated on natural zeolite (EG@NZ), and pure clove powder (ClP) was used as an active agent to obtain BSG/Gel/Gl/xEG@NZ and BSG/Gel/Gl/xClP (x = 5, 10, and 15 %wt.) active films. Both BSG/Gel/Gl/xEG@NZ and BSG/Gel/Gl/xClP films show enhanced tensile, oxygen barrier, antioxidant, and antibacterial properties, and low toxicity and genotoxicity values. All BSG/Gel/Gl/xEG@NZ films presented a higher oxygen barrier, higher total phenolic content (TPC) values, higher antioxidant activity according to a 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, higher inhibition zones against Staphylococcus aureus and Escherichia coli, and lower toxicity and genotoxicity than all BSG/Gel/Gl/xClP films. Thus, the superiority of the nanoencapsulated EG in NZ as compared to the physical encapsulated EG in ClP is proved. Briefly, BSG/Gel/Gl/15EG@NZ active film exhibited ~218% higher tensile strength, ~93% higher TPC value, and ~90% lower effective concentration for a 60% antioxidant activity value (EC₆₀) as compared to the pure BSG/Gel/Gl film. The zones against S. aureus and E. coli were 45 and 30 mm, respectively, and the oxygen barrier was zero. The use of this film extended the shelf life of fresh minced meat by two days and exhibited the high potential to be used as active packaging material. Full article

In the face of increasingly severe cybersecurity threats, incomplete information and environmental dynamics have become central challenges in network attack–defense scenarios. In real-world network environments, defenders often find it difficult to fully perceive attack behaviors and network states, leading to a high degree of uncertainty in the system. Traditional approaches are inadequate in dealing with the diversification of attack strategies and the dynamic evolution of network structures, making it difficult to achieve highly adaptive defense strategies and efficient multi-agent coordination. To address these challenges, this paper proposes a multi-agent network defense approach based on joint game modeling, termed JG-Defense (Joint Game-based Defense), which aims to enhance the efficiency and robustness of defense decision-making in environments characterized by incomplete information. The method integrates Bayesian game theory, graph neural networks, and a proximal policy optimization framework, and it introduces two core mechanisms. First, a Dynamic Communication Graph Neural Network (DCGNN) is used to model the dynamic network structure, improving the perception of topological changes and attack evolution trends. A multi-agent communication mechanism is incorporated within the DCGNN to enable the sharing of local observations and strategy coordination, thereby enhancing global consistency. Second, a joint game loss function is constructed to embed the game equilibrium objective into the reinforcement learning process, optimizing both the rationality and long-term benefit of agent strategies. Experimental results demonstrate that JG-Defense outperforms the Cybermonic model by 15.83% in overall defense performance. Furthermore, under the traditional PPO loss function, the DCGNN model improves defense performance by 11.81% compared to the Cybermonic model. These results verify that the proposed integrated approach achieves superior global strategy coordination in dynamic attack–defense scenarios with incomplete information. Full article

Concrete bridges, as a vital component of modern transportation infrastructure, have their structural durability directly tied to safety and service life. In recent years, with the aging of bridge structures and increasingly complex environmental conditions, various durability-related deteriorations have become more prominent, significantly affecting structural performance and maintenance costs. This paper presents a systematic analysis of concrete carbonation as a key chemical process and its impact on durability-related pathologies. Particular attention is given to the formation mechanisms and influencing factors of critical deterioration modes such as cracking, reinforcement corrosion, and freeze–thaw damage. A multi-level prevention and mitigation strategy is proposed, encompassing optimized structural material design, strict construction quality control, and effective maintenance and repair techniques. The study concludes that the durability issues of concrete bridge structures exhibit a strong multi-factor coupling effect and proposes a core durability assurance framework. Finally, the paper briefly outlines emerging trends in intelligent monitoring and digital operation and maintenance, offering insights for future durability management of bridges. Full article

Understanding vegetation dynamics and climate variability in the vicinity of Internally Displaced Person (IDP) camps is critical due to the high dependency of displaced populations on local natural resources. This study investigates vegetation cover changes and long-term climate variability around the Sortony IDP camp in Darfur, Sudan, using satellite and climate data spanning 1980 to 2024. High-resolution imagery from PlanetScope and Sentinel–2 Level 2A was used to assess vegetation cover changes from 2015 to 2024, while precipitation, temperature, and drought trends were analyzed over 44 years (1980–2024). Vegetation changes were quantified using the Normalized Difference Vegetation Index (NDVI), and drought conditions were assessed through the Standardized Precipitation Evapotranspiration Index (SPEI) at 6-, 9-, and 12-month timescales. Future precipitation predictions were modeled using the Autoregressive Integrated Moving Average (ARIMA) model. The results revealed a substantial increase in vegetative cover: the dense vegetation class increased by 3.50%, moderate vegetation by 17.33%, and low vegetation by 30.22%. In contrast, sparse and non-vegetated areas declined by 4.55% and 46.51%, respectively. The SPEI analysis indicated a marked reduction in drought frequency and severity after 2015, following a period of prolonged drought from 2000 to 2014. Forecasts suggest continued increases in rainfall through 2034, which may further support vegetation regrowth. These findings underscore the complex interplay between climatic factors and human activity in conflict-affected landscapes. The observed vegetation recovery highlights the region’s potential for ecological resilience, reinforcing the urgent need for sustainable land-use planning and climate-adaptive management strategies in humanitarian and post-conflict settings such as Darfur. Full article

Background: Unplanned pregnancy is a public health issue and understanding women’s decision making aids practitioners in assessing fertility trends, contraception use, and family planning counselling. In Italy, Catholicism reinforces ‘natural reproduction’ and ‘traditional’ contraception, making it an ‘Imperfect Contraceptive Society.’ A valid and reliable measure of pregnancy intentionality is increasingly important, and the London Measure of Unplanned Pregnancy (LMUP) has proved effective. Objectives and Methods: This study comprised four stages: (1) English–Italian translation and back-translation to create the Italian version [LMUP-IT]; (2) online data collection from postnatal women; (3) evaluation of its psychometric properties (targeting, reliability, construct validity via CFA and measurement invariance with a UK sample, ‘known groups’ hypothesis testing); and (4) exploratory analysis of its associations with perinatal mental health. The sample comprised 450 postnatal women (M_age = 33.6 ± 4.5). Results: The LMUP-IT was shown to be reliable (ωT = 0.81, α = 0.76), with acceptable targeting. Measurement invariance testing confirmed consistency with the UK sample in factor structure, loadings, intercepts, and errors. LMUP-IT scores significantly correlated with well-known indicators of perinatal mental health. Conclusions: Overall, the LMUP-IT is a reliable measure of pregnancy intention in Italian for postpartum women. Understanding pregnancy intention will help healthcare professionals tailor interventions to better support women’s mental health during the transition to motherhood. Full article

Background: Armed conflicts impose complex logistical and behavioral challenges on healthcare systems, particularly in managing acute conditions such as ST-elevation myocardial infarction (STEMI) and ischemic stroke. Although both diagnoses require timely intervention, their clinical pathways differ significantly. Few studies have systematically compared their management during active warfare, particularly within the warzone. Methods: This retrospective cohort study was conducted at Soroka University Medical Center (SUMC), the sole tertiary hospital in southern Israel and the main referral center for cardiovascular and neurological emergencies in the region. We included all adult patients (≥18 years) admitted with new-onset STEMI or ischemic stroke during three-month periods of wartime (October–December 2023) and matched routine periods in 2021 and 2022. Patients with in-hospital events, inter-hospital transfers, or foreign citizenship were excluded. Data on demographics, comorbidities, arrival characteristics, treatment timelines, and outcomes were extracted from electronic medical records. Categorical variables were compared using Chi-squared or Fisher’s exact test, and continuous variables using t-tests or Mann–Whitney U tests, as appropriate. Multivariable logistic and linear regression models were adjusted for age, sex, Charlson Comorbidity Index (CCI), and mode of arrival. Interaction terms assessed whether wartime modified the associations differently for STEMI and stroke. Results: A total of 410 patients were included (193 with STEMI and 217 with stroke). Patients with STEMI were significantly more likely to arrive by self-transport during the war (38, 57.6% vs. 32, 25.2%, p < 0.001) and had higher rates of late arrival beyond 12 h (19, 28.8% vs. 13, 10.2%, p = 0.002). These findings support the conclusion that patients were more prone to delayed and unstructured presentations during a crisis. In contrast, patients with stroke showed a reduction of 354 min in symptom-to-door times during the war [median 246 (30–4320 range) vs. 600 min (12–2329 range), p = 0.026]. Regression models revealed longer delays for stroke vs. STEMI in routine settings [β = 543.07 min (239.68–846.47 95% CI), p < 0.001], along with significantly lower in-hospital (OR = 0.39, 95% CI= 0.15–0.97, p = 0.05) and 30-day mortality (OR = 0.43, 95% CI= 0.19–0.94, p = 0.04). However, these differences were no longer significant during wartime. Patients with STEMI showed a trend toward lower 180-day mortality during the war (OR = 0.33, 95% CI = 0.09–0.99; p = 0.07), although this difference did not reach statistical significance. Conclusions: During wartime, patients with stroke arrived earlier and in greater numbers, while patients with STEMI showed reduced admissions and delayed, self-initiated transport. Despite these shifts, treatment timelines and short-term outcomes were maintained. These diagnosis-specific patterns highlight the importance of reinforcing EMS access for STEMI and preserving centralized protocol-based coordination for stroke during crises. Full article

Biocompatible polymers have emerged as essential materials in medical 3D printing, enabling the fabrication of scaffolds, tissue constructs, drug delivery systems, and biosensors for applications in and on the human body. This review aims to provide a comprehensive overview of the current state of 3D-printable biocompatible polymers and their composites, with an emphasis on their processing methods, properties, and biomedical uses. The scope of this work includes both natural and synthetic biocompatible polymers, polymer–nanocomposite systems, and bioinks that do not require photo initiators. The relevant literature was critically examined to classify materials by type, evaluate their compatibility with major 3D printing techniques such as stereolithography, selective laser sintering, and fused deposition modeling, and assess their performance in various medical applications. Key findings highlight that reinforced polymer composites, tailored surface chemistries, and hybrid printing strategies significantly expand the range of functional, customizable, and affordable biomedical devices. This review concludes by discussing present-day applications and emerging trends, underscoring that 3D-printable biocompatible polymers are rapidly transitioning from research to clinical practice, offering transformative potential for patient-specific healthcare solutions. Full article

The development of innovative and environmentally sustainable construction materials is a strategic priority in the context of the ecological transition and circular economy. Geopolymers and alkali-activated materials, derived from industrial and construction waste rich in aluminosilicates, are gaining increasing attention as low-carbon alternatives to ordinary Portland cement (OPC), which remains one of the main contributors to anthropogenic CO₂ emissions and landfill-bound construction waste. This review provides a comprehensive analysis of geopolymer-based solutions for building and architectural applications, with a particular focus on modular multilayer panels. Key aspects, such as chemical formulation, mechanical and thermal performance, durability, technological compatibility, and architectural flexibility, are critically examined. The discussion integrates considerations of disassemblability, reusability, and end-of-life scenarios, adopting a life cycle perspective to assess the circular potential of geopolymer building systems. Advanced fabrication strategies, including 3D printing and fibre reinforcement, are evaluated for their contribution to performance enhancement and material customisation. In parallel, the use of parametric modelling and digital tools such as building information modelling (BIM) coupled with life cycle assessment (LCA) enables holistic performance monitoring and optimisation throughout the design and construction process. The review also explores the emerging application of artificial intelligence (AI) and machine learning for predictive mix design and material property forecasting, identifying key trends and limitations in current research. Representative quantitative indicators demonstrate the performance and environmental potential of geopolymer systems: compressive strengths typically range from 30 to 80 MPa, with thermal conductivity values as low as 0.08–0.18 W/m·K for insulating panels. Life cycle assessments report 40–60% reductions in CO₂ emissions compared with OPC-based systems, underscoring their contribution to climate-neutral construction. Although significant progress has been made, challenges remain in terms of long-term durability, standardisation, data availability, and regulatory acceptance. Future perspectives are outlined, emphasising the need for interdisciplinary collaboration, digital integration, and performance-based codes to support the full deployment of geopolymer technologies in sustainable building and architecture. Full article

Background: Healthcare-associated infections (HAIs) remain a significant challenge in intensive care units (ICUs), especially in trauma settings where invasive interventions are frequent. This study aimed to assess the impact of a structured quality improvement project (QIP) on nosocomial infection rates and patient outcomes in a polytrauma ICU. Methods: We conducted a retrospective observational study at the “Pius Brînzeu” County Emergency Clinical Hospital, Timișoara. A total of 78 ICU trauma patients were included: 35 in the Pre-QIP group and 43 in the Post-QIP group. The QIP integrated evidence-based interventions, including hand hygiene reinforcement, individualized protective equipment, improved nurse staffing, and antimicrobial stewardship. Outcomes analyzed included nosocomial infection rate, ICU length of stay, antibiotic use, mechanical ventilation days, and mortality. Multivariable logistic, linear, and Poisson regression models were applied to control for confounding variables. Results: The Post-QIP group showed a significantly lower number of infections per patient (0.60 ± 0.95 vs. 1.41 ± 1.97, p = 0.03) and a trend toward lower mortality (0.19 vs. 0.34, p = 0.18). While ICU stay, antibiotic use, and ventilation days decreased post-QIP, these changes were not statistically significant. ISS and Charlson scores were consistent predictors of worse outcomes. Conclusions: Implementation of a targeted, multidisciplinary QIP was associated with improved infection control and patient outcomes. These results support the feasibility and value of structured infection prevention strategies in resource-constrained ICU settings. Full article

With the rapid expansion of underground rail transit construction in China, the high carbon emissions associated with subway tunnels and stations have become an increasing concern. This study systematically examines the carbon emissions of prefabricated concrete–filled steel pipe columns (PCSPCs) during the construction phase of a Beijing subway station built via the pile beam arch (PBA) method, applying the life cycle assessment (LCA) methodology as a case study. An analytical framework for the synergistic optimization of carbon emissions and costs was developed. By systematically adjusting key design parameters—such as the column diameter, wall thickness, and concrete strength—it was possible to minimize both carbon emissions and project costs while meeting the ultimate load-bearing capacity requirements. The results indicate that the production phase of PCSPCs accounts for as much as 98.845% of total carbon emissions, with labor, materials, and machinery contributing 10.342%, 88.724%, and 0.934%, respectively. A sensitivity analysis revealed that steel plates have the greatest impact on carbon emissions, followed by steel reinforcement, whereas concrete and cement exhibit relatively lower sensitivities. The ultimate load-bearing capacity of PCSPCs increases with larger column diameters, thicker walls, and higher concrete strength grades, with the relationships displaying a nonlinear trend. The damage modes and performance of PCSPCs under different design parameters were further verified through finite element analysis. On the basis of the optimization algorithm used to adjust the design parameters, the carbon emissions and costs of the PCSPCs were reduced by 10.32% and 21.55%, respectively, while still meeting the load-bearing capacity requirements. Full article

Under the global decarbonization trend, combined cooling, heating, and power (CCHP) systems are critical for improving regional energy efficiency. However, the integration of high-penetration variable renewable energy (RE) sources introduces significant volatility and multi-dimensional uncertainties, challenging conventional operation strategies designed for stable energy inputs. This review systematically examines recent advances in CCHP optimization under high-RE scenarios, with a focus on flexibility-enabled operation mechanisms and uncertainty-aware optimization strategies. It first analyzes the evolving architecture of variable RE-driven CCHP systems and core challenges arising from RE intermittency, demand volatility, and multi-energy coupling. Subsequently, it categorizes key flexibility resources and clarifies their roles in mitigating uncertainties. The review further elaborates on optimization methodologies tailored to high-RE contexts, along with their comparative analysis and selection criteria. Additionally, it details the formulation of optimization models, model formulation, and solution techniques. Key findings include the following: Generalized energy storage, which integrates physical and virtual storage, increases renewable energy utilization by 12–18% and reduces costs by 45%. Hybrid optimization strategies that combine robust optimization and deep reinforcement learning lower operational costs by 15–20% while strengthening system robustness against renewable energy volatility by 30–40%. Multi-energy synergy and exergy-efficient flexibility resources collectively improve system efficiency by 8–15% and reduce carbon emissions by 12–18%. Overall, this work provides a comprehensive technical pathway for enhancing the efficiency, stability, and low-carbon performance of CCHP systems in high-RE environments, supporting their scalable contribution to global decarbonization efforts. Full article

The construction industry is a major source of environmental degradation as it is responsible for a significant share of global CO₂ emissions, especially from cement and aggregate consumption. This study fills the need for sustainable construction materials by developing and evaluating a low-carbon fiber-reinforced concrete (FRC) made of steel slag powder (SSP), processed recycled concrete aggregates (PRCAs), and waste steel rivet fibers (WSRFs) derived from industrial waste. The research seeks to reduce dependency on virgin materials while maintaining high values of mechanical performance and durability in structural applications. Sixteen concrete mixes were used in the experimental investigations with control, SSP, SSP+RCA, and RCA, reinforced with various fiber dosages (0%, 0.2%, 0.8%, 1.4%) by concrete volume. Workability, density, compressive strength, tensile strength, and water absorption were measured according to the appropriate standards. Compressive and tensile strength increased in all mixes and the 1.4% WSRF mix had the best performance. However, it was found that a fiber content of 0.8% was optimal, which balanced the improvement in strength, durability, and workability by sustainable reuse of recycled materials and demolition waste. It was found by failure mode analysis that the transition was from brittle to ductile behavior as the fiber content increased. The relationship between compressive, tensile strength, and fiber content was visualized as a 3D response surface in order to support these mechanical trends. It is concluded in this study that 15% SSP, 40% PRCA, and 0.8% WSRF are feasible, specific solutions to improve concrete performance and advance the circular economy. Full article

To enhance the wear resistance of laser-clad coatings, this study investigates the underlying modulation mechanisms of scanning speed on the microstructure and properties of TiC-TiB₂-reinforced 316L stainless steel composite coatings. TiC/TiB₂ particle-reinforced 316L stainless steel composite coatings were fabricated on 45# steel substrates via laser cladding. Our analysis reveals that scanning speed critically governs the thermal cycle of the melt pool, thereby modulating the coating’s microstructure and properties: Lower scanning speeds prolong melt pool duration, consequently intensifying ceramic particle dissolution, coarsening, and tendencies toward agglomeration and settling. Conversely, higher scanning speeds promote rapid solidification, which both preserves ceramic particles and refines the matrix grains. With increasing scanning speed, accelerated melt pool cooling rates drive a microstructural transition from coarse dendrites to refined equiaxed grains, accompanied by dramatically enhanced uniformity in ceramic particle distribution. Coatings deposited at higher scanning speeds exhibit a 22% increase in hardness compared to those at lower speeds. Wear resistance evolution parallels this hardness trend: at 480 mm/min scanning speed, wear reduction can be expected, with the wear volume decreasing by 58.60% and the friction coefficient reducing by 42.1% relative to 120 mm/min. Full article

This article explores the papacy as a multifaceted form of cultural heritage, emphasizing the pope not only as a religious leader but also as a living symbol and institutional embodiment of Catholic heritage. Positioned at the intersection of theology, history, and heritage science, the study seeks to bridge the gap between spiritual authority and cultural memory by introducing a novel interpretive category: the pope as a living component of intangible religious heritage. The research combines a comprehensive literature review with an analysis of papal documentation, especially papal constitutions. Special attention is given to public engagement with the papacy, as reflected in internet search trends during significant ecclesiastical events such as papal deaths and conclaves. The results indicate that the pope functions as a living link in the continuity of Catholic identity, with digital indicators revealing peaks of global interest aligned with pivotal moments in Church leadership. The study also defines the roles and functions of the pope as a narrative bearer, initiator, and symbolic custodian of papal cultural heritage. Overall, the findings reinforce the papacy’s dual role as both a theological and sociocultural institution, offering new perspectives for understanding religious leadership as a medium of cultural transmission and public relevance in a digitized world. Full article

The present work aims to study the effect of cyclic loading on the tensile behavior of a chemically stabilized sandy soil, whether or not reinforced with polypropylene or sisal fibers. To this end, a series of splitting tensile strength tests were carried out by varying the frequency of the cyclic loading. During cyclic loading a substantial decrease in accumulated plastic axial displacement was observed with rising frequency when fibers were incorporated. On average, the reduction was 28% for polypropylene fibers and 14% for sisal fibers. For the polypropylene fibers, this effect is more pronounced because of a greater number of randomly distributed fibers, creating a strong and dense interlocking network. Regarding the load-displacement characteristics, fiber inclusion leads to a more ductile tensile response, which is identified by a secondary peak strength and residual strength. The cyclic loading frequency does not show a distinct trend concerning the post-cyclic tensile strength behavior; this behavior is dependent on the mechanical properties of materials (cemented matrix and fibers). Nevertheless, the cyclic stage resulted in an increased post-cyclic tensile strength for sisal fibers (ranging from 23% to 51%), although no clear trend was observed with respect to frequency variation. In contrast, for polypropylene fibers, the cyclic stage resulted in a more ductile tensile mechanical response, with post-cyclic tensile strength increasing from 1% to 16% as the frequency decreased. Full article