Search Results (461)

Fused deposition modelling (FDM) is increasingly used to produce high-performance polymer components; however, the mechanical performance of printed parts is often limited by weak interlayer adhesion, void formation, and residual thermal stresses. In this study, the effects of nozzle temperature, bed temperature, and post-treatment annealing temperature on the tensile and flexural strength of FDM-printed polyether ether ketone (PEEK) were investigated and optimized using Response Surface Methodology (RSM). A face-centred central composite design was employed to evaluate the individual, quadratic, and interaction effects of the three thermal parameters. The results showed that post-treatment annealing temperature was the most influential factor, contributing 56.48% to tensile strength and 52.73% to flexural strength, followed by nozzle temperature, which contributed 30.56% and 30.15%, respectively. Bed temperature showed a comparatively smaller individual effect; however, its interaction with nozzle temperature significantly influenced both tensile and flexural strength. The confirmation experiment performed at 200 °C post-treatment temperature, 414 °C nozzle temperature, and 142 °C bed temperature produced a tensile strength of 55.65 MPa and a flexural strength of 81.08 MPa, with prediction errors of 5.63% and 4.08%, respectively. SEM fracture analysis provided qualitative evidence that improved thermal processing reduced interlayer separation and visible void-related defects while promoting a more cohesive fracture morphology. These improvements are attributed to enhanced interlayer fusion, possible polymer-chain diffusion across layer boundaries, and thermal-stress relaxation during annealing. The findings demonstrate that thermal-parameter optimization and post-treatment annealing can improve the mechanical performance of FDM-printed PEEK within the investigated processing window. Full article

Fractures exert a significant influence on rock mass deformation and seepage pathways, thereby posing a serious challenge to the safe and efficient extraction of deep mines. This problem is particularly evident in deep mines located near the sea, where fractures are extensively developed. For such mines, the overlying seawater represents a considerable potential risk to mining safety. Therefore, investigating the distribution characteristics of deep fractures and clarifying the coupling relationships among the fracture, stress, seepage, and temperature fields are important for ensuring safe and efficient production in deep mines near the sea. Taking the auxiliary shaft of the Sanshandao Gold Mine as the engineering case, this study uses extensive measured fracture data, determines fracture locations by their centroids, and adopts kernel density estimation to non-parametrically characterize the fracture spatial distribution. Fourier convolution is then employed to rapidly reconstruct fracture positions in the discrete fracture network (DFN) model. The results demonstrate that the proposed kernel density estimation method can effectively identify the spatial distribution characteristics of fractures. Subsequently, the fracture field of the underground rock mass is reconstructed by the Monte Carlo method, and a thermal–hydro–mechanical multi-field coupling model incorporating the fracture field is established. The numerical results indicate that fluid flow is primarily concentrated along fractures, and that heat transfer within fractures is markedly faster than that in the rock matrix. The presence of fractures significantly affects the stress field of the underground rock mass, and their influence on the stress distribution increases as fracture length becomes greater. Accordingly, the effects of fractures should not be neglected in numerical analyses. The findings provide reliable support for mine stability calculations and safety evaluations. Full article

Cryogenic environments impose severe thermal and mechanical stresses on polymer components, yet the effects of long-term cryogenic cycling on their subsequent room-temperature performance remain insufficiently understood. This study investigated the influence of cryogenic cyclic aging on the mechanical and tribological behaviour of polyimide (PI)-based materials, including neat PI and composites reinforced with MoS₂, graphite, and/or PTFE. Repeated cryogenic cycling was followed by mechanical characterisation and tribological testing at 25 °C in air and vacuum. This work systematically compares neat and filled PI materials after cryogenic cyclic aging and correlates mechanical changes with transfer-film formation and wear behaviour. Cryogenic cyclic aging had only minor effects on weight and thermal stability but significantly altered the viscoelastic behaviour, increasing creep and residual strain, with variations depending on the polymer structure and filler content. Fracture toughness showed a statistically significant improvement only for PI2 (up to 93%). Changes in PI1, PI3, PI4, and PI5 fell within the experimental scatter and were interpreted as non-significant trends. In air, abrasive wear dominated in unreinforced PI, while graphite/PI composites exhibited adhesive wear and improved transfer film formation, reducing wear rates by up to 26%. In vacuum, the wear rate of aged graphite/PI increased by up to two orders of magnitude. Full article

A catastrophic Ms7.8 earthquake occurred in Tangshan in 1976 at a focal depth of approximately 12 km, resulting in severe casualties and substantial economic losses. Given its unique tectonic setting, the seismogenic structure and dynamic genesis of the Tangshan earthquake have long remained a key research topic in seismotectonic studies. To better characterize the tectonic framework, seismogenic mechanisms, and deep–shallow dynamical coupling within the Tangshan seismic zone, we employ multi-scale wavelet decomposition on high-resolution residual gravity anomalies to isolate crustal structure signals across different depth ranges. Integrating these structural signatures with the spatial distribution of seismicity yields a comprehensive framework for interpreting the regional tectonic evolution. The Tangshan seismic zone is positioned within the intricate structural architecture of the Tangshan rhombic fault block, a system embedded within the broader context of the North China Craton (NCC) destruction. Seismicity displays a distinct preferred orientation, with events concentrated along block-bounding faults and gravity anomaly gradient zones. With increasing wavelet decomposition levels, the gravity anomalies exhibit a systematic transition from spatially dispersed patterns associated with shallow structures to more concentrated features reflecting deeper geological domains. Shallow anomalies from the first to third decomposition orders, which are primarily controlled by Quaternary sedimentary layers, show a fragmented distribution that corresponds well with the development of local flower structures and the occurrence of diffuse shallow seismicity. The fourth- to seventh-order anomalies clearly delineate the rhombic block and its bounding peripheral faults, highlighting the structural intersections that hosted the Tangshan mainshock and its associated aftershock sequence. In contrast, the eighth- to tenth-order deep-seated anomalies corresponding to deeper structural levels exhibit pronounced coalescence, effectively imaging mantle upwelling and large-scale density heterogeneities within the lithospheric mantle. These concentrated gravity highs are closely coupled with mantle thermal activity, whose upward ascent induces thermal weakening of the lower crust and facilitates progressive stress transfer toward shallower crustal levels. Concurrently, frictional locking of shallow high-angle faults promotes intense stress accumulation within the rigid basement. The interplay between deep-seated dynamic concentration and shallow structural confinement ultimately triggers the catastrophic coseismic rupture responsible for the Tangshan earthquake. By delineating the structural transition from deep-seated aggregation centers to shallow dispersed fracture zones, this study establishes a robust framework for assessing seismogenic environments and regional seismic hazard potential across the progressively destroyed NCC. Full article

The demand for large-scale high-performance components with tailored properties in the aerospace and automotive industries has increased interest in multi-material additive manufacturing (AM). Among AM techniques, the Wire Arc Additive Manufacturing (WAAM) process is preferred for bimetallic fabrication due to high deposition rates, low equipment costs, and efficient material utilization. However, differences in metallurgical and thermal properties between dissimilar alloys can cause heat accumulation, leading to thermal stresses, cracking, and weak interfacial bonds. To the best of the authors’ knowledge, no study has reported the fabrication and characterization of a 17-4PH SS/Inconel 625 joint using the large-scale CMT-WAAM Process. To fill this gap, this study characterizes the microstructure and elemental distribution of the joint using scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray Microscopy (XRM) and energy dispersive spectroscopy (EDS). Microstructural analysis revealed a martensitic matrix with retained δ-ferrite in the 17-4PH region, a fully austenitic γ-phase in the Inconel 625 region, and a mixed BCC–FCC transition zone at the interface. EDS results demonstrated a Fe–Ni compositional gradient across the interface. Radiographic inspection confirmed a defect-free build, and XRM results showed a porosity of less than 0.003% only in the 17-4PH region. Tensile testing confirmed joint integrity, with fracture occurring in the Inconel 625 region, and average yield and ultimate tensile strengths of 391 ± 7 MPa and 676 ± 9 MPa, respectively. The simplified Johnson-Cook constitutive model successfully predicted the ultimate tensile strength (UTS), with a prediction error of 9.3% compared to the experimental result. Furthermore, a novel 3D-structured light scanner technique was developed and validated with an extensometer to provide insight into localized strain behavior. Full article

Boron carbide (B₄C) holds significant application potential in the fields of lightweight, high-hardness protective and high-end wear-resistant components due to its low density and exceptional hardness. However, its strong covalent bonding leads to low sintering activity and weak grain-boundary cohesion, resulting in high brittleness and crack sensitivity. These inherent properties make it difficult to achieve simultaneous full densification and toughness enhancement, severely limiting the reliability of B₄C under complex service conditions. Although diamond is an attractive reinforcement because of its high elastic modulus and low coefficient of thermal expansion, the simultaneous realization of densification, graphitization suppression, and fracture-resistance improvement in diamond/B₄C composites remains insufficiently understood. In this study, diamond particles were introduced into the B₄C matrix and consolidated by rapid high-temperature and high-pressure (HTHP) sintering to synergistically promote densification and fracture toughening. The effects of sintering temperature and diamond content on phase evolution, densification, microstructure, and mechanical properties were systematically investigated, and the associated toughening mechanisms were analyzed. The results indicate that the hardness generally increases with rising sintering temperature and diamond content. The primary toughening mechanisms are identified as the pull-out of diamond particles and crack deflection induced by residual stresses generated during the cooling process. Although the composite with 20 wt.% diamond exhibits higher hardness, it also experiences severe macroscopic cracking. The composite with 10 wt.% diamond sintered at 1450 °C under 5.3 GPa for 4 min exhibits the optimal balance of properties, achieving a relative density of 98.85%, a Vickers hardness of 40.72 GPa, and a fracture toughness of 9.20 MPa·m^1/2. This work confirms the effectiveness of combining diamond reinforcement with HTHP sintering in simultaneously achieving densification and toughening of B₄C-based composites, providing a new pathway for developing high-performance lightweight protective ceramics. Full article

Bisphenol A type epoxy resin has the problem of relatively high brittleness after curing. Although traditional polysiloxane toughening methods can improve toughness, they often come at the expense of strength. In this paper, methylphenyl dimethoxysilane (MPS) was used as a monomer to synthesize end-hydroxyl poly(methylphenyl)siloxane (PMPS), which was then used to modify E51 epoxy resin. The structure and reaction degree were characterized by infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, matrix-assisted laser desorption/ionization time-of-flight/time-of-flight mass spectrometry and viscosity tests. The mechanical test results show that when the PMPS content is 20 wt%, the tensile, flexural, compressive and impact strengths of the modified resin increase by 31.26%, 26.16%, 18.53% and 98.66%, respectively, compared with the unmodified resin, and the tensile and flexural elastic moduli increase by 38.36% and 32.25%, respectively. The fracture toughness increases by 60.29%, indicating that the strength, stiffness and toughness of the material have all been improved. Dynamic mechanical analysis shows that the glass transition temperature and crosslinking density of the system gradually decrease with increasing PMPS content. Thermogravimetric analysis shows that the introduction of PMPS increases the char yield and decreases the maximum thermal decomposition rate, thereby enhancing the thermal stability of the system. Microscopic morphology analysis by optical microscopy, scanning electron microscopy and atomic force microscopy shows that the system has good compatibility, and the internal different modulus phases are distributed in a network-like manner, forming a uniform co-continuous or bicontinuous phase structure. This structure effectively promotes stress transfer and energy dissipation, alleviates local stress concentration, and thus comprehensively improves the mechanical properties of the resin system. Full article

In this investigation, with increasing oxidation time or temperature, the observed mass gain abided by the parabolic law. TiCN-HfC-WC cermet contained different layers, with each one having a unique composition. Thermal fracture occurred in the sub-oxidation layer, and the flexural strength gradually decreased from 1270.6 MPa to 149.9 MPa. Ther-mal stress equations for calculating the radial, circumferential, and axial stresses were es-tablished. The thermal stress differences between neighboring layers determined the ther-mal fracture; when they were zero, the physical parameters of the layers were related, which could be used to guide cermet material design. Full article

To clarify how injection-induced cooling and reservoir properties jointly control rock damage during hydraulic fracturing of deep shale reservoirs, this study develops a coupled thermo–hydro–mechanical phase-field model incorporating fracture pressurization, matrix seepage, heat transfer, thermoelastic stress redistribution, and tensile damage evolution. The hydraulic fracture component is verified against the classical KGD analytical benchmark, and the thermal damage component is benchmarked against a ceramic quenching experiment. The phase-field formulation is constructed using tensile-compressive strain-energy decomposition so that only the tensile part of the elastic energy contributes to damage evolution, while the compressive stiffness is retained. The results show that low-temperature fluid injections produce a steep but spatially limited cooling zone near the fracture wall. The constrained contraction of the cooled rock generates additional thermoelastic tensile stress, strengthens fracture-tip stress localization, and accelerates phase-field damage accumulation. In the baseline case, thermal cooling increases the peak tensile stress near the fracture tip along profile c from 10.2 MPa in the hydraulic-only case to 22.5 MPa at t = 2 h, while the phase-field damage value increases from 0.03 to 0.77. Five-case sensitivity analyses show that, as α_T increases from 0.5 × 10⁻⁵ to 1.5 × 10⁻⁵ 1/°C, the fracture-tip tensile stress at t = 2 h increases from approximately 18.6 MPa to 25.7 MPa, and the damage value increases from approximately 0.80 to 0.96. As permeability increases from 0.0001 mD to 0.01 mD, the pore pressure at 2 m from the fracture wall increases from approximately 50.4 MPa to 71.2 MPa, and the tensile stress along profile c increases from approximately 16.4 MPa to 21.8 MPa. These results demonstrate that coupled thermal and hydraulic effects govern fracture initiation, localization, and propagation tendency during thermally assisted hydraulic fracturing in deep shale reservoirs. Full article

The performance and durability of lithium metal solid-state batteries are governed by the dynamic evolution of the lithium/solid-electrolyte (Li/SSE) interface, where electrochemical reactions, mass transport, and mechanical constraints are intrinsically coupled. This review presents an integrated electro-chemo-mechanical framework that links interfacial stripping dynamics to distinct degradation regimes controlled by current density, stack pressure, and thermal activation. We show that stable cycling emerges only within a narrow flux-balance window in which lithium creep and vacancy diffusion compensate stripping-induced volume loss without triggering electrolyte fracture or filament penetration. By synthesizing recent experimental, modeling, and materials engineering advances, the review maps the transitions between void-dominated instability, pressure-assisted stabilization, and stress-limited failure. Particular emphasis is placed on adaptive pressure strategies, compliant interlayer design, and microstructural interface engineering as pathways to expand the operational stability window. The analysis highlights that interfacial stability is not solely a materials property but a systems-level outcome arising from coupled electro-mechanical boundary conditions and temperature-dependent transport processes. This perspective provides design principles for developing next-generation solid-state batteries capable of stable high-rate cycling and long-term reliability. Full article

Zirconia-toughened alumina (ZTA) ceramics are promising for load-bearing biomedical applications because they combine the hardness, chemical stability, wear resistance, and biocompatibility of alumina with the transformation-toughening capability of zirconia. Grinding is indispensable for achieving dimensional accuracy and surface quality, yet it inevitably introduces surface and subsurface cracks, residual stresses, and a local tetragonal-to-monoclinic transformation of zirconia. These changes can degrade fracture toughness, increase reliability scatter, and reduce long-term service stability. Annealing is therefore often considered a post-grinding recovery strategy because it can relax residual stresses, blunt crack tips, and partially restore the zirconia phase state. However, the extent of recovery depends strongly on the initial damage state, ZTA microstructure, and thermal schedule. This review systematically summarizes the current understanding of grinding-induced damage and annealing-assisted recovery in ZTA ceramics, with particular emphasis on the coupled relationships among subsurface damage, residual-stress evolution, phase transformation, and fracture toughness. Particular attention is given to distinguishing direct ZTA-specific evidence from mechanistic interpretations inferred from related zirconia-containing ceramic systems, because datasets based exclusively on ZTA remain relatively limited. By integrating the existing evidence, this review proposes a coupled processing-damage-recovery framework and identifies the key knowledge gaps that must be addressed to achieve more reliable process optimization in advanced ZTA components. Full article

The sealing behavior of fracture-filling minerals in the near-field of the deep geological repository (DGR) is critical for the safe disposal of high-level radioactive waste (HLW). In granite host rocks, natural fractures are often filled with polymineralic assemblages of calcite, quartz, and clay minerals; however, their coupled compaction–pressure solution mechanisms under thermal–hydraulic–mechanical–chemical (THMC) conditions remain poorly understood. In this study, 12 fracture sealing tests were conducted on Beishan granite and its typical fracture fillings at 90 °C and 15 MPa effective stress, using different pore fluids and systematically varying grain size (75–250 μm), mineral proportions, and clay content. The results indicate that stress-assisted dissolution–precipitation of calcite in saturated CaCO₃ solution is a key process contributing to porosity reduction and chemo-mechanical densification of the fracture filling, achieving a compaction strain of 24.6%—substantially higher than those obtained in deionized water (20.6%) and under dry conditions (14.8%). Fine-grained calcite compacts more effectively than its coarse-grained counterpart, reaching a porosity as low as 4.8%; rigid quartz locally redistributes contact stress at quartz–calcite interfaces, promoting preferential deformation or dissolution of adjacent calcite, although increasing quartz abundance reduces the bulk compaction efficiency. A moderate amount of clay minerals (~20 wt%) further reduces porosity to 2.1% through lubrication and micropore filling. The study reveals a multi-stage process transitioning from mechanical compaction to chemo-mechanical sealing, and a synergistic mechanism dominated by calcite compaction–pressure solution, augmented by quartz stress redistribution and clay lubrication. These findings provide direct experimental evidence for the progressive chemo-mechanical densification of mineral-filled granite fractures, and offer quantitative constraints for long-term THMC modeling of fracture sealing behavior in HLW repositories. Full article

This study presents the fabrication of a Cr₃C₂-25NiCr/NiCr coating on Co₃W₃ steel utilizing high-velocity oxygen fuel (HVOF) spraying. The effects of the vacuum heat treatment process on the microstructures, mechanical properties, and wear mechanisms of the coating were systematically analyzed. The results indicated that the microstructure became denser following heat treatment. During the spraying procedure, decarburization resulted in transformation of the metastable phase structure into a stable one. In comparison to the sprayed coating, there was a 93.8% reduction in porosity. The precipitation of nano-secondary carbides shifted the mechanism of solid-solution strengthening to precipitation strengthening, resulting in a 29.1% increase in microhardness. Meanwhile, the thermal softening effect led to a 114.3% increase in fracture toughness. Wear experiments demonstrated that the friction-induced amorphous structure effectively mitigated stress concentration and inhibited crack initiation. The polycrystalline interface transition region between the nano-secondary carbides and the matrix facilitated the shedding of nano-secondary carbides, forming abrasive particles that generated a rolling effect, which significantly reduced the coefficient of friction. The semi-coherent interface between secondary carbides and NiCr decreased the interfacial energy and enhanced the bonding strength, effectively preventing the shedding of carbides during the wear process. Consequently, a dense microstructure, the type of interface, and high hardness and toughness were critical factors in enhancing its wear resistance. Full article

To address the durability limitations of conventional crack sealants under coupled extreme temperatures and traffic loads in long-life pavements, a bio-oil composite-modified patching material was developed using 90# base asphalt as the matrix, synergistically modified with crumb rubber (CR) and epoxidized soybean oil (ESO). To resolve the contradictory requirements for high elasticity and thermal expansion/contraction coordination in sealants, ESO was introduced; its polar epoxy groups optimize phase compatibility and promote low-temperature stress relaxation without restricting thermal deformability. Rheological evaluations revealed that the optimal system (OPT) successfully extended the service temperature window from PG 76–−24 °C (baseline) to PG 82–−24 °C, significantly enhancing its adaptability to extreme climatic fluctuations. At −24 °C, OPT exhibited a reduced creep stiffness (S) of 164 MPa and an increased creep rate (m) of 0.312, with a cracking resistance ratio (k) as low as 525.6; the quantitative significance of these metrics lies in granting the sealant superior stress relaxation capacity, enabling it to accommodate dynamic crack widening without interfacial debonding or brittle fracture. Fatigue testing via time sweeps demonstrated that N_f50 reached 2890 cycles, highlighting robust long-term resistance against high-frequency shear strains induced by tire edges. Micro-mechanistic analyses (FTIR, TG/DTG, and DSC) confirmed that the modification is primarily driven by physical blending. The elevation of the thermal decomposition threshold (T5%) to 302.4 °C and the residue at 600 °C to 44.8% provide a critical safety margin for high-temperature construction heating, preventing thermal degradation. Furthermore, the glass transition temperature (T_g) decreased to approximately −35.2 °C. These findings establish a rigorous quantitative and mechanistic framework for designing sustainable, high-performance patching materials for resilient pavement maintenance. Full article

This study presents a coupled numerical–experimental investigation into the early-age thermo-mechanical behaviour of 3D-printed concrete (3DPC), with particular emphasis on strength development, interlayer bonding, and thermally induced cracking that govern structural buildability and performance. A coupled multiphysics modelling framework was developed in COMSOL Multiphysics by integrating hydration kinetics, maturity theory, thermo-mechanical coupling, and a cohesive-zone-based interlayer damage formulation through user-defined time-dependent constitutive relationships and domain activation functions. The model simulated the temporal evolution of temperature, stiffness, stress development, and interlayer degradation during the early-age printing process. The model simulates the temporal evolution of temperature, stiffness, and interlayer damage and was validated against experimental results from compression, interlayer bond, and fracture tests conducted under varying printing time gaps and curing temperatures. The results demonstrate that increasing interlayer deposition intervals up to 60 min leads to reductions of approximately 38% in interlayer bond strength and a significant reduction in apparent compressive strength exceeding 80% between 0 and 60 min deposition delay. It should be noted that this reduction primarily reflects interlayer-dominated failure and loss of structural continuity rather than intrinsic degradation of the bulk cementitious matrix, primarily due to hydration discontinuity, moisture loss, and progressive substrate stiffening. Elevated curing temperatures further intensify thermal gradients, resulting in higher residual stresses and increased crack susceptibility at interlayer interfaces. The numerical predictions showed good agreement with the experimental responses, with peak-force prediction errors below 5% and RMSE values of approximately 0.30–0.45 kN along the post-peak softening, confirming the reliability of the proposed modelling approach. The findings highlight the critical importance of printing continuity and thermal control in governing early-age structural performance and provide quantitative guidance for optimising process parameters in extrusion-based 3D concrete printing. Full article