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Search Results (302)

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Keywords = the green efficiency of water resources

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21 pages, 3832 KiB  
Article
Effects of Water Use Efficiency Combined with Advancements in Nitrogen and Soil Water Management for Sustainable Agriculture in the Loess Plateau, China
by Hafeez Noor, Fida Noor, Zhiqiang Gao, Majed Alotaibi and Mahmoud F. Seleiman
Water 2025, 17(15), 2329; https://doi.org/10.3390/w17152329 - 5 Aug 2025
Abstract
In China’s Loess Plateau, sustainable agricultural end products are affected by an insufficiency of water resources. Rising crop water use efficiency (WUE) through field management pattern improvement is a crucial plan of action to address this issue. However, there is no agreement among [...] Read more.
In China’s Loess Plateau, sustainable agricultural end products are affected by an insufficiency of water resources. Rising crop water use efficiency (WUE) through field management pattern improvement is a crucial plan of action to address this issue. However, there is no agreement among researchers on the most appropriate field management practices regarding WUE, which requires further integrated quantitative analysis. We conducted a meta-analysis by quantifying the effect of agricultural practices surrounding nitrogen (N) fertilizer management. The two experimental cultivars were Yunhan–20410 and Yunhan–618. The subplots included nitrogen 0 kg·ha−1 (N0), 90 kg·ha−1 (N90), 180 kg·ha−1 (N180), 210 kg·ha−1 (N210), and 240 kg·ha−1 (N240). Our results show that higher N rates (up to N210) enhanced water consumption during the node-flowering and flowering-maturity time periods. YH–618 showed higher water use during the sowing–greening and node-flowering periods but decreased use during the greening-node and flowering-maturity periods compared to YH–20410. The N210 treatment under YH–618 maximized water use efficiency (WUE). Increased N rates (N180–N210) decreased covering temperatures (Tmax, Tmin, Taver) during flowering, increasing the level of grain filling. Spike numbers rose with N application, with an off-peak at N210 for strong-gluten wheat. The 1000-grain weight was at first enhanced but decreased at the far end of N180–N210. YH–618 with N210 achieved a harvest index (HI) similar to that of YH–20410 with N180, while excessive N (N240) or water reduced the HI. Dry matter accumulation increased up to N210, resulting in earlier stabilization. Soil water consumption from wintering to jointing was strongly correlated with pre-flowering dry matter biological process and yield, while jointing–flowering water use was linked to post-flowering dry matter and spike numbers. Post-flowering dry matter accumulation was critical for yield, whereas spike numbers positively impacted yield but negatively affected 1000-grain weight. In conclusion, our results provide evidence for determining suitable integrated agricultural establishment strategies to ensure efficient water use and sustainable production in the Loess Plateau region. Full article
(This article belongs to the Special Issue Soil–Water Interaction and Management)
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16 pages, 2460 KiB  
Article
Continuous Chamber Gangue Storage for Sustainable Mining in Coal Mines: Principles, Methods, and Environmental Benefits
by Jinhai Liu, Yuanhang Wang, Jiajie Li, Desire Ntokoma, Zhengxing Yu, Sitao Zhu and Michael Hitch
Sustainability 2025, 17(15), 6865; https://doi.org/10.3390/su17156865 - 28 Jul 2025
Viewed by 259
Abstract
Coal gangue, a major by-product of coal mining, poses significant environmental challenges due to its large-scale accumulation, land occupation, and potential for air and water pollution. This manuscript presents a comprehensive overview of continuous chamber gangue storage technology as a sustainable mining solution [...] Read more.
Coal gangue, a major by-product of coal mining, poses significant environmental challenges due to its large-scale accumulation, land occupation, and potential for air and water pollution. This manuscript presents a comprehensive overview of continuous chamber gangue storage technology as a sustainable mining solution for coal mines. The principles of this approach emphasize minimizing disturbance to overlying strata, enabling uninterrupted mining operations, and reducing both production costs and environmental risks. By storing the surface or underground gangue in continuous chambers, the proposed method ensures the roof stability, maximizes the waste storage, and prevents the interaction between mining and waste management processes. Detailed storage sequences and excavation methods are discussed, including continuous and jump-back excavation strategies tailored to varying roof conditions. The process flows for both underground and ground-based chamber storage are described, highlighting the integration of gangue crushing, paste preparation, and pipeline transport for efficient underground storage. In a case study with annual storage of 500,000 t gangue, the annual economic benefit reached CNY 1,111,425,000. This technology not only addresses the urgent need for sustainable coal gangue management, but also aligns with the goals of resource conservation, ecological protection, and the advancement of green mining practices in the coal industry. Full article
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24 pages, 3062 KiB  
Article
Green Hydrogen in Jordan: Stakeholder Perspectives on Technological, Infrastructure, and Economic Barriers
by Hussam J. Khasawneh, Rawan A. Maaitah and Ahmad AlShdaifat
Energies 2025, 18(15), 3929; https://doi.org/10.3390/en18153929 - 23 Jul 2025
Viewed by 316
Abstract
Green hydrogen, produced via renewable-powered electrolysis, offers a promising path toward deep decarbonisation in energy systems. This study investigates the major technological, infrastructural, and economic challenges facing green hydrogen production in Jordan—a resource-constrained yet renewable-rich country. Key barriers were identified through a structured [...] Read more.
Green hydrogen, produced via renewable-powered electrolysis, offers a promising path toward deep decarbonisation in energy systems. This study investigates the major technological, infrastructural, and economic challenges facing green hydrogen production in Jordan—a resource-constrained yet renewable-rich country. Key barriers were identified through a structured survey of 52 national stakeholders, including water scarcity, low electrolysis efficiency, limited grid compatibility, and underdeveloped transport infrastructure. Respondents emphasised that overcoming these challenges requires investment in smart grid technologies, seawater desalination, advanced electrolysers, and policy instruments such as subsidies and public–private partnerships. These findings are consistent with global assessments, which recognise similar structural and financial obstacles in scaling up green hydrogen across emerging economies. Despite the constraints, over 50% of surveyed stakeholders expressed optimism about Jordan’s potential to develop a competitive green hydrogen sector, especially for industrial and power generation uses. This paper provides empirical, context-specific insights into the conditions required to scale green hydrogen in developing economies. It proposes an integrated roadmap focusing on infrastructure modernisation, targeted financial mechanisms, and enabling policy frameworks. Full article
(This article belongs to the Special Issue Green Hydrogen Energy Production)
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20 pages, 2995 KiB  
Article
Analysis of Bacterial Community During Cow Manure and Wheat Straw Composting and the Isolation of Lignin-Degrading Bacteria from the Compost
by Hanxiang Yang, Jianguo Hu, Bingxin Zhang, Yan Li, Chenxian Yang, Fusheng Chen, Tingwei Zhu and Ying Xin
Microorganisms 2025, 13(8), 1716; https://doi.org/10.3390/microorganisms13081716 - 22 Jul 2025
Viewed by 359
Abstract
Biodegradation is a green and efficient method for lignin depolymerization and conversion. In order to screen potential bacterial strains for efficient lignin degradation, composts of cow dung and wheat straw were prepared, and the dynamic changes in the predicted bacterial community structure and [...] Read more.
Biodegradation is a green and efficient method for lignin depolymerization and conversion. In order to screen potential bacterial strains for efficient lignin degradation, composts of cow dung and wheat straw were prepared, and the dynamic changes in the predicted bacterial community structure and function in different periods of the composts were investigated. Then, bacteria with an efficient lignin degradation ability were finally screened out from the compost samples. Based on the monitoring results of the physicochemical indexes of the composting process, it was found that the temperature and pH of the compost firstly increased and then decreased with the extension of time, and the water content and C/N gradually decreased. High-throughput sequencing of compost samples from the initial (DA), high-temperature (DB), and cooling (DC) periods revealed that the number of OTUs increased sharply then stabilized around 2000, and the alpha diversity of the bacterial community decreased firstly and then increased. The predominant phyla identified included Proteobacteria, Firmicutes, Chloroflexi, and Bacteroidetes, determined by the relative abundance of beta-diversity-associated species. Functional gene analysis conducted using Tax4Fun revealed that the genes were primarily categorized into Metabolism, Genetic Information Processing, Environmental Information Processing, and Cellular Processes. Based on the decolorization of aniline blue and the degradation efficiency of alkali lignin, eight bacterial strains were isolated from compost samples at the three stages. Cupriavidus sp. F1 showed the highest degradation of alkali lignin with 66.01%. Cupriavidus sp. D8 showed the highest lignin degradation potential with all three enzyme activities significantly higher than the other strains. The results provide a strategy for the lignin degradation and utilization of biomass resources. Full article
(This article belongs to the Section Microbial Biotechnology)
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24 pages, 18983 KiB  
Article
Multi-Factor Analysis and Graded Remediation Strategy for Goaf Stability in Underground Metal Mines: Fluid–Solid Coupling Simulation and Genetic Algorithm-Based Optimization Approach
by Xuzhao Yuan, Xiaoquan Li, Xuefeng Li, Tianlong Su, Han Du and Danhua Zhu
Symmetry 2025, 17(7), 1024; https://doi.org/10.3390/sym17071024 - 30 Jun 2025
Viewed by 283
Abstract
To ensure the green, safe, and efficient extraction of mineral resources and promote sustainability, the stability of mined-out areas has become a critical factor affecting safe production and ecological restoration in underground metal mines. The instability of underground goafs poses a significant threat [...] Read more.
To ensure the green, safe, and efficient extraction of mineral resources and promote sustainability, the stability of mined-out areas has become a critical factor affecting safe production and ecological restoration in underground metal mines. The instability of underground goafs poses a significant threat to mine safety, especially when irregular excavation patterns interact with high ground stress, exacerbating instability risks. Most existing studies lack a systematic and multidisciplinary integrated framework for comprehensive evaluation and management. This paper proposes a trinity research system of “assessment–optimization–governance”, integrating theoretical analysis, three-dimensional fluid–solid coupling numerical simulation, and a filling sequence optimization method based on genetic algorithms. An analysis of data measured from 243 pillars and 49 goafs indicates that approximately 20–30% of the pillars have a factor of safety (FoS) below 1.0, signaling immediate instability risks; additionally, 58% do not meet the threshold for long-term stability (FoS ≥ 1.5). Statistical and spatial analyses highlight that pillar width-to-height ratio (W/H) and cross-sectional area significantly influence stability; when W/H exceeds 1.5, FoS typically surpasses 2.0. Numerical simulations reveal pore water pressures of 1.4–1.8 MPa in deeper goafs, substantially reducing effective stress and accelerating plastic zone expansion. Stability classification categorizes the 49 goafs into 7 “poor”, 37 “moderate”, and 5 “good” zones. A genetic algorithm-optimized filling sequence prioritizes high-risk area remediation, reducing maximum principal stress by 60.96% and pore pressure by 28.6%. Cemented waste rock filling applied in high-risk areas, complemented by general waste rock filling in moderate-risk areas, significantly enhances overall stability. This integrated method provides a scientific foundation for stability assessment and dynamic remediation planning under complex hydrogeological conditions, offering a risk-informed and scenario-specific application of existing tools that improves engineering applicability. Full article
(This article belongs to the Section Mathematics)
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19 pages, 2927 KiB  
Article
Restoration, Indicators, and Participatory Solutions: Addressing Water Scarcity in Mediterranean Agriculture
by Enrico Vito Perrino, Pandi Zdruli, Lea Piscitelli and Daniela D’Agostino
Agronomy 2025, 15(7), 1517; https://doi.org/10.3390/agronomy15071517 - 22 Jun 2025
Viewed by 509
Abstract
Agricultural water resource management is increasingly challenged by climate variability, land degradation, and socio-economic pressures, particularly in the Mediterranean region. This study, conducted in 2023–2024 within the REACT4MED project (PRIMA initiative), addresses sustainable water use through a comparative analysis of organic and conventional [...] Read more.
Agricultural water resource management is increasingly challenged by climate variability, land degradation, and socio-economic pressures, particularly in the Mediterranean region. This study, conducted in 2023–2024 within the REACT4MED project (PRIMA initiative), addresses sustainable water use through a comparative analysis of organic and conventional farms in the Stornara and Tara area (Puglia, Italy). The research aimed to identify critical indicators for sustainable water management and develop ecosystem restoration strategies that can be replicated across similar Mediterranean agro-ecosystems. An interdisciplinary, participatory approach was adopted, combining technical analyses and stakeholder engagement through three workshops involving 30 participants from diverse sectors. Fieldwork and laboratory assessments included soil sampling and analysis of parameters such as pH, electrical conductivity, soil organic carbon, nutrients, and salinity. Cartographic studies of vegetation, land use, and pedological characterization supplemented the dataset. The key challenges identified were water loss in distribution systems, seawater intrusion, water pumping from unauthorized wells, and inadequate public policies. Soil quality was significantly influenced by salt stress, hence affecting crop productivity, while socio-economic factors affected farm income. Restoration strategies emphasized the need for water-efficient irrigation, less water-intensive crops, and green vegetation in infrastructure channels while incorporating also the native flora. Enhancing plant biodiversity through weed management in drainage channels proved beneficial for pathogen control. Proposed socio-economic measures include increased inclusion of women and youth in agricultural management activities. Integrated technical and participatory approaches are essential for effective water resource governance in Mediterranean agriculture. This study offers scalable, context-specific indicators and solutions for sustainable land and water management in the face of ongoing desertification and climate stress. Full article
(This article belongs to the Section Water Use and Irrigation)
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15 pages, 2632 KiB  
Article
Spatio-Temporal Dynamics and Contributing Factors of Irrigation Water Use in the Loess Plateau
by Jiayu He, Yayun Hu, Luocheng Shi, Haitao Wang, Yan Tong, Wen Dai and Mengmeng Zhang
Land 2025, 14(6), 1286; https://doi.org/10.3390/land14061286 - 16 Jun 2025
Viewed by 368
Abstract
The “Grain for Green” policy has led to a reduction in cultivated land area in the Loess Plateau, intensifying the conflict between ecological conservation and food security. As a key strategy to mitigate this tension, irrigated farmland has undergone significant changes in both [...] Read more.
The “Grain for Green” policy has led to a reduction in cultivated land area in the Loess Plateau, intensifying the conflict between ecological conservation and food security. As a key strategy to mitigate this tension, irrigated farmland has undergone significant changes in both its spatial extent and water consumption, which may further exacerbate the water crisis. Hence, the spatio-temporal dynamics and driving forces behind these changes require greater attention and have not yet been comprehensively explored. This study integrates multi-source datasets and employs piecewise linear regression and the Logarithmic Mean Divisia Index (LMDI) model to analyze the spatio-temporal evolution of cultivated land and irrigation water use. Furthermore, it quantifies the contributions of key factors such as cultivated land area, irrigation intensity, and crop planting structure to irrigation water dynamics. The results show that (1) The total cultivated land area in the Loess Plateau decreased by 12.4% from 1985 to 2020, with increases primarily concentrated along the Yellow River between Hekou and Longmen, while decreases were predominantly observed around major cities such as Xi’an, Taiyuan, and Yuncheng. Conversely, the irrigated area exhibited an overall upward trend, with minor declines occurring between 1977 and 1985. (2) While the total irrigation water use increased overall, piecewise linear regression analysis identified four distinct phases, with the first three phases showing growth, followed by a decline after 2001. (3) The expansion of agricultural irrigation areas emerged as the primary driver of increased irrigation water use, whereas advancements in irrigation efficiency effectively reduced water consumption. This study provides novel insights into the spatio-temporal dynamics of irrigation water use in the Loess Plateau and offers valuable guidance for optimizing water resource management and advancing sustainable development in the region. Full article
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16 pages, 3741 KiB  
Article
Mechanical Properties of Large-Volume Waste Concrete Lumps Cemented by Desert Mortar: Laboratory Tests
by Hui Chen, Zhiyuan Qi, Baiyun Yu and Xinyu Li
Buildings 2025, 15(12), 2060; https://doi.org/10.3390/buildings15122060 - 15 Jun 2025
Viewed by 450
Abstract
In response to the high cost and environmental impact of backfill materials in Xinjiang mines, an eco-friendly, large-volume composite was developed by bonding desert-sand mortar to waste concrete. A rock-filled concrete process produced a highly flowable mortar from desert sand, cement, and fly [...] Read more.
In response to the high cost and environmental impact of backfill materials in Xinjiang mines, an eco-friendly, large-volume composite was developed by bonding desert-sand mortar to waste concrete. A rock-filled concrete process produced a highly flowable mortar from desert sand, cement, and fly ash. Waste concrete blocks served as coarse aggregate. Specimens were cured for 28 days, then subjected to uniaxial compression tests on a mining rock-mechanics system using water-to-binder ratios of 0.30, 0.35, and 0.40 and aggregate sizes of 30–40 mm, 40–50 mm, and 50–60 mm. Mechanical performance—failure modes, stress–strain response, and related properties—was systematically evaluated. Crack propagation was tracked via digital image correlation (DIC) and acoustic emission (AE) techniques. Failure patterns indicated that the pure-mortar specimens exhibited classic brittle fractures with through-going cracks. Aggregate-containing specimens showed mixed-mode failure, with cracks flowing around aggregates and secondary branches forming non-through-going damage networks. Optimization identified a 0.30 water-to-binder ratio (Groups 3 and 6) as optimal, yielding an average strength of 25 MPa. Among the aggregate sizes, 40–50 mm (Group 7) performed best, with 22.58 MPa. The AE data revealed a three-stage evolution—linear-elastic, nonlinear crack growth, and critical failure—with signal density positively correlating to fracture energy. DIC maps showed unidirectional energy release in pure-mortar specimens, whereas aggregate-containing specimens displayed chaotic energy patterns. This confirms that aggregates alter stress fields at crack tips and redirect energy-dissipation paths, shifting failure from single-crack propagation to a multi-scale damage network. These results provide a theoretical basis and technical support for the resource-efficient use of mining waste and advance green backfill technology, thereby contributing to the sustainable development of mining operations. Full article
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19 pages, 301 KiB  
Review
Emerging Trends in Sustainable Biological Resources and Bioeconomy for Food Production
by Luis A. Trujillo-Cayado, Rosa M. Sánchez-García, Irene García-Domínguez, Azahara Rodríguez-Luna, Elena Hurtado-Fernández and Jenifer Santos
Appl. Sci. 2025, 15(12), 6555; https://doi.org/10.3390/app15126555 - 11 Jun 2025
Viewed by 734
Abstract
The mounting global population and the challenges posed by climate change underline the need for sustainable food production systems. This review synthesizes evidence for a dual-track bioeconomy, green (terrestrial plants and insects) and blue (aquatic algae), as complementary pathways toward sustainable nutrition. A [...] Read more.
The mounting global population and the challenges posed by climate change underline the need for sustainable food production systems. This review synthesizes evidence for a dual-track bioeconomy, green (terrestrial plants and insects) and blue (aquatic algae), as complementary pathways toward sustainable nutrition. A comprehensive review of the extant literature, technical reports, and policy documents published between 2015 and 2025 was conducted, with a particular focus on environmental, nutritional, and techno-economic metrics. In addition, precision agriculture datasets, gene-editing breakthroughs, and circular biorefinery case studies were extracted and compared. As demonstrated in this study, the use of green resources, such as legumes, oilseeds, and edible insects, results in a significant reduction in greenhouse gas emissions, land use, and water footprints compared with conventional livestock production. In addition, these alternative protein sources offer substantial benefits in terms of bioactive lipids. Blue resources, centered on micro- and macroalgae, furnish additional proteins, long-chain polyunsaturated fatty acids, and antioxidant pigments and sequester carbon on non-arable or wastewater substrates. The transition to bio-based resources is facilitated by technological innovations, such as gene editing and advanced extraction methods, which promote the efficient valorization of agricultural residues. In conclusion, the study strongly suggests that policy support be expedited and that research into bioeconomy technologies be increased to ensure the sustainable meeting of future food demands. Full article
(This article belongs to the Special Issue Application of Natural Components in Food Production)
23 pages, 2023 KiB  
Article
Integrating the Water Footprint and DPSIR Model to Evaluate Agricultural Water Sustainability in Arid Regions: A Case Study of the Turpan–Hami Basin
by Lingyun Zhang, Yang Yu, Zengkun Guo, Xiaoyun Ding, Lingxiao Sun, Jing He, Chunlan Li and Ruide Yu
Agronomy 2025, 15(6), 1393; https://doi.org/10.3390/agronomy15061393 - 5 Jun 2025
Viewed by 621
Abstract
Water resources are a key constraint on sustainable development in arid regions, especially for agricultural production where water use is intensive. To assess the sustainability of agricultural water use in such environments, this study utilizes 2010–2020 agricultural data from the Turpan–Hami Basin and [...] Read more.
Water resources are a key constraint on sustainable development in arid regions, especially for agricultural production where water use is intensive. To assess the sustainability of agricultural water use in such environments, this study utilizes 2010–2020 agricultural data from the Turpan–Hami Basin and is among the first to integrate the water footprint (WF) theory with the DPSIR (driver–pressure–state–impact–response) model into a comprehensive framework for evaluating water resource sustainability in arid agricultural systems. The agricultural blue, green, and grey WF in the Turpan–Hami Basin were quantified for 2010–2020, followed by a sustainability assessment under the DPSIR framework using a comprehensive weighting method. The results showed a continuous increase in the WF, dominated by the blue WF (>60%), largely due to crops like cotton and grapes, intensifying regional water stress. Turpan experienced prolonged resource overload, while Hami exhibited slightly higher sustainability. DPSIR analysis revealed stronger policy responses in Turpan and significant ecological investments in Hami. Key influencing factors included the crop yield, WF modulus, per capita WF, and water quality shortage index. Overall, sustainability in the basin fluctuated between “Basically Sustainable (Level III)” and “Insufficiently Sustainable (Level IV)”, with slight improvement in 2020. The findings highlight the need for region-specific agricultural optimization, strengthened ecological governance, and improved water-saving strategies to enhance water use efficiency and sustainability in arid regions. Full article
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23 pages, 13387 KiB  
Article
Transcriptomic and Metabolic Analysis Reveal Potential Mechanism of Starch Accumulation in Spirodela polyrhiza Under Nutrient Stress
by Xin Fang, Yan Hong, Yang Fang, Li Cheng, Zhaofeng Li, Caiming Li and Xiaofeng Ban
Plants 2025, 14(11), 1617; https://doi.org/10.3390/plants14111617 - 26 May 2025
Cited by 1 | Viewed by 526
Abstract
Compared with traditional grain starch sources, duckweed (Spirodela polyrhiza, S. polyrhiza for simple) does not require soil to produce starch, and the process is less affected by the external environment. Moreover, it produces high levels of starch under certain conditions. This [...] Read more.
Compared with traditional grain starch sources, duckweed (Spirodela polyrhiza, S. polyrhiza for simple) does not require soil to produce starch, and the process is less affected by the external environment. Moreover, it produces high levels of starch under certain conditions. This study investigated the patterns and mechanisms of starch accumulation in S. polyrhiza ZH0196 under nutrient stress by determining the changes in starch content, photosynthesis, and amylase activity at different stress induction times. Under nutrient stress, the culture solution was replaced with deionized water. The starch content increased from 1.95% to 41.71% (dry weight) after 2 days of nutrient stress induction. Short-term nutrient-stress treatment had little effect on frond photosynthesis, enhanced the activity of starch synthesis-related enzyme, and weakened the activity of degradation-related enzymes. The transcriptome results further indicated that the key genes and metabolic patterns of starch synthesis promoted starch accumulation in S. polyrhiza ZH0196 fronds by accelerating the response to CO2 fixation via the Calvin cycle, promoting straight-chain starch synthesis, and decreasing starch degradation after short-term oligotrophic treatment. This study suggests that nutrient stress is a green and efficient method of increasing the starch yield of duckweed, which represents an important insight for developing duckweed starch resources. Full article
(This article belongs to the Special Issue Duckweed: Research Meets Applications—2nd Edition)
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20 pages, 13001 KiB  
Article
Exploring Biomass Waste-Derived Biochar as a Catalyst for Levulinic Acid Conversion to γ-Valerolactone: Insights into Synthesis, Characterization, and Catalytic Performance
by Joao Carlos Alves Macedo, Maryam Shirinkar, Richard Landers and André Henrique Rosa
Biomass 2025, 5(2), 29; https://doi.org/10.3390/biomass5020029 - 17 May 2025
Cited by 2 | Viewed by 1961
Abstract
The transition from fossil resources to renewable raw materials derived from lignocellulosic waste is crucial for economic and environmental sustainability. Advancing toward a bio-based economy necessitates the development of innovative heterogeneous catalysts. This study explores the use of modified sugarcane bagasse biochar, embedded [...] Read more.
The transition from fossil resources to renewable raw materials derived from lignocellulosic waste is crucial for economic and environmental sustainability. Advancing toward a bio-based economy necessitates the development of innovative heterogeneous catalysts. This study explores the use of modified sugarcane bagasse biochar, embedded with ruthenium and iron particles, as a green catalyst for converting levulinic acid (LA) to γ-valerolactone (GVL). The efficiency of both raw and modified biochar in the LA to GVL conversion process, utilizing formic acid (FA) exclusively as the hydrogen source, was systematically assessed through characterization techniques, including XRD, TGA, XPS, and SEM/EDS. The gelification method using alginate enhanced the ruthenium and iron content on the surface of the biochar. The results demonstrate that the modified material has significant potential for efficient LA-to-GVL conversion, achieving a yield of 73.0 ± 9.2% under optimized conditions (0.5 g of BC500Fe/3%Ru at 180 °C for 3 h, with 4 mmol LA, 8 mmol FA, and 10 mL of water). Iron on the biochar surface facilitated the formation of adsorption sites for LA, supporting the notion of this novel catalyst for LA conversion in an aqueous medium in the presence of FA. This research underscores the potential of this green catalyst in advancing sustainable biomass conversion and contributes to the ongoing shift towards a bio-based economy. Full article
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22 pages, 503 KiB  
Article
Impact of Nitrogen Fertilization on Rosemary: Assessment of Physiological Traits, Vegetation Indices, and Environmental Resource Use Efficiency
by Christos A. Dordas
Nitrogen 2025, 6(2), 33; https://doi.org/10.3390/nitrogen6020033 - 2 May 2025
Viewed by 557
Abstract
Rosemary (Salvia rosmarinus L.) is a versatile and resilient plant with significant culinary, medicinal, and ecological value. This study evaluates the impact of four nitrogen (N) fertilization levels (0, 50, 100, and 150 kg N ha⁻¹) on the morphological, physiological, and agronomic [...] Read more.
Rosemary (Salvia rosmarinus L.) is a versatile and resilient plant with significant culinary, medicinal, and ecological value. This study evaluates the impact of four nitrogen (N) fertilization levels (0, 50, 100, and 150 kg N ha⁻¹) on the morphological, physiological, and agronomic traits, as well as vegetative indices, of rosemary over two growing seasons (2022 and 2023). The results indicate that plant height and leaf area index (LAI) increased with N application. Additionally, physiological characteristics such as chlorophyll content, photosynthetic efficiency, and assimilation rates (A) increased by an average of 32%, 17%, and 55%, respectively, compared to the control. Biomass production also improved with N fertilization, with yields rising by 32% in 2022 and 58% in 2023. Furthermore, both essential oil concentration and essential oil yield were enhanced by N application. Radiation use efficiency (RUE), water use efficiency (WUE), agronomic efficiency (AE), and partial factor productivity (PFP) also increased, indicating more efficient utilization of environmental resources. Moreover, higher N rates consistently enhanced vegetation indices, reflecting improved plant health, greenness, biomass, photosynthetic activity, and energy utilization. Therefore, this study highlights that the optimal N range appears to balance biomass yield and essential oil yield while maximizing the efficiency of environmental resource use. Full article
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26 pages, 13129 KiB  
Article
Assessing Socio-Economic Vulnerabilities to Urban Heat: Correlations with Land Use and Urban Morphology in Melbourne, Australia
by Cheuk Yin Wai, Muhammad Atiq Ur Rehman Tariq, Nitin Muttil and Hing-Wah Chau
Land 2025, 14(5), 958; https://doi.org/10.3390/land14050958 - 29 Apr 2025
Cited by 1 | Viewed by 995
Abstract
Modern cities are rapidly evolving in terms of urban morphology, driven by exponential population growth that accelerates the urbanisation process. The changes in land use have increased urban area and density, intensifying the urban heat island (UHI) effect, which poses one of the [...] Read more.
Modern cities are rapidly evolving in terms of urban morphology, driven by exponential population growth that accelerates the urbanisation process. The changes in land use have increased urban area and density, intensifying the urban heat island (UHI) effect, which poses one of the biggest threats to human health and well-being, especially in metropolitan regions. One of the most effective strategies to counter urban heat is the implementation of green infrastructure and the use of suitable building materials that help reduce heat stress. However, access to green spaces and the affordability of efficient building materials are not the same among citizens. This paper aims to identify the socio-economic characteristics of communities in Melbourne, Australia, that contribute to their vulnerability to urban heat under local conditions. This study employs remote sensing and geographical information systems (GIS) to conduct a macro-scale analysis, to investigate the correlation between urban heat patterns and socio-economic characteristics, taking into account factors such as vegetation cover, built-up areas, and land use types. The results from the satellite images and the geospatial data reveal that Deer Park, located in the western suburbs of Melbourne, has the highest land surface temperature (LST) at 32.54 °C, a UHI intensity of 1.84 °C, a normalised difference vegetation index (NDVI) of 0.11, and a normalised difference moisture index (NDMI) of −0.081. The LST and UHI intensity indicate a strong negative correlation with the NDVI (r = −0.42) and NDMI (r = −0.6). In contrast, the NDVI and NDMI have a positive correlation with the index of economic resources (IER) with r values of 0.29 and 0.24, indicating that the areas with better finance resources tend to have better vegetation coverage or plant health with less water stress, leading to lower LST and UHI intensity. This study helps to identify the most critical areas in the Greater Melbourne region that are vulnerable to the risk of urban heat and extreme heat events, providing insights for the local city councils to develop effective mitigation strategies and urban development policies that promote a more sustainable and liveable community. Full article
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20 pages, 4008 KiB  
Article
Green Synthesis and Characterization of Fe-Ti Mixed Nanoparticles for Enhanced Lead Removal from Aqueous Solutions
by Shamika P. W. R. Hewage and Harshica Fernando
Molecules 2025, 30(9), 1902; https://doi.org/10.3390/molecules30091902 - 24 Apr 2025
Viewed by 601
Abstract
Heavy metal contamination in water resources presents a significant environmental and public health challenge, with lead being particularly concerning due to its toxicity and persistence. This study reports the green synthesis of Fe-Ti mixed oxide nanoparticles (NPs) using dextrose as a green source [...] Read more.
Heavy metal contamination in water resources presents a significant environmental and public health challenge, with lead being particularly concerning due to its toxicity and persistence. This study reports the green synthesis of Fe-Ti mixed oxide nanoparticles (NPs) using dextrose as a green source and investigates their effectiveness in lead removal from aqueous solutions. The synthesized NPs were characterized using XRD, FTIR, XPS, SEM-EDS, and BET analysis, revealing an amorphous structure with a high surface area (292.89 m2 g−1) and mesoporous characteristics. XPS analysis confirmed the presence of mixed Fe3+/Fe2+ valence states in a Ti4+-rich framework, creating diverse binding sites for lead adsorption. The material exhibited optimal lead removal at pH 5, with adsorption following pseudo-second-order kinetics (R2 > 0.99) and a Langmuir isotherm model (R2 > 0.98). Maximum adsorption capacity reached 25.10 mg g−1 at 40 °C, showing endothermic behavior. The low point of zero charge (PZC, 0.22) and surface hydroxyl groups enabled efficient lead binding possibly through multiple mechanisms. Dose optimization studies established 6 g L−1 as the optimal adsorbent concentration. The synergistic combination of iron’s affinity for heavy metals and titanium’s structural stability, coupled with environmentally friendly synthesis, resulted in a promising material for sustainable water treatment applications. Full article
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