Search Results (272)

Lead (Pb²⁺) and cadmium (Cd²⁺) are among the most hazardous heavy metal pollutants in wastewater owing to their high toxicity, environmental persistence, and detrimental impacts on human health and aquatic ecosystems. In this study, a novel ternary magnetic composite, SnFe₂O₄/activated carbon/polypyrrole (SnFe₂O₄/AC/PPy), was effectively synthesized and tested as an effective adsorbent in the removal of Pb²⁺ and Cd²⁺ from aqueous water. The composite was prepared by depositing spinel SnFe₂O₄ nanoparticles on activated carbon, followed by in situ polymerization of polypyrrole to enhance surface functionality and adsorption affinity. The successful fabrication of the porous SnFe₂O₄/AC/PPy hybrid composite was confirmed through FTIR, XRD, SEM–EDS, BET, XPS, and VSM characterization. The composite demonstrated a relatively high surface area (352.3 m²/g) and adequate magnetic responsiveness (12.33 emu/g), ensuring facile magnetic separation following wastewater treatment. Batch adsorption experiments showed great removal efficiency of 95.02 and 92.48% for Pb²⁺ and Cd²⁺ ions, respectively, at optimum conditions. The adsorption equilibrium data followed the Langmuir isotherm model with maximum adsorption capacities of 187.07 mg/g for Pb²⁺ and 96.45 mg/g for Cd²⁺ ions, which were attributed to monolayer adsorption on homogenous active sites. The kinetic and isothermal model indicated that the adsorption process was controlled by the combination of physical and chemical interactions. Thermodynamic parameters showed negative Gibbs free energy and enthalpy changes (ΔH° = −49.74 kJ/mol for Pb²⁺ and −38.82 kJ/mol for Cd²⁺ ions), confirming the spontaneous and exothermic nature of adsorption. Furthermore, the increasingly negative ΔG° values at lower temperatures indicated that the adsorption was thermodynamically more favorable under cooler conditions. According to the regeneration studies, the composite maintained a high removal efficiency after five consecutive cycles. In general, SnFe₂O₄/AC/PPy composite has good potential as a stable, reusable, and high-performance adsorbent to treat heavy metal wastewater. Full article

The objective of this study is to develop a nanosized, visible-light-responsive photocatalyst with magnetic separability and recyclability for repeated use. Spinel ferrite nanoparticles, which are environmentally friendly, are promising candidates for achieving this goal. Spinel ferrite nanoparticles were synthesized via a low-temperature hydrothermal method to investigate their microstructural characteristics, magnetic properties, and photocatalytic performance. Initially, four ternary spinel ferrite (MFe₂O₄, where M = Mg, Mn, Co, and Zn) nanoparticles were compared in terms of their physical properties and photodegradation efficiencies of organic dye methylene blue (MB). Among them, the MgFe₂O₄ and ZnFe₂O₄ samples exhibited superior photocatalytic activity compared to the MnFe₂O₄ and CoFe₂O₄ samples. Subsequently, a systematic investigation of the Zn–Mg ferrite system (Zn_1−xMg_xFe₂O₄, x = 0 to 0.8 in increments of 0.2) was carried out. The results revealed that the x = 0.8 samples achieved the highest photodegradation efficiency of 99 for a 10 MB aqueous solution under visible-light irradiation for 90 min. This improved performance is attributed to formation of a heterojunction of Zn–Mg nanoferrite/Fe₂O₃, which promotes light harvesting and prevents photogenerated charge recommendation, thus significantly improving photocatalytic activity. Full article

Effective thermal management is crucial for the performance, thermal safety, and lifespan of lithium-ion batteries in electric vehicles (EVs). Thermal management strategies are essential for preventing overheating, thermal imbalance, and the associated risk of thermal runaway. Nanofluids are emerging and attracting considerable attention as potential coolants for high-power energy storage and electronics systems. This review updates and summarizes the most recent advances in nanofluid-based cooling strategies for battery thermal management systems (BTMSs) over the past five years, emphasizing their implications for battery thermal safety. Three main nanofluid-based cooling strategies have been evaluated in depth, including nanofluid-based indirect liquid cooling, nanoparticle-enhanced PCM cooling, and nanofluid-based heat pipe cooling. Various nanofluid formulations, including mono, hybrid, and ternary nanofluids, have been considered and evaluated for their heat dissipation under high charge/discharge and abuse-relevant conditions. Thermal and hydraulic performance characteristics, including maximum temperature, maximum temperature difference, and pressure drop, have been comprehensively evaluated for different nanofluid-based cooling strategies. The findings demonstrated that nanofluids significantly improved heat transfer rates and enhanced temperature control efficiency. In particular, hybrid and ternary nanofluids exhibit superior thermal performance and effectively suppress the escalation of safety-critical temperatures. Beyond summarizing cooling performance, this review further discusses the role of nanofluid-based cooling strategies as functional thermal-control layers within intelligent BTMS architectures. Particular attention is given to their compatibility with sensing networks, BMS-/VCU-level supervisory control, predictive thermal models, actuator responsiveness, fault-warning algorithms, and long-term reliability under realistic driving and fast charging conditions. Therefore, this review provides architecture-oriented insights for developing safe, energy-efficient, and control-ready BTMSs for next-generation high-power and connected EVs. Full article

A numerical investigation of forced convection heat transfer in a three-dimensional T-shaped bifurcating channel with an upstream rotating cylinder and a downstream vibrating wavy wall is presented. The working fluid is a ternary hybrid nanofluid (Fe₂O₃, CuO, MoS₂ in water) exhibiting Casson rheology under an inclined magnetic field. The novelty of this work lies in the first integrated configuration combining these simultaneous mechanical, magnetic, and non-Newtonian effects. Using COMSOL Multiphysics, 413 parametric combinations of Reynolds number, Hartmann number, Casson parameter, nanoparticle shape and volume fraction, magnetic field angle, cylinder rotation speed, wall amplitude (Am), and period were solved. Average Nusselt and Bejan numbers quantified heat transfer enhancement and thermodynamic irreversibility. To interpret the high-dimensional parameter space and to circumvent the prohibitive computational cost of additional 3D magnetohydrodynamics simulations, machine learning (XGBoost) models were developed to rank feature importance and provide fast, accurate surrogate predictions (R² > 0.99). Cylinder rotation dominates heat transfer, increasing the Nusselt number by over 980% (feature importance 0.42) with a modest entropy penalty. Nanoparticle volume fraction reduces the Nusselt number via viscous damping. Magnetic field parameters negligibly affect heat transfer but strongly influence entropy generation; a perpendicular field recovers up to 97% thermal efficiency at high Hartmann numbers. Full article

Increasing environmental pollution has intensified the focus on sustainability, encouraging the development of eco-friendly materials. This study reports the synthesis of binary (ZnO–TiO₂) and ternary (SnO₂–ZnO–TiO₂) compounds and their loading with Au/Ag/Pt/P noble metals (NMs) to enhance photodegradation efficiency under visible light compared to pristine TiO₂. The compounds were synthesized in a single step via laser pyrolysis, and then noble metal deposition through chemical impregnation and reduction was performed. Structural and morphological analyses revealed TiO₂-based nanoparticles with varied morphologies decorated with noble metal nanoparticles with sizes between 2 and 6 nm (for Pt and Pd). Photocatalytic tests demonstrated a significant improvement in Methyl Orange (MO) degradation under visible light, especially for Ag-loaded samples. The degradation rate increased from 1.03 × 10⁻³ min⁻¹ (TZ) to 22.65 × 10⁻³ min⁻¹ (TZS_Ag), while it was 0.09 × 10⁻³ min⁻¹ for the commercial P25 sample. Biocompatibility assays indicated lower cytotoxicity than Degussa P25, with Au- and Pd-loaded samples showing improved compatibility with HaCaT and HEK293 cells. Overall, these findings demonstrate that the developed TiO₂-based nanocomposites, designed through a novel and sustainable strategy combining binary/ternary heterostructures with noble metal loading, are promising candidates for efficient visible light-driven photocatalytic environmental decontamination with enhanced biological compatibility. Full article

In this study, a novel magnetic metal–organic framework (MOF) composite, Pd@UiO-66@Fe₃O₄, was successfully synthesized as a high-performance heterogeneous catalyst for the Suzuki–Miyaura cross-coupling reaction. The material was prepared by loading nano-sized carboxylated Fe₃O₄ onto UiO-66 via an in situ solvothermal method, followed by the encapsulation of Pd nanoparticles using an ultrasound-assisted dual-solvent method (DSA). Characterization results, including PXRD and TEM, confirmed that the ternary composite retains the structural integrity of UiO-66 while incorporating magnetic functionality and well-dispersed Pd active sites. The catalyst exhibited high catalytic performance for the coupling of aryl iodides and aryl boronic acids. Furthermore, the catalyst demonstrated good compatibility with the substrates examined and excellent stability. Due to the integration of carboxylated Fe₃O₄, the composite could be easily separated from the reaction mixture using an external magnet and reused for at least five cycles without a significant loss in catalytic activity. The high activity and durability are attributed to the integrated roles of the Pd nanoparticles, the porous MOF support, and the magnetic Fe₃O₄ component, which respectively provide catalytic active sites, structural stabilization/dispersion, and magnetic recoverability. Full article

Water pollution caused by antibiotics is a growing problem. Therefore, photodegradation by efficient catalysts is an environmentally friendly technology that can effectively degrade organic pollutants in water. In this work, a method was innovatively used to prepare a ternary heterostructure of plasmon-enhanced Ag-CuO/TiO₂. The composite was synthesized through a facile stepwise strategy involving the formation of CuO nanorods, TiO₂ coating, and subsequent deposition of Ag nanoparticles on their surface using AgNO₃, enabling intimate interfacial contact among the different components. The prepared samples were characterized by XRD, HRTEM, XPS, and UV-Vis. The chemical composition of the composite Ag-CuO/TiO₂ showed a Cu/Ti atomic ratio of 2.58, as well as a Ag/Cu ratio of 0.91. The UV-Vis spectrum reveals the largest absorption peak at 550 nm for the composite Ag-CuO/TiO₂. The prepared Ag-CuO/TiO₂ composites were applied to the visible-light degradation of tetracycline hydrochloride, with the photocatalytic degradation rate reaching 80.7% under the optimal conditions within 60 min, which is significantly better than CuO and CuO/TiO₂ without silver nanoparticles. Capture experiments indicated that h⁺ are involved during the course of the photodegradation and that h⁺ are the main active substances. Furthermore, the proposed mechanism for the photodegradation of the Ag-CuO/TiO₂ composites is given. It has potential applications in the treatment of organic pollutants in water. Full article

Diesel engines are commonly used in transportation and power generation, but their operation is associated with incomplete combustion and emissions. In this research, four different nanocatalyst additives including Ag, Ag/TiO₂, Ce/TiO₂, and Ag/CeO₂/TiO₂ were studied as diesel fuel additives to improve combustion efficiency and minimize regulated emissions. These nanoparticles were synthesized and characterized by employing X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) techniques. The prepared fuel blends were tested in a single-cylinder diesel engine at additive concentrations of 50, 75, and 100 ppm under varying engine loads. Among the tested formulations, the ternary Ag/CeO₂/TiO₂ blend demonstrated the highest performance. When compared with the baseline diesel fuel, it reduced CO emissions by 32.5%, HC emissions by 27.8%, and NO_x emissions by 29.4%. At the same time, the amount of CO₂ emission has increased by 18.81%, which shows that the combustion is more complete. Also, the same formulation has decreased brake-specific fuel consumption (BSFC) by 18.7% and increased brake thermal efficiency (BTE) by 16.3%. The improved performance is due to the cooperative effect of CeO₂ oxygen buffering, TiO₂ surface-assisted oxidation, and oxidation activity of the silver species. The findings show that the ternary nanocatalyst formulation is an effective approach for optimizing diesel fuel combustion and emissions. Full article

The severe performance degradation of lithium-ion batteries at low temperatures limits their applications in extreme environments. Herein, we report the development of a low-temperature-capable 2.5 Ah 18650 cylindrical battery employing a LiNi_0.8Co_0.15Al_0.05O₂ cathode with optimized conductive additive formulations. The ternary conductive architecture is rationally designed based on dimensional complementarity: a zero-dimensional Super P (SP) nanoparticle ensures percolation through point-to-point contacts, a one-dimensional multi-walled carbon nanotube (MWCNT) establishes long-range electron highways via line-to-point bridging, and a two-dimensional graphene nanoplatelet (GNP) provides face-to-point encapsulation of active particles, mechanically buffering volume expansion and suppressing interfacial degradation. This hierarchical point–line–plane network generates redundant electron transport pathways while steric hindrance effects mitigate aggregation of each component. Through systematic comparative investigation of GNP/MWCNT/SP ternary and MWCNT/SP binary conductive systems, we elucidate the distinct roles of low-dimensional nanocarbons in electrochemical performance enhancement. Film resistivity measurements reveal that the ternary system achieves a 67% reduction in cathode resistivity (to 9.1 Ω·cm at 20 °C) compared to conventional SP (27.5 Ω·cm), outperforming previously reported binary nanocarbon systems for high-nickel cathodes (typically 40–55% reduction at comparable loadings). This enhancement is achieved at a constant total conductive additive loading of 2.5 wt%, demonstrating that dimensional optimization rather than quantity increase governs electrical transport properties. Electrochemical evaluations demonstrate that the fabricated 18650 cells deliver exceptional rate capability (10C continuous and 20C pulse discharge) and remarkable low-temperature performance (76.8% capacity retention at −40 °C under 1C). Notably, while both conductive formulations exhibit comparable rate performan ce and temperature adaptability, the ternary GNP/MWCNT/SP system demonstrates significant superiority in cycling stability, achieving 94.9% capacity retention after 1000 cycles at ambient temperature versus inferior retention for the binary counterpart. Electrochemical impedance spectroscopy analyses indicate reduced polarization and enhanced lithium-ion diffusion kinetics in the ternary system. This study establishes a high-performance low-temperature 18650 battery chemistry and provides quantitative mechanistic insights into how dimensional synergy in conductive additive design governs the rate capability, thermal behavior, and cycling stability of nickel-rich cathodes operating under extreme conditions. Full article

Cyclic pollutants such as dyes, antibiotics, phenols and VOCs in water and atmosphere feature stable structures and are difficult to mineralize, which constitutes the core problem in current environmental governance. Semiconductor photocatalysis provides a green strategy for the advanced treatment of such pollutants. Electrospun black TiO₂/Ag-loaded SiO₂ nanofiber membranes have become a research hotspot owing to their multi-component synergistic advantages. This paper systematically reviews the preparation processes and structure regulation methods of electrospun SiO₂ nanofiber membranes; expounds the loading strategies of black TiO₂ and Ag nanoparticles, the interface regulation mechanisms and the synergistic photocatalytic mechanism of the ternary composite system; summarizes the application progress in the degradation of cyclic pollutants in water and atmospheric VOCs; and emphatically analyzes the performance characteristics and key issues in the ring-opening degradation of cyclic pollutants. Studies show that the high specific surface area and porous structure of SiO₂ nanofiber membranes offer excellent support for catalytic reactions. In addition, black TiO₂ achieves a full-spectrum response through defect engineering; the SPR effect and Schottky barrier of Ag significantly improve carrier separation efficiency; and the synergistic effect of the three components enhances the adsorption–catalytic degradation capacity. Current challenges remain in ring-opening efficiency and stability, requiring multi-method breakthroughs to overcome bottlenecks, clarify mechanisms and promote engineering applications. This paper provides theoretical references for the development of high-performance fiber-based photocatalytic materials and lays a foundation for the practical application of electrospun inorganic nanofiber membranes in the field of environmental catalysis. Full article

With the rapid development of electronic devices and wireless communication systems, electromagnetic interference pollution has become a critical concern, driving the urgent demand for high-performance, lightweight, and flexible electromagnetic interference (EMI) shielding materials. To endow fabrics with excellent electromagnetic shielding, a Fe₃O₄/Ag/RGO ternary nanocomposite-coated cotton fabric for electrical conductivity and EMI shielding application was developed. The cotton fabric pretreated with dopamine was coated with graphene oxide (GO), followed by silver nanoparticles (Ag) via a microwave-assisted chemical reduction method, and Ag/reduced graphene oxide (RGO)-coated cotton. Subsequently, nano-ferroferric oxide was deposited on Ag/RGO-coated cotton fabric using a coprecipitation method. The results show that the surface resistance of Fe₃O₄/Ag/RGO-coated cotton fabric arrives at 1.68 Ω/sq, demonstrating excellent electrically conductive performance. Fe₃O₄/Ag/RGO-coated cotton fabric demonstrates outstanding electromagnetic shielding performance, with SE values exceeding 45 dB across the entire 1–18 GHz range. The flexibility and superior electromagnetic shielding performance of Fe₃O₄/Ag/RGO-coated cotton fabric render it a promising candidate for applications in wearable electronics, aerospace, advanced protective systems, and military protective clothing. Full article

Active and cost-effective catalysts are essential for obtaining high hydrogen evolution activity. In this paper, we report ZnO/ZnLDH/ZnLDO as a novel ternary Zn²⁺-based heterostructure obtained via the partial structural reconstruction of Zn-based layered double hydroxides (LDH) in a Zn²⁺-containing solution and evaluate its catalytic performance in hydrogen evolution under solar light. The reconstruction strategy induces the formation of a ZnLDH/ZnLDO platform decorated with small ZnO nanoparticles (~3 nm) that are generated in situ during the reconstruction process. The catalysts were extensively characterized for their structure and morphology by XRD, SEM, and TEM/HRTEM, while XPS analysis reveals electronic modulation across the interfaced units. For photocatalytic H₂ evolution under simulated solar light, the optimized ZnO/ZnLDH/ZnLDO (x = 15%) achieves the highest performance with a hydrogen evolution rate of 1.8 mmol h⁻¹ gcat⁻¹, outperforming the individual (ZnLDH, ZnLDO) and binary (ZnO/ZnLDH, ZnO/ZnLDO) catalysts. The enhanced activity is attributed to cascade-type charge transfer across the ternary Zn²⁺-based structures, which promotes efficient charge separation. However, excessive reconstruction (high x%) or high-temperature calcination alter the LDH/LDO balance, resulting in decreased photocatalytic activity. This work provides a new idea for designing active multiple interfaced heterostructured photocatalysts by using the partial reconstruction of LDH as a facile and cost-effective approach. Full article

This study focuses on the development and characterization of advanced composite materials based on poly(ε-caprolactone) (PCL) and poly(vinylidene fluoride) (PVDF), with or without silver nanoparticles (AgNPs), planned for peripheral nerve or bone regeneration. The complementary properties of PCL (biocompatibility and biodegradability) and PVDF (mechanical stability and piezoelectric functionality) were exploited by blending the polymers in different ratios, resulting in binary (PCL/PVDF) and ternary (PCL/PVDF/AgNPs) composites. Green-synthesized AgNPs were integrated to enhance antimicrobial activity and to support tissue repair through improved signal transmission. Functional thin films and electrospun fibres were obtained and subjected to advanced characterization techniques, including scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermal analysis. The results demonstrated appropriate morphology, chemical composition, structural stability, and favourable interactions with simulated physiological media. Preliminary biocompatibility assays confirmed good cell viability, supporting the biomedical applicability of the designed scaffolds. Overall, the obtained results highlight the potential of AgNPs-functionalized PCL/PVDF binary and ternary composites as promising candidates for flexible, durable, and bioactive implants in peripheral nerve or bone regeneration. Full article

The peripheries of rare-metal metallogenic systems frequently host skarn-type or hydrothermal vein-type Pb-Zn deposits, though their genetic connections with parental systems remain debated. The newly identified Gariatong W-Mo polymetallic metallogenic system in the Lhasa Terrane displays well-defined Nb-Ta-Rb, Mo-W, W-Mo, W-Bi, and Pb-Zn-Ag metallogenic zoning, establishing it as an exemplary site for investigating genetic relationships between Pb-Zn and rare-metal mineralization. This investigation targets skarn-type Pb-Zn deposits spatially associated with rare-metal orebodies at Gariatong, utilizing integrated analytical approaches, including in situ LA-ICP-MS trace-element analysis of sulfides, sulfur isotope geochemistry, and LA-ICP-MS elemental mapping of sphalerite, to constrain metal sources, characterize fluid evolution, and establish genetic correlations with the rare-metal system. Key findings include the following: (1) sphalerite shows enrichment in Fe, Mn, Co, and Cd, while pyrite contains elevated As, Pb, Co, Cu, and Mn. Fe, Cd, and Mn primarily occur as solid solutions or nanoparticles, whereas As and Pb exist as micro-inclusions. (2) Sphalerite Zn/Cd ratios (73.6–184) and Co-Ni-As ternary diagrams confirm a magmatic–hydrothermal skarn origin. (3) Mineralization occurred under moderate-temperature, mildly oxidized conditions, as constrained by sphalerite Fe contents and mineral assemblages. Sulfur isotope compositions (δ³⁴S = −1.0‰ to 3.2‰; mean: 1.9‰) indicate a magmatic sulfur source. This study reveals that the Nb-Ta-Rb mineralization, quartz-vein- and greisen-type W-Mo deposits, and skarn-type Pb-Zn orebodies—all genetically associated with highly fractionated granites—constitute an integrated magmatic–hydrothermal system with vertical (depth-related) zoning relative to the granitic intrusion. These results provide critical constraints for understanding rare-metal–Pb-Zn genetic associations and suggest that Pb-Zn mineralization may serve as a key exploration indicator for rare metals in the Lhasa Terrane. Full article

The study addresses a selected issue in industrial cooling, that is, how to transport heat more efficiently when the process involves fiber spinning and extrusion, in which conventional fluids usually cannot work. We considered a ternary nanofluid that passed around a porous stretching cylinder and particularly considered the synergistic effect of quadratic thermal buoyancy, and the thermally generated double-diffusive heat and solute (TGDHS) effect. Through the Casson fluid model and considering the magnetic fields, radiations, and nonlinear chemical reactions, we reduced complex PDEs to simple ODEs. The results were evident using the BVP4C numerical method. Although in reality, magnetic fields and thermal radiation become a retarding force, the quadratic thermal buoyancy is the driving force behind accelerating the flow. An important trade-off that we discovered is that a heavier Casson fluid reduces heat and mass transfer. The addition of Nimonic 80A, AA7072, and AA7075 nanoparticles to ethylene glycol consistently enhances heat transfer, outperforming the base fluid by 7.8% even at low concentrations. While AA7072 and AA7075 drive significant increases of over 16%, Nimonic 80A offers a much more marginal contribution of 1.23%. Consequently, the Nusselt number is far more sensitive to the concentration of the aluminum alloys than to the Nimonic 80A. Finally, this work demonstrates that the most significant parameter in intensifying convective heat and mass transfer in such industrial systems is the strong forces of buoyancy. Full article