Search Results (747)

Flocculants are indispensable in water and wastewater treatment, enabling the aggregation and removal of suspended particles, colloids, and emulsions. However, the conventional development and application of flocculants rely heavily on empirical methods, which are time-consuming, resource-intensive, and environmentally problematic due to issues such as sludge production and chemical residues. Recent advances in machine learning (ML) have opened transformative avenues for the design, optimization, and intelligent application of flocculants. This review systematically examines the integration of ML into flocculant research, covering algorithmic approaches, data-driven structure–property modeling, high-throughput formulation screening, and smart process control. ML models—including random forests, neural networks, and Gaussian processes—have successfully predicted flocculation performance, guided synthesis optimization, and enabled real-time dosing control. Applications extend to both synthetic and bioflocculants, with ML facilitating strain engineering, fermentation yield prediction, and polymer degradability assessments. Furthermore, the convergence of ML with IoT, digital twins, and life cycle assessment tools has accelerated the transition toward sustainable, adaptive, and low-impact treatment technologies. Despite its potential, challenges remain in data standardization, model interpretability, and real-world implementation. This review concludes by outlining strategic pathways for future research, including the development of open datasets, hybrid physics–ML frameworks, and interdisciplinary collaborations. By leveraging ML, the next generation of flocculant systems can be more effective, environmentally benign, and intelligently controlled, contributing to global water sustainability goals. Full article

This study evaluates the agronomic potential of two types of vermicompost—one produced solely from wine industry residues (WIR) and one incorporating sewage sludge (WIR + SS)—under rainfed and deficit irrigation conditions in Mediterranean vineyards. The vermicompost was obtained through a two-phase process involving initial thermophilic pre-composting, followed by vermicomposting using Eisenia fetida for 90 days. The conditions were optimized to ensure aerobic decomposition and maintain proper moisture levels (70–85%) and temperature control. This resulted in end products that met the legal standards required for agricultural use. However, population dynamics revealed significantly higher worm reproduction and biomass in the WIR treatment, suggesting superior substrate quality. When applied to grapevines, WIR vermicompost increased soil organic matter, nitrogen availability, and overall fertility. Under rainfed conditions, it improved vegetative growth, yield, and must quality, with increases in yeast assimilable nitrogen (YAN), sugar content, and amino acid levels comparable to those achieved using chemical fertilizers, as opposed to the no-fertilizer trial. Foliar analyses at veraison revealed stronger nutrient uptake, particularly of nitrogen and potassium, which was correlated with improved oenological parameters compared to the no-fertilizer trial. In contrast, WIR + SS compost was less favorable due to lower worm activity and elevated trace elements, despite remaining within legal limits. These results support the use of vermicompost derived solely from wine residues as a sustainable alternative to chemical fertilizers, in line with the goals of the circular economy in viticulture. Full article

This work studies and analyzes the transition from a linear to a circular economy through wastewater treatment and resource recovery. As wastewater volumes grow, sustainable management becomes critical. This study highlights the reuse of treated effluent, beneficial sludge utilization, and energy generation via anaerobic digestion. Wastewater treatment plants should be envisioned as hubs for recovering water, materials, and energy, rather than disposal facilities. Emphasizing resource efficiency, the circular economy approach offers viable solutions to challenges related to resource scarcity, climate change, and ecological impact. Full article

Petroleum oily sludge (OLS), a hazardous by-product of the petroleum industry, and high-alkali lignite (HAL), an underutilized low-rank coal, pose significant challenges to sustainable waste management and resource efficiency. This study systematically investigated the combustion behavior, reaction pathways, and gaseous-pollutant-release mechanisms across varying blend ratios, utilizing integrated thermogravimetric-mass spectrometry analysis (TG-MS), interaction analysis, and kinetic modeling. The key findings reveal that co-combustion significantly enhances the combustion performance compared to individual fuels. This is evidenced by reduced ignition and burnout temperatures, as well as an improved comprehensive combustion index. Notably, an interaction analysis revealed coexisting synergistic and antagonistic effects, with the synergistic effect peaking at a blending ratio of 50% OLS due to the complementary properties of the fuels. The activation energy was found to be at its minimum value of 32.5 kJ/mol at this ratio, indicating lower reaction barriers. Regarding gas emissions, co-combustion at a 50% OLS blending ratio reduces incomplete combustion products while increasing CO₂, indicating a more complete reaction. Crucially, sulfur-containing pollutants (SO₂, H₂S) are suppressed, whereas nitrogen-containing emissions (NH₃, NO₂) increase but remain controllable. This study provides novel insights into the synergistic mechanisms between OLS and HAL during co-combustion, offering foundational insights for the optimization of OLS-HAL combustion systems toward efficient energy recovery and sustainable industrial waste management. Full article

The fatigue resistance of cement-stabilized macadam (CSM) plays a vital role in ensuring the long-term durability of pavement structures. However, limited cementitious material (CM) content often leads to high packing voids, which significantly compromise fatigue performance. Existing studies have rarely explored the coupled mechanism between pore structure and fatigue behavior, especially in the context of solid-waste-based CMs. In this study, a cost-effective alkali-activated sludge gasification slag (ASS) was proposed as a sustainable CM substitute for ordinary Portland cement (OPC) in CSM. A dual evaluation approach combining cross-sectional image analysis and fatigue loading tests was employed to reveal the effect pathway of void structure optimization on fatigue resistance. The results showed that ASS exhibited excellent cementitious reactivity, forming highly polymerized C-A-S-H/C-S-H gels that contributed to a denser microstructure and superior mechanical performance. At a 6% binder dosage, the void ratio of ASS–CSM was reduced to 30%, 3% lower than that of OPC–CSM. The 28-day unconfined compressive strength and compressive resilient modulus reached 5.7 MPa and 1183 MPa, representing improvements of 35.7% and 4.1% compared to those of OPC. Under cyclic loading, the ASS system achieved higher energy absorption and more uniform stress distribution, effectively suppressing fatigue crack initiation and propagation. Moreover, the production cost and carbon emissions of ASS were 249.52 CNY/t and 174.51 kg CO₂e/t—reductions of 10.9% and 76.2% relative to those of OPC, respectively. These findings demonstrate that ASS not only improves fatigue performance through pore structure refinement but also offers significant economic and environmental advantages, providing a theoretical foundation for the large-scale application of solid-waste-based binders in pavement engineering. Full article

This study evaluates the agronomic and environmental performance of pelletized compost derived from olive mill waste as a sustainable alternative to mineral fertilizers for cultivating wheat (Triticum turgidum L.) under conventional tillage methods. A field experiment was conducted in semi-arid Spain, employing three fertilization strategies: inorganic (MAP + Urea), sewage sludge (SS), and organic compost pellets (OCP), each providing 150 kg N ha⁻¹. The parameters analyzed included wheat yield, grain quality, soil properties, and greenhouse gas (GHG) emissions. Inorganic fertilization yielded the highest productivity and nutrient uptake. However, the OCP treatment reduced grain yield by only 15%, while improving soil microbial activity and enzymatic responses. The SS and OCP treatments showed increased CO₂ and N₂O emissions compared to the control and inorganic plots. However, the OCP treatment also acted as a CH₄ sink. Nutrient use efficiency was greatest under mineral fertilization, though the OCP treatment outperformed the SS treatment. These results highlight the potential of OCP as a circular bio-based fertilizer that can enhance soil function and partially replace mineral inputs. Optimizing application timing is critical to aligning nutrient release with crop demand. Further long-term trials are necessary to evaluate their impact on the soil and improve environmental outcomes. Full article

Sewage sludge, characterized by its high organic matter and nutrient content, as well as the presence of microbial pathogens and other contaminants, requires proper management due to its significant generation rate. The table olive sector, which is highly significant in Spain as a global leader in production and export, generates various waste streams such the Organic Solid By-Products from Table Olive Processing (OSBTOP), which are mainly derived from the olive pit after the pitting process. The main aim of this study was to enhance the methane production performance of sewage sludge through co-digestion with OSBTOP as a co-substrate. Batch assays demonstrated that employing OSBTOP as a co-substrate increased methane content by 35–41% across all tested mixtures. While the highest methane yield was produced at a 40:60 (sludge:OSBTOP) ratio, a 60:40 mixture proved to be a more advantageous option for scale-up and practical application. This is attributed to factors such as the higher availability of sludge and its inherent buffering capacity, which counteracts the accumulation of volatile fatty acids and promotes process stability, thereby contributing to the study’s objective of significantly enhancing methane production from sewage sludge through co-digestion. In semi-continuous operation, methane yields in the co-digestion scenario exceeded those of mixed sludge digestion, showing a yield of 180 versus 120 LCH₄⁻¹ · kgVS_added⁻¹, representing a 50% improvement. This study highlights the potential of anaerobic digestion as a strategy for valorizing OSBTOP, a by-product with no prior studies, while demonstrating that its co-digestion with sewage sludge enhances methane generation, offering a sustainable approach to organic waste treatment. Full article

This paper describes the process of drying sewage sludge mixtures with the addition of various components: straw chaff, wood sawdust, ash, bark, wood chips, and walnut shells. The tests were conducted in two series: summer and autumn (with maximum insolation of 24.1 and 29.8 MJ∙m⁻², respectively). Using a set of sensors with which the experimental station was equipped, the parameters of the environment (temperature, humidity, and insolation) and the parameters of the dried mixtures (temperature and humidity) were measured. Based on the results obtained, the influence of external factors on the parameters, time, and drying effect of the respective mixtures was analyzed. With the initial moisture content of the mixtures ranging from 41 to 79%, a final moisture content of 6 to 49% was obtained, depending on the components and drying conditions. It was found that the drying rate was most influenced by the amount of solar energy and the associated outdoor (maximum 29 °C and 19 °C) and indoor (maximum 33 °C and 24 °C) air temperatures, and in the second series, there was an additional effect of the temperature of the mixtures (maximum 30 °C), upon which the intensity of water evaporation depended. Straw chaff and walnut shells proved to be the best additives, for which the highest drying rates were obtained (max. 50 to 60% humidity drop). The possibility of using dried materials for agricultural and energy purposes was indicated. This approach is in line with the principles of sustainable development. Full article

Macro- and microelements in waste can be returned to the soil as fertilizers and their sustainable use can reduce the need to extract natural resources. For example, the use of carbonate-clay flour, sewage sludge and waste sulfate sulfur to improve soil properties enables the natural recycling of the nutrients contained in these materials. Soil physicochemical properties with the application of waste and the bioavailability of nutrients and trace elements were assessed before and after a 3-month incubation period. This study showed that when carbonate-clay flour was applied alone or together with sewage sludge and waste sulfur, it improved the properties of the soil, inducing a reduction in acidification and an increase in the content of available P, K and Mg. Sewage sludge also provided Zn, Cu, Ni and Cr in addition to organic carbon. Sulfate did not cause soil acidification. The results indicate that the use of carbonate-clay flour alone, as well as with the addition of sewage sludge and sulfate sulfur, can be recommended for the deacidification of soil and serve as a remediation tool for, for example, the precipitation of chemical pollutants. The valorization of the waste used fits into the circular economy approach. Full article

The storage of sewage sludge in landfills is still the primary method of their disposal in many countries. Therefore, finding sustainable solutions for the reuse of this waste is an important issue to be addressed. This paper presents the results of research on processing sewage sludge generated at the wastewater treatment plants of Almaty, Kazakhstan, for use in the manufacturing of ceramic bricks. The chemical composition of the sewage sludge was determined, showing the presence of 35.7% silicon dioxide, 7.3% aluminum oxide, 11.2% iron oxide, and 10.6% calcium oxide. Experimental studies established that adding sewage sludge to clay reduces the compressive strength of ceramic bricks while increasing their flexural strength. Furthermore, as the proportion of sewage sludge in the clay mixture increases, the average density of the ceramic bricks decreases, while water absorption increases. It was also found that ceramic bricks made from a mixture of 90% clay and 10% sewage sludge demonstrated the best physico-mechanical properties. This composition showed increased flexural strength and a simultaneous reduction in the average density by 15.4%, indicating the improved structural quality of the manufactured bricks. Full article

Soil degradation and water scarcity pose major challenges to sustainable agriculture in semiarid regions, requiring innovative strategies to enhance water use efficiency (WUE) and soil fertility. This study assessed the effects of sewage sludge biochar (SSB) on soil properties, WUE, and common bean yield through a small-scale controlled field experiment under rainfed conditions in Northeast Brazil. Four SSB application rates (5, 10, 20, and 40 t ha⁻¹) were compared with conventional NPK fertilization, treated sewage sludge (SS), and chicken manure (CM). The application of 20 t ha⁻¹ (B20) significantly improved soil organic carbon, nitrogen content, water retention, and microbial biomass. B20 also increased WUE by 148% and grain yield by 146% relative to NPK, while maintaining safe levels of potentially toxic elements (PTE) in bean grains. Although 40 t ha⁻¹ (B40) enhanced soil fertility further, it posed a risk of PTE accumulation, reinforcing the advantage of B20 as an optimal and safe dose. These results highlight the potential of SSB to replace or complement conventional fertilizers, especially in sandy soils with limited water retention. The study supports SSB application as a sustainable soil management practice that aligns with circular economy principles, offering a viable solution for improving productivity and environmental resilience in semiarid agriculture. Full article

Eutrophication driven by nitrogen and phosphorus discharge remains a critical global environmental challenge. This study developed a sustainable strategy for synergistic nutrient removal and recovery by fabricating MgO-coated biochar (Mg-MBC600) through co-pyrolysis of municipal sludge and sunflower stalk (300–700 °C). Systematic investigations revealed temperature-dependent adsorption performance, with optimal nutrient removal achieved at 600 °C pyrolysis. The Mg-MBC600 composite exhibited enhanced physicochemical properties, including a specific surface area of 156.08 m²/g and pore volume of 0.1829 cm³/g, attributable to magnesium-induced structural modifications. Advanced characterization confirmed the homogeneous dispersion of MgO nanoparticles (~50 nm) across carbon matrices, forming active sites for chemisorption via electron-sharing interactions. The maximum adsorption capacities of Mg-MBC600 for nitrogen and phosphorus reached 84.92 mg/L and 182.27 mg/L, respectively. Adsorption kinetics adhered to the pseudo-second-order model, indicating rate-limiting chemical bonding mechanisms. Equilibrium studies demonstrated hybrid monolayer–multilayer adsorption. Solution pH exerted dual-phase control: acidic conditions (pH 3–5) favored phosphate removal through Mg₃(PO₄)₂ precipitation, while neutral–alkaline conditions (pH 7–8) promoted NH₄⁺ adsorption via MgNH₄PO₄ crystallization. XPS analysis verified that MgO-mediated chemical precipitation and surface complexation dominated nutrient immobilization. This approach establishes a circular economy framework by converting waste biomass into multifunctional adsorbents, simultaneously addressing sludge management challenges and enabling eco-friendly wastewater remediation. Full article

This study explores the feasibility of utilizing granite sawing sludge (FC) as a precursor to produce alkali-activated materials (AAMs). To enhance the reactivity of the system, metakaolin (MK) was added and binary mixtures were synthetized. A multidisciplinary approach, including mineralogical, chemical and mechanical analysis, was employed to assess the suitability of these precursors to produce AAMs. X-Ray diffraction (XRD) and Fourier-Transform Infrared spectroscopy (FT-IR) confirmed the occurred activation reaction with the consequent increase in the amorphous content. Raman spectroscopy was used to further explore the mineralogical composition of the consolidated specimens, helping in the detection of salts, whose formation is ascribed to secondary carbonatation processes. Morphological analysis (SEM-EDS) displayed relatively uniform microstructures for all specimens. Compressive strength tests revealed that MK rich samples achieved best values compared to FC rich formulations, which exhibited reduced strength resistance. This study highlights, for the first time, the benefits of incorporating Cuasso al Monte granite sawing sludges into alkali-activated binders. Results suggested that the incorporation of FC is recommended for both environmental and economic advantages. Full article

The treatment of wastewater and the utilization of the by-products of these processes are an important part of the circular economy. The sewage sludge, a result of wastewater treatment, could be used as a material for plant nutrient supply and/or soil-improving products. The city of Nyíregyháza, Hungary, with 120,000 citizens, has a well-planned water treatment plant operated by Nyírségvíz Ltd., which, in cooperation with the Research Institute of Nyíregyháza, developed a municipal sewage sludge compost (SSC). The closed loop of sewage water treatment and the agricultural utilization of its by-product has been developed and managed. The compost product called Nyírkomposzt was planned for acidic sandy soils. Beyond the agronomic benefits, the sustainable and environmentally sound utilization of SSC reduces sewage sludge disposal. This active involvement of a water utility company demonstrates the potential of cross-sectoral cooperation in solving environmental problems. The quality of the compost fits the Hungarian legislation. To study the effects of 0, 9, 18, and 27 t ha⁻¹ doses of compost on acidic sandy soil, a long-term small plot experiment was started in 2003. The cumulative effects of the regular (every third year, last treatment before sampling in 2021) application of the SSC showed positive changes in basic soil properties, depending on the doses used. Increasing values were found in the case of pH from 4.5 to 6, plant available P₂O₅ from 240 to 690 ppm, and plant available K₂O from 180 to 200 ppm. The plant-available zinc and copper content also increased. Soil organic matter and total N content stabilized at around 0.9% and 0.08%, respectively. The grain yields of winter rye also increased in both investigated years. The yields of 18 t ha⁻¹ treatment were about two times higher compared to the control, but only in 2022 was the difference significant. Our findings underscore the potential of well-planned SSC applications to improve the fertility of ploughed, acidic sandy soil, taking into account the theory of the circular economy by utilizing wastes and decreasing landfilling. Full article

The poultry industry produces significant quantities of keratin-rich waste, primarily feathers, whose traditional disposal methods—incineration or chemical treatment—result in environmental damage and resource depletion. This research introduces a sustainable biotechnological method for the valorization of feather waste utilizing Gordonia alkanivorans S7, an actinomycete strain extracted from petroleum plant sludge. This is the inaugural publication illustrating keratinolytic activity in the Gordonia genus. The optimization of the degradation process via the Taguchi approach led to the effective biodegradation of untreated home chicken feathers, achieving dry mass loss of up to 99% after 168 h in a mineral medium. The agricultural potential of the obtained keratin hydrolysate, which was high in organic components (C 31.2%, N 8.9%, H 5.1%, and S 1.7%), was assessed. Phytotoxicity tests demonstrated that the feather hydrolysate led to better growth of the indicator plants—Sorghum saccharatum and Lepidium sativum. The highest values of root growth stimulation were 26% for S. saccharatum and 31% for L. sativum, at a dose of 0.01%. Shoot growth stimulation was noted only for L. sativum, reaching 38% (0.01%), 53% (0.05%), and 37% (0.1%), as compared to the control sample. These results demonstrate the process’s combined economic and environmental benefits, providing a fresh approach to the production of bio-based plant biostimulants and sustainable keratin waste management. Full article