Search Results (3,864)

Rapid changes in Arctic summer sea ice exert substantial influences on the polar climate system, maritime navigation, and resource exploitation, while subseasonal-to-seasonal (S2S) prediction of sea ice state remains highly uncertain. Using daily observations and reanalysis data of sea ice concentration (SIC) and thickness (SIT) from 1979 to 2023, together with concurrent atmospheric and oceanic fields, this study develops a multivariate linear Markov model to perform S2S predictions of Arctic summer sea ice. Sensitivity experiments with different variable combinations, weighting strategies, and modal truncation schemes are conducted, and predictive skill is systematically evaluated against persistence and climatological baselines. Results indicate that the model exhibits stable forecast skill without pronounced error accumulation at extended lead times. SIC predictability is primarily governed by its intrinsic spatiotemporal persistence and is significantly modulated by oceanic thermodynamic forcing, particularly sea surface temperature and surface net energy flux, highlighting a pronounced oceanic memory effect. In contrast, local atmospheric dynamic variables provide limited incremental skill. For SIT, predictability is dominated by its own historical state, with SIC contributing marginal short-term improvement and air–sea coupling exerting weak influence. Overall, the proposed framework effectively extracts dominant predictable signals with clear physical interpretability, providing a computationally efficient statistical approach for S2S prediction of Arctic summer sea ice. Full article

Sustainable fertilizer technologies are essential to address nutrient losses, environmental pollution, and inefficiencies associated with conventional urea application. In this study, humic acid–functionalized starch (St–HA) gel coatings were developed and optimized via a Wurster fluidized-bed system to produce controlled-release urea granules, with an additional carnauba wax outer layer to further extend nutrient release duration. The coating formulation was synthesized through in situ crosslinking of tapioca starch with humic acid using N,N′-methylenebisacrylamide and potassium persulfate, yielding a cohesive film. A central composite rotatable design (CCRD) was employed to investigate the influence of atomizing air pressure, fluidizing air flow rate, fluidized-bed temperature, and spray rate on coating performance. Comprehensive characterization; including FTIR, XRD, rheological analysis, thermogravimetric studies, water retention, biodegradability, and surface abrasion, confirmed chemical crosslinking, structural stability, and mechanical robustness of the coatings. Nitrogen release analysis in both water and soil demonstrated a substantial extension of release longevity from less than 2 days (uncoated) to 18–20 days for St–HA-coated urea, and up to 28 days with the additional wax coating. Coated granules exhibited low abrasion (8–24%), high water-retention capacity, and 68% biodegradation in 60 days, ensuring environmental compatibility. The findings establish St–HA/wax hybrid coatings as a viable, eco-friendly strategy for controlled-release fertilizers, integrating renewable feedstocks with scalable industrial processing for precision nutrient management. Full article

Basic zinc sulfate with an empirical formula of ZnSO₄∙3 Zn(OH)₂∙3.5 H₂O (or Zn₄SO₄(OH)₆∙3.5 H₂O) was precipitated using stoichiometric amounts of ZnSO₄ and NaOH, followed by drying and storage in air. The XRD pattern suggests that the product contains tri- and tetrahydrate of basic zinc sulfate. Penta-, mono-, and hemihydrates of basic zinc sulfate can be produced by storing the original material in air at various temperatures and humidity levels, and especially by immersion in aqueous solutions. The precipitate was characterized by its specific surface area and zeta potential, and it has an isoelectric point (IEP) at pH 8.9. Ion exchange with an excess of CuSO₄ results in conversion to brochantite Cu₄(OH)₆SO₄ (as detected by XRD) and in an increase in the specific surface area. The conversion was complete at room temperature with a sufficient excess of CuSO₄, but it was not complete at 50 or 60 °C. Apparently, the conversion into brochantite is exothermic. The IEP of brochantites obtained from ZnSO₄∙3 Zn(OH)₂∙3.5 H₂O by ion exchange was at a pH of about 10, which is higher than the previously reported IEP. Full article

This study investigates the operation of an air source heat pump (ASHP) working with combined radiant floor (RF) and fan coil unit (FCU) heating systems in hot summer and cold winter (HSCW) regions. Intermittent heating demands and ASHP sensitivity to supply water temperature in these regions lead to insufficient steady-state assumptions, while experimental evidence on transient heating behavior, thermal comfort development, and operational limits remains limited. In this study, experiments were conducted to analyze six supply water temperatures (ranging from 35 °C to 45 °C) with respect to the system’s dynamic thermal response, vertical air temperature difference, floor surface temperature, power consumption, and coefficient of performance (COP). The results show that start-up heating is dominated by FCU convection, causing pronounced vertical temperature stratification, while radiant heat becomes dominant as the system approaches steady operation. A good vertical air temperature difference with respect to breathing zones and ankle-level temperature differences below 2 °C was achieved after sufficient operating time. Increasing the supply water temperature accelerated the heating response, where the time required for the average indoor temperature to reach 18 °C decreased from 5.5 h at 35 °C to 2.2 h at 45 °C. However, this improvement was accompanied by reduced energy efficiency, with the mean ASHP unit COP declining from 2.5 to 2.3. Excessively high supply temperatures further induced premature indoor overheating and the frequent start–stop cycling of the heat pump, thereby limiting thermal benefits and increasing power demand. These findings provide experimentally grounded insight into the operation and performance limits of ASHP RF–FCU heating systems. Full article

In recent years, China’s rapid economic development has driven the improvement of infrastructure, with mass concrete widely applied in engineering for its unique structural functions. However, mass concrete is prone to temperature stress and thermal cracks due to its low thermal conductivity, huge volume, complex construction conditions, and frequent environmental changes, which pose potential structural safety risks. The hydration heat of mass concrete can also cause structural deformation, so targeted measures must be taken based on actual engineering conditions to minimize cracks. Real-time temperature monitoring during pouring is of crucial significance to ensure the quality and safety of mass concrete in practical projects. Taking the Phase I Project of Qingdao Metro Line 9 as the research object, this paper explores the temperature variation characteristics of mass concrete during pouring and forming on-site. It analyzes the temperature changes in mass concrete based on field temperature-monitoring data and laboratory test results, plots temperature measurement curves, and identifies the temperature variation trend of mass concrete caused by hydration heat. A numerical model is established via ANSYS to study the effects of ventilation temperature and velocity by simulation. Results show that the temperature of mass concrete pouring blocks rises rapidly to a peak and then decreases to room temperature, which is analyzed from the perspectives of hydration heat reaction mechanism and heat transfer. Laboratory test data are highly consistent with field data, verifying the temperature variation characteristics of concrete pouring. The numerical simulation of heat transfer-influencing factors reveals that the optimal ventilation velocity is 4 m/s for sufficient air circulation in the foundation pit; when the ventilation temperature is below 25 °C, the surface temperature of concrete decreases significantly with an obvious cooling effect. Full article

This study investigates the spatiotemporal variability of the near-surface air temperature lapse rate (NSATLR) in Calabria, a region representative of typical Mediterranean environmental and climatic conditions. Through the integration of observational datasets and model simulations, a global sensitivity analysis using the Sobol method, and Bayesian linear regression modelling across annual, seasonal, and monthly scales, the primary drivers of near-surface air temperature (NSAT) variability were identified. Results demonstrate that altitude is the dominant factor influencing temperature distribution, with minimal contributions from other geographical parameters such as latitude, longitude, and proximity to the sea. The Bayesian models yielded robust performance for mean and maximum temperatures, while minimum temperature proved more challenging to predict. Lapse rate analyses confirmed a consistent inverse relationship between temperature and elevation, with the steepest gradients observed for Tmin. In particular, a significant long-term decline in lapse rates over the past 70 years, especially during winter and autumn, points to accelerated warming at higher elevations, primarily driven by rising Tmin values. This trend suggests a gradual homogenization of temperature across altitudes, with important implications for ecosystem dynamics, snowpack stability, and climate-sensitive sectors such as agriculture and urban planning. Full article

Renewable energy is an important pillar of decarbonization in reducing the impact of climate change. Among the renewable energy sources, solar photovoltaic energy is one of the fastest-growing across West Africa, especially in Côte d’Ivoire. However, its dependence on weather and climate could affect future power system operations. This study aims to quantify how climate change could affect future solar PV potential in Côte d’Ivoire under the RCP8.5 scenario. For this purpose, we used three regional climate model simulations (RCMs) generated by the new high-resolution Coordinated Regional Climate Downscaling Experiment (CORDEX) for the Africa domain (AFR-22). Future changes were computed for two time slices: the near future (2021–2040) and the middle future (2041–2060), relative to the reference period (1986–2005). The performance of the RCMs and their ensemble mean in simulating relevant climate variables was first evaluated with respect to the ERA5 reanalysis and satellite-based (SARAH-2) data during the reference period. Our results indicate that all available RCMs and their ensemble mean reasonably simulate the annual cycle and the spatial patterns features of surface solar radiation, near-air temperature and solar PV potential in Côte d’Ivoire. We also conclude that Côte d’Ivoire is expected to experience a moderate decrease in annual mean solar PV potential during the mid-21st century. The average decrease in solar PV potential over Côte d’Ivoire could range from 0.55% to 2.16% in the near future and from 1.30% to 3.50% during the middle future, according to the considered RCMs. This decline in solar PV potential will be particularly noticeable during the period from June to October in all climatic zones. Overall, these findings provide valuable information for renewable energy planners to ensure the long-term success of solar PV energy projects in the context of climate change in Côte d’Ivoire. Full article

This study presents a GIS-driven multi-criteria decision analysis (MCDA) framework for regional suitability screening of data center (DC) development in the United Kingdom. The methodology integrates spatial exclusion of constrained zones, raster standardization of climate and infrastructure indicators, Analytic Hierarchy Process (AHP) weighting, and Weighted Linear Combination (WLC) to generate a national suitability surface at 1 km resolution. Climate indicators (temperature, air frost days, humidity, and solar radiation) and infrastructure and environmental constraint indicators (grid access, transport proximity, environmental protections, and population distribution) were standardized and combined within a GIS-based decision framework. Hard constraints such as protected areas and flood zones were applied through binary exclusion, while climatic and infrastructure factors were evaluated using weighted suitability scoring. Five candidate regions were identified from the suitability analysis: the Scottish Highlands, Northeast England, Southwest England (Cornwall), Northwest England, and Eastern England. These regions were further evaluated against key requirements including power infrastructure accessibility, workforce and connectivity availability, and exposure to environmental and hydro-climate constraints. The final comparison identified Lincolnshire as the most suitable region due to strong grid accessibility, favorable composite climate suitability, adequate population proximity, and limited overlap with protected areas. The proposed framework demonstrates how climate-driven cooling suitability can be integrated with infrastructure accessibility and environmental constraints within a unified spatial decision model for national-scale digital infrastructure planning. Full article

High-temperature particulate matter (PM) filtration remains a fundamental challenge, because most fiber filters not only face the challenge of high temperatures but also suffer from an inherent trade-off between capture efficiency, pressure drop, and service life. This paper reports a hierarchical layered zirconia (ZrO₂) ceramic fiber aerogel featuring a continuous multiscale gradient. The aerogel was prepared by gradient air-blown spinning, and the resulting structure has directional order, with the fiber diameter gradually decreasing from upstream to downstream, thus forming a pore size gradient and achieving hierarchical particle interception across multiple scales. This rational design simultaneously suppresses surface clogging and reduces flow resistance, resolving the longstanding trade-off between efficiency and permeability. Consequently, this aerogel achieves an ultra-high filtration efficiency of 99.96%, a low pressure drop of 156 Pa, and a high dust-holding capacity of 101 g m⁻². The material also exhibits outstanding mechanical toughness (80% compressive strain elasticity and 25.75% tensile fracture strain) and thermal stability up to 1000 °C. Moreover, it maintains over 99.95% filtration efficiency at high temperatures and can be fully regenerated through 800 °C heat treatment. This work establishes a structure-based design paradigm for high-temperature filtration media and provides a scalable pathway for next-generation industrial flue gas purification. Full article

Accurate mapping of near-surface air temperature ($T_{\mathrm{air}}$) at the fine spatial resolution is required for city-scale monitoring and remains a critical challenge in Earth Observation (EO). Reliance on ground-based measurements is constrained by their sparse spatial coverage and high operational costs. We present a novel, scalable machine learning framework designed to overcome this limitation. Our method utilizes interpretable Convolutional Neural Networks (CNNs) to fuse high-resolution Landsat data, integrating both thermal and reflective spectral bands, with contextual spatiotemporal metadata. This approach allows for inference, at 30 m resolution, of $T_{\mathrm{air}}$ fields without relying on dense, localized ground monitoring networks. Our hybrid CNN architecture is optimized for spatial generalization, maintaining strong and transferable performance (station-wise $R^2\approx 0.88$) across diverse environments from humid coasts ($R^2\approx 0.89$) to arid interiors ($R^2\approx 0.84$). Although focused on a specific geographical region, our results suggest a robust and reproducible pathway for generating spatially consistent temperature fields from globally available EO archives, directly supporting urban heat island mitigation, climate policy development, and high-resolution public health assessment worldwide. Full article

In this study, a three-dimensional simulation of a walking-beam reheating furnace was developed to improve the steel slab reheating process and reduce surface oxidation kinetics using computational fluid dynamics (CFD). Combustion, heat transfer, fluid dynamics, and chemical reaction models were integrated into the numerical framework of this study. In addition, dynamic mesh remeshing was coupled through user-defined functions (UDFs), enabling the simultaneous simulation of slab movement and evolution of the involved transport phenomena. Turbulence was modeled with the realizable k-ε formulation, combustion with the Eddy Dissipation model, and radiation with the P-1 model coupled with WSGGM to include CO₂ and H₂O gas radiation. Scale formation was modeled using customized functions based on Arrhenius-type kinetics and Wagner’s oxidation model, evaluating its growth as a function of time, temperature, and furnace atmosphere. The predicted thermal evolution inside the furnace was validated using industrial data, yielding an average deviation of 5%. Furthermore, the proposed operating conditions led to an average slab temperature of 1289.77 °C at the exit of the homogenization zone, which was 16 °C higher than that under the current operation but still within the target range (1250 ± 50 °C). The reduction in combustion air decreased energy losses and improved product quality, lowering the molar oxygen content in the furnace atmosphere from 4.9 × 10² mol to 6.7 × 10¹ mol. Additionally, annual savings of 4,793,472 kg of natural gas and 13,884 tons of steel were estimated owing to reduced oxidation losses. The proposed air–fuel adjustment led to estimated annual energy savings (equivalent to 4,793,472 kg of natural gas) and a reduction in material loss due to oxidation from 4.5% to 3.75% (an absolute reduction of 0.75 percentage points; relative reduction ≈ 16.7%), which has a significant industrial impact on metal conservation and descaling cost reduction. Although there are CFD studies on plate overheating and scale growth separately, this work presents three main contributions: (1) the integration, within a single numerical framework, of combustion, radiation, species transport, oxidation kinetics, and actual plate movement using a dynamic mesh; (2) validation against continuous industrial records (16 thermocouples) and quantification of operational benefits such as fuel savings and reduced material loss; and (3) a comparative analysis between actual and optimized conditions, which standardize the air–methane ratio. Full article

Ensuring the required microclimate parameters is the most critical task in hot climates. In pig farms, air cooling is provided by means of steam-compression chillers or evaporative cooling, which is the simplest way to cool the air. The implementation of evaporative cooling depends largely on the interaction of the media involved in this process. This paper considers the process of interaction of cooling water with the surface of a cellular polycarbonate heat exchanger. A mathematical model describing the process of wetting the sprayed surface of the heat exchanger is obtained. The authors determined the theoretical water flow rate required to provide air cooling for a given operation mode. Experimental trials of a recuperative heat recovery unit with a heat exchanger made of cellular polycarbonate equipped with a water evaporative cooling system were carried out. The authors conducted a comparative assessment to evaluate the effectiveness of evaporative cooling in a heat recovery unit equipped with a polycarbonate heat exchanger versus panel evaporative systems using wetted paper pads at pig farms in the Vladimir and Tambov regions of Russia. The panel evaporative coolers provided a temperature reduction of 11.3 °C without any splashing effect. Under the same operating conditions, the heat recovery unit achieved an inlet air temperature reduction of 10.5 °C, accompanied by splashing. When the water flow rate supplied for evaporation was reduced until the splashing ceased, the cooling temperature drop decreased to 10.1 °C, which is 11% lower, compared with the paper pads. The study revealed characteristic operating modes for the unit that ensure effective air cooling, depending on the cooling water flow rate. Since the prevailing temperature during the system’s main operating time is significantly lower than the design temperature (the absolute temperature maximum), to achieve effective cooling of the supply air without splashing or excessive water waste, the cooling circuit water should circulate at a flow rate within 40 to 63% of the maximum design value. Alternatively, an automated control system should be employed to regulate the water supply based on outdoor air temperature and humidity. Full article

Wintertime extratropical cyclones frequently traverse the Kuroshio–Oyashio Extension frontal system. However, their net impacts on synoptic sea-surface temperature (SST) variability and mixed-layer structure remain uncertain in the presence of strong fronts and intrinsic ocean variability. Using reanalysis data, we classify extreme events into cyclone cold-sector and warm-sector types based on synoptic air–sea flux anomalies. With ensembles of single-column model experiments, we decompose the upper-ocean response into surface heat-flux forcing, wind-driven mechanical mixing, Ekman temperature advection, wave-breaking mixing, and freshwater effects. Cold-sector events amplify synoptic SST variability and deepen the mixed layer, whereas warm-sector events suppress SST variability and shoal the mixed layer. Surface heat flux is the primary driver of both responses. Ekman advection provides crucial modulation within the frontal zone. Wave-breaking mixing generally damps temperature perturbations. Freshwater forcing exerts a pronounced regional influence southeast of the subarctic front. The combined effects yield an asymmetric spatial fingerprint on SST variability and mixed-layer depth across the frontal system. Comparison between forced variability and total reanalysis variability indicates that within the frontal zone, atmospheric impacts can be redistributed or partly offset by intrinsic ocean processes, while outside the frontal zone, the behavior is closer to an externally forced response. Full article

The urban heat island effect is well recognized and has been quantified using ground observations within and outside urban areas. Earth Observation has further revealed small-scale local spatial differences, especially in urban surface temperatures, that have been shown to be highly correlated with differences in the urban fabric. However, surface temperatures do not directly translate to human-experienced temperatures, and hence high-resolution air temperature data is of high relevance. However, air temperature is not easily measured from space, and seldom do ground measurements allow for small-scale differences to be quantified to a satisfactory degree. In the present study, we assessed the added value of an air temperature product downscaled using machine learning compared to the high-resolution reanalysis model that formed its foundation. The downscaled product was developed using satellite data, local observations from privately owned weather stations, and high-resolution reanalysis. The comparison focused on Denmark’s four largest urban areas and examined the two data product’s ability to describe the urban heat island effect at the city scale as well as intra-city differences in air temperatures. Both data products show similar urban heat island effects at the city scale, while the downscaled product shows greater intra-city variance in air temperature, with patterns that are somewhat correlated with both urban density and urban green spaces. Generally, the downscaling product offers city planners a better data basis for evaluating where to prioritize contingency and mitigation measures within the urban space. Full article

Atmospheric aerosols modulate Earth’s radiation balance through direct effects and through their role as cloud condensation nuclei (CCN), contributing to variability in near-surface temperature (NST). Galactic cosmic rays (GCRs) further influence aerosol–cloud interactions by enhancing particle formation and growth, but combined aerosol optical depth (AOD)–GCR effects on NST remain poorly constrained across climates. Using satellite and reanalysis data, we examine joint influences on NST anomalies at three neutron-monitoring stations, Oulu, Newark, and Hermanus, during 2000–2022. The sites share similar geomagnetic cutoffs but contrasting climates, enabling separation of ionization from geomagnetic shielding. Multiple linear regression (MLR) captures AOD effects and their modulation by GCR flux. Adding an interaction term (AOD × GCR) improves fit, raising adjusted R² from 0.22→0.31 (Oulu), 0.37→0.52 (Newark), and 0.69→0.78 (Hermanus). ECMWF reanalysis shows hydrophilic organic matter aerosol (OMA) dominates (0.19, 0.29, 0.41 µg kg⁻¹ at Oulu, Newark and Hermanus), with sulphate elevated at Oulu/Newark and coarse sea salt at Hermanus. Elevated OMA and sulphate at Oulu/Newark imply GCR-enhanced fine CCN and cooling, whereas humid, sea-salt-rich Hermanus favors ion-mediated growth of larger hygroscopic particles that increase longwave trapping and warming. Findings provide site-specific evidence that GCR ionization modulates aerosol processes and contributes to regional NST variability, informing improved parameterizations in climate models. Full article