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20 pages, 2489 KB  
Article
Modelling, Optimisation, and Construction of a High-Temperature Superconducting Maglev Demonstrator
by Chenxuan Zhang, Qian Dong, Hongye Zhang and Markus Mueller
Machines 2026, 14(1), 108; https://doi.org/10.3390/machines14010108 - 16 Jan 2026
Viewed by 214
Abstract
To achieve global carbon-neutrality goals, magnetic levitation (maglev) technologies offer a promising pathway toward sustainable, energy-efficient transportation systems. In this study, a comprehensive methodology was developed to analyse and optimise the levitation performance of high-temperature superconducting (HTS) maglev systems. Several permanent magnet guideway [...] Read more.
To achieve global carbon-neutrality goals, magnetic levitation (maglev) technologies offer a promising pathway toward sustainable, energy-efficient transportation systems. In this study, a comprehensive methodology was developed to analyse and optimise the levitation performance of high-temperature superconducting (HTS) maglev systems. Several permanent magnet guideway (PMG) configurations were compared, and an optimised PMG Halbach array design was identified that enhances flux concentration and significantly improves levitation performance. To accurately model the electromagnetic interaction between the HTS bulk and the external magnetic field, finite element models based on the H-formulation were established in both two dimensions (2D) and three dimensions (3D). An HTS maglev demonstrator was built using YBCO bulks, and an experimental platform was constructed to measure levitation force. While the 2D model offers fast computation, it shows deviations from the measurements due to geometric simplifications, whereas the 3D model predicts levitation forces for the cylindrical bulk with much higher accuracy, with errors remaining below 10%. The strong agreement between experimental measurements and the 3D simulation across the entire force–height cycle confirms that the proposed model reliably reproduces the electromagnetic coupling and resulting levitation forces in HTS maglev systems. The paper provides a practical and systematic reference for the optimal design and experimental validation of HTS bulk-based maglev systems. Full article
(This article belongs to the Section Vehicle Engineering)
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11 pages, 4932 KB  
Article
Enhanced Electron–Phonon Coupling of Superconductivity in Indium-Doped Topological Crystalline Insulator SnTe
by Kwan-Young Lee, Gareoung Kim, Jae Hyun Yun, Jin Hee Kim and Jong-Soo Rhyee
Materials 2026, 19(1), 73; https://doi.org/10.3390/ma19010073 - 24 Dec 2025
Viewed by 442
Abstract
Indium-doped SnTe (Sn1−xInxTe) provides a model platform for exploring the emergence of superconductivity within a topological crystalline insulator. Here, we present a systematic investigation of the structural, transport, and thermodynamic properties of high-quality single crystals with 0.0 ≤ x [...] Read more.
Indium-doped SnTe (Sn1−xInxTe) provides a model platform for exploring the emergence of superconductivity within a topological crystalline insulator. Here, we present a systematic investigation of the structural, transport, and thermodynamic properties of high-quality single crystals with 0.0 ≤ x ≤ 0.5. All compositions up to x = 0.4 form a single-phase cubic structure, enabling a controlled study of the superconducting state. Electrical resistivity and specific heat measurements reveal a bulk, fully gapped s-wave superconducting phase whose transition temperature increases monotonically with In concentration, reaching Tc ≈ 4.7 K at x = 0.5. Analysis of the electronic specific heat and McMillan formalism shows that the electron–phonon coupling constant λel-ph systematically increases with doping, while the Debye temperature systematically decreases, resulting in the lattice softening. This behavior, together with the observed evolution of the normal-state resistivity exponent from Fermi-liquid (n ≈ 2.04) toward non-Fermi-liquid values (n ≈ 1.72), demonstrates a clear crossover from weak to strong interaction with increasing In content. These results establish Sn1−xInxTe as a tunable superconducting system in which coupling strength can be continuously controlled, offering a promising platform for future studies on the interplay between phonon-mediated superconductivity and crystalline topological band structure. Full article
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13 pages, 5502 KB  
Article
Levitation Characteristics of an Aged Superconducting Magnetic Bearing
by Tilo Espenhahn, Marcus Dietzel and Ruben Hühne
Appl. Sci. 2025, 15(23), 12563; https://doi.org/10.3390/app152312563 - 27 Nov 2025
Viewed by 473
Abstract
Superconducting magnetic bearings are friction-free devices and therefore in principle suitable for long-term operation, as no wear is observed. However, other degradation mechanisms can influence the operation. Up to now, it has not been clear to what extent degradation of either the bulk [...] Read more.
Superconducting magnetic bearings are friction-free devices and therefore in principle suitable for long-term operation, as no wear is observed. However, other degradation mechanisms can influence the operation. Up to now, it has not been clear to what extent degradation of either the bulk superconductors or the permanent magnets impacts the overall bearing performance on long timescales. Therefore, we studied the bearing properties of a 20-year-old rotational superconducting magnetic bearing, which was cooled down occasionally in an open liquid nitrogen bath for presentation. Otherwise, the bearing was stored under ambient conditions. To characterize the current status, we measured the bearing’s static and dynamic stiffness in radial and axial directions. Comparing our results to the values measured after the setup of the bearing revealed a stiffness degradation of up to 77%. This decrease is mainly attributed to the degradation of the bearing’s superconducting bulks and the permanent magnets. Analysis of both components showed clear signs of degradation. The permanent magnetic rotor’s magnetic field is around 19% smaller compared to the original state. The superconducting bulks now only inhomogeneously trap magnetic flux. Critical current calculation based on this data revealed a significant reduction compared to the original measurements. Nonetheless, the bearing allows for a stable levitation. Full article
(This article belongs to the Special Issue Applied Superconductivity: Material, Design, and Application)
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32 pages, 6546 KB  
Review
Sputter-Deposited Superconducting Thin Films for Use in SRF Cavities
by Bharath Reddy Lakki Reddy Venkata, Aleksandr Zubtsovskii and Xin Jiang
Nanomaterials 2025, 15(19), 1522; https://doi.org/10.3390/nano15191522 - 5 Oct 2025
Viewed by 1490
Abstract
Particle accelerators are powerful tools in fundamental research, medicine, and industry that provide high-energy beams that can be used to study matter and to enable advanced applications. The state-of-the-art particle accelerators are fundamentally constructed from superconducting radio-frequency (SRF) cavities, which act as resonant [...] Read more.
Particle accelerators are powerful tools in fundamental research, medicine, and industry that provide high-energy beams that can be used to study matter and to enable advanced applications. The state-of-the-art particle accelerators are fundamentally constructed from superconducting radio-frequency (SRF) cavities, which act as resonant structures for the acceleration of charged particles. The performance of such cavities is governed by inherent superconducting material properties such as the transition temperature, critical fields, penetration depth, and other related parameters and material quality. For the last few decades, bulk niobium has been the preferred material for SRF cavities, enabling accelerating gradients on the order of ~50 MV/m; however, its intrinsic limitations, high cost, and complicated manufacturing have motivated the search for alternative strategies. Among these, sputter-deposited superconducting thin films offer a promising route to address these challenges by reducing costs, improving thermal stability, and providing access to numerous high-Tc superconductors. This review focuses on progress in sputtered superconducting materials for SRF applications, in particular Nb, NbN, NbTiN, Nb3Sn, Nb3Al, V3Si, Mo–Re, and MgB2. We review how deposition process parameters such as deposition pressure, substrate temperature, substrate bias, duty cycle, and reactive gas flow influence film microstructure, stoichiometry, and superconducting properties, and link these to RF performance. High-energy deposition techniques, such as HiPIMS, have enabled the deposition of dense Nb and nitride films with high transition temperatures and low surface resistance. In contrast, sputtering of Nb3Sn offers tunable stoichiometry when compared to vapour diffusion. Relatively new material systems, such as Nb3Al, V3Si, Mo-Re, and MgB2, are just a few of the possibilities offered, but challenges with impurity control, interface engineering, and cavity-scale uniformity will remain. We believe that future progress will depend upon energetic sputtering, multilayer architectures, and systematic demonstrations at the cavity scale. Full article
(This article belongs to the Section 2D and Carbon Nanomaterials)
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20 pages, 2093 KB  
Review
A Practical Guide Paper on Bulk and PLD Thin-Film Metals Commonly Used as Photocathodes in RF and SRF Guns
by Alessio Perrone, Muhammad Rizwan Aziz, Francisco Gontad, Nikolaos A. Vainos and Anna Paola Caricato
Chemistry 2025, 7(4), 123; https://doi.org/10.3390/chemistry7040123 - 30 Jul 2025
Viewed by 1574
Abstract
This paper serves as a comprehensive and practical resource to guide researchers in selecting suitable metals for use as photocathodes in radio-frequency (RF) and superconducting radio-frequency (SRF) electron guns. It offers an in-depth review of bulk and thin-film metals commonly employed in many [...] Read more.
This paper serves as a comprehensive and practical resource to guide researchers in selecting suitable metals for use as photocathodes in radio-frequency (RF) and superconducting radio-frequency (SRF) electron guns. It offers an in-depth review of bulk and thin-film metals commonly employed in many applications. The investigation includes the photoemission, optical, chemical, mechanical, and physical properties of metallic materials used in photocathodes, with a particular focus on key performance parameters such as quantum efficiency, operational lifetime, chemical inertness, thermal emittance, response time, dark current, and work function. In addition to these primary attributes, this study examines essential parameters such as surface roughness, morphology, injector compatibility, manufacturing techniques, and the impact of chemical environmental factors on overall performance. The aim is to provide researchers with detailed insights to make well-informed decisions on materials and device selection. The holistic approach of this work associates, in tabular format, all photo-emissive, optical, mechanical, physical, and chemical properties of bulk and thin-film metallic photocathodes with experimental data, aspiring to provide unique tools for maximizing the effectiveness of laser cleaning treatment. Full article
(This article belongs to the Section Electrochemistry and Photoredox Processes)
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8 pages, 720 KB  
Article
Microscopic Characterization of Pb10−xCux(PO4)6O by 31P and 63/65Cu NMR Measurements
by Qing-Ping Ding, Yue Sun, Qiang Hou, Wei Wei, Xin Zhou, Xinyue Wang, Zhixiang Shi and Yuji Furukawa
J. Compos. Sci. 2025, 9(7), 377; https://doi.org/10.3390/jcs9070377 - 18 Jul 2025
Cited by 1 | Viewed by 2976
Abstract
The report of the first room-temperature, ambient-pressure superconductivity in copper-doped lead apatite Pb10−xCux(PO4)6O has attracted lots of attention. However, subsequent studies revealed the presence of numerous impurity phases in the polycrystalline sample, and the [...] Read more.
The report of the first room-temperature, ambient-pressure superconductivity in copper-doped lead apatite Pb10−xCux(PO4)6O has attracted lots of attention. However, subsequent studies revealed the presence of numerous impurity phases in the polycrystalline sample, and the sharp superconducting-like transition is not due to a superconducting transition but most likely due to a reduction in resistivity caused by the first-order structural phase transition of Cu2S at around 385 K from the β phase at high temperature to the γ phase at low temperature. Before now, only bulk measurements have been performed on a Pb10−xCux(PO4)6O powder sample, which could be affected by the impurity phases, masking the intrinsic properties of Pb10−xCux(PO4)6O. In this study, 31P and 63/65Cu nuclear magnetic resonance (NMR) measurements have been performed on a Pb10−xCux(PO4)6O powder sample to investigate its physical properties from a microscopic point of view. Our NMR data evidence the non-magnetic insulating nature of Pb10−xCux(PO4)6O without any trace of electron correlation effects. Furthermore, the 63/65Cu NMR results suggest that no copper or very little copper is substituted for Pb in Pb10(PO4)6O prepared by sintering Pb2SO5 and Cu3P. Full article
(This article belongs to the Special Issue Optical–Electric–Magnetic Multifunctional Composite Materials)
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12 pages, 4829 KB  
Article
Pressure-Induced Structural Stabilities and Superconductivity in Rhodium Borides
by Junyi Du, Weiguo Sun, Xiaofeng Li and Xinfang Su
Materials 2025, 18(13), 3125; https://doi.org/10.3390/ma18133125 - 1 Jul 2025
Cited by 1 | Viewed by 645
Abstract
Transition metal borides have garnered significant research interest due to their versatile properties, including superconductivity and exceptional hardness. This study examines the stable crystal structures of Rhodium-Boron (Rh-B) compounds under high pressure using first-principles structural searching. Beyond the previously known Rh2B, [...] Read more.
Transition metal borides have garnered significant research interest due to their versatile properties, including superconductivity and exceptional hardness. This study examines the stable crystal structures of Rhodium-Boron (Rh-B) compounds under high pressure using first-principles structural searching. Beyond the previously known Rh2B, RhB2, and RhB4 phases, three new boron-rich phases—C2/m-RhB6, Amm2-RhB6, and Cmca-RhB8—are identified, each characterized by three-dimensional covalent bonding networks. Their mechanical and thermodynamic stability is validated through elastic property assessments and phonon dispersion calculations. Surprisingly, these phases exhibit low bulk and shear moduli, ruling them out as candidates for hard materials. The metallic character of these borides is evident from their electronic density of states, which exhibits a sharp peak at the EF-a signature often associated with superconducting systems. Indeed, our calculations predict Tc values of 8.93 K and 9.36 K for Amm2-RhB6 and Cmca-RhB8, respectively, at 100 GPa. Full article
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17 pages, 2892 KB  
Article
Stoichiometry of Bulk Nb1−βSnβ Superconductors Synthesised by Arc Melting
by Mahboobeh Shahbazi, Henrietta E. Cathey, Ali Dehghan Manshadi, Jose Alarco and Ian D. R. Mackinnon
Materials 2025, 18(13), 3050; https://doi.org/10.3390/ma18133050 - 27 Jun 2025
Viewed by 793
Abstract
We present an alternative process for production of binary Nb1−βSnβ superconducting phases using pre- and post-treatment of arc-melted Nb + Sn ingots. This process combines sequential sintering, arc melting, and annealing procedures that provide dense, bulk samples of Nb1−β [...] Read more.
We present an alternative process for production of binary Nb1−βSnβ superconducting phases using pre- and post-treatment of arc-melted Nb + Sn ingots. This process combines sequential sintering, arc melting, and annealing procedures that provide dense, bulk samples of Nb1−βSnβ with varying stoichiometry between 0.18 < β < 0.25 depending on annealing time and temperature. We show, through magnetization measurements of these Nb1−βSnβ bulks, that annealing of arc-melted samples at 900 °C for 3 h significantly enhances Jc values compared with arc-melted Nb1−βSnβ samples without annealing. Microstructural analyses show that optimum grain size and orientation are achieved by sintering and annealing at lower temperatures (i.e., 720 °C and 900 °C, respectively) with short annealing times (i.e., <10 h). Processing at higher temperatures and for longer times enhances grain growth and results in fewer pinning centres. The optimum process creates effective pinning centres that deliver a Jc = 6.16 × 104 A/cm2 at 10 K (and ~0.2 T), compared with Jc = 3.4 × 104 A/cm2 for Nb1−βSnβ subjected to a longer annealing time at a higher temperature and Jc = 775 A/cm2 for an arc-melted sample without post-annealing. We suggest that further work addressing post-treatment annealing times between 3 h < tpost < 60 h at temperatures between 900 °C and 1000 °C will provide the opportunity to control stoichiometric and microstructural imperfections in bulk Nb1−βSnβ materials. Full article
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26 pages, 2686 KB  
Article
Quantum Entanglement Between Charge Qubit and Mechanical Cat-States in Nanoelectromechanical System
by Matija Tečer and Danko Radić
Mathematics 2025, 13(13), 2054; https://doi.org/10.3390/math13132054 - 20 Jun 2025
Viewed by 673
Abstract
We present a detailed mathematical description, both an analytical model and a numerical simulation, of a physical system based on a superconducting nanoelectromechanical setup that generates nanomechanical cat-states entangled with charge qubit states. The system consists of a superconducting grain in a regime [...] Read more.
We present a detailed mathematical description, both an analytical model and a numerical simulation, of a physical system based on a superconducting nanoelectromechanical setup that generates nanomechanical cat-states entangled with charge qubit states. The system consists of a superconducting grain in a regime of the Cooper pair box (the charge qubit) that performs mechanical vibrations between two bulk superconductors. Operation of the device is based on the AC Josephson effect, i.e., the phase difference between superconducting electrodes is controlled by a DC bias voltage following the operational switch on/off protocol. We compare an analytical idealised solution with numerical simulation using experimentally feasible parameters, different decoherence processes, as well as imperfections of experimental procedures such as time-control of the bias voltage, to get insight into how they influence the time-evolution of the realistic system, deteriorate the quantum coherence, and affect the formation of the cat-states. Full article
(This article belongs to the Section E: Applied Mathematics)
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16 pages, 3025 KB  
Article
A Permanent Magnet Hybrid Levitation Based on High-Temperature Superconducting Magnetic Levitation
by Tianyu Xing, Lingfeng Gao, Peiyu Yin, Can Peng and Zigang Deng
Actuators 2025, 14(6), 285; https://doi.org/10.3390/act14060285 - 10 Jun 2025
Cited by 1 | Viewed by 1552
Abstract
This paper proposes an A-shape hybrid levitation system combining high-temperature superconducting (HTS) maglev and permanent magnet levitation (PML) technologies to address the lateral instability of the PML system. By tilting the PM arrays and HTS bulks on both sides at a specific angle, [...] Read more.
This paper proposes an A-shape hybrid levitation system combining high-temperature superconducting (HTS) maglev and permanent magnet levitation (PML) technologies to address the lateral instability of the PML system. By tilting the PM arrays and HTS bulks on both sides at a specific angle, the system’s cross-section forms an “A” shape. This configuration offers dual advantages: the A-shape PML significantly mitigates unstable lateral deflection forces while preserving levitation capacity, whereas the A-shape HTS maglev enhances guidance force. Through systematic analysis, the effects of the tilt angle and the magnetization direction of the PM arrays on levitation performance are investigated and optimized. The simulation results demonstrate that, at the lateral movement of 5 mm, for the PML system, a tilt angle of 45° reduces lateral deflection force by 94.4%, and synergistic optimization of the tilt angle of 40° and magnetization direction of 38° achieves an 84.6% reduction. The HTS maglev system enhances guidance force, with a 45.3% improvement at a 60° tilt angle and a 30° magnetization direction. This study presents a promising solution for developing a stable, high-load-capacity hybrid levitation system. Full article
(This article belongs to the Special Issue Actuators in Magnetic Levitation Technology and Vibration Control)
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14 pages, 465 KB  
Article
Orbital Selectivity in Pure and Electron-Doped MoO2 Superconductor
by Luis Craco
Processes 2025, 13(2), 565; https://doi.org/10.3390/pr13020565 - 17 Feb 2025
Cited by 1 | Viewed by 890
Abstract
Inspired by experiments manifesting unconventional metallic behavior in MoO2±δ and superconductivity in KxMoO2δ, we present t2g-DFT+DMFT results for monoclinic MoO2. We unearth the role played by multi-orbital, many-particle physics [...] Read more.
Inspired by experiments manifesting unconventional metallic behavior in MoO2±δ and superconductivity in KxMoO2δ, we present t2g-DFT+DMFT results for monoclinic MoO2. We unearth the role played by multi-orbital, many-particle physics in understanding the emergence of 4d-orbital selectivity with coexisting pseudogapped, resilient, and Fermi-liquid quasiparticles, which might host unconventional superconductivity in K-doped MoO2 bulk crystals at low temperatures. Our findings highlight the capability of DFT+DMFT to bridge the gap between electronic structure and electric transport in multi-orbital Hubbard models, providing insights into spin and charge fluctuations, as well as their role in orbital-selective non-Fermi liquid formation. Full article
(This article belongs to the Special Issue Transport and Energy Conversion at the Nanoscale and Molecular Scale)
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13 pages, 2577 KB  
Article
High-Performance Acoustic Transducers with Exfoliated NbSe2 Nanosheets and Hybrid Force Mechanisms
by Dong-Kwan Lee, Won-Jin Kim, Kun-Woo Nam and Sung-Hoon Park
Materials 2025, 18(4), 763; https://doi.org/10.3390/ma18040763 - 9 Feb 2025
Viewed by 1422
Abstract
The transition metal dichalcogenide (TMDC) NbSe2 is a highly conductive and superconducting material with great potential for next-generation electronic and optoelectronic devices. However, its bulk form suffers from reduced charge density and conductivity due to interlayer van der Waals interactions. To address [...] Read more.
The transition metal dichalcogenide (TMDC) NbSe2 is a highly conductive and superconducting material with great potential for next-generation electronic and optoelectronic devices. However, its bulk form suffers from reduced charge density and conductivity due to interlayer van der Waals interactions. To address this, we exfoliated NbSe₂ into nanosheets using lithium-ion intercalation and utilized them as diaphragms in acoustic transducers. Conventional electromagnetic and electrostatic mechanisms have limitations in sound pressure level (SPL) performance at high and low frequencies, respectively. To overcome this, we developed a hybrid force mechanism combining the strengths of both approaches. The NbSe₂ nanosheets were successfully prepared and analyzed, and the NbSe2-based hybrid acoustic transducer (N-HAT) demonstrated significantly improved SPL performance across a wide frequency range. This study offers a novel approach for designing high-performance acoustic devices by harnessing the unique properties of NbSe2. Full article
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19 pages, 5887 KB  
Review
The Influence of Laser Cleaning Treatment on the Quantum Efficiency of the Most Used Metallic Photocathodes: An Overview
by Alessio Perrone, Muhammad R. Aziz and Nikolaos A. Vainos
Materials 2025, 18(3), 690; https://doi.org/10.3390/ma18030690 - 5 Feb 2025
Cited by 3 | Viewed by 1655
Abstract
This paper presents a comprehensive investigation into the quantum efficiency (QE) of metallic photocathodes used in modern high-performance radio frequency (RF) and superconducting radio frequency (SRF) guns. The study specifically examines how laser cleaning treatment impacts the QE of these photocathodes, providing detailed [...] Read more.
This paper presents a comprehensive investigation into the quantum efficiency (QE) of metallic photocathodes used in modern high-performance radio frequency (RF) and superconducting radio frequency (SRF) guns. The study specifically examines how laser cleaning treatment impacts the QE of these photocathodes, providing detailed insights into their performance and potential improvements for accelerator applications, and assesses the chemical and environmental factors affecting the surface composition of metallic laser-photocathodes used in modern high-performance radio frequency (RF) and superconducting radio frequency (SRF) electron guns. This paper overviews the photocathode rejuvenation effects of laser cleaning treatment. Laser cleaning removes the oxides and hydrides responsible for the deterioration of photocathodes, increases the photoelectron emission quantum efficiency (QE) and extends the operational lifetime of high-brightness electron injectors. QE enhancement is analyzed with the aim of parametric cleaning process optimization. This study excludes semiconductor and thermionic cathodes, focusing solely on the widely used bulk and thin-film photocathodes of Cu, Mg, Y, Pb and Nb. Laser cleaning enhancement of QE in Cu from 5 × 10−5 to 1.2 × 10−4, in Mg from 5.0 × 10−4 to 1.8 × 10−3, in Y from 10−5 to 3.3 × 10−4, in Pb from 3 × 10−5 to 8 × 10−5, and in Nb from 2.1 × 10−7 to 2.5 × 10−5 is demonstrated. The analysis concludes with a specialized practical guide for improving photocathode efficacy and lifetime in RF and SRF guns. Full article
(This article belongs to the Special Issue Advances in Laser Processing Technology of Materials)
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16 pages, 2798 KB  
Article
Structural and Transport Properties of Thin InAs Layers Grown on InxAl1−xAs Metamorphic Buffers
by Giulio Senesi, Katarzyna Skibinska, Alessandro Paghi, Gaurav Shukla, Francesco Giazotto, Fabio Beltram, Stefan Heun and Lucia Sorba
Nanomaterials 2025, 15(3), 173; https://doi.org/10.3390/nano15030173 - 23 Jan 2025
Cited by 1 | Viewed by 1882
Abstract
Indium Arsenide is a III–V semiconductor with low electron effective mass, a small band gap, strong spin–orbit coupling, and a large g-factor. These properties and its surface Fermi level pinned in the conduction band make InAs a good candidate for developing superconducting solid-state [...] Read more.
Indium Arsenide is a III–V semiconductor with low electron effective mass, a small band gap, strong spin–orbit coupling, and a large g-factor. These properties and its surface Fermi level pinned in the conduction band make InAs a good candidate for developing superconducting solid-state quantum devices. Here, we report the epitaxial growth of very thin InAs layers with thicknesses ranging from 12.5 nm to 500 nm grown by Molecular Beam Epitaxy on InxAl1−xAs metamorphic buffers. Differently than InAs substrates, these buffers have the advantage of being insulating at cryogenic temperatures, which allows for multiple device operations on the same wafer and thus making the approach scalable. The structural properties of the InAs layers were investigated by high-resolution X-ray diffraction, demonstrating the high crystal quality of the InAs layers. Furthermore, their transport properties, such as total and sheet carrier concentration, sheet resistance, and carrier mobility, were measured in the van der Pauw configuration at room temperature. A simple conduction model was employed to quantify the surface, bulk, and interface contributions to the overall carrier concentration and mobility. Full article
(This article belongs to the Section Synthesis, Interfaces and Nanostructures)
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12 pages, 2296 KB  
Article
Effects of Homogeneous Doping on Electron–Phonon Coupling in SrTiO3
by Minwoo Park and Suk Bum Chung
Nanomaterials 2025, 15(2), 137; https://doi.org/10.3390/nano15020137 - 17 Jan 2025
Cited by 1 | Viewed by 1660
Abstract
Bulk n-type SrTiO3 (STO) has long been known to possess a superconducting ground state at an exceptionally dilute carrier density. This has raised questions about the applicability of the BCS-Eliashberg paradigm with its underlying adiabatic assumption. However, recent experimental reports have set [...] Read more.
Bulk n-type SrTiO3 (STO) has long been known to possess a superconducting ground state at an exceptionally dilute carrier density. This has raised questions about the applicability of the BCS-Eliashberg paradigm with its underlying adiabatic assumption. However, recent experimental reports have set the pairing gap to the critical temperature (Tc) ratio at the BCS value for superconductivity in Nb-doped STO, even though the adiabaticity condition the BCS pairing requires is satisfied over the entire superconducting dome only by the lowest branch of optical phonons. In spite of the strong implications these reports have on specifying the pairing glue, they have not proved sufficient in explaining the magnitude of the optimal doping. This motivated us to apply density functional theory to Nb-doped STO to analyze how the phonon band structures and the electron–phonon coupling evolve with doping. To describe the very low doping concentration, we tuned the homogeneous background charge, from which we obtained a first-principles result on the doping-dependent phonon frequency that is in good agreement with experimental data for Nb-doped STO. Using the EPW code, we obtain the doping-dependent phonon dispersion and the electron–phonon coupling strength. Within the framework of our calculation, we found that the electron–phonon coupling forms a dome in a doping range lower than the experimentally observed superconducting dome of the Nb-doped STO. Additionally, we examined the doping dependence of both the orbital angular momentum quenching in the electron–phonon coupling and the phonon displacement correlation length and found the former to have a strong correlation with our electron–phonon coupling in the overdoped region. Full article
(This article belongs to the Special Issue Low-Dimensional Perovskite Materials and Devices)
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