Search Results (1,064)

Sulfur-containing fertilizers increase production costs, which leads to low utilization of this nutrient. Thus, evaluating how the absence of sulfur influences the early development of Urochloa brizantha is essential. Study was conducted in a greenhouse at the Federal University of Rondonópolis in a completely randomized design, with six treatments in a 3 × 2 factorial scheme, and eight replications. Three cultivars of U. brizantha (Marandu, Xaraés and Piatã) were evaluated under two fertilization strategies: with or without sulfur fertilization. Sufur presence increased the number of leaves and forage mass, in which cultivar Xaraés presented the greatest means. Piatã was the cultivar most sensitive to sulfur deficiency at establishment, which reduced forage mass, number of leaves and number of tillers by 42%, 32%, and 45%, respectively. Despite these differences between cultivars, sulfur efficiently increased the forage yield. Sulfur fertilization increased the concentrations of nutrients in the plants without significantly affecting the uptake of nitrogen, phosphorus, potassium, calcium and magnesium. Sulfur omission resulted in increased phosphorus uptake in all grass. In contrast, Marandu grass exhibited the greatest reduction in sulfur uptake. Therefore, the use of sulfur in the fertilization of grasses is recommended, it is important to evaluate the responses of each cultivar to better adjust the fertilization management. Full article

This study evaluated the inhibitory efficacy of sulphur dioxide, hydrogen peroxide, copper sulphate pentahydrate, chlorine-based formulations, a chlorine-free formulation, ethanol, and acetic acid against Cladosporium cladosporioides, Aspergillus niger, and Penicillium expansum. An in vitro inhibition test was employed to investigate the inhibitory properties. The results demonstrated different sensitivities of filamentous fungi to the inhibitors. All tested substances displayed fungicidal properties. Sulphur dioxide (40% NH₄HSO₃ solution) inhibited growth at a 4% v/v concentration. No minimum effective concentration was established for H₂O₂; only a 30% w/v solution inhibited P. expansum. CuSO₄·5H₂O completely inhibited fungal growth at 5% w/v solution, with 2.5% w/v also proving effective. For the chlorine-based product, 40% w/v solution (48 g∙L⁻¹ active chlorine) had the most substantial effect, though it only slowed growth, and NaClO solution completely inhibited growth at 2.35 g NaClO per 100 g of product (50% w/v solution). FungiSAN demonstrated fungicidal effects; however, the recommended dose was insufficient for complete inhibition. Ethanol exhibited the lowest efficacy, while the inhibitory threshold for CH₃COOH was found to be a 5% v/v solution. The findings of this study may serve as a basis for informed decision-making when selecting the most suitable product, depending on specific application conditions. Full article

The main advantage of using biomass for energy generation is the reduction in carbon dioxide emissions. For a fast reduction effect, it is important to use biomass characterised by an annual growth cycle. These may be fallen leaves. The fuel properties of the leaves can change during the growth period. These changes can result from both the natural growth process and environmental factors—particulate matter adsorption. The main objective was to determine changes in the characteristics of leaves and needles during the growth period (from May to October). Furthermore, to determine the effect of adsorbed particulate matter, the washing process was carried out. Studies were carried out for three tree species: Norway maple, horse chestnut and European larch. Proximate and ultimate analysis was performed and mercury content was determined. During the growth period, beneficial changes were observed: an increase in carbon content and a decrease in hydrogen and sulphur content. The unfavourable change was a significant increase in ash content, which caused a decrease in calorific value. The increase in ash content was caused by adsorbed particulate matter. They were mostly absorbed by the tissues of the needle and leaves and could not be removed by washing the surface. Full article

The maritime sector is undergoing rapid transformation, driven by increasingly stringent international regulations targeting air pollution. While newly built vessels integrate advanced technologies for compliance, the global fleet averages 21.8 years of age and must meet emission requirements through retrofitting or operational changes. This study evaluates, at environmental and economic levels, two key sulphur abatement strategies for a 1998-built cruise vessel nearing the end of its service life: (i) the installation of open-loop scrubbers with fuel enhancement devices, and (ii) a switch to marine diesel oil as main fuel. The analysis was based on real operational data from a cruise vessel. For the environmental assessment, a Tier III hybrid emissions model was used. The results show that scrubbers reduce SO_x emissions by approximately 97% but increase fuel consumption by 3.6%, raising both CO₂ and NO_x emissions, while particulate matter decreases by only 6.7%. In contrast, switching to MDO achieves over 99% SO_x reduction, an 89% drop in particulate matter, and a nearly 5% reduction in CO₂ emissions. At an economic level, it was found that, despite a CAPEX of nearly USD 1.9 million, scrubber installation provides an average annual net saving exceeding USD 8.2 million. From the deterministic and probabilistic analyses performed, including Monte Carlo simulations under various fuel price correlation scenarios, scrubber installation consistently shows high profitability, with NPVs surpassing USD 70 million and payback periods under four months. Full article

Mining by-products present both an environmental challenge and a resource opportunity. This review investigates their potential application in road pavement construction, focusing on materials such as fly ash, slag, sulphur, red mud, tailings, and silica fume. Drawing from laboratory and field studies, the review examines their roles across pavement layers—subgrade, base, subbase, asphalt mixtures, and rigid pavements—emphasising mechanical properties, durability, moisture resistance, and ageing performance. When properly processed or stabilised, many of these wastes meet or exceed conventional performance standards, contributing to reduced use of virgin materials and greenhouse gas emissions. However, issues such as variability in composition, leaching risks, and a lack of standardised design protocols remain barriers to adoption. This review aims to consolidate current research, evaluate practical feasibility, and identify directions for future studies that would enable the responsible and effective reuse of mining waste in transportation infrastructure. Full article

The study at the Peggy Guggenheim Collection in Venice highlights critical interactions between indoor air quality, visitor dynamics, and microclimatic conditions, offering insights into preventive conservation of modern artworks. By analyzing pollutants such as ammonia, formaldehyde, and organic acids, alongside visitor density and environmental data, the research identified key patterns and risks. Through three seasonal monitoring campaigns, the concentrations of SO₂ (sulphur dioxide), NO (nitric oxide), NO₂ (nitrogen dioxide), NO_x (nitrogen oxides), HONO (nitrous acid), HNO₃ (nitric acid), O₃ (ozone), NH₃ (ammonia), CH₃COOH (acetic acid), HCOOH (formic acid), and HCHO (formaldehyde) were determined using passive samplers, as well as temperature and relative humidity data loggers. In addition, two specific short-term monitoring campaigns focused on NH₃ were performed to evaluate the influence of visitor presence on indoor concentrations of the above compounds and environmental parameters. NH₃ and HCHO concentrations spiked during high visitor occupancy, with NH₃ levels doubling in crowded periods. Short-term NH₃ campaigns confirmed a direct correlation between visitor numbers and the above indoor concentrations, likely due to human emissions (e.g., sweat, breath) and off-gassing from materials. The indoor/outdoor ratios indicated that several pollutants originated from indoor sources, with ammonia and acetic acid showing the highest indoor concentrations. By measuring the number of visitors and microclimate parameters (temperature and humidity) every 3 s, we were able to precisely estimate the causality and the temporal shift between these quantities, both at small time scale (a few minute delay between peaks) and at medium time scale (daily average conditions due to the continuous inflow and outflow of visitors). Full article

Coal-fired power plants exacerbate hazy weather under low winter temperatures, while sulphate ions (SO₄²⁻) in condensable particulate matter (CPM) emitted from ultra-low emission coal-fired power plants accelerate sulphate formation. The transformation of gaseous precursors (SO₂, NOx, NH₃) is the main pathway for sulphate formation by homogeneous or non-homogeneous reactions. For the sustainability of the world, in this paper, the effects of condensation temperature, H₂O, NO_X and NH₃ on the SO₄²⁻ generation characteristics under low-temperature rapid condensation conditions are investigated. With lower temperatures, especially from 0 °C cooling to −20 °C, the concentration of SO₄²⁻ was as high as 26.79 mg/m³. With a greater proportion of H₂SO₄ in the aerosol state, and a faster rate of sulphate formation, H₂O vapour condensation can provide a reaction site for sulphuric acid aerosol generation. SO₄²⁻ in CPM is mainly derived from the non-homogeneous reaction of SO₂. SO₃ is an important component of CPM and provides a reaction site for the formation of SO₄²⁻. SO₂ and SO₃, in combination with Stefan flow, jointly play a synergistic role in the generation of SO₄²⁻. The content of SO₄²⁻ was as high as 36.18 mg/m³. While NO_X sometimes inhibits the formation of SO₄²⁻, NH₃ has a key role in the nucleation process of CPM. NH₃, SO₂ and NO_X have been found to rapidly form sulphate with particle sizes up to 5 µm at sub-zero temperatures and promote the formation of sulphuric acid aerosols. Full article

The efficient production of high-quality bedding plants is essential for greenhouse growers aiming to meet market demands while minimising costs. This study investigated the effects of supplemental lighting (prolonged photoperiod) and retardant treatments on the growth, development, mineral composition, and flowering of vegetatively propagated Petunia × atkinsiana (Surfinia^® ‘Lime’ and ‘Purple’) and Calibrachoa × hybrida (Superbells^® ‘Unique Red’ and ‘Unique Golden Yellow’) cultivars. The plants were subjected to extended lighting for up to 16 h during the rooting phase and treated with or without a growth retardant. The supplemental light significantly accelerated the flowering, improved the shoot branching, and enhanced the mineral nutrient accumulation, particularly of calcium, sulphur, and magnesium. The illuminated plants also exhibited higher chlorophyll content and more favourable dry-mass accumulation. The growth retardants reduced the plant height and concentrations of nitrogen, phosphorus, and potassium but increased the calcium and magnesium contents. The combination of lighting and growth regulation optimised the plant morphology and nutritional status, producing compact, well-branched plants with enhanced visual appeal. Earlier flowering of illuminated plants is valuable from a commercial perspective, allowing earlier selling and improved product marketability. These findings confirm the synergistic benefits of early photoperiod control and chemical growth regulation in enhancing the commercial quality and sustainability of bedding plant production. Full article

5-Hydroxymethylfurfural (HMF) is a versatile platform molecule with the potential to replace many fossil fuel derivatives. It can be obtained through the dehydration of carbohydrates. In this study, we present a simple and cost-effective microwave-assisted method for producing HMF. This method involves the use of readily available sucrose as a substrate and glucose-derived bifunctional hydrochars as carbocatalysts. These catalysts were produced via hydrothermal carbonisation using thiourea and urea as nitrogen and sulphur sources, respectively, to introduce Brønsted acidic and basic sites into the materials. Using a microwave reactor, we found that the S, N-doped hydrochars were active in sucrose dehydration in water. Catalytic results showed that HMF yield depended on the balance between acidic and basic sites as well as the types of S and N species present on the surfaces of these hydrochars. The best-performing catalyst achieved an encouraging HMF yield of 37%. The potential of N, S-co-doped biochar as a green solid catalyst for various biorefinery processes was demonstrated. A simple kinetic model was developed to elucidate the kinetics of the main reaction pathways of this cascade process, showing a very good fit with the experimental results. The calculated rate constants revealed that reactions with a 5% sucrose loading exhibited significantly higher fructose dehydration rates and produced fewer side products than reactions using a more diluted substrate. No isomerisation of glucose into fructose was observed in an air atmosphere. On the contrary, a limited rate of isomerisation of glucose into fructose was recorded in an oxygen atmosphere. Therefore, efforts should focus on achieving a high glucose-to-fructose isomerisation rate (an intermediate reaction step) to improve HMF selectivity by reducing humin formation. Full article

Niobium, with its unique properties, plays a key role in high-tech industries, but its recovery from secondary sources remains poorly studied. The kinetics of niobium leaching from niobium-containing middlings obtained via the water treatment of dust chamber sublimations of titanium chlorinators is considered in this study. The leaching process was conducted using a fluoride–sulphuric acid solution. The experiments were performed at 25–90 °C in agitation mode. Kinetic data were analysed using compression-core and mixed-control models, which made it possible to establish the limiting stages of the process. A mixed mechanism, including a chemical reaction on the surface and diffusion through a layer of products with an activation energy of 30.05 kJ/mol, was established. The niobium recovery degree increased from 35.25 to 93.5% as the temperature increased, highlighting its effect on the process. The insoluble residue, rich in titanium, and the liquid phase with niobium and zirconium have the potential for further processing. The results provide the basis to optimise technologies intended to recover niobium from man-made raw materials, contributing to an increase in resource efficiency. Full article

To extend the spectral utilisation of In₂S₃, an In₂S₃/C₃N₄ nanocomposite was prepared. The effects of different sulphur sources, electrodes, and bias voltages on the optoelectronic performance were examined. Photoelectric properties in response to light sources with wavelengths of 405, 532, 650, 780, 808, 980, and 1064 nm were investigated using Au electrodes and the carbon electrodes with 5B pencil drawings. This study shows that the aggregation states of the In₂S₃/C₃N₄ nanocomposite possess photocurrent switching responses in the broadband region of the light spectrum. Combining two types of partially visible light-absorbing material extends utilisation to the near-infrared region. Impurities or defects embody an electron-donating effect. Since the energy levels of defects or impurities with an electron-donating effect are close to the conduction band, low-energy lights (especially NIR) can be utilised. The non-equilibrium carrier concentration (photogenerated electrons) of the nanocomposites increases significantly under NIR photoexcitation conditions. Thus, photoconductive behaviour is manifested. A good photoelectric signal was still measured when zero bias was applied. This demonstrates self-powered photoelectric response characteristics. Different sulphur sources significantly affect the photoelectric performance, suggesting that they create different defects that affect charge transport and base current noise. It is believed that interfacial interactions in the In₂S₃/C₃N₄ nanocomposite create a built-in electric field that enhances the separation and transfer of electrons and holes produced by light stimulation. The presence of the built-in electric field also leads to energy band bending, which facilitates the utilisation of the light with longer wavelengths. This study provides a reference for multidisciplinary applications. Full article

Air pollution is the world’s greatest environmental health risk. Pollutants that pose large health concerns are particulate matter (PM_2.5 and PM₁₀), ozone (O₃), carbon monoxide (CO), nitrogen dioxide (NO₂), and sulphur dioxide (SO₂). These compounds (especially PM_2.5 and PM₁₀) contribute to the onset of diseases, such as respiratory diseases (e.g., asthma, chronic obstructive pulmonary disease (COPD), or lung cancer) and cardiovascular diseases. Abatement interventions are implemented to reduce air pollution and thereby the risk of these diseases. This systematic review examined the published scientific evidence on the cost-effectiveness of strategies aimed at reducing or controlling air pollution and assessed the reporting quality of included studies. It employed rigorous data extraction and quality scoring procedures to ensure the reliability and validity of our findings. Overall, there is substantial evidence supporting the cost-effectiveness of interventions aimed at reducing air pollution. Seventy-four studies and four policy reports were included in this review. Predominantly, cost–benefit analyses have been reported (n = 40), reflecting the multisectoral impacts and associated costs of air pollution. Only four cost–utility analyses were found, indicating the need for more research within this domain. Additionally, eight articles reported one or more non-economic results. Thirty-nine studies focused on particulate matter (PM), and eleven focused on nitrogen oxides (NOx). The quality assessment yielded moderate results. The heterogeneity of studies and moderate quality of reporting make it difficult to compare results and draw definitive conclusions. Full article

In this study, a response surface methodology (RSM) using a central composite design (CCD) was implemented to investigate the influence of process variables on ethyl levulinate (EL) production from the ethanolysis of waste corn cob samples, using sulphuric acid as a catalyst. The effects of four independent variables, namely, the temperature (A), the corn cob content (B), corn cob/H₂SO₄ mass ratio (C) and the reaction time (D) on the yields of EL (Y₁), diethyl ether (DEE) (Y₂) and solid residue (Y₃) were explored. Using multiple regression analysis, the experimental results were fitted to quadratic polynomial models. The predicted yields based on the fitted models were well within the experimental uncertainties. Optimum conditions for maximising the EL yield were found to be 176 °C, 14.6 wt. %, 21:1 and 6.75 h for A to D, respectively. A moderate-to-high EL yield (29.2%) from corn cob was achieved in optimised conditions, a result comparable to those obtained from model C₆ carbohydrate compounds. Side products were also produced, including diethyl ether, furfural, levulinic acid, 5-hydroxymethyl furfural, ethyl acetate, ethyl formate and water. Total unknown losses of only 5.69% were reported after material balancing. The results suggest that lignocellulosic waste such as corn cob can be used as a potential feedstock for the production of ethyl levulinate by direct acid-catalysed ethanolysis, but that the treatment of side products will need to be considered. Full article

The accelerated urbanisation that is occurring in many regions of the world is resulting in a corresponding increase in the volume of sewage sludge. This sludge is then stored in specialised landfills, the area of which is increasing annually. One of the methods of utilising this sludge is through its combustion in power plants, where it serves to generate heat. However, due to the low calorific value of sewage sludge, it is recommended to combust it in conjunction with high-calorific fuel. To improve energy efficiency of sewage residue biomass utilisation by co-combustion with coal, it is necessary to determine the main combustion parameters and mass fraction in the mixture. The objective of this study is to estimate the primary parameters of combustion of sewage sludge and coal by employing the synchronous thermal analysis method, in addition to determining the concentrations of gaseous substances formed during the combustion process. A comprehensive technical and elemental analysis of the fuels was conducted, and their thermal properties were thoroughly determined. The inorganic residue from sewage sludge combustion was analysed by scanning electron microscopy for the content of trace elements and basic oxides. Thermogravimetric analysis (TGA) of fuels was conducted in an oxidising medium, utilising a 6 mg suspension with a heating rate of 20 °C/min. The profiles of TG, DTG, and DSC curves were then utilised to determine the ignition and burnout temperatures, maximum mass loss rate, combustion index, and synergistic effects. The mixture of coal with 25% sewage sludge was found to have the most energy-efficient performance compared to other mixtures, with a 3% reduction in ignition temperature compared to coal. Concentrations of carbon dioxide, carbon monoxide, nitrogen oxides, and sulphur oxides were also determined. Full article

The complex dynamics between oxygen exposure, sulphur dioxide use, and wine quality are of the utmost importance in modern winemaking. While SO₂ acts as an effective antiseptic and antioxidant, its excessive use raises health concerns, prompting stricter regulations (Council Regulation EC No. 1493/1999; Commission Regulation EC No. 1622/2000) and increasing interest in natural alternatives. In this context, Bioma SA developed plant-based additives derived from vineyard by-products rich in phenolic compounds to replace SO₂ in vinification. This study has evaluated the impact of these additives on the inorganic elemental composition of Sangiovese wines, comparing traditional sulphite-based vinification with the Bioma-based alternative. Using triple quadrupole ICP-MS, 23 elements were quantified and analysed via ANOVA and principal component analysis (PCA). The results revealed significant effects of the vinification protocol and ageing method on key elements such as Mn, Rb, Sr, Ni, and As. Importantly, all toxic elements, Pb (≤5.9 µg/L), Cd (≤0.3 µg/L), and As (≤12.1 µg/L), remained well below EU safety thresholds. PCA further highlighted distinct elemental profiles between traditional and Bioma wines. These findings confirm that Bioma additives enable the production of wines with reduced sulphur content and compliant elemental safety, supporting their potential as sustainable, health-conscious alternatives in modern oenology. Full article