Search Results (67)

The insufficient optimization of calcination process parameters severely restricts the enhancement of rice husk ash (RHA) volcanic ash activity. In this study, an intelligent muffle furnace was used for multi-parameter coupled regulation, combined with microscopic characterization techniques, to elucidate the effects of temperature, cooling mode, heating rate, and holding time on the reactivity of RHA. The results showed that the effect of calcination temperature on the volcanic ash activity of RHA was dominant. RHA calcined at 600–700 °C showed a honeycomb porous structure, displayed broad amorphous SiO₂ diffraction peaks and up to 95% content of SiO₂, and exhibited the best volcanic ash activity. The increased crystallinity of RHA calcined at 800 °C led to a decrease in its activity. The subcooling treatment with distilled water effectively rebuilt the lamellar structure, reduced the crystallinity, and enhanced the reactivity. The samples incorporated with 600 °C calcined RHA showed higher compressive strength at 3 days compared to 800 °C calcined RHA. Full article

To enhance the steam parameters of steam injection boilers during the thermal recovery of heavy oil while ensuring the safe and stable operation of boiler pipelines, this study conducted two-phase flow boiling numerical simulations in a horizontal heated tube with an inner diameter of 65 mm, using water and water vapor as working fluids. The analysis focused on the gas–liquid phase distribution, temperature profiles, near-wall fluid velocity, and pressure drop along both the axial and radial directions of the tube. Furthermore, the effects of heat flux density, mass flow rate, and inlet subcooling on these parameters were systematically investigated. The results reveal that higher heat fluxes intensify the velocity difference between the upper and lower tube walls and enlarge the temperature gradient across the wall surface. A reduction in mass flow rate increases the gas phase fraction within the tube and causes the occurrence of identical flow patterns at earlier axial positions. Additionally, the onset of nucleate boiling shifts upstream, accompanied by an increase and upstream movement of the wall’s maximum temperature. An increase in inlet subcooling prolongs the time required for the working fluid mixture to reach saturation, thereby decreasing the gas phase fraction and delaying the appearance of the same flow patterns. Finally, preventive and control strategies for ensuring the safe operation of steam injection boiler pipelines during heavy oil recovery are proposed from the perspective of flow pattern regulation. Full article

With ambitious targets set by the EU for the reduction of emissions from the energy sector by 2030, there is a need to design and develop more building projects using renewable energy sources. Even though in Europe, heating and cooling share from renewable resources is increasing, and in 2021, the total share in this sector in Croatia was at 38%, the share of heat production by heat pumps is rather low. One possibility to increase this share is to install energy piles when constructing a building, which is becoming an increasingly common practice. This case study focuses on such a system designed for a large, non-residential building in Zagreb, Croatia. The complex was designed as 13 separate dilatations, with central heating and cooling of all facilities, covered by 260 energy piles (130 pairs in serial connection), with a length of the polyethylene pipe of 20 m in a double loop inserted within the pile. The thermo-technical system was designed as a bivalent parallel system, with natural gas covering peak heating loads and a dry cooler covering cooling peak loads when the loads cannot be covered only by ground-source heat pumps. In the parallel bivalent system, the geothermal source will work with a much higher number of working hours at full load than is the case for geothermal systems that are dimensioned to peak consumption. Therefore, the thermal response test was conducted on two energy piles, connected in series, to obtain thermogeological parameters and determine the heat extraction and rejection rates. The established steady-state heat rate defines the long-term ability to extract heat energy during constant thermal load, with the inlet water temperature from the pile completely stabilized, i.e., no significant further sub-cooling is achieved in the function of the geothermal field operation time. Considering the heating and cooling loads of the building, modeling of the system was performed in such a manner that it utilized renewable energy as much as possible by finding a bivalent point where the geothermal system works efficiently. It was concluded that the optimal use of the geothermal field covers total heating needs and 70% for cooling, with dry coolers covering the remaining 30%. Additionally, based on the measured thermogeological parameters, simulations of the thermal response test were conducted to determine heat extraction and rejection rates for energy piles with various geometrical parameters of the heat exchanger pipe and fluid flow variations. Full article

The hydrate blockage avoidance performance of two anti-agglomerants (coconut amidopropyl dimethylamine, propylene bis (octadecylamidopropyl dimethylammonium chloride)) and their mixtures with polyvinylpyrrolidone (PVP) was tested in a high-pressure rocking cell apparatus. The effect of gas–liquid ratio, water content and PVP concentration were analyzed. A method for evaluating the kinetic inhibiting and anti-agglomerating performance of hydrate inhibitors was established. It was found that coconut amidopropyl dimethylamine had good anti-agglomerating performance at a low gas–liquid ratio (0.5) and various water content levels (20~80%), while propylene bis (octadecylamidopropyl dimethylammonium chloride) had a good anti-agglomerating performance only at a low gas–liquid ratio (0.5) and high water content (80%), and the hydrate volume fraction was up to 23.27% for good anti-agglomeration. When PVP was mixed with the above two anti-agglomerants, it was found that coconut amidopropyl dimethylamine could significantly reduce the kinetic inhibition performance of PVP, while propylene bis (octadecylamidopropyl dimethylammonium chloride) had no significant effect on the kinetic inhibition performance of PVP. The maximum subcooling was 4.4 °C. PVP had no significant effect on the anti-agglomerating performance of the two anti-agglomerants, and the maximum hydrate volume fraction was 18.87% when the agglomeration was well inhibited. Full article

In this study, a quenching experiment was conducted at atmospheric pressure to investigate the flow and heat-transfer characteristics of cylindrical rods made from SS, FeCrAl, and Zr-4 under various subcooling degrees (ΔT_sub). The inverse heat-conduction problem (IHCP) method and image-processing technique were utilized to determine the surface temperature and heat flux, vapor film thickness, and quench front propagation. The results show that smaller solid kρc_p and larger ΔT_sub result in relatively more efficient quenching boiling heat transfer, thinner vapor film thickness, and greater quench front propagation velocity. The quench front originates at the bottom of the test specimen and becomes progressively larger in velocity with time. It eventually converges with the downward-propagating quench front in the upper middle of the test specimen. Moreover, at the beginning of quench front propagation, the SS and FeCrAl test specimens have a constant velocity region. However, because the Zr-4 test specimen has a small kρc_p, the velocities gradually increase from the onset of quench front generation. Furthermore, the measured average quench front velocities are consistent with the experimental datum from the literature. However, the predicted model proposed by Duffey underestimates the propagation velocity due to ignoring the cooling effect of film boiling. Full article

The hypervapotron structure was considered to be a feasible configuration to meet the high heat-dissipating requirement of divertors in nuclear fusion devices. In this work, symmetric CuCrZr-based transverse microchannels (TMHC) and longitudinal microchannels (LMHC) with an integrated hypervapotron channel were proposed and manufactured, and subcooled flow boiling experiments were conducted using deionized water at an inlet temperature of 20 °C with a traditional flat-type hypervapotron channel (FHC) for comparison. The LMHC and TMHC obtained lower wall temperatures than the FHC for all conditions, and the TMHC yielded the lowest temperatures. The heat transfer coefficients of the LMHC and TMHC outperformed the FHC due to the enlarged heat transfer area, and the TMHC had the greatest heat transfer coefficient (maximumly increased by 132% compared to the FHC) because the transverse-arranged microchannels were conductive, promoting the convection and liquid replenishment ability by introducing branch flow between fins; however, the microchannels of the LMHC were insensible to flow velocities due to the block effect of longitudinal microchannels. The LMHC obtained the largest pressure drop, and the pressure drop for the FHC and TMHC were comparable since the transverse-placed microchannels had little effect on frictional pressure loss. The TMHC attained the greatest comprehensive thermohydraulic performance which might bring significant insight to the structural design of hypervapotron devices. Full article

Experiments on specimen cooling dynamics and possible film boiling around a body are very important in various industrial applications, such as nucleate boiling, to decrease drag reduction or achieve better surface properties in coating technologies. The objective of this study was to investigate the interaction between the heat transfer processes and cooling dynamics of a sample in different boundary conditions. This article presents new experimental data on specimens coated with Al–TiO₂ film and Leidenfrost phenomenon (LP) formation on the film’s surface. Furthermore, this manuscript presents numerical heat and mass transfer parameter results. The comparative analysis of new experiments on Al–TiO₂ film specimens and other coatings such as polished aluminium, Al–MgO, Al–MgH₂ and Al–TiH₂ provides further detail on oxide and hydride materials. In the experimental cooling dynamics experiments, specimens were heated up to 450 °C, while the sub-cooling water temperatures were 14*‒20 °C (room temperature), 40 °C and 60 °C. The specimens’ cooling dynamics were calculated by applying Newton’s cooling law, and heat transfer was estimated by calculating the heat flux $q$ transferred from the specimens’ surface and the Bi parameter. The metadata results from the performed experiments were used to numerically model the cooling dynamics curves for different material specimens. Approximated polynomial equations are proposed for the polished aluminium, Al–TiO₂, Al–MgO, Al–MgH₂ and Al–TiH₂ materials. The provided comparative analysis makes it possible to see the differences between oxides and hydrides and to choose materials for practical application in the industrial sector. The presented results could also be used in software packages to model heat transfer processes. Full article

Direct contact condensation (DCC) is a phenomenon observed when steam interacts with subcooled water, exhibiting higher heat and mass transfer rates compared to wall condensation. It has garnered significant interest across industries such as nuclear, chemical, and power due to its advantageous characteristics. In the context of pressure-relief tanks, understanding and optimizing the DCC process are critical for safety and efficiency. The efficiency of pressure-relief tanks depends on the amount of steam condensed per unit of time, which directly affects their operational parameters and design. This study focuses on investigating the direct gas–liquid contact condensation process in pressure-relief tanks using computational fluid dynamics (CFD). Through experimental validation and a sensitivity analysis, the study provides insights into the influence of inlet steam parameters and basin temperature on the steam plume characteristics. Furthermore, steady-state and transient calculation models are developed to simulate the behaviour of the pressure-relief tank, providing valuable data for safety analysis and design optimization. There is a relatively high-pressure area in the upper part of the bubble hole of the pressure-relief tube, and the value increases as it is closer to the holes. The steam velocity in the bubbling hole near the 90° elbow position is higher. This study contributes to the understanding of steam condensation dynamics in pressure-relief tanks. When the steam emission and pressure are fixed, the equilibrium temperature increases linearly as the initial temperature increases (where a = 1, b = 20 in y = a x+ b correlation), the equilibrium pressure increases nearly exponentially, and the equilibrium gas volume decreases. When the steam emission and initial temperature are fixed, the equilibrium temperature does not change as the steam discharge pressure increases. The correlations between the predicted equilibrium parameters and the inlet steam parameters and tank temperature provide valuable insights for optimizing a pressure-relief tank design and improving the operational safety in diverse industrial contexts. Full article

An experimental validation of a steady-state model for water-to-water heat pumps is conducted on a 10 kW test bench. The objective of the model is to predict the capacity and the required compressor power, based on the inlet conditions of the secondary fluids in the evaporator and condenser. Detailed manufacturer performance maps based on the AHRI 540-2020 standard are utilized to model the fixed-speed scroll compressor. A new semi-empirical model for the thermostatic expansion valve incorporates condensing temperature effects on superheating prediction. Sub-models for individual components, including detailed representations of the evaporator and condenser, are integrated into a global model, resulting in a set nonlinear equation solved using an equation solver with appropriate guess values. The validation of the model is conducted in an experimental test facility equipped with two precisely controlled secondary fluid loops. The heat pump is instrumented to measure condensation and evaporation pressures, the compressor discharge temperature, compressor power, superheating, and sub-cooling. The results are divided into three sub-sections: the first validates the complete heat pump model by comparing its power consumption and COPs in heating and cooling; the second compares the predicted and measured operational conditions; finally, it is shown how the model can be used to predict the non-operational conditions of the heat pump for specific scenarios. Full article

Methane hydrate formation is analytically studied in the presence of the water memory effect using the classical nucleation theory. The memory effect is introduced as a change in nucleation site from a three-dimensional heterogenous nucleation on a solid surface with cap-shaped hydrate clusters (3D-HEN) to a two-dimensional nucleation on the solid hydrate residue surface with monolayer disk-shaped hydrate clusters (2D-NOH). The analysis on the stationary nucleation of methane hydrate under isobaric conditions shows that the memory effect caused an average decrease of 4.4 K in metastable zone width, or subcooling. This decrease can be erased at higher dissociation temperatures (ΔT > 17.2 K) due to a decrease in the concentration of 2D-NOH nucleation sites. Moreover, the probability of hydrate formation is estimated for the purpose of quantifying risk associated with methane hydrate formation in the presence of the memory effect. Full article

The reflooding phase, a crucial recovery process after a loss of coolant accident (LOCA) in reactors, involves cooling overheated fuel rods with subcooled water. Its complex nature, notably in its flow regime and heat transfer, makes prediction challenging, resulting in high uncertainty and computation cost. In this study, we utilized the data assimilation (DA) technique to enhance the prediction of reflooding phenomena and subsequently deployed machine learning models to predict the accuracy of the safety and performance analysis code (SPACE) simulation. To generate the dataset for the machine learning model, we employed the sampling method for highly nonlinear system uncertainty analysis (STARU), providing a high-quality dataset for a complex problem such as a reflooding simulation. In this dataset, the physical models were assimilated under their selected uncertainty bands and utilized the effective sampling approach of STARU, generating the high-quality output and efficient enhancement of SPACE predictions. Consequently, the implemented machine learning model can be used to enhance model development and uncertainty quantification (UQ) analysis using the system code. Full article

The pressure drop characteristics of subcooled water were experimentally investigated in a circular cooling channel with and without a twisted tape (TT) under high heat fluxes, which was designed for the water-cooling structure of the divertor target in a tokamak device. The working medium was deionized water, and the main parameters were mass flux G = 3000–8000 kg·m⁻²·s⁻¹, inlet pressure of the test section p = 3, 4.2, 5 MPa, equivalent one-side heating flux q_e = 5~10 MW·m⁻². The off-center circular channel is electrically heated to simulate the unilateral radiation heating on the divertor target by high-temperature plasma. The pressure drop experiment of vertical upward circular cooling channels under high and unilateral heat flux is carried out. The influences of the TT and system parameters such as q_e, G, and p on the pressure drop of the test section (Δp) were discussed in detail. In the single-phase (SP) flow region, Δp is mainly affected by the TT, G, and q_e. The pressure drop with a TT is significantly higher than that without a TT, a higher G and a lower q_e lead to a greater Δp. In the subcooled boiling (SB) flow region, Δp is correlated with the TT, q_e, G, and p: the influence of the TT and G decreases, while the influence of p increases. The higher the q_e, the higher the G, and the lower the p, the larger the Δp. The results show that almost all of the SP pressure drop correlations for heated circular channels overestimate the experimental pressure drop coefficient ratio for a given viscosity ratio. According to the test results, a new correlation of SP pressure drop under high and unilateral heat fluxes has been proposed, the average error (AE) and root mean square error (RMSE) of which are 0.26% and 3.17%, respectively. Full article

To study the pressure drop characteristics of hypervapotron, which was designed as a water-cooling structure in the divertor dome of the fusion reactor, the pressure drop tests of subcooled water were carried out in a vertically upward hypervapotron. To simulate the one-side radiant heating condition in the engineering application, the non-uniform heat fluxes were obtained by using the off-center electrically heating method. The system parameters were as follows: mass flux G = 2000–5000 kg·m⁻²·s⁻¹, inlet pressure p = 2–4 MPa, and equivalent one-side radiating heat flux q_e = 0–5 MW·m⁻². The effects of the parameters on the pressure drop were discussed in detail. It was observed that in the single-phase (SP) region, the pressure drop was little influenced by the inlet fluid temperature (T_b,in). However, in the subcooled boiling region, the pressure drop increased rapidly with the increasing T_b,in. A higher G leads to a high pressure drop. In the SP region, the influence of p on the pressure drop is not obvious, and the pressure drop decreased with the increasing q_e. The test data are used to evaluate the typical pressure drop correlation, and the results show that none of these correlations can predict the pressure drop well under the test conditions. Therefore, a new pressure drop correlation is proposed for subcooled water in a hypervapotron under high and non-uniform heat fluxes. The new correlation has a high prediction accuracy for the test data, and the mean relative error (MRE) and root mean square error (RMSE) are 0.72% and 4.33%, respectively. The test results have a reference value for the design of the water-cooling structure of the diverter. Full article

Flashing flows of initially sub-cooled water in a converging–diverging nozzle is investigated numerically in the framework of the two-fluid model (TFM). The thermal non-equilibrium effect of phase change is considered by an interfacial heat transfer model, while the pressure jump across the interface is ignored. The bubble size distribution induced by nucleation, bubble growth/shrinkage, coalescence, and breakup is described based on the interfacial area transport equation (IATE) and constant bubble number density model (CBND), respectively. The results are compared with the experimental data. Satisfactory prediction of the axial pressure distribution along the nozzle as well as the flashing inception, is achieved by the TFM-IATE coupling method. It was also found that the vapor production in the diverging section was overpredicted, and the radial gas volume fraction distribution deviated from the experiment. The radial diameter profiles exhibit opposite patterns at the nozzle throat and near the outlet, and similar trends can be observed for the superheated degree. A poly-disperse method is suggested to be introduced to describe the evolution of interfacial area concentration. Full article

Amidst the background of “double carbon”, energy saving and emission reduction is a popular direction in the current refrigeration industry. Therefore, the research on the boiling heat transfer of gas–liquid two-phase flow is helpful to strengthen the heat transfer and design a more efficient heat exchanger. In this paper, a research method combining numerical simulation and experimental verification is adopted. Firstly, an experimental platform used for the subcooled flow boiling of refrigerant in casing tubes is introduced and experiments are carried out to obtain experimental data, which provides a theoretical basis for the development of numerical simulation and verifies the feasibility of numerical simulation. A numerical model of subcooled flow boiling in R22 was established and the grid independence test was carried out. Based on the simulation results, three factors affecting the boiling heat transfer of R22 are analyzed: First, the boiling heat transfer coefficient of R22 increases with the increase of the mass flow rate of R22, but the increase decreases when the mass flow rate increases from 0.018 kg/s to 0.020 kg/s. Second, the boiling heat transfer coefficient of R22 increases significantly with the increase of hot water flow rate. Third, the influence of R22 subcooling on boiling heat transfer is more complex. When the subcooling is 5 °C and 1 °C, heat transfer can be enhanced; high subcooling at 5 °C can enhance convective heat transfer and low subcooling at 1 °C can accelerate the arrival of saturated boiling. In this paper, three kinds of bubble behaviors affecting heat transfer in supercooled flow boiling, including sliding, polymerization, and bounce are also studied, which provides a basis for further research on heat transfer mechanism of supercooled flow boiling. Full article