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Keywords = strength–ductility balance

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17 pages, 5353 KiB  
Article
Evaluation of Hardfacing Layers Applied by FCAW-S on S355MC Steel and Their Influence on Its Mechanical Properties
by Fineas Morariu, Timotei Morariu, Alexandru Bârsan, Sever-Gabriel Racz and Dan Dobrotă
Materials 2025, 18(15), 3664; https://doi.org/10.3390/ma18153664 - 4 Aug 2025
Abstract
Enhancing the wear resistance of structural steels used in demanding industrial applications is critical for extending components’ lifespan and ensuring mechanical reliability. In this study, we investigated the influence of flux-cored arc welding (FCAW) hardfacing on the tensile behavior of S355MC steel. Protective [...] Read more.
Enhancing the wear resistance of structural steels used in demanding industrial applications is critical for extending components’ lifespan and ensuring mechanical reliability. In this study, we investigated the influence of flux-cored arc welding (FCAW) hardfacing on the tensile behavior of S355MC steel. Protective Fe-Cr-C alloy layers were deposited in one and two successive passes using automated FCAW, followed by tensile testing of specimens oriented at varying angles relative to the weld bead direction. The methodology integrated 3D scanning and digital image correlation to accurately capture geometric and deformation parameters. The experimental results revealed a consistent reduction in tensile strength and ductility in all the welded configurations compared to the base material. The application of the second weld layer further intensified this effect, while specimen orientation influenced the degree of mechanical degradation. Microstructural analysis confirmed carbide refinement and good adhesion, but also identified welding-induced defects and residual stresses as factors that contributed to performance loss. The findings highlight a clear trade-off between improved surface wear resistance and compromised structural properties, underscoring the importance of process optimization. Strategic selection of welding parameters and bead orientation is essential to balance functional durability with mechanical integrity in industrial applications. Full article
(This article belongs to the Special Issue Advances in Welding of Alloy and Composites (2nd Edition))
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20 pages, 7843 KiB  
Article
Effect of Ageing on a Novel Cobalt-Free Precipitation-Hardenable Martensitic Alloy Produced by SLM: Mechanical, Tribological and Corrosion Behaviour
by Inés Pérez-Gonzalo, Florentino Alvarez-Antolin, Alejandro González-Pociño and Luis Borja Peral-Martinez
J. Manuf. Mater. Process. 2025, 9(8), 261; https://doi.org/10.3390/jmmp9080261 - 4 Aug 2025
Viewed by 33
Abstract
This study investigates the mechanical, tribological, and electrochemical behaviour of a novel precipitation-hardenable martensitic alloy produced by selective laser melting (SLM). The alloy was specifically engineered with an optimised composition, free from cobalt and molybdenum, and featuring reduced nickel content (7 wt.%) and [...] Read more.
This study investigates the mechanical, tribological, and electrochemical behaviour of a novel precipitation-hardenable martensitic alloy produced by selective laser melting (SLM). The alloy was specifically engineered with an optimised composition, free from cobalt and molybdenum, and featuring reduced nickel content (7 wt.%) and 8 wt.% chromium. It has been developed as a cost-effective and sustainable alternative to conventional maraging steels, while maintaining high mechanical strength and a refined microstructure tailored to the steep thermal gradients inherent to the SLM process. Several ageing heat treatments were assessed to evaluate their influence on microstructure, hardness, tensile strength, retained austenite content, dislocation density, as well as wear behaviour (pin-on-disc test) and corrosion resistance (polarisation curves in 3.5%NaCl). The results indicate that ageing at 540 °C for 2 h offers an optimal combination of hardness (550–560 HV), tensile strength (~1700 MPa), microstructural stability, and wear resistance, with a 90% improvement compared to the as-built condition. In contrast, ageing at 600 °C for 1 h enhances ductility and corrosion resistance (Rp = 462.2 kΩ; Ecorr = –111.8 mV), at the expense of a higher fraction of reverted austenite (~34%) and reduced hardness (450 HV). This study demonstrates that the mechanical, surface, and electrochemical performance of this novel SLM-produced alloy can be effectively tailored through controlled thermal treatments, offering promising opportunities for demanding applications requiring a customised balance of strength, durability, and corrosion behaviour. Full article
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21 pages, 8317 KiB  
Article
Mechanical Properties and Ballistic Performance for Different Coatings on HARDOX 450 Steel for Defense Applications
by Cosmin Nicolescu, Tudor Viorel Tiganescu, Aurora Antoniac, Ovidiu Iorga, Brandusa Ghiban, Alexandru Pascu, Alexandru Streza and Iulian Antoniac
Crystals 2025, 15(8), 687; https://doi.org/10.3390/cryst15080687 - 29 Jul 2025
Viewed by 303
Abstract
The aim of the current study is to investigate the mechanical properties and ballistic performance of HARDOX 450 steel for defense applications in different conditions: uncoated, alumina-coated, and LINE X polyurea-coated. Tensile tests and Vickers microhardness measurements were conducted, along with fracture surface [...] Read more.
The aim of the current study is to investigate the mechanical properties and ballistic performance of HARDOX 450 steel for defense applications in different conditions: uncoated, alumina-coated, and LINE X polyurea-coated. Tensile tests and Vickers microhardness measurements were conducted, along with fracture surface analysis using stereomicroscopy, scanning electron microscopy, and computed tomography. Experimental results showed that uncoated HARDOX 450 steel exhibited the highest strength and hardness, with ductile fracture features. Polyurea-coated HARDOX 450 steel samples retained good mechanical properties and demonstrated effective ballistic protection, including the containment of fragments. In contrast, alumina-coated HARDOX 450 steel samples exhibited reduced strength and ballistic resistance, attributed to the microstructural changes in HARDOX 450 steel caused by the high-temperature deposition process of alumina. Numerical simulations performed with the 5.56 × 45 mm bullet used in the simulation, along with its ballistic impact interaction with the Hardox 450 target model, aligned well with experimental ballistic impact results for all the samples. Overall, LINE X polyurea coating on HARDOX 450 steel proved to be the more suitable coating for applications requiring a balance of mechanical strength and ballistic impact resistance. Full article
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17 pages, 8074 KiB  
Article
Cyclic Behavior Enhancement of Existing RC Bridge Columns with UHPC Jackets: Experimental and Parametric Study on Jacket Thickness
by Songtao Gu and Rui Zhang
Buildings 2025, 15(15), 2609; https://doi.org/10.3390/buildings15152609 - 23 Jul 2025
Viewed by 196
Abstract
Ultra-high-performance concrete (UHPC) jackets present a promising solution for enhancing the seismic resilience of seismically deficient reinforced concrete (RC) bridge columns. This study investigates jacket thickness optimization through integrated experimental and numerical analyses. Quasi-static cyclic tests on a control column and a specimen [...] Read more.
Ultra-high-performance concrete (UHPC) jackets present a promising solution for enhancing the seismic resilience of seismically deficient reinforced concrete (RC) bridge columns. This study investigates jacket thickness optimization through integrated experimental and numerical analyses. Quasi-static cyclic tests on a control column and a specimen retrofitted with a 30-mm UHPC jacket over the plastic hinge region demonstrated significant performance improvements: delayed damage initiation, controlled cracking, a 24.6% increase in lateral load capacity, 139.5% higher energy dissipation at 3% drift, and mitigated post-peak strength degradation. A validated OpenSees numerical model accurately replicated this behavior and enabled parametric studies of 15-mm, 30-mm, and 45-mm jackets. Results identified the 30-mm thickness as optimal, balancing substantial gains in lateral strength (~12% higher than other thicknesses), ductility, and energy dissipation while avoiding premature failure modes—insufficient confinement in the 15-mm jacket and strain incompatibility-induced brittle failure in the 45-mm jacket. These findings provide quantitative design guidance, establishing 30 mm as the recommended thickness for efficient seismic retrofitting of existing RC bridge columns. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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17 pages, 6308 KiB  
Article
Effect of Heat Treatment on Microstructure and Mechanical Properties of (TiB + TiC) /Ti-6Al-4V Composites Fabricated by Directed Energy Deposition
by Hai Gu, Guoqing Dai, Jie Jiang, Zulei Liang, Jianhua Sun, Jie Zhang and Bin Li
Metals 2025, 15(7), 806; https://doi.org/10.3390/met15070806 - 18 Jul 2025
Viewed by 263
Abstract
The titanium matrix composites (TMCs) fabricated via Directed Energy Deposition (DED) effectively overcome the issue of coarse columnar grains typically observed in additively manufactured titanium alloys. In this study, systematic annealing heat treatments were applied to in situ (TiB + TiC)/Ti-6Al-4V composites to [...] Read more.
The titanium matrix composites (TMCs) fabricated via Directed Energy Deposition (DED) effectively overcome the issue of coarse columnar grains typically observed in additively manufactured titanium alloys. In this study, systematic annealing heat treatments were applied to in situ (TiB + TiC)/Ti-6Al-4V composites to refine the microstructure and tailor mechanical properties. The results reveal that the plate-like α phase in the as-deposited composites gradually transforms into an equiaxed morphology with increasing annealing temperature and holding time. Notably, when the annealing temperature exceeds 1000 °C, significant coarsening of the TiC phase is observed, while the TiB phase remains morphologically stable. Annealing promotes decomposition of acicular martensite and stress relaxation, leading to a reduction in hardness compared to the as-deposited state. However, the reticulated distribution of the TiB and TiC reinforcement phases contributes to enhanced tensile performance. Specifically, the as-deposited composite achieves a tensile strength of 1109 MPa in the XOY direction, representing a 21.6% improvement over the as-cast counterpart, while maintaining a ductility of 2.47%. These findings demonstrate that post-deposition annealing is an effective strategy to regulate microstructure and achieve a desirable balance between strength and ductility in DED-fabricated titanium matrix composites. Full article
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14 pages, 10913 KiB  
Article
Lattice Distortion Effects on Mechanical Properties in Nb-Ti-V-Zr Refractory Medium-Entropy Alloys
by Xiaochang Xie, Ping Yang, Yuefei Jia and Yandong Jia
Materials 2025, 18(14), 3356; https://doi.org/10.3390/ma18143356 - 17 Jul 2025
Viewed by 248
Abstract
Medium-entropy alloys (MEAs) have attracted significant attention due to their unique structure–property relationships. In this study, we examine the effects of lattice distortion on the mechanical properties of Nb-Ti-V-Zr MEAs, focusing on two alloy series: Nb(Ti1.5V)xZr and Nb(TiV)x [...] Read more.
Medium-entropy alloys (MEAs) have attracted significant attention due to their unique structure–property relationships. In this study, we examine the effects of lattice distortion on the mechanical properties of Nb-Ti-V-Zr MEAs, focusing on two alloy series: Nb(Ti1.5V)xZr and Nb(TiV)xZr (x = 1, 2, 3, 4 and 5). Experimental results show that the Nb(TiV)xZr r alloys exhibit greater atomic size mismatches and increased lattice distortion compared to the Nb(Ti1.5V)xZr alloys, leading to higher yield strengths via enhanced solid-solution strengthening. However, excessive lattice distortion does not ensure an optimal strength–ductility balance, as the alloys with the highest distortion demonstrate limited plasticity. Thus, moderate reduction in lattice distortion proves beneficial in achieving an excellent compromise between strength and ductility. These findings offer valuable guidance for leveraging lattice distortion in the design of high-strength, high-ductility, body-centered cubic (BCC) MEAs for extreme environments. Full article
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18 pages, 4137 KiB  
Article
Three-Dimensional Printed Porous PLA Scaffolds with Dual Functionality: Cell Proliferation Enhancement and Antibacterial Properties
by Renad N. AlQurashi, Noora M. Bataweel, Mehal Atallah AlQriqri, Sarah H. Alqahtani, Ahmad A. Basalah and Laila A. Damiati
Polymers 2025, 17(14), 1928; https://doi.org/10.3390/polym17141928 - 13 Jul 2025
Viewed by 522
Abstract
Scaffold architecture plays a significant role in regulating cellular and microbial interactions in tissue engineering applications. This study evaluates the performance of 3D-printed poly (lactic acid) (PLA) scaffolds with varying porosity levels (20%, 40%, 60%, 80%, and 100%) in mechanical strength, supporting human [...] Read more.
Scaffold architecture plays a significant role in regulating cellular and microbial interactions in tissue engineering applications. This study evaluates the performance of 3D-printed poly (lactic acid) (PLA) scaffolds with varying porosity levels (20%, 40%, 60%, 80%, and 100%) in mechanical strength, supporting human skin fibroblast (HSF) viability and reducing bacterial colonization of Gram-positive bacteria (Staphylococcus epidermidis, Staphylococcus aureus), and Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli). The maximum tensile strength (28 MPa) was achieved in the 100% dense scaffold. Increasing porosity drastically decreased tensile strength, where 80% PLA scaffold possessed 16 MPa strength. At greater levels of porosity (60% and 40%), tensile strengths greatly decrease (8 MPa and 4 MPa), while ductility increases, especially at high porosity levels. HSF viability, assessed using the AlamarBlue assay, showed a time-dependent increase in cell proliferation, with the highest viability observed on scaffolds with 60% and 80% porosity. SEM imaging confirmed strong cell adhesion on the 80% porous scaffold, indicating that intermediate-to-high porosity enhances cell attachment and metabolic activity. In contrast, bacterial adhesion showed species-specific responses to scaffold porosity. S. epidermidis and E. coli exhibited a progressive increase in adherence with porosity, peaking at 100%. P. aeruginosa showed maximum adhesion at 80%, suggesting a porosity “sweet spot” that favors its colonization. S. aureus adhered most strongly to scaffolds with intermediate porosities (40–60%) and significantly less at 100% porosity. The current study provides insights into scaffold design considerations, emphasizing the need for optimized scaffold architecture that balances regenerative potential with infection control in tissue engineering applications. Full article
(This article belongs to the Special Issue Advances in Functional Polymer Materials for Biomedical Applications)
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24 pages, 6554 KiB  
Article
Modeling Mechanical Properties of Industrial C-Mn Cast Steels Using Artificial Neural Networks
by Saurabh Tiwari, Seongjun Heo, Nokeun Park and Nagireddy Gari S. Reddy
Metals 2025, 15(7), 790; https://doi.org/10.3390/met15070790 - 12 Jul 2025
Viewed by 290
Abstract
This study develops a comprehensive artificial neural network (ANN) model for predicting the mechanical properties of carbon–manganese cast steel, specifically, the yield strength (YS), tensile strength (TS), elongation (El), and reduction of area (RA), based on the chemical composition (16 alloying elements) and [...] Read more.
This study develops a comprehensive artificial neural network (ANN) model for predicting the mechanical properties of carbon–manganese cast steel, specifically, the yield strength (YS), tensile strength (TS), elongation (El), and reduction of area (RA), based on the chemical composition (16 alloying elements) and heat treatment parameters. The neural network model, employing a 20-44-44-4 architecture and trained on 400 samples from an industrial dataset of 500 samples, achieved 90% of test predictions within a 5% deviation from actual values, with mean prediction errors of 3.45% for YS and 4.9% for %EL. A user-friendly graphical interface was developed to make these predictive capabilities accessible, without requiring programming expertise. Sensitivity analyses revealed that increasing the copper content from 0.05% to 0.2% enhanced the yield strength from 320 to 360 MPa while reducing the ductility, whereas niobium functioned as an effective grain refiner, improving both the strength and ductility. The combined effects of carbon and manganese demonstrated complex synergistic behavior, with the yield strength varying between 280 and 460 MPa and the tensile strength ranging from 460 to 740 MPa across the composition space. Optimal strength–ductility balance was achieved at moderate compositions of 1.0–1.2 wt% Mn and 0.20–0.24 wt% C. The model provides an efficient alternative to costly experimental trials for optimizing C-Mn steels, with prediction errors consistently below 6% compared with 8–20% for traditional empirical methods. This approach establishes quantitative guidelines for designing complex multi-element alloys with targeted mechanical properties, representing a significant advancement in computational material engineering for industrial applications. Full article
(This article belongs to the Special Issue Advances in Constitutive Modeling for Metals and Alloys)
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27 pages, 18408 KiB  
Article
Optimizing Al7072 Grooved Joints After Gas Tungsten Arc Welding
by Wei Guo, Qinwei Yu, Pengshen Zhang, Shunjie Yao, Hui Wang and Hongliang Li
Metals 2025, 15(7), 767; https://doi.org/10.3390/met15070767 - 8 Jul 2025
Viewed by 212
Abstract
Aluminum alloy, due to its low melting point and high thermal conductivity, deforms and contracts significantly during welding. To mitigate this and achieve full penetration in a single pass, this study uses GTAW (Gas Tungsten Arc Welding) additive manufacturing and optimizes welding groove [...] Read more.
Aluminum alloy, due to its low melting point and high thermal conductivity, deforms and contracts significantly during welding. To mitigate this and achieve full penetration in a single pass, this study uses GTAW (Gas Tungsten Arc Welding) additive manufacturing and optimizes welding groove parameters via the Box-Behnken Response Surface Methodology. The focus is on improving tensile strength and penetration depth by analyzing the effects of groove angle, root face width, and root gap. The results show that groove angle most significantly affects tensile strength and penetration depth. Hardness profiles exhibit a W-shape, with base material hardness decreasing and weld zone hardness increasing as groove angle rises. Root face width reduces hardness fluctuation in the weld zone, and an appropriate root gap compensates for thermal expansion, enhancing joint performance. The interaction between root face width and root gap most impacts tensile strength, while groove angle and root face width interaction most affects penetration depth. The optimal welding parameters for 7xxx aluminum alloy GTAW are a groove angle of 70.8°, root face width of 1.38 mm, and root gap of 0 mm. This results in a tensile strength of 297.95 MPa and penetration depth of 5 mm, a 90.38% increase in tensile strength compared to the RSM experimental worst group. Microstructural analysis reveals the presence of β-Mg2Si and η-MgZn2 strengthening phases, which contribute to the material’s enhanced mechanical properties. Fracture surface examination exhibits characteristic ductile fracture features, including dimples and shear lips, confirming the material’s high ductility. The coexistence of these strengthening phases and ductile fracture behavior indicates excellent overall mechanical performance, balancing strength and plasticity. Full article
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14 pages, 5112 KiB  
Article
Effect of Si Doping on Microstructure and Mechanical and Electrochemical Properties of (AlCrFeNi)100-xSix (x = 2, 4, 6) Dual-Phase Eutectic High-Entropy Alloys
by Subo Yu, Kaiwen Kang, Borui Zhang, Aoxiang Li and Gong Li
Metals 2025, 15(7), 762; https://doi.org/10.3390/met15070762 - 6 Jul 2025
Viewed by 300
Abstract
The effects of silicon (Si) doping on the microstructure, mechanical properties, and electrochemical corrosion behavior of dual-phase eutectic high-entropy alloys (AlCrFeNi)100-xSix (x = 2, 4, 6 at.%) were systematically investigated. The results reveal that with increasing Si content, all three [...] Read more.
The effects of silicon (Si) doping on the microstructure, mechanical properties, and electrochemical corrosion behavior of dual-phase eutectic high-entropy alloys (AlCrFeNi)100-xSix (x = 2, 4, 6 at.%) were systematically investigated. The results reveal that with increasing Si content, all three alloys maintain a sunflower-like eutectic microstructure composed of A2 and B2 phases, characterized by an expanding central region and a densification and refinement of the lamellar two-phase structure in the petal regions; the volume of phase B2 gradually increases, accompanied by the precipitation of nanoscale B2 particles. The test results of mechanical properties show that Si doping enhances the compressive strength and Vickers hardness but significantly reduces ductility, exhibiting a typical inverse strength–ductility relationship. Electrochemical corrosion tests demonstrate that higher Si content deteriorates corrosion resistance, with corrosion predominantly occurring in the B2 phase. Among the studied alloys, the Si2 variant exhibits the most balanced overall performance. This work provides valuable insights into the role of Si in tuning the microstructure and properties of eutectic high-entropy alloys and methodology for their compositional design and engineering applications. Full article
(This article belongs to the Special Issue High-Entropy Alloys: Processing and Properties)
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14 pages, 3388 KiB  
Article
A Flake Powder Metallurgy Approach for Fabricating Al/CNT Composites: Combining Dual-Matrix and Shift-Speed Ball Milling to Optimize Mechanical Properties
by Hamed Rezvanpour and Alberto Vergnano
Designs 2025, 9(4), 82; https://doi.org/10.3390/designs9040082 - 1 Jul 2025
Viewed by 350
Abstract
This study presents a novel flake powder metallurgy approach for fabricating Al/CNT composites, combining the dual-matrix (DM) method with shift-speed ball milling (SSBM) to optimize mechanical performance. Samples prepared via DM-SSBM were systematically compared to those produced by conventional high-speed ball milling (HSBM), [...] Read more.
This study presents a novel flake powder metallurgy approach for fabricating Al/CNT composites, combining the dual-matrix (DM) method with shift-speed ball milling (SSBM) to optimize mechanical performance. Samples prepared via DM-SSBM were systematically compared to those produced by conventional high-speed ball milling (HSBM), single-stage SSBM, and dual-matrix (DM) routes. Tensile testing revealed that the DM1MR50-SSBM composite achieved a superior balance of strength and ductility, with an ultimate tensile strength of ~267 MPa, elongation of ~9.9%, and the highest energy absorption capacity (~23.4 MJ/m3) among all tested samples. In contrast, the HSBM sample, while achieving the highest tensile strength (~328 MPa), exhibited limited elongation (~4.7%), resulting in lower overall toughness. The enhanced mechanical response of the DM-SSBM composites is attributed to improved CNT dispersion, refined cold-welding interfaces, and pure Al matrix softness, which together facilitate superior load transfer and hinder crack propagation under tensile stress. In the final consolidated state, aluminum forms a continuous matrix embedding the CNTs, justifying the use of the term “aluminum matrix” to describe the composite structure. These findings highlight the DM-SSBM approach as a promising method for developing lightweight, high-toughness aluminum composites suitable for energy-absorbing structural applications. Full article
(This article belongs to the Special Issue Post-manufacturing Testing and Characterization of Materials)
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27 pages, 9778 KiB  
Article
Flexural Behavior of Pre-Tensioned Precast High-Performance Steel-Fiber-Reinforced Concrete Girder Without Conventional Reinforcement: Full-Scale Test and FE Modeling
by Ling Kang, Haiyun Zou, Tingmin Mu, Feifei Pei and Haoyuan Bai
Buildings 2025, 15(13), 2308; https://doi.org/10.3390/buildings15132308 - 1 Jul 2025
Viewed by 370
Abstract
In contrast to brittle normal-strength concrete (NSC), high-performance steel-fiber-reinforced concrete (HPSFRC) provides better tensile and shear resistance, enabling enhanced bridge girder design. To achieve a balance between cost efficiency and quality, reducing conventional reinforcement is a viable cost-saving strategy. This study focused on [...] Read more.
In contrast to brittle normal-strength concrete (NSC), high-performance steel-fiber-reinforced concrete (HPSFRC) provides better tensile and shear resistance, enabling enhanced bridge girder design. To achieve a balance between cost efficiency and quality, reducing conventional reinforcement is a viable cost-saving strategy. This study focused on the flexural behavior of a type of pre-tensioned precast HPSFRC girder without longitudinal and shear reinforcement. This type of girder consists of HPSFRC and prestressed steel strands, balancing structural performance, fabrication convenience, and cost-effectiveness. A 30.0 m full-scale girder was randomly selected from the prefabrication factory and tested through a four-point bending test. The failure mode, load–deflection relationship, and strain distribution were investigated. The experimental results demonstrated that the girder exhibited ductile deflection-hardening behavior (47% progressive increase in load after the first crack), extensive cracking patterns, and large total deflection (1/86 of effective span length), meeting both the serviceability and ultimate limit state design requirements. To complement the experimental results, a nonlinear finite element model (FEM) was developed and validated against the test data. The flexural capacity predicted by the FEM had a marginal 0.8% difference from the test result, and the predicted load–deflection curve, crack distribution, and load–strain curve were in adequate agreement with the test outcomes, demonstrating reliability of the FEM in predicting the flexural behavior of the girder. Based on the FEM, parametric analysis was conducted to investigate the effects of key parameters, namely concrete tensile strength, concrete compressive strength, and prestress level, on the flexural responses of the girder. Eventually, design recommendations and future studies were suggested. Full article
(This article belongs to the Special Issue Advances in Mechanical Behavior of Prefabricated Structures)
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25 pages, 6245 KiB  
Review
Effect of Interstitial Oxygen on the Microstructure and Mechanical Properties of Titanium Alloys: A Review
by Yaojia Ren, Jiajun Xu, Yingkang Wei, Yingying Liu, Jilei Zhu and Shifeng Liu
Crystals 2025, 15(7), 618; https://doi.org/10.3390/cryst15070618 - 30 Jun 2025
Viewed by 416
Abstract
Titanium alloys are of significant value in aerospace, biomedical, and marine engineering applications due to their excellent specific strength and favorable biocompatibility. As a crucial interstitial solute, oxygen significantly influences the mechanical properties of titanium alloys. However, excessive oxygen content can lead to [...] Read more.
Titanium alloys are of significant value in aerospace, biomedical, and marine engineering applications due to their excellent specific strength and favorable biocompatibility. As a crucial interstitial solute, oxygen significantly influences the mechanical properties of titanium alloys. However, excessive oxygen content can lead to severe embrittlement and a significant reduction in ductility. This paper systematically reviews the mechanisms of microstructural evolution induced by oxygen in conventionally manufactured titanium alloys and their impact on mechanical properties, highlighting that conventional processes require complex post-treatments (PT) to achieve a balance between strength and plasticity. This assessment further explores the regulatory mechanisms of oxygen on the microstructure and mechanical properties of laser additive manufactured (LAM) titanium alloys, elucidating the fundamental phenomena regarding the oxygen–microstructure–property relationship. Finally, based on the current research progress, this paper provides an outlook on the future development directions and key research priorities in this field. This review offers valuable insights into the role of oxygen in titanium alloys and the development of high-performance titanium alloys. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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22 pages, 11408 KiB  
Article
The Influence of Beryllium Incorporation into an Al-5wt.%Cu-1wt.%Si Alloy on the Solidification Cooling Rate, Microstructural Length Scale, and Corrosion Resistance
by Joyce Ranay Santos, Milena Poletto Araújo, Talita Vida, Fabio Faria Conde, Noé Cheung, Amauri Garcia and Crystopher Brito
Metals 2025, 15(7), 736; https://doi.org/10.3390/met15070736 - 30 Jun 2025
Viewed by 328
Abstract
The addition of beryllium (Be) to Al–Cu alloys enhances their mechanical properties and corrosion resistance. This study aims to investigate the effects of solidification cooling rates and the addition of Be on the microstructural refinement and corrosion behavior of an Al–5wt.%Cu–1wt.%Si–0.5wt.%Be alloy. Radial [...] Read more.
The addition of beryllium (Be) to Al–Cu alloys enhances their mechanical properties and corrosion resistance. This study aims to investigate the effects of solidification cooling rates and the addition of Be on the microstructural refinement and corrosion behavior of an Al–5wt.%Cu–1wt.%Si–0.5wt.%Be alloy. Radial solidification under unsteady-state conditions was performed using a stepped brass mold, producing four distinct cooling rates. An experimental growth law, λ2 = 26T˙1/3, was established, confirming the influence of Be and the cooling rate on dendritic size reduction. The final microstructure was characterized by an α-Al dendritic matrix with eutectic compounds (α-Al + θ-Al2Cu + Si + Fe-rich phase) confined to the interdendritic regions. No Be-containing intermetallic phases were detected, and beryllium remained homogeneously distributed within the eutectic. Notably, Be addition promoted a morphological transformation of the Fe-rich phases from angular or acicular forms into a Chinese-script-like structure, which is associated with reduced local stress concentrations. Tensile tests revealed an ultimate tensile strength of 248.8 ± 11.2 MPa and elongation of approximately 6.4 ± 0.5%, indicating a favorable balance between strength and ductility. Corrosion resistance assessment by EIS and polarization tests in a 0.06 M NaCl solution showed a corrosion rate of 28.9 µm·year−1 and an Epit of −645 mV for the Be-containing alloy, which are lower than those measured for the reference Al–Cu and Al–Cu–Si alloys. Full article
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17 pages, 5649 KiB  
Article
Heat Treatment Analysis and Mechanical Characterization of a Recycled Gravity Die Cast EN 42000 Alloy
by Cristian Cascioli, Riccardo Arcaleni, Alessandro Morri and Lorella Ceschini
Metals 2025, 15(7), 726; https://doi.org/10.3390/met15070726 - 29 Jun 2025
Viewed by 426
Abstract
Recycled aluminum–silicon alloys provide significant environmental benefits by reducing the consumption of raw materials and lowering carbon emissions. However, their industrial application is limited by the presence of iron-based intermetallic compounds and the insufficient investigation in the literature regarding their effects on mechanical [...] Read more.
Recycled aluminum–silicon alloys provide significant environmental benefits by reducing the consumption of raw materials and lowering carbon emissions. However, their industrial application is limited by the presence of iron-based intermetallic compounds and the insufficient investigation in the literature regarding their effects on mechanical behavior. This study focuses on a recycled EN 42000 alloy, comprising 95% recycled aluminum, with a focus on the effect of its elevated iron content (0.447 wt%) on aging behavior and mechanical performance. Laboratory-scale specimens were produced through gravity die casting and subjected to T6 heat treatment, consisting of solution, quenching, and artificial aging from 160 °C to 190 °C for up to 8 h. To investigate overaging, analyses were conducted at 160 °C and 170 °C for durations up to 184 h. Tensile tests were conducted on specimens aged under the most promising conditions. Based on innovative quality indices and predictive modeling, aging at 160 °C for 4.5 h was identified as the optimal condition, providing a well-balanced combination of strength and ductility (YS = 258 MPa, UTS = 313 MPa, and e% = 3.9%). Mechanical behavior was also assessed through microstructural and fractographic analyses, highlighting the capability of EN 42000 to achieve properties suitable for high-performance automotive components. Full article
(This article belongs to the Special Issue Sustainability Approaches in the Recycling of Light Alloys)
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