Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (190)

Search Parameters:
Keywords = strain-rate-dependent plasticity

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
14 pages, 5622 KiB  
Article
Molecular Dynamics Simulations on the Deformation Behaviors and Mechanical Properties of the γ/γ′ Superalloy with Different Phase Volume Fractions
by Xinmao Qin, Wanjun Yan, Yilong Liang and Fei Li
Crystals 2025, 15(8), 706; https://doi.org/10.3390/cryst15080706 (registering DOI) - 31 Jul 2025
Viewed by 130
Abstract
Based on molecular dynamics simulation, we conducted a comprehensive study on the tensile behaviors and properties of the γ(Ni)/γ(Ni3Al) superalloy with varying γ(Ni3Al) phase volume fractions (Vγ) under high-temperature, [...] Read more.
Based on molecular dynamics simulation, we conducted a comprehensive study on the tensile behaviors and properties of the γ(Ni)/γ(Ni3Al) superalloy with varying γ(Ni3Al) phase volume fractions (Vγ) under high-temperature, high-strain-rate service environments. Our investigation revealed that the tensile behavior of the superalloy depends critically on the Vγ. When the Vγ increased from 13.5 to 67%, the system’s tensile strength exhibited a non-monotonic response, peaking at Vγ = 40.3% before progressively decreasing. Conversely, the maximum uniform plastic strain decreased linearly and significantly when Vγ increased. These results establish an atomistically informed framework that elucidates the composition–microstructure–property relationships in γ(Ni)/γ(Ni3Al) superalloys, specifically addressing how Vγ governs variations in deformation mechanisms and mechanical performance. Furthermore, this work provides quantitative design paradigm for optimizing γ(Ni3Al) precipitate architecture and compositional tuning in the Ni-based γ(Ni)/γ(Ni3Al) superalloy. Full article
(This article belongs to the Special Issue Advances in High-Performance Alloys)
Show Figures

Figure 1

18 pages, 6795 KiB  
Article
Strain-Rate-Dependent Tensile Behaviour and Viscoelastic Modelling of Kevlar® 29 Plain-Woven Fabric for Ballistic Applications
by Kun Liu, Ying Feng, Bao Kang, Jie Song, Zhongxin Li, Zhilin Wu and Wei Zhang
Polymers 2025, 17(15), 2097; https://doi.org/10.3390/polym17152097 - 30 Jul 2025
Viewed by 161
Abstract
Aramid fibre has become a critical material for individual soft body armour due to its lightweight nature and exceptional impact resistance. To investigate its energy absorption mechanism, quasi-static and dynamic tensile experiments were conducted on Kevlar® 29 plain-woven fabric using a universal [...] Read more.
Aramid fibre has become a critical material for individual soft body armour due to its lightweight nature and exceptional impact resistance. To investigate its energy absorption mechanism, quasi-static and dynamic tensile experiments were conducted on Kevlar® 29 plain-woven fabric using a universal material testing machine and a Split Hopkinson Tensile Bar (SHTB) apparatus. Tensile mechanical responses were obtained under various strain rates. Fracture morphology was characterised using scanning electron microscopy (SEM) and ultra-depth three-dimensional microscopy, followed by an analysis of microstructural damage patterns. Considering the strain rate effect, a viscoelastic constitutive model was developed. The results indicate that the tensile mechanical properties of Kevlar® 29 plain-woven fabric are strain-rate dependent. Tensile strength, elastic modulus, and toughness increase with strain rate, whereas fracture strain decreases. Under quasi-static loading, the fracture surface exhibits plastic flow, with slight axial splitting and tapered fibre ends, indicating ductile failure. In contrast, dynamic loading leads to pronounced axial splitting with reduced split depth, simultaneous rupture of fibre skin and core layers, and fibrillation phenomena, suggesting brittle fracture characteristics. The modified three-element viscoelastic constitutive model effectively captures the strain-rate effect and accurately describes the tensile behaviour of the plain-woven fabric across different strain rates. These findings provide valuable data support for research on ballistic mechanisms and the performance optimisation of protective materials. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
Show Figures

Figure 1

27 pages, 21183 KiB  
Article
Fracture Initiation in Aluminum Alloys Under Multiaxial Loading at Various Low Strain Rates
by Mehmet Haskul and Eray Arslan
Metals 2025, 15(7), 785; https://doi.org/10.3390/met15070785 - 11 Jul 2025
Viewed by 292
Abstract
The initiation of ductile fractures in medium-strength AW5754 and high-strength AW6082 aluminum alloys at different quasi-static strain rates and under multiaxial stress states was investigated through a series of tensile tests using various specimen geometries. The sensitivity of the stress triaxiality locus to [...] Read more.
The initiation of ductile fractures in medium-strength AW5754 and high-strength AW6082 aluminum alloys at different quasi-static strain rates and under multiaxial stress states was investigated through a series of tensile tests using various specimen geometries. The sensitivity of the stress triaxiality locus to variations in the loading rate was examined for these two aluminum alloy families. Fractographic and elemental analyses were also conducted via SEM and EDS. Numerical simulations based on the finite element method (FEM) were performed using ABAQUS/Standard to determine the actual stress triaxialities and the equivalent plastic strains at fracture. The numerical approach was validated by comparing the simulation results with the experimental findings. These simulations facilitated the generation of a stress triaxiality locus through a curve-fitting process. Among the considered fitting functions, an exponential function was selected as it provided the most accurate relation between the equivalent plastic strain at fracture and the corresponding stress state across different strain rates. The results reveal different strain rate dependencies for the two alloys within a very low strain rate range. The resulting stress triaxiality loci provide a valuable tool for predicting fracture strains and for more accurately evaluating stress states. Overall, the findings of this study significantly advance the understanding of the fracture initiation behavior of aluminum alloys under multiaxial loading conditions and their sensitivity to various quasi-static loading rates. Full article
Show Figures

Figure 1

20 pages, 9160 KiB  
Article
Plasticized Starch/Gelatin Blends with Humidity-Activated Shape-Memory Behavior
by Victor Oliver-Cuenca, Ana Muñoz-Menzinger, Marina P. Arrieta, Daniel López and Laura Peponi
Polymers 2025, 17(13), 1763; https://doi.org/10.3390/polym17131763 - 26 Jun 2025
Viewed by 338
Abstract
Biodegradable and bio-based polymers, such as starch and gelatin, are emerging as an important alternative to the use of conventional polymers. In this work, different proportions (1/1, 1/1.5, 1/2, and 1/2.5) of these bio-based polymers will be investigated, with the primary objective of [...] Read more.
Biodegradable and bio-based polymers, such as starch and gelatin, are emerging as an important alternative to the use of conventional polymers. In this work, different proportions (1/1, 1/1.5, 1/2, and 1/2.5) of these bio-based polymers will be investigated, with the primary objective of considering their strong moisture dependence as an advantage instead of a problem, as commonly considered. For this interesting challenge, the humidity-activated shape memory effect has been studied in both neat and plasticized starch. Additionally, for the first time, to the best of our knowledge, the shape-memory behavior activated by humidity in gelatin, as well as in starch/gelatin blends, is reported. In all cases, starch, gelatin, and their plasticized blends show excellent values in terms of strain fixity ratio, obtaining values of about 100% in all cases, and strain recovery ratio, with values higher than 90% for the samples studied. Moreover, considering their potential application as food packaging, mechanical response, wettability, water permeability, water uptake rate, and roughness is also studied in this work, taking into account the effect of the different amounts of gelatin on the final behavior of the materials. Full article
(This article belongs to the Special Issue Organic-Inorganic Hybrid Materials, 4th Edition)
Show Figures

Figure 1

10 pages, 12690 KiB  
Article
Temperature-Dependent Charpy Impact Toughness and Deformation Mechanisms of Austenitic Fe-32Mn-0.6C Steel
by Jianchao Xiong, Yue Cui, Xin Wang, Caiyi Liu, Silvia Barella, Marco Belfi, Andrea Gruttadauria, Yuhui Wang, Yan Peng and Carlo Mapelli
Materials 2025, 18(12), 2845; https://doi.org/10.3390/ma18122845 - 17 Jun 2025
Viewed by 372
Abstract
The Charpy impact toughness of single-phase austenitic Fe-32Mn-0.6C steel was systematically investigated across a wide temperature spectrum from 25 °C to −196 °C using Charpy V-notch impact tests. The material exhibited a remarkable temperature dependence of impact energy, decreasing dramatically from 120 J [...] Read more.
The Charpy impact toughness of single-phase austenitic Fe-32Mn-0.6C steel was systematically investigated across a wide temperature spectrum from 25 °C to −196 °C using Charpy V-notch impact tests. The material exhibited a remarkable temperature dependence of impact energy, decreasing dramatically from 120 J at ambient temperature (25 °C) to 13 J under cryogenic conditions (−196 °C). Notably, a steep transition in impact energy occurred within the critical temperature window of −100 °C to −150 °C. Microstructural analysis revealed that synergistic effects of high strain rates and low temperatures significantly restrict dislocation slip and multiplication mechanisms, while also suppressing deformation twinning activation. This restricted plasticity accommodation mechanism fundamentally differs from the deformation characteristics reported in conventional low-carbon high-manganese steels and other face-centered cubic (FCC) alloy systems. Full article
(This article belongs to the Special Issue Physical Metallurgy of Metals and Alloys (3rd Edition))
Show Figures

Figure 1

12 pages, 1701 KiB  
Article
Effects of Hydration on the Mechanical Properties of Salt-Doped Poly(methyl methacrylate)
by Asae Ito, Naoki Uchida, Yusuke Hiejima and Koh-hei Nitta
Molecules 2025, 30(12), 2568; https://doi.org/10.3390/molecules30122568 - 12 Jun 2025
Viewed by 338
Abstract
The mechanical performance of poly(methyl methacrylate) (PMMA) is highly sensitive to moisture absorption, which induces plasticization and softening. In this study, we investigated the ductilization mechanism of PMMA by incorporating various metal salts with different cations (Li+ and Mg2+) and [...] Read more.
The mechanical performance of poly(methyl methacrylate) (PMMA) is highly sensitive to moisture absorption, which induces plasticization and softening. In this study, we investigated the ductilization mechanism of PMMA by incorporating various metal salts with different cations (Li+ and Mg2+) and controlling water absorption through hygroscopic interactions. A nonequilibrium constitutive model is introduced, in which localized water domains around salt-rich regions gradually diffuse into the PMMA matrix during tensile deformation. The stress–strain behavior is described by combining rigid (dry) and soft (hydrated) matrix components, connected through an internal kinetic variable governed by the strain-dependent diffusion rate. The model successfully reproduces experimental tensile data and captures the transition from brittle to ductile behavior as a function of the moisture content. Notably, Mg salts exhibit stronger water binding and slower moisture redistribution than Li salts, resulting in distinct mechanical responses. These findings provide a mechanistic framework for tailoring the ductility of hygroscopic polymer systems via ion–water–polymer interactions. Full article
Show Figures

Figure 1

10 pages, 1472 KiB  
Technical Note
Modeling of Tensile Tests Flow Curves Using an Explicit Piecewise Inverse Approach
by Aditya Vuppala, Holger Brüggemann, David Bailly and Emad Scharifi
Metals 2025, 15(6), 638; https://doi.org/10.3390/met15060638 - 5 Jun 2025
Viewed by 436
Abstract
Tensile tests are a common method for characterizing plastic behavior for sheet metal forming applications. During tensile testing at the beginning of the deformation, the stress state is uniaxial; however, as the deformation proceeds, the state changes to triaxial, making the post-processing of [...] Read more.
Tensile tests are a common method for characterizing plastic behavior for sheet metal forming applications. During tensile testing at the beginning of the deformation, the stress state is uniaxial; however, as the deformation proceeds, the state changes to triaxial, making the post-processing of experimental data challenging using analytical methods. In contrast, inverse approaches in which the behavior is represented by constitutive equations and the parameters are fitted using an iterative procedure are extremely dependent on the empirical equation chosen at the outset and can be computationally expensive. The inverse piecewise flow curve determination method, previously developed for compression tests, is extended in this paper to tensile testing. A stepwise approach is proposed to calculate constant strain rate flow curves accounting for the unique characteristics of tensile deformation. To capture the effects of localized strain rate variations during necking, a parallel flow curve determination strategy is introduced. Tensile test flow curves for manganese-boron steel 22MnB5, a material commonly used in hot stamping applications, are determined, and the approach is demonstrated for virtual force–displacement curves. It has been shown that these curves can replicate the virtual experimental flow curves data with a maximum deviation of 1%. Full article
Show Figures

Figure 1

23 pages, 4355 KiB  
Article
Experimental and Numerical Investigation of Strain Rate Dependent Flow and Fracture Behavior of 6181A-T4 Alloy Using the Johnson–Cook Model
by Ecenur Öztürk, Onur Cavusoglu and Ahmet Güral
Crystals 2025, 15(6), 528; https://doi.org/10.3390/cryst15060528 - 30 May 2025
Cited by 1 | Viewed by 663
Abstract
The use of aluminum alloys for lightweighting in the automotive industry is becoming widespread. In this study, Johnson–Cook plasticity and damage model parameters were determined to predict the plasticity and damage behavior of 6181A-T4 sheet material using finite element analysis software. Uniaxial tensile [...] Read more.
The use of aluminum alloys for lightweighting in the automotive industry is becoming widespread. In this study, Johnson–Cook plasticity and damage model parameters were determined to predict the plasticity and damage behavior of 6181A-T4 sheet material using finite element analysis software. Uniaxial tensile tests were performed at four different deformation rates (0.0083–0.333 s−1) using tensile test specimens with four different triaxiality values (0.33, 0.36, 0.45, and 0.74). For a 3 mm thick 6181A-T4 aluminum alloy sheet, Johnson–Cook plasticity parameters were determined by the curve fitting method, and damage parameters were optimized using LS-OPT 7.0 software. Finite element analyses using Johnson–Cook plasticity and damage model parameters were compared with the experimental results, and it was observed that the finite element analyses produced very successful predictions. With the increase in strain rate, the yield strength increased, while the tensile strength showed limited change; uniform elongation, coefficient of hardening, and toughness showed a decreasing trend, and the fracture mode showed a transition from ductile to more brittle behavior. The coefficient of determination (R2) values between the Johnson–Cook model and the experimental data ranged from 0.8601 to 0.9837 depending on the strain-rate value. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
Show Figures

Figure 1

18 pages, 3776 KiB  
Article
A Viscoelastic-Plastic Creep Model for Initial Damaged Coal Sample Affected by Loading Rate
by Peng Huang, Yimei Wei, Meng Li, Erkan Topal, Xinyong Teng and Wei Wang
Appl. Sci. 2025, 15(10), 5265; https://doi.org/10.3390/app15105265 - 8 May 2025
Viewed by 400
Abstract
Underground engineering rock masses are significantly affected by stress redistribution induced by mining or adjacent engineering disturbances, leading to initial damage accumulation in coal-rock masses. Under sustained geostress, these masses exhibit pronounced time-dependent creep behavior, posing serious threats to long-term engineering stability. Dynamic [...] Read more.
Underground engineering rock masses are significantly affected by stress redistribution induced by mining or adjacent engineering disturbances, leading to initial damage accumulation in coal-rock masses. Under sustained geostress, these masses exhibit pronounced time-dependent creep behavior, posing serious threats to long-term engineering stability. Dynamic loading effects triggered by adjacent mining activities (manifested as medium strain-rate loading) further exacerbate damage evolution and significantly influence creep characteristics. In this study, coal samples with identical initial damage were prepared, and graded loading creep tests were conducted at rates of 0.005 mm·s−1 (50 microstrains·s−1), 0.01 mm·s−1 (100 microstrains·s−1), 0.05 mm·s−1 (500 microstrains·s−1), and 0.1 mm·s−1 (1000 microstrains·s−1) to systematically analyze the coupled effects of loading rate on creep behavior. Experimental results demonstrate that increased loading rates markedly shorten creep duration, with damage rates during the acceleration phase showing nonlinear surges (e.g., abrupt instability at 0.1 mm·s−1 (1000 microstrains·s−1)). Based on experimental data, an integer-order viscoelastic-plastic creep model incorporating stress-dependent viscosity coefficients and damage correlation functions was developed, fully characterizing four behaviors stages: instantaneous deformation, deceleration, steady-state, and accelerated creep. Optimized via the Levenberg–Marquardt algorithm, the model achieved correlation coefficients exceeding 0.96, validating its accuracy. This model clarifies the impact mechanisms of loading rates on the long-term mechanical behavior of initially damaged coal samples, providing theoretical support for stability assessment and hazard prevention in underground engineering. Full article
(This article belongs to the Special Issue Technologies and Methods for Exploitation of Geological Resources)
Show Figures

Figure 1

14 pages, 3374 KiB  
Article
Deformation of Polyethylene Subjected to Static and Nonstatic Stresses and Krypton Ions Irradiation
by Anatoliy I. Kupchishin, Artem L. Kozlovsky, Marat N. Niyazov, Kairat B. Tlebaev, Oleksandr. V. Bondar and Alexander D. Pogrebnjak
Polymers 2025, 17(8), 1081; https://doi.org/10.3390/polym17081081 - 17 Apr 2025
Viewed by 342
Abstract
The dependence of polyethylene deformation on applied mechanical stress under varying load conditions and radiation doses was investigated experimentally. Obtained results reveal significant alterations in the mechanical properties of polyethylene following irradiation with krypton ions at doses of 1.5 × 106, [...] Read more.
The dependence of polyethylene deformation on applied mechanical stress under varying load conditions and radiation doses was investigated experimentally. Obtained results reveal significant alterations in the mechanical properties of polyethylene following irradiation with krypton ions at doses of 1.5 × 106, 1.6 × 107, 5.0 × 108, and 1.0 × 109 ions/s. The stress–strain curves obtained for both the unirradiated and irradiated samples are numerically modeled using frameworks developed by the authors. The findings indicate that irradiation with krypton ions at an energy level of 147 MeV exerts a pronounced impact on the deformation and strength characteristics of polyethylene. Notably, increasing the radiation dose to 109 particles/s results in a 2.5-fold increase in the rate of mechanical stress. Furthermore, the degree of deformation distortions in molecular chains induced by high-energy Kr15+ ion irradiation has been quantified as a function of irradiation fluence. Increasing the irradiation fluence from 106 ion/cm2 to 107 ion/cm2 causes only minor variations in deformation distortions, which are attributed to the localized isolation of latent tracks and associated changes in electron density. A comparative analysis of the mechanical behavior of irradiated polymer materials further revealed differences between ion and electron irradiation effects. It was observed that Teflon films lose their plasticity after irradiation, whereas polyethylene films exhibit enhanced elongation and tearing performance at higher strain values relative to their non-irradiated counterparts. This behavior was consistently observed for films irradiated with both ions and electrons. However, an important distinction was identified: high-energy electron irradiation degrades the strength of polyethylene, whereas krypton ion irradiation at 147 MeV does not result in strength reduction. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
Show Figures

Figure 1

15 pages, 7180 KiB  
Article
SHPB Experiment and MPM Simulation on Dynamic Properties of Unsaturated Clay Under Impact Loading
by Yingkang Yao, Futian Zhao, Junjie Li, Jun Liu, Zheng Liu, Yue Wang, Ruihong Zhuang, Li Liu, Yingbo Zhao and Zequan Xu
Appl. Sci. 2025, 15(6), 3123; https://doi.org/10.3390/app15063123 - 13 Mar 2025
Cited by 1 | Viewed by 635
Abstract
Accurate characterization of soil dynamic response is paramount for geotechnical and protective engineering. However, the impact properties of unsaturated cohesive soil have not been well characterized due to lack of sufficient research. For this purpose, impact tests using the Split Hopkinson Pressure Bar [...] Read more.
Accurate characterization of soil dynamic response is paramount for geotechnical and protective engineering. However, the impact properties of unsaturated cohesive soil have not been well characterized due to lack of sufficient research. For this purpose, impact tests using the Split Hopkinson Pressure Bar (SHPB) were elaborately designed to investigate the dynamic stress–strain response of unsaturated clay with strain rates of 204~590 s−1. As the strain rate increased up to 500 s−1, a lock-up behavior was observed in the plastic flow stage, which can be explained as the breakage and rearrangement of soil gains under a high level of stress. Further, the strain rate dependency of the dynamic strength was quantitatively characterized by the Cowper Symonds (CS) model and the CS coefficients were determined to be the intercept of 55 and slope of 0.8 in the double logarithmic scale of Dynamic Increase Factor (DIF) and strain rate space. Furthermore, the SHPB test was reproduced using a modified Material Particle Method (MPM), which involves an improved dynamic constitutive model for unsaturated soil considering the strain rate effect. The simulated stress–strain curves basically agree with the experimental results, indicating the feasibility of MPM for investigating the dynamic properties of unsaturated soil under SHPB impact loading. Full article
Show Figures

Figure 1

37 pages, 11657 KiB  
Article
Experimental Evaluation of Temperature and Strain-Rate-Dependent Mechanical Properties of Austenitic Stainless Steel SS316LN and a New Methodology to Evaluate Parameters of Johnson–Cook and Ramberg–Osgood Material Models
by Sanjay Kumar Pandey and Mahendra Kumar Samal
Solids 2025, 6(1), 7; https://doi.org/10.3390/solids6010007 - 11 Feb 2025
Viewed by 1768
Abstract
Austenitic stainless steel SS316LN is used as the material of construction of the vessel and core components of fast breeder reactors, which operate at an elevated temperature of 550 °C. For design and integrity analysis using the finite element method, material models, such [...] Read more.
Austenitic stainless steel SS316LN is used as the material of construction of the vessel and core components of fast breeder reactors, which operate at an elevated temperature of 550 °C. For design and integrity analysis using the finite element method, material models, such as Johnson–Cook and Ramberg–Osgood, are widely used. However, the temperature- and strain-rate-dependent plasticity and damage parameters of these models for this material are not available in the literature. Moreover, the method of evaluation of temperature and strain-rate-dependent plasticity parameters, in literature, has some major shortcomings, which have been addressed in this work. In addition, a new optimization-based procedure has been developed to evaluate all nine plasticity and damage parameters, which uses results of combined finite element analysis and experimental data. The procedure has been validated extensively by testing tensile specimens at different temperatures, by testing notched tensile specimens of different notch radii, and by carrying out high strain-rate tests using a split Hopkinson pressure bar test setup. The parameters of the Johnson–Cook material model, evaluated in this work, have been used in finite element analysis to simulate load-displacement behavior and fracture strains of various types of specimens, and the results have been compared with experimental data in order to check the accuracy of the parameters. The procedure developed in this work shall help the researchers to adopt such a technique for accurate estimation of both plasticity and damage parameters of different types of material models. Full article
(This article belongs to the Topic Multi-scale Modeling and Optimisation of Materials)
Show Figures

Figure 1

25 pages, 4926 KiB  
Review
Progress in Plastic Work–Heat Conversion of Metallic Crystals
by Peng-Fei Yue, Shao-Dan Yang, Yan Gao, Rong-Hao Shi, Guo-Shang Zhang, Zhi-Yuan Zhu, Dong Han and Ke-Xing Song
Crystals 2025, 15(2), 164; https://doi.org/10.3390/cryst15020164 - 8 Feb 2025
Viewed by 704
Abstract
The Taylor–Quinney coefficient (TQC) is a critical parameter quantifying the thermal conversion of plastic work during deformation in metallic crystals. This review provides a comprehensive summary of recent advances in TQC research, spanning experimental, theoretical, and computational perspectives. The fundamental principles of the [...] Read more.
The Taylor–Quinney coefficient (TQC) is a critical parameter quantifying the thermal conversion of plastic work during deformation in metallic crystals. This review provides a comprehensive summary of recent advances in TQC research, spanning experimental, theoretical, and computational perspectives. The fundamental principles of the TQC are introduced, emphasizing its thermodynamic background and dependence on microstructural features. Experimental studies demonstrate how the strain rate, temperature, and microstructure influence the TQC, with advanced techniques such as infrared thermography and high-speed imaging enabling precise measurements under dynamic conditions. Theoretical models, including internal variable frameworks and nonequilibrium thermodynamics, offer insights into the energy distribution mechanisms and provide predictive capabilities across diverse loading scenarios. Computational simulations, using methods like finite element analysis and molecular dynamics, reveal multiscale thermal conversion mechanisms and the role of dislocation motion and localized heat accumulation in governing TQC values. Challenges and opportunities for TQC research are highlighted, including the need for multiscale modeling, the exploration of complex stress states, and applications under extreme environments. Future directions should focus on integrating advanced experimental techniques and computational models to optimize material design and performance. This review aims to deepen the understanding of the TQC and its implications for energy dissipation and material reliability in high-performance applications. Full article
Show Figures

Figure 1

17 pages, 3232 KiB  
Article
Evaluation of Blended Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Properties Containing Various 3HHx Monomers
by Nara Shin, Su Hyun Kim, Jinok Oh, Suwon Kim, Yeda Lee, Yuni Shin, Suhye Choi, Shashi Kant Bhatia, Jong-Min Jeon, Jeong-Jun Yoon, Jeong Chan Joo and Yung-Hun Yang
Polymers 2024, 16(21), 3077; https://doi.org/10.3390/polym16213077 - 31 Oct 2024
Cited by 2 | Viewed by 1248
Abstract
Polyhydroxyalkanoate (PHA), specifically poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (P(3HB-co-3HHx), PHBHHx) with physical properties governed by the 3-hydroxyhexanoate (3HHx) mole fraction, is a promising bioplastic. Although engineered strains used to produce P(3HB-co-3HHx) with various 3HHx mole contents and fermentation techniques have been [...] Read more.
Polyhydroxyalkanoate (PHA), specifically poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (P(3HB-co-3HHx), PHBHHx) with physical properties governed by the 3-hydroxyhexanoate (3HHx) mole fraction, is a promising bioplastic. Although engineered strains used to produce P(3HB-co-3HHx) with various 3HHx mole contents and fermentation techniques have been studied, mass production with specific 3HHx fractions and monomers depends on the batch, supply of substrates, and strains, resulting in the time-consuming development of strains and complex culture conditions for P(3HB-co-3HHx). To overcome these limitations, we blended poly(3-hydroxybutyrate) [(P(3HB), produced from C. necator H16] and P(3HB-co-20 mol%3HHx) [from C. necator 2668/pCB81] to prepare films with various 3HHx contents. We evaluated the molecular weight and physical, thermal, and mechanical properties of these films and confirmed the influence of the 3HHx monomer content on the mechanical and thermal properties as well as degradability of the blended P(3HB-co-3HHx) films containing various 3HHx mole fractions, similar to that of original microbial-based P(3HB-co-3HHx). Moreover, the degradation rate analyzed via Microbulbifer sp. was >76% at all blending ratios within 2 days, whereas a weaker effect of the 3HHx mole fraction of the blended polymer on degradation was observed. P(3HB-co-3HHx) could be produced via simple blending using abundantly produced P(3HB) and P(3HB-co-20 mol%HHx), and the resulting copolymer is applicable as a biodegradable plastic. Full article
Show Figures

Figure 1

18 pages, 3104 KiB  
Article
Stress–Dilatancy Behavior of Highly Elastic Rubber-Added Cohesionless Materials
by Haifeng Zhang, Xinrui Zhang, Linjie Li and Zihua Jiang
Materials 2024, 17(21), 5264; https://doi.org/10.3390/ma17215264 - 29 Oct 2024
Viewed by 995
Abstract
Dilatancy is commonly defined as the ratio of the rates of plastic volumetric strain to plastic deviatoric strain, denoted as Dp. Owing to the high modulus of elasticity, the elastic volumetric and deviatoric strain rates under shear stress in conventional cohesionless [...] Read more.
Dilatancy is commonly defined as the ratio of the rates of plastic volumetric strain to plastic deviatoric strain, denoted as Dp. Owing to the high modulus of elasticity, the elastic volumetric and deviatoric strain rates under shear stress in conventional cohesionless materials are negligible. Therefore, using the ratio of the rates of total volumetric to deviatoric strain (Dt) as an approximation is common in studying stress–dilatancy behavior and calibrating dilatancy model parameters. This approach is also common in the study of rubber-added cohesionless materials (RCM). However, RCM with a common range of rubber content exhibit a significantly lower modulus of elasticity compared to conventional cohesionless materials. Further research is needed to evaluate the potential impact of elastic strain rates in RCM on stress–dilatancy analysis. Therefore, comparisons were conducted on the stress–dilatancy responses of a series of tests on RCM, where dilatancy is calculated by Dp and Dt, respectively. Furthermore, a modified method for calibrating the parameters of a state-dependent dilatancy model considering Dp is presented. It turns out that Dp is better suited and more precise for dilatancy analysis on highly elastic RCM. Additionally, the dilatancy model can more precisely capture the test results of RCM with parameters calibrated by the proposed method. Full article
(This article belongs to the Section Construction and Building Materials)
Show Figures

Figure 1

Back to TopTop