Search Results (40)

Hydrogen production is increasingly vital for global decarbonization but remains a water- and energy-intensive process, especially in arid regions. Despite growing attention to its climate benefits, limited research has addressed the environmental impacts of water sourcing. This study employs a life cycle assessment (LCA) approach to evaluate three water supply strategies for hydrogen production: (1) seawater desalination without brine treatment (BT), (2) desalination with partial BT, and (3) freshwater purification. Scenarios are modeled for the United Arab Emirates (UAE), Australia, and Spain, representing diverse electricity mixes and water stress conditions. Both electrolysis and steam methane reforming (SMR) are evaluated as hydrogen production methods. Results show that desalination scenarios contribute substantially to human health and ecosystem impacts due to high energy use and brine discharge. Although partial BT aims to reduce direct marine discharge impacts, its substantial energy demand can offset these benefits by increasing other environmental burdens, such as marine eutrophication, especially in regions reliant on carbon-intensive electricity grids. Freshwater scenarios offer lower environmental impact overall but raise water availability concerns. Across all regions, feedwater for SMR shows nearly 50% lower impacts than for electrolysis. This study focuses solely on the environmental impacts associated with water sourcing and treatment for hydrogen production, excluding the downstream impacts of the hydrogen generation process itself. This study highlights the trade-offs between water sourcing, brine treatment, and freshwater purification for hydrogen production, offering insights for optimizing sustainable hydrogen systems in water-stressed regions. Full article

Solid oxide fuel cells (SOFCs) represent a pivotal technology in renewable energy due to their clean and efficient power generation capabilities. Their role in potential carbon mitigation enhances their viability. SOFCs can operate via a variety of alternative fuels, including hydrocarbons, alcohols, solid carbon, and ammonia. However, several solutions have been proposed to overcome various technical issues and to allow for stable operation in dry methane, without coking in the anode layer. To avoid coke formation thermodynamically, methane is typically reformed, contributing to an increased degradation rate through the addition of oxygen-containing gases into the fuel gas to increase the O/C ratio. The performance achieved by reforming catalytic materials, comprising active sites, supports, and electrochemical testing, significantly influences catalyst performance, showing relatively high open-circuit voltages and coking-resistance of the CH₄ reforming catalysts. In the next step, the operating principles and thermodynamics of methane reforming are explored, including their traditional catalyst materials and their accompanying challenges. This work explores the components and functions of SOFCs, particularly focusing on anode materials such as perovskites, Ruddlesden–Popper oxides, and spinels, along with their structure–property relationships, including their ionic and electronic conductivity, thermal expansion coefficients, and acidity/basicity. Mechanistic and kinetic studies of common reforming processes, including steam reforming, partial oxidation, CO₂ reforming, and the mixed steam and dry reforming of methane, are analyzed. Furthermore, this review examines catalyst deactivation mechanisms, specifically carbon and metal sulfide formation, and the performance of methane reforming and partial oxidation catalysts in SOFCs. Single-cell performance, including that of various perovskite and related oxides, activity/stability enhancement by infiltration, and the simulation and modeling of electrochemical performance, is discussed. This review also addresses research challenges in regards to methane reforming and partial oxidation within SOFCs, such as gas composition changes and large thermal gradients in stack systems. Finally, this review investigates the modeling of catalytic and non-catalytic processes using different dimension and segment simulations of steam methane reforming, presenting new engineering designs, material developments, and the latest knowledge to guide the development of and the driving force behind an oxygen concentration gradient through the external circuit to the cathode. Full article

This study employed a two-stage fixed-bed pyrolysis-reforming reactor to investigate H₂ production behaviors from municipal solid waste (MSW) and biomass with their self-derived catalysts under different operating parameters. The self-derived catalysts are prepared by mechanically mixing pyrolysis-derived chars with CaO and iron powders. The main results are as follows: (1) The higher oxygen content in biomass facilitates oxidative dehydrogenation reactions, enabling in situ generation of H₂O, which results in a higher H₂/CO ratio for biomass compared to MSW under steam-free conditions. (2) There are optimal values for the reforming temperature and steam-to-feedstock ratio (S/F) to achieve best performance. In the presence of steam, MSW generally exhibits superior H₂ and syngas production performance to biomass; (3) Both MSW char (MSWC)- and biomass char (BC)-based catalysts showed satisfied H₂ production and tar cracking performance at 850–900 °C, and the MSWC-based catalyst demonstrated better catalytic activity than the BC-based catalyst due to its higher contents of several active metals. In addition, the iron powder can be recycled easily, proving the effectiveness of the self-derived convenient and cheap catalysts. Full article

Hydrogen is an ideal feedstock fuel for solid oxide fuel cells (SOFCs). The steam reforming of methane (SRM) is the predominant method of producing hydrogen. However, the process of SRM relies on the involvement of a catalyst, and the reforming efficiency is constrained by the limited surface area in the traditional catalyst system. In this study, a mixer structure is applied to improve the mixing of the methane. Nano-sized pores are introduced to the struts of the mixer structure, forming a hierarchical structure, to effectively reduce the weight and increase the surface area of the self-catalytic reactors, hence increasing the catalytic efficiency. The hierarchical structure increases the reforming efficiency at all temperatures, and the level of improvement reaches its peak when the conversion rate of methane increases by 192% at 800 °C and by 40% at 900 °C compared to the self-catalyst without a hierarchical structure. Full article

Hydrogen is a clean, non-polluting fuel and a key player in decarbonizing the energy sector. Interest in hydrogen production has grown due to climate change concerns and the need for sustainable alternatives. Despite advancements in waste-to-hydrogen technologies, the efficient conversion of mixed plastic waste via an integrated thermochemical process remains insufficiently explored. This study introduces a novel multi-stage pyrolysis-reforming framework to maximize hydrogen yield from mixed plastic waste, including polyethylene (HDPE), polypropylene (PP), and polystyrene (PS). Hydrogen yield optimization is achieved through the integration of two water–gas shift reactors and a pressure swing adsorption unit, enabling hydrogen production rates of up to 31.85 kmol/h (64.21 kg/h) from 300 kg/h of mixed plastic wastes, consisting of 100 kg/h each of HDPE, PP, and PS. Key process parameters were evaluated, revealing that increasing reforming temperature from 500 °C to 1000 °C boosts hydrogen yield by 83.53%, although gains beyond 700 °C are minimal. Higher reforming pressures reduce hydrogen and carbon monoxide yields, while a steam-to-plastic ratio of two enhances production efficiency. This work highlights a novel, scalable, and thermochemically efficient strategy for valorizing mixed plastic waste into hydrogen, contributing to circular economy goals and sustainable energy transition. Full article

Iron-based oxygen carriers (OCs) have received much attention due to their low costs, high mechanical strengths and high-temperature stabilities in the chemical looping gasification (CLG) of biomass, but their chemical reactivity is very ordinary. Converter steel slags (CSSs) are steelmaking wastes and rich in Fe₂O₃, CaO and MgO, which have good oxidative ability and good stability as well as catalytic effects on biomass gasification. Therefore, the composite OCs prepared by mechanically mixing CSSs with iron-based OCs are expected to be used to increase the hydrogen production in the CLG of biomass. In this study, the catalytic performance of CSS/Fe₂O₃ composite OCs prepared by mechanically mixing CSSs with iron-based OCs on the gasification of brewers’ spent grains (BSGs) were investigated in a tubular furnace experimental apparatus. The results showed that when the weight ratio of the CSSs in composite OCs was 0.5, the relative volume fraction of hydrogen reached the maximum value of 49.1%, the product gas yield was 0.85 Nm³/kg and the gasification efficiency was 64.05%. It could be found by X-ray diffraction patterns and scanning electron microscope characterizations that the addition of CSSs helped to form MgFe₂O₄, which are efficient catalysts for H₂ production. Owing to the large and widely distributed surface pores of CSSs, mixing them with iron-based OCs was beneficial for catalytic steam reforming to produce hydrogen. Full article

Several Cu and Ni-based catalysts were synthetized over Ce-based supports, either pure or mixed with different amounts of alumina (1:2 and 1:3 mol/mol). Different metal loadings (10–40 wt%) and preparation methods (wet impregnation, co-precipitation, and flame-spray pyrolysis—FSP) were compared for the oxidative steam reforming of methanol. Characterization of the catalysts has been performed, e.g., through XRD, BET, XPS, TPR, SEM, and EDX analyses. All the catalysts have been tested in a bench-scale continuous setup. The hydrogen yield and methanol conversion obtained have been correlated with the operating conditions, metal content, crystallinity of the catalyst particles, total surface area, and with the interaction of the metal with the support. A Cu loading of 20% wt/wt was optimal, while the presence of alumina was not beneficial, decreasing catalyst activity at low temperatures compared with catalysts supported on pure CeO₂. Ni-based catalysts were a possible alternative, but the activity towards the methanation reaction at relatively high temperatures decreased inevitably the hydrogen yield. Durability and deactivation tests showed that the best-performing catalyst, 20% wt. Cu/CeO₂ prepared through coprecipitation was stable for a long period of time. Full methanol conversion was achieved at 280 °C, and the highest yield of H₂ was ca. 80% at 340 °C, higher than the literature data. Full article

Steam reforming is an effective method for improving heat sinks of hypersonic aircraft at high flight Mach numbers. However, unlike the industrial process of producing hydrogen with a high water content, the catalytic steam reforming mechanism for the regeneration cooling process of hydrocarbon fuels with a water content below 30% is still unclear. Catalytic steam reforming (CSR) and catalytic thermal cracking (CTC) reactions occur at low temperatures, with the main products being hydrogen and carbon oxides. Thermal cracking (TC) reactions occur at high temperatures, with the main products being alkanes and alkenes. The above reaction exists simultaneously in the regeneration cooling channel, which is referred to as partial catalytic steam reforming (PCSR). Based on the experimental measurement results, an improved neural network correction method was used to establish a four-step global reaction model for the PCSR of n-decane under low water conditions. The reliability of the four-step model was verified by combining the model with a numerical simulation program and comparing it with the experimental results obtained by electric heating hydrocarbon fuels with a pressure of 3 MPa and a water content of 5/10/15%. The experimental and predicted results using the developed kinetic model are consistent with an error of less than 5% in the decane conversion rate. The average absolute error between the fuel outlet temperature and total heat sink is less than 10%. Using the PCSR model to predict the heat transfer characteristics of mixed fuels with different water contents, the convective heat transfer coefficient is basically the same, and the Nu number is affected by the thermal conductivity coefficient, showing different patterns with changes in the water content. Full article

The global energy market is shifting toward renewable, sustainable, and low-carbon hydrogen energy due to global environmental issues, such as rising carbon dioxide emissions, climate change, and global warming. Currently, a majority of hydrogen demands are achieved by steam methane reforming and other conventional processes, which, again, are very carbon-intensive methods, and the hydrogen produced by them needs to be purified prior to their application. Hence, researchers are continuously endeavoring to develop sustainable and efficient methods for hydrogen generation and purification. Membrane-based gas-separation technologies were proven to be more efficient than conventional technologies. This review explores the transition from conventional separation techniques, such as pressure swing adsorption and cryogenic distillation, to advanced membrane-based technologies with high selectivity and efficiency for hydrogen purification. Major emphasis is placed on various membrane materials and their corresponding membrane performance. First, we discuss various metal membranes, including dense, alloyed, and amorphous metal membranes, which exhibit high hydrogen solubility and selectivity. Further, various inorganic membranes, such as zeolites, silica, and CMSMs, are also discussed. Major emphasis is placed on the development of polymeric materials and membranes for the selective separation of hydrogen from CH₄, CO₂, and N₂. In addition, cutting-edge mixed-matrix membranes are also delineated, which involve the incorporation of inorganic fillers to improve performance. This review provides a comprehensive overview of advancements in gas-separation membranes and membrane materials in terms of hydrogen selectivity, permeability, and durability in practical applications. By analyzing various conventional and advanced technologies, this review provides a comprehensive material perspective on hydrogen separation membranes, thereby endorsing hydrogen energy for a sustainable future. Full article

Copper-based catalysts are widely used in methanol steam reforming to produce hydrogen. In this paper, the supportive effect of the crystal phase of ZrO₂ on Cu-based catalysts in methanol steam reforming is discussed. Monoclinic(m-), Tetragonal(t-) and mixed ZrO₂ phases were prepared, and structure–activity relationships were investigated with XRD, H₂-TPR, BET, HR-TEM and XPS. It was found that the catalyst with a 81.4% monoclinic ZrO₂ crystal phase exhibited the highest methanol conversion (88.5%) and the highest hydrogen production rate (104.6 μmol/g_cat·s) at 275 °C as it displayed the best reducing properties and more oxygen vacancies on the catalyst surface. Oxygen vacancies can produce more Cu¹⁺ + Cu⁰, which is the active species for methanol steam reforming on the catalyst surface, and therefore affect catalytic activity. Full article

Catalytic studies hydrogen production via steam reforming of ethanol (SRE) are essential for process optimization. Likewise, selecting the ideal support for the active phase can be critical to achieve high conversion rates during the catalytic steam reforming process. In this work, copper-based catalysts were synthesized using two different supports, NaY zeolite and Nb₂O₅/Al₂O₃ mixed oxides. The materials were prepared using wet impregnation and characterized for their physicochemical properties using different analytical techniques. Differences in the catalyst morphologies were readily attributed to the characteristics of the support. The Cu/NaY catalyst exhibited a higher specific surface area (210.40 m² g⁻¹) compared to the Cu/Nb₂O₅/Al₂O₃ catalyst (26.00 m² g⁻¹), resulting in a homogeneous metal dispersion over the support surface. The obtained results showed that, at 300 °C, both the Cu/Nb₂O₅/Al₂O₃ and Cu/NaY catalysts produced approximately 50% hydrogen and 40% acetaldehyde, but with significant differences in conversion (6% and 56%, respectively). At 450 °C, a greater product distribution and a 10% higher conversion were observed when the catalyst was supported on NaY compared to Nb₂O₅/Al₂O₃. Hence, the performance of copper-based catalysts was influenced significantly by the textural properties of the support. Full article

In this study, vermiculite was explored as a support material for nickel catalysts in two key processes in syngas production: dry reforming of methane with CO₂ and steam reforming of ethanol. The vermiculite underwent acid or base treatment, followed by the preparation of Ni catalysts through incipient wetness impregnation. Characterization was conducted using various techniques, including X-ray diffraction (XRD), SEM–EDS, FTIR, and temperature-programmed reduction (H₂-TPR). TG-TD analyses were performed to assess the formation of carbon deposits on spent catalysts. The Ni-based catalysts were used in reaction tests without a reduction pre-treatment. Initially, raw vermiculite-supported nickel showed limited catalytic activity in the dry reforming of methane. After acid (Ni/VTA) or base (Ni/VTB) treatment, vermiculite proved to be an effective support for nickel catalysts that displayed outstanding performance, achieving high methane conversion and hydrogen yield. The acidic treatment improved the reduction of nickel species and reduced carbon deposition, outperforming the Ni over alkali treated support. The prepared catalysts were also evaluated in ethanol steam reforming under various conditions including temperature, water/ethanol ratio, and space velocity, with acid-treated catalysts confirming the best performance. Full article

To reduce air pollution worldwide, regulations on exhaust gas emissions from ships are becoming increasingly stringent. One fuel that is being considered as an alternative to replace the heavy fuel oil used in existing ship engines and thereby reduce harmful emissions, such as NO_x, SO_x, and greenhouse gases, is sulfur-free liquefied petroleum gas (LPG). To assess the viability of this alternative, it is necessary to understand propane reactivity, the main component of LPG, and develop after-treatment devices applicable to LPG engines. This research evaluated the performance of three prototype Pd-based three-way catalysts (TWCs) with varying Pd loadings (6.5, 4.1, and 1.4 g/L), focusing on their effectiveness concerning propane reactivity in LPG engines. For the fresh samples, catalysts with 4.1 g/L Pd demonstrated performance that was comparable to, or even surpassed, those containing 6.5 g/L Pd. Notably, the temperature of 50% conversion (T₅₀) for NO and C₃H₈ in the fresh Pd-4.1 was lower by 14 °C and 10 °C, respectively, compared to the fresh Pd-6.5 sample, despite having 37% less precious-metal loading. However, after hydrothermal aging at 900 °C for 100 h, the performance of the 4.1 g/L Pd catalyst significantly deteriorated, exhibiting lower efficiency than the 6.5 g/L Pd catalyst. The study also delved into various probe reactions, including the water–gas shift and propane steam reforming. Advanced analytical techniques, such as N₂ physisorption and scanning transmission electron microscopy, were employed to elucidate the texture and structural characteristics of the catalyst, providing a comprehensive understanding of its behavior and potential applications. Through this research, within the efforts of the maritime sector to address challenges posed by emission regulations and rising costs associated with precious metals, this study has the potential to contribute to the development of cost-effective emission control solutions. Full article

Hydrogen as an energy vector is going to play an important role in the global energy mix. On the other hand, wastewater management has become a worldwide concern, as urban settlements have been considerably increasing for decades. Consequently, biodigestion to produce biogas (rich in methane) in water treatment plants could be an interesting starting point to obtain a valuable gas that can be converted into hydrogen through steam reforming. The aim of this work was to review the main aspects concerning steam reforming of biogas from wastewater treatment plants. For this purpose, the whole chain, from water treatment to hydrogen production and purification, was considered, paying attention to the main challenges and new technologies for its optimization. Thus, a wide range of possibilities is offered, from direct energy use of syngas to high purification of hydrogen (mainly through pressure swing adsorption or membrane reactors), presenting advantages and disadvantages. In any case, the role of catalysts seems to be essential, and aspects such as hydrogen sulfide and coke deposition control should be addressed. In conclusion, biogas steam reforming applied to wastewater treatment plants is a reality, with serious possibilities for its global implementation at the industrial level, according to techno-economic assessment. Full article

Hydrogen is an essential vector for transitioning today’s energy system. As a fuel or reactant in critical industrial sectors such as transportation and metallurgy, H₂ can diversify the energy mix and supply and provide an opportunity to mitigate greenhouse-gas emissions. The pyrolysis of methane in liquid catalysts represents a promising alternative to producing hydrogen, as its energy demand is comparable to steam methane reforming, and no CO₂ is produced in the base reaction. In this work, methane pyrolysis experiments were conducted using a graphite crucible filled with liquid ternary Cu-Ni-Sn alloys at 1160.0 °C. A statistical design of experiments allowed the generation of a model equation that predicts the achievable conversion rates in the ranges of the experiments. Furthermore, the experimental results are evaluated considering densities as well as surface tensions and viscosities in the investigated system, calculated with Butler and KRP equations, respectively. The highest methane conversion rate of 40.15% was achieved utilizing a melt of pure copper. The findings show that a combination of high catalytic activity with a high density and a low viscosity and surface tension of the melt results in a higher hydrogen yield. Furthermore, the autocatalytic effect of pyrolysis carbon is measured. Full article