Search Results (954)

The Cau River Basin in northeastern Vietnam is an ecologically and economically important watershed, yet it has lacked comprehensive hydrological modelling to date. Characterised by highly complex topography, diverse land use/land cover, and limited hydrometeorological data, the basin presents challenges for water resource assessment and management. This study applies the SWAT hydrological model to simulate streamflow dynamics in the Cau River Basin over a 31-year period (1990–2020) using multiple-source geospatial data, including a 30 m digital elevation model, official soil and land use maps, and daily climate records from six meteorological stations. Model calibration (1997–2008) and validation (2009–2020) were conducted using the SWAT-CUP tool, achieving strong performance with a Nash–Sutcliffe Efficiency (NSE) of 0.95 and 0.90, and R² of 0.95 and 0.91, respectively. Sensitivity analysis identified four key parameters most influential on streamflow (curve number, saturated hydraulic conductivity, soil evaporation compensation factor, and available water capacity), supporting a more focused and effective calibration process. Model results revealed substantial spatio-temporal variability in runoff, with annual surface runoff ranging from 19.8 mm (2011) to 56.4 mm (2013), generally lower in upstream sub-watersheds (<30 mm) and higher in downstream areas (>60 mm). The simulations also showed a clear seasonal contrast between the wet and dry periods. These findings support evidence-based strategies for flood and drought mitigation, inform agricultural and land use planning, and offer a transferable modelling framework for similarly complex watersheds. Full article

This study investigates the production and economic feasibility of biochar for smallholder and family farms in Central Amazonia, with potential implications for other tropical regions. The costs of construction of a prototype mobile kiln and biochar production were evaluated, using small-sized biomass from acai (Euterpe oleracea Mart.) agro-industrial residues as feedstock. The biochar produced was characterised in terms of its liming capacity (calcium carbonate equivalence, CaCO_3eq), nutrient content via organic fertilisation methods, and ash analysis by ICP-OES. Field trials with cowpea assessed economic outcomes, as well scenarios of fractional biochar application and cost comparison between biochar production in the prototype kiln and a traditional earth-brick kiln. The prototype kiln showed production costs of USD 0.87–2.06 kg⁻¹, whereas traditional kiln significantly reduced costs (USD 0.03–0.08 kg⁻¹). Biochar application alone increased cowpea revenue by 34%, while combining biochar and lime raised cowpea revenues by up to 84.6%. Owing to high input costs and the low value of the crop, the control treatment generated greater net revenue compared to treatments using lime alone. Moreover, biochar produced in traditional kilns provided a 94% increase in net revenue compared to liming. The estimated externalities indicated that carbon credits represented the most significant potential source of income (USD 2217 ha⁻¹). Finally, fractional biochar application in ten years can retain over 97% of soil carbon content, demonstrating potential for sustainable agriculture and carbon sequestration and a potential further motivation for farmers if integrated into carbon markets. Public policies and technological adaptations are essential for facilitating biochar adoption by small-scale tropical farmers. Full article

Metro carriages, as enclosed transport microenvironments, have been understudied regarding pollution characteristics and health risks from ACs, especially during high-temperature summers that amplify exposure. This study applied NTS techniques for the first time across three major Chengdu metro lines, systematically identifying sixteen ACs, including hazardous species such as acetophenone, benzonitrile, and benzoic acid that are often overlooked in conventional BTEX-focused monitoring. The TAC concentration reached 41.40 ± 5.20 µg/m³, with half of the compounds exhibiting significant increases during peak commuting periods. Source apportionment using diagnostic ratios and PMF identified five major contributors: carriage material emissions (36.62%), human sources (22.50%), traffic exhaust infiltration (16.67%), organic solvents (16.55%), and industrial emissions (7.66%). Although both non-cancer (HI) and cancer (TCR) risks for all population groups were below international thresholds, summer tourists experienced higher exposure than daily commuters. Notably, child tourists showed the greatest vulnerability, with a TCR of 5.83 × 10⁻⁷, far exceeding that of commuting children (1.88 × 10⁻⁷). Benzene was the dominant contributor, accounting for over 50% of HI and 70% of TCR. This study presents the first integrated NTS and quantitative risk assessment to characterise ACs in summer metro environments, revealing a broader range of hazardous compounds beyond BTEX. It quantifies population-specific risks, highlights children’s heightened vulnerability. The findings fill critical gaps in ACs exposure and provide a scientific basis for improved air quality management and pollution mitigation strategies in urban rail transit systems. Full article

The complex plant cell wall heteropolysaccharide xylan, and its breakdown products xylo-oligosaccharides and xylose, are value-added compounds with a plethora of potential applications in diverse areas. They are nonetheless currently poorly exploited, with a major bottleneck being the unavailability of efficient, low-cost, high-yield production processes. The major objective of the present study is to identify and characterise a high-yield process for the preparation of highly pure xylan/XOS products from the macroalga Palmaria palmata. Currently, most xylan is extracted from land-sourced lignocellulosic feedstocks, but we take advantage of the high xylan content, xylan aqueous solubility, lignin-free nature, weakly linked cell wall matrix, and sustainability of the macroalga to identify a simple, sustainable, high-yield, novel-xylan-structure extraction process. This is composed of five steps: alga oven drying, milling, aqueous extraction, centrifugation, and dialysis, and we show that the alga preservation step plays a critical role in component extractability, with oven drying at high temperatures, ~100 °C, enhancing the subsequent aqueous extraction process, and providing for xylan yields as high as 80% of a highly pure (~90%) xylan product. The process developed herein and the insights gained will promote a greater availability of these bioactive compounds and open up their application potential. Full article

In this study, we examined the microclimates at eight entrances to a karst system distributed between an elevation of 812 and 906 m in Southern Spain. The karst system, characterised by subvertical open tectonic joints that form narrow shafts, developed on the slope of a mountainous area with a Mediterranean climate and strong chimney effect, resulting in an intense airflow throughout the year. The airflows modify the entrance temperatures, creating a distinctive pattern in each opening that changes with the seasons. The objective of this work is to characterise the outflows and find simple temperature-based parameters that provide information about the karst interior. The entrances were monitored for five years (2017–2022) with temperature–humidity dataloggers at different depths. Other data collected include discrete wind measurements and outside weather data. The most significant parameters identified were the characteristic temperature (T_y), recorded at the end of the outflow season, and the rate of cooling/warming, which ranges between 0.1 and 0.9 °C/month. These parameters allowed the entrances to be grouped based on the efficiency of heat exchange between the outside air and the cave walls, which depends on the rock-boundary geometry. This research demonstrates that simple temperature studies with data recorded at selected positions will allow us to understand geometric aspects of inaccessible karst systems. Dynamic high-airflow cave systems could become a natural source of evidence for climate change and its effects on the underground world. Full article

The agro-industrial sector produces large amounts of by-products that have a high environmental impact, so it has become essential to recover food waste at all levels. This is because it often contains bioactive molecules that can be a valuable source of new products such as animal feed, biopolymers, or products for human use, (e.g., cosmetics and nutraceuticals) due to its antioxidant, antimicrobial, and anti-inflammatory properties. Advanced analytical methodologies such as liquid chromatography coupled to mass spectrometry (LC-MS) are crucial for the characterisation of bioactive chemicals in these waste materials. LC-MS enables both targeted and untargeted metabolomic approaches, facilitating the identification and quantification of a wide range of secondary metabolites, including polyphenols, flavonoids, alkaloids, and terpenoids. The choice of extraction methodology is essential for the precise identification and quantification of these metabolites. This study provides an overview of LC-MS as an effective tool for analysing complex extracts derived from plant waste, discussing both methodological aspects and typical bioactive metabolites identified, and offering examples of their potential applications in cosmeceutics. Full article

The increase in power generation facilities from nonprogrammable renewable sources is posing several challenges for the management of electrical systems, due to phenomena such as congestion and reverse power flows. In mitigating these phenomena, Power-to-Gas plants can make an important contribution. In this paper, a linear optimisation study is presented for the sizing of a Power-to-Hydrogen plant consisting of a PEM electrolyser, a hydrogen storage system composed of multiple compressed hydrogen tanks, and a fuel cell for the eventual reconversion of hydrogen to electricity. The plant was sized with the objective of minimising reverse power flows in a medium-voltage distribution network characterised by a high presence of photovoltaic systems, considering economic aspects such as investment costs and the revenue obtainable from the sale of hydrogen and excess energy generated by the photovoltaic systems. The study also assessed the impact that the electrolysis plant has on the power grid in terms of power losses. The results obtained showed that by installing a 737 kW electrolyser, the annual reverse power flows are reduced by 81.61%, while also reducing losses in the transformer and feeders supplying the ring network in question by 17.32% and 29.25%, respectively, on the day with the highest reverse power flows. Full article

Stylistic neutrality is the basis for the stylistic evaluation of maps. Furthermore, the stylistic neutrality of a map as a cartographic text may be related to objectivity. However, what constitutes stylistic neutrality is not clearly stated in the field of cartography. The problem is complicated by the fact that the stylistically neutral image is a hypothetical image. The aim of this research is to investigate stylistic neutrality by exploring the peculiarities of cartographic language functioning in different fields of social activity. The research combines descriptive analysis, stylistic analysis, cartographic and interpretative methods. Firstly, the research reveals the concept of cartographic stylistic neutrality, in line with the cartographic linguistic paradigm. Secondly, an analysis of the characteristics of cartographic language in different fields of social activity from the point of view of stylistic neutrality is carried out. Thirdly, an example is developed to illustrate stylistic cartographic neutrality. Stylistic neutrality is characterised by the stylistic features of cartographic language: clarity, accuracy, conciseness, calmness, abstractness, temperance, neutrality and moderateness. The style of cartographic production for inventory and research activities is closest to stylistic neutrality, while the style of reflective activity is the most expressive and acts as a source of concreteness for stylistic neutrality. Full article

The environmental impact of petroleum-based plastics has driven a global shift toward sustainable alternatives like biodegradable polymers, including polylactic acid (PLA), polybutylene succinate (PBS), and polycaprolactone (PCL). Yet, these bioplastics often face limitations in mechanical and thermal properties, hindering broader use. Reinforcement with cellulose nanofibrils (CNFs) has shown promise, yet most research focuses on conventional sources like wood pulp and cotton, neglecting agricultural residues. This review addresses the potential of maize husk, a lignocellulosic waste abundant in South Africa, as a source of CNFs. It evaluates the literature on the structure, extraction, characterisation, and integration of maize husk-derived CNFs into biodegradable polymers. The review examines the chemical composition, extraction methods, and key physicochemical properties that affect performance when blended with PLA, PBS, or PCL. However, high lignin content and heterogeneity pose extraction and dispersion challenges. Optimised maize husk CNFs can enhance the mechanical strength, barrier properties, and thermal resistance of biopolymer systems. This review highlights potential applications in packaging, biomedical, and agricultural sectors, aligning with South African bioeconomic goals. It concludes by identifying research priorities for improving compatibility and processing at an industrial scale, paving the way for maize husk CNFs as effective, locally sourced reinforcements in green material innovation. Full article

Background: Myocarditis and pericarditis are recognised risks following COVID-19 vaccination, including the mRNA-1273 vaccine. Most cases occur shortly following the second dose of this vaccine, and incidence is highest among young males. However, little is known about risk factors beyond age and sex and about the longer-term clinical course. This study aims to identify possible risk factors for myocarditis and pericarditis following mRNA-1273 vaccination, to characterise the clinical course of myocarditis and pericarditis, both associated with mRNA-1273 vaccination and not associated with vaccination, and to identify risk factors for severe outcomes (i.e., cardiac or thromboembolic complications, severe hospital outcomes, all-cause hospital readmission, and death). Methods: This study is being conducted within the Vaccine Monitoring Collaboration for Europe (VAC4EU) association using routinely collected healthcare data from five data sources from four European countries (Denmark, Norway, Spain, and the United Kingdom). The study is being performed using a common data model, and all analyses are performed separately in each data source in a federated manner following a common protocol. A case–cohort analysis set is identified within each data source for identifying potential risk factors for myocarditis and pericarditis following mRNA-1273 vaccination using logistic regression analysis. The clinical course of myocarditis and pericarditis is being assessed using a cohort study design and describes all cases (i.e., cases associated with mRNA-1273 and unexposed cases). Cox regression analysis is applied to assess the associations between risk factors and several follow-up outcomes. Conclusions: This protocol describes the study methodology of an international collaborative initiative with the aim of assessing the risk factors and clinical course of myocarditis and pericarditis following mRNA-1273 vaccination using a federated network of five European data sources. Full article

Homelessness is characterised by a wide range of risk factors of a multidimensional and unstable nature. The COVID-19 pandemic intensified these risk factors associated with homelessness but also prompted the development of prevention and care actions. This study identified and mapped the intervention programmes carried out for people experiencing homelessness in the wake of the COVID-19 pandemic. To achieve the study purpose, a thematic analysis of the scientific literature was conducted following the search strategy and analysis methodology characteristic of informetrics and scientometrics. The sources of information used were WoS, Scopus, PubMed, PsycINFO and ERIC. The paucity of planned actions, most of which have a local impact, reinforces the need to strengthen research that presents robust evidence on this issue. China and Europe are under-represented compared to other types of studies linked to COVID-19 and the prevalence of homelessness. Several clusters are distinguished among the plans: they are carried out in buildings or in geographical areas and according to the impact on the group (preventive, substance-related disorder support, health care and diagnostic). Among the emerging themes, health and social variables are represented, including communication and trust between health, community and homeless groups. The reduction in the thematic dimensionality shows equal planning between health care actions (81.8%) and psychosocial and prevention support (72.8%), an aspect that confirms the importance of joint actions. In this line, among the various clusters of the network analysis, the relationship between hotel, mental health support, substance-related disorder, social intervention and access to permanent housing was found. The studies analysed also highlight social exclusion, stigma, victimisation, living conditions and the risk of contagion among this group. This situation has not gone unnoticed among the studies analysed, which present proposals for the continuation of the projects. Full article

Background/Objectives: Endophytic fungi are valuable sources of bioactive compounds with potential therapeutic applications. This study aimed to evaluate the antifungal activity of secondary metabolites produced by Fusarium sp. isolated from Dizygostemon riparius, with particular focus on the impact of culture medium supplementation with halogenated and metallic additives on metabolite production. Methods: The fungus was cultivated in standard Czapek medium and media supplemented with NH₄Br or MnCl₂. Methanolic extracts were obtained, fractionated, and chemically characterised via LC-ESI-HRMS. In vitro antifungal assays, including MIC and MFC determinations and biofilm inhibition tests, were performed against Candida albicans strains. In vivo toxicity and efficacy were assessed using Tenebrio molitor larvae. Results: Fifteen metabolites were annotated, including known antifungals such as fusaric acid and cyclosporin A. Fractions EMBr4 and EMC5 demonstrated fungicidal activity with MIC values close to fluconazole and significantly inhibited biofilm formation and maturation. In vivo, these fractions displayed low acute toxicity and improved survival in infected larvae, comparable to fluconazole treatment. Conclusions: The results indicate that culture medium modulation enhances the production of bioactive metabolites by Fusarium sp., leading to extracts with notable antifungal efficacy and safety. EMBr4 and EMC5 are promising candidates for further development as antifungal agents, particularly for targeting biofilm-associated Candida infections. These findings support the potential of endophytic fungi as sources of novel therapeutics and warrant further mechanistic and pharmacological investigations. Full article

Electric vehicles (EVs) have introduced new operational challenges for distribution network service providers (DNSPs), particularly for voltage regulation due to unpredictable charging behaviour and the intermittent nature of distributed energy resources (DERs). This study focuses on formulating an empirical EV load model that characterises charging behaviour over a broad spectrum of supply voltage magnitudes to enable more accurate representation of EV demand under varying grid conditions. The empirical model is informed by laboratory evaluation of one Level 1 and two Level 2 chargers, along with five EV models. The testing revealed that all the chargers operated in a constant current (CC) mode across the applied voltage range, except for certain Level 2 chargers, which transitioned to constant power (CP) operation at voltages above 230 V. A model of a typical low voltage network has been developed using the OpenDSS software package (version 10.2.0.1) to evaluate the performance of the proposed empirical load model against traditional CP load modelling. In addition, a 24 h case study is presented to provide insights into the practical implications of increasing EV charging load. The results demonstrate that the CP model consistently overestimated network demand and voltage drops and failed to capture the voltage-dependent behaviour of EV charging in response to source voltage change. In contrast, the empirical model provided a more realistic reflection of network response, offering DNSPs improved accuracy for system planning. Full article

A multiproxy methodology has been employed to characterise two granite anchors discovered on the seabed near the island of Nueva Tabarca (Alicante, Southeast Spain). According to the significant archaeological context where they were found, the studied anchors can be dated from the Roman ages (late Republican period). One of the most interesting aspects is the absence of regional geological outcrops with rocks compatible with the granite used in the production of the anchor, which shows a foreign origin consistent with the connection of the anchor to maritime transport across the Mediterranean Sea. The lack of precise information about the artifact’s origin underscores the interest and need for the application of petrological techniques to determine its provenance. The methodology utilised encompasses five distinct techniques: (1) non-destructive textural analysis using X-ray microcomputed tomography; (2) K–Ar dating; (3) petrological characterisation through optical microscopy; (4) geochemical characterisation using X-ray fluorescence and atomic absorption spectrometry. The results allow for a comparison of the anchor rock’s characteristics with various granite outcrops along the Mediterranean coasts (Eastern, Central, and Western sectors), suggesting potential source areas based on petrological compatibility with the material under study. The findings point to the origin of the Nueva Tabarca granite anchor being granite outcrops in Southern Italy (Calabria), reinforcing the connection between the Spanish southeastern coasts and Southern Italy. These results highlight the utility and significance of multiproxy petrological methodologies in the geoarchaeological study of decontextualised artifacts. Full article

This paper addresses the critical need for detailed electricity and peak power demand maps for urban public transportation vehicles. Current approaches often rely on overly general assumptions, leading to considerable errors in specific applications or, conversely, overly specific measurements that limit generalisability. We aim to present a comprehensive data-driven methodology for analysing energy consumption within a large urban agglomeration. The method leverages a unique and extensive set of real-world performance data, collected over two years from onboard recorders on all public bus lines in the Capital City of Warsaw. This large dataset enables a robust probabilistic analysis, ensuring high accuracy of the results. For this study, three representative bus lines were selected. The approach involves isolating inter-stop trips, for which instantaneous power waveforms and energy consumption are determined using classical mathematical models of vehicle drive systems. The extracted data for these sections is then characterised using probability distributions. This methodology provides accurate calculation results for specific operating conditions and allows for generalisation with additional factors like air conditioning or heating. The direct result of this paper is a detailed urban map of energy demand and peak power for public transport vehicles. Such a map is invaluable for planning new traffic routes, verifying existing ones regarding energy consumption, and providing a reliable input source for strategic charger deployment analysis along the route. Full article