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Keywords = solid-core heat transfer model

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23 pages, 3097 KB  
Article
Preliminary Neutronic Design and Thermal-Hydraulic Feasibility Analysis for a Liquid-Solid Space Reactor Using Cross-Shaped Spiral Fuel
by Zhichao Qiu, Kun Zhuang, Xiaoyu Wang, Yong Gao, Yun Cao, Daping Liu, Jingen Chen and Sipeng Wang
Energies 2026, 19(7), 1811; https://doi.org/10.3390/en19071811 - 7 Apr 2026
Abstract
As the key technology of space exploration, space power has been a major area of international research focus. A lot of research work has been carried out around the world for the space nuclear reactor using the heat pipe, liquid metal and gas [...] Read more.
As the key technology of space exploration, space power has been a major area of international research focus. A lot of research work has been carried out around the world for the space nuclear reactor using the heat pipe, liquid metal and gas cooling methods. With the development of molten salt reactor in the Generation IV reactor system, molten salt dissolving fissile material and acting as a coolant at the same time has become a new cooling scheme, which provides new ideas for the design of space nuclear reactors. In this study, a novel reactor, the liquid-solid dual-fuel space nuclear reactor (LSSNR) was preliminarily proposed, combining the molten salt fuel and cross-shaped spiral solid fuel to achieve the design goals of 30-year lifetime and an active core weight of less than 200 kg. Monte Carlo neutron transport code OpenMC based on ENDF/B-VII.1 library was employed for neutronics design in the aspect of fuel type, cladding material, reflector material and the spectral shift absorber. Then, the thickness of the control drum absorber was optimized to meet the requirement of the sufficient shutdown margin, lower solid fuel enrichment, and 30-effective-full power-years (EFPY) operation lifetime. Finally, UC solid fuel with U-235 enrichment of 80.98 wt.% and B4C thickness of 0.75 cm were adopted in LSSNR, and BeO was adopted as the reflector and the matrix material of the control drum. A spectral shift absorber Gd2O3 was used to avoid the subcritical LSSNR returning to criticality in a launch accident. The keff with the control drum in the innermost position is 0.954949, and the keff reaches 1.00592 after 30 EFPY of operation. The total mass of the active core is 158.11 kg. In addition, the thermal-hydraulic feasibility of LSSNR using cross-shaped spiral fuel was analyzed based on a 4/61 reactor core model. The structure of cross-shaped spiral fuel achieves enhanced heat transfer by generating turbulence, which leads to a uniform temperature distribution of the coolant flow field and reduces local temperature peaks. Based on the LSSNR scheme, some neutronic characteristics were analyzed. Results demonstrate that the LSSNR has strongly negative reactivity coefficients due to the thermal expansion of liquid fuel, and the fission gas-induced pressure meets safety requirements. One hundred years after the end of core life, the total radioactivity of reactor core is reduced by 99% and is 7.1305 Ci. Full article
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31 pages, 6152 KB  
Article
Enhanced Structural Decoupling and Spatiotemporal Evolution of Thermal–Mass Coupling in LaNi5-Based Solid-State Hydrogen Storage Reactors
by Tao Wu, Yayi Wang, Yuhang Liu, Yong Gao, Rengen Ding and Jian Miao
Materials 2026, 19(7), 1308; https://doi.org/10.3390/ma19071308 - 26 Mar 2026
Viewed by 311
Abstract
Hydrogen energy is pivotal to the global energy transition, and the development of high-efficiency, safe hydrogen storage technologies constitutes a prerequisite for its large-scale commercialization. Kinetic bottlenecks including slow reactions, delayed front propagation, and marked spatial heterogeneity driven by strong thermal–mass transfer coupling [...] Read more.
Hydrogen energy is pivotal to the global energy transition, and the development of high-efficiency, safe hydrogen storage technologies constitutes a prerequisite for its large-scale commercialization. Kinetic bottlenecks including slow reactions, delayed front propagation, and marked spatial heterogeneity driven by strong thermal–mass transfer coupling restrict the engineering application of solid-state metal hydrides. However, the current research mainly focusing on overall performance lacks a systematic understanding of the spatiotemporal evolution mechanisms and their intrinsic links to internal structural control. In this work, a 3D multiphysics model of a LaNi5-based reactor is developed to systematically elucidate spatiotemporal evolution patterns, facilitating the proposal of a structural decoupling framework based on synergistic thermal–mass resistance reconfiguration. Both absorption and desorption show distinct three-stage evolution, shifting from kinetic dominance to transfer limitation: absorption causes core self-inhibition via heat-hydrogen supply mismatch, leading to much lower core than surface storage capacity; desorption results in significant inner-layer lag due to endothermic cooling-driven pressure drops. Thermal–mass coupling-induced inverted spatiotemporal evolution is identified as the root cause of spatial heterogeneity. Quantitative comparison of straight-pipe, spiral-tube, and honeycomb structures reveals that internal architectures achieve effective thermal–mass decoupling through expanded heat-exchange areas, reconstructed diffusion pathways, and optimized heat source distribution. Notably, the honeycomb structure with a parallel micro-unit network achieves 89.1% and 86.6% reductions in absorption and desorption times, respectively, showing superior dynamic performance and field uniformity. This study provides a theoretical basis for the mechanism-driven design and synergistic performance optimization of high-efficiency solid-state hydrogen storage reactors. Full article
(This article belongs to the Section Energy Materials)
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20 pages, 5719 KB  
Article
Heat Transfer and Thermo-Mechanical Analysis of Plastic-Strain Evolution in Laser-Welded Thin-Walled Laminated Cooling Plates with Non-Uniform Stiffness
by Chengkun Li, Yujia Cai, Han Wang, Zhihang Zhang, Fang Han, Xiaoqing Zhu, Chengcheng Wang and Zhibo Dong
Energies 2026, 19(6), 1536; https://doi.org/10.3390/en19061536 - 20 Mar 2026
Viewed by 218
Abstract
Thin-walled laminated cooling plates integrate internal channels and pin-fin cores, producing reduced and spatially non-uniform stiffness that changes welding restraint and distortion. This study investigates stiffness-controlled plastic-strain evolution in laser butt welding of GH3230 laminated plates, with geometrically identical solid plates as reference. [...] Read more.
Thin-walled laminated cooling plates integrate internal channels and pin-fin cores, producing reduced and spatially non-uniform stiffness that changes welding restraint and distortion. This study investigates stiffness-controlled plastic-strain evolution in laser butt welding of GH3230 laminated plates, with geometrically identical solid plates as reference. A coupled heat-transfer and thermo-mechanical finite element model was developed in MSC Marc using a composite Gaussian surface–volumetric moving heat source and temperature-dependent properties. The thermal solution was validated against near-weld thermal cycles and fusion geometry; mechanical predictions were evaluated by CMM distortion and residual-stress measurements. Both structures show comparable residual-stress magnitudes and spatial trends, indicating that residual stress is governed mainly by the local weld thermal gradient. In contrast, the laminated plate exhibits larger angular/bending distortion. Simulations show that, although the plastic-strain pattern is similar, the laminated plate develops higher peak plastic strain confined to a narrower band near the weld, with the transverse plastic strain dominating. Plastic strain–temperature paths reveal continued transverse plastic-strain accumulation during cooling with limited recovery, consistent with restraint redistribution induced by stiffness non-uniformity. An equivalent restraint–stiffness spring model explains this “narrower-but-stronger” plastic zone and links stiffness to yielding and residual plastic-strain magnitude, supporting distortion prediction and stiffness-informed control of welded laminated cooling plates. Full article
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23 pages, 7133 KB  
Article
Energy Transfer Characteristics of Surface Vortex Heat Flow Under Non-Isothermal Conditions Based on the Lattice Boltzmann Method
by Qing Yan, Lin Li and Yunfeng Tan
Processes 2026, 14(2), 378; https://doi.org/10.3390/pr14020378 - 21 Jan 2026
Cited by 6 | Viewed by 323
Abstract
During liquid drainage from intermediate vessels in various industrial processes such as continuous steel casting, aircraft fuel supply, and chemical separation, free-surface vortices commonly occur. The formation and evolution of these vortices not only entrain surface slag and gas, but also lead to [...] Read more.
During liquid drainage from intermediate vessels in various industrial processes such as continuous steel casting, aircraft fuel supply, and chemical separation, free-surface vortices commonly occur. The formation and evolution of these vortices not only entrain surface slag and gas, but also lead to deterioration of downstream product quality and abnormal equipment operation. The vortex evolution process exhibits notable three-dimensional unsteadiness, multi-scale turbulence, and dynamic gas–liquid interfacial changes, accompanied by strong coupling effects between temperature gradients and flow field structures. Traditional macroscopic numerical models show clear limitations in accurately capturing these complex physical mechanisms. To address these challenges, this study developed a mesoscopic numerical model for gas-liquid two-phase vortex flow based on the lattice Boltzmann method. The model systematically reveals the dynamic behavior during vortex evolution and the multi-field coupling mechanism with the temperature field while providing an in-depth analysis of how initial perturbation velocity regulates vortex intensity and stability. The results indicate that vortex evolution begins near the bottom drain outlet, with the tangential velocity distribution conforming to the theoretical Rankine vortex model. The vortex core velocity during the critical penetration stage is significantly higher than that during the initial depression stage. An increase in the initial perturbation velocity not only enhances vortex intensity and induces low-frequency oscillations of the vortex core but also markedly promotes the global convective heat transfer process. With regard to the temperature field, an increase in fluid temperature reduces the viscosity coefficient, thereby weakening viscous dissipation effects, which accelerates vortex development and prolongs drainage time. Meanwhile, the vortex structure—through the induction of Taylor vortices and a spiral pumping effect—drives shear mixing and radial thermal diffusion between fluid regions at different temperatures, leading to dynamic reconstruction and homogenization of the temperature field. The outcomes of this study not only provide a solid theoretical foundation for understanding the generation, evolution, and heat transfer mechanisms of vortices under industrial thermal conditions, but also offer clear engineering guidance for practical production-enabling optimized operational parameters to suppress vortices and enhance drainage efficiency. Full article
(This article belongs to the Section Energy Systems)
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56 pages, 3273 KB  
Systematic Review
Artificial Intelligence and Machine Learning in Cold Spray Additive Manufacturing: A Systematic Literature Review
by Habib Afsharnia and Javaid Butt
J. Manuf. Mater. Process. 2025, 9(10), 334; https://doi.org/10.3390/jmmp9100334 - 13 Oct 2025
Cited by 1 | Viewed by 2925
Abstract
Due to its unique benefits over conventional subtractive manufacturing, additive manufacturing methods continue to attract interest in both academia and industry. One such method is called Cold Spray Additive Manufacturing (CSAM), a solid-state coating deposition technology to manufacture repair metallic components using a [...] Read more.
Due to its unique benefits over conventional subtractive manufacturing, additive manufacturing methods continue to attract interest in both academia and industry. One such method is called Cold Spray Additive Manufacturing (CSAM), a solid-state coating deposition technology to manufacture repair metallic components using a gas jet and powder particles. CSAM offers low heat input, stable phases, suitability for heat-sensitive substrates, and high deposition rates. However, persistent challenges include porosity control, geometric accuracy near edges and concavities, anisotropy, and cost sensitivities linked to gas selection and nozzle wear. Interdisciplinary research across manufacturing science, materials characterisation, robotics, control, artificial intelligence (AI), and machine learning (ML) is deployed to overcome these issues. ML supports quality prediction, inverse parameter design, in situ monitoring, and surrogate models that couple process physics with data. To demonstrate the impact of AI and ML on CSAM, this study presents a systematic literature review to identify, evaluate, and analyse published studies in this domain. The most relevant studies in the literature are analysed using keyword co-occurrence and clustering. Four themes were identified: design for CSAM, material analytics, real-time monitoring and defect analytics, and deposition and AI-enabled optimisation. Based on this synthesis, core challenges are identified as small and varied datasets, transfer and identifiability limits, and fragmented sensing. Main opportunities are outlined as physics-based surrogates, active learning, uncertainty-aware inversion, and cloud-edge control for reliable and adaptable ML use in CSAM. By systematically mapping the current landscape, this work provides a critical roadmap for researchers to target the most significant challenges and opportunities in applying AI/ML to industrialise CSAM. Full article
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17 pages, 3109 KB  
Article
Simulation of Eddy Current Suppression and Efficiency Recovery in Mining MCR-WPT Systems Based on Explosion-Proof Slotting
by Yingying Wang, Jiahui Yu, Jindi Pang, Shuangli Chen and Yudong Wang
Electronics 2025, 14(19), 3899; https://doi.org/10.3390/electronics14193899 - 30 Sep 2025
Viewed by 666
Abstract
To meet safety regulations in underground coal mines, wireless power transfer (WPT) systems must house both the transmitter and receiver within explosion-proof enclosures. However, eddy currents induced on the surfaces of these non-ferromagnetic metal enclosures significantly hinder magnetic flux coupling, thereby reducing transmission [...] Read more.
To meet safety regulations in underground coal mines, wireless power transfer (WPT) systems must house both the transmitter and receiver within explosion-proof enclosures. However, eddy currents induced on the surfaces of these non-ferromagnetic metal enclosures significantly hinder magnetic flux coupling, thereby reducing transmission efficiency. This paper proposes a slotting technique applied to explosion-proof enclosures to suppress eddy currents, along with the integration of magnetic flux focusing materials into the coils to enhance coupling. Simulations were conducted to compare three system configurations: (i) a WPT system without enclosures, (ii) a system with solid (unslotted) enclosures, and (iii) a system with slotted enclosures. The results show that solid enclosures reduce efficiency to nearly zero, whereas slotted enclosures restore efficiency to 90% of the baseline system without enclosures. Joule heating remains low in the slotted explosion-proof enclosures, with energy losses of 2.552 J for the transmitter enclosure and 2.578 J for the receiver enclosure. A conservative first-order estimation confirms that the corresponding temperature rise in the enclosure surfaces remains below 50 °C, which is well within the 150 °C limit stipulated by the Chinese National Standard GB 3836.1-2021 (Explosive Atmospheres—Part 1: Equipment General Requirements). These findings confirm effective eddy current suppression and efficiency recovery without compromising explosion-proof safety. The core innovation of this work lies not merely in the physical slotting approach, but in the development of a precise equivalent circuit model that fully incorporates all mutual inductance components representing eddy current effects in non-ferromagnetic explosion-proof enclosures, and its integration into the overall MCR-WPT system circuit. Full article
(This article belongs to the Section Electronic Materials, Devices and Applications)
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21 pages, 18800 KB  
Article
Research on Thermo-Mechanical Response of Solid-State Core Matrix in a Heat Pipe Cooled Reactor
by Xintong Peng, Cong Liu, Yangbin Deng, Jingyu Nie, Yingwei Wu and Guanghui Su
Energies 2025, 18(6), 1423; https://doi.org/10.3390/en18061423 - 13 Mar 2025
Cited by 2 | Viewed by 1178
Abstract
Due to its advantages of simple structure and high inherent safety, the heat pipe cooled reactor (HPR) could be widely applied in deep-sea navigation, deep-space exploration and land-based power supply as a promising advanced special nuclear power equipment option. In HPRs, the space [...] Read more.
Due to its advantages of simple structure and high inherent safety, the heat pipe cooled reactor (HPR) could be widely applied in deep-sea navigation, deep-space exploration and land-based power supply as a promising advanced special nuclear power equipment option. In HPRs, the space between the components (fuel rods and heat pipes) is filled with solid matrix material, forming a continuous solid reactor core. Thermo-mechanical response of the solid core is a special issue for HPRs and has great impacts on reactor safety. Considering the irradiation and burnup effects, the thermal and mechanical modeling of an HPR was conducted with ABAQUS-2021 in this study. The thermo-mechanical response under long-term normal operation, accident transients and single heat pipe failed conditions was simulated and analyzed. The whole core presents relatively good isothermality due to the high thermal conductivity of the solid matrix. As for the mechanical performance, the maximum stress was about 300 MPa, and the maximum displacement of the matrix could be as high as 3.7 mm. It could lead to significant variation of the reactor physical parameters, which warrants further attention in reactor design and safety analysis. Reactivity insertion accidents or single heat pipe failure has obvious influence on the thermo-mechanical performance of the local matrix, but they did not cause any failure risks, because the HPR design eliminates the dramatic power flash-up and the solid-state core avoids the heat transfer crisis caused by the coolant phase transition. A quantitative evaluation of thermo-mechanical performance was completed by this research, which is of great value for reactor design and safety evaluation of HPRs. Full article
(This article belongs to the Special Issue Optimal Design and Analysis of Advanced Nuclear Reactors)
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26 pages, 11173 KB  
Article
Optimization Design of Casting Process for Large Long Lead Cylinder of Aluminum Alloy
by Liang Huang, Yan Cao, Mengfei Zhang, Zhichao Meng, Tuo Wang and Xiaozhe Zhu
Materials 2025, 18(3), 531; https://doi.org/10.3390/ma18030531 - 24 Jan 2025
Viewed by 4132
Abstract
As the core component of chain-less ammunition transmission system, the large long lead cylinder adopts ZL205A alloy, which has the advantages of high strength and wear resistance. However, in its main casting production process, the forming quality is mainly determined by the casting [...] Read more.
As the core component of chain-less ammunition transmission system, the large long lead cylinder adopts ZL205A alloy, which has the advantages of high strength and wear resistance. However, in its main casting production process, the forming quality is mainly determined by the casting process parameters under the premise of determining a reasonable casting system. Considering that the casting process parameters are the process feedback expression of the macroscopic forming quality and comprehensive mechanical properties by controlling the coupling effect of the metal liquid flow in the microscopic flow field, the directional solidification crystallization of the alloy and the solid–liquid heat transfer and heat transfer during the filling and solidification process, the accurate and reasonable selection of casting process parameters is conducive to the stable guarantee of pouring quality. On the basis of the optimized column gap casting system, this study combined numerical simulation and data statistics. Within the rationality of each casting process parameter constructed by single-factor analysis, the response surface method was used to construct a quantitative guidance relationship of each process parameter coupling mapping casting defect, and based on this model, the optimal process parameter combination was realized as follows: compared with traditional metal mold casting and unoptimized low pressure casting, the tensile strength of non-porous casting with holding pressure 14.68 kPa, casting temperature 717.152 °C and mold preheating temperature 256.12 °C increased by 6.6% and 4.1%, respectively, hardness increased by 14.3% and 8.4% respectively, and the elongation is increased by 16.9% and 10.6%, respectively, thus efficiently and accurately improving the process quality. Full article
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27 pages, 8131 KB  
Article
Formation Conditions of Unusual Extremely Reduced High-Temperature Mineral Assemblages in Rocks of Combustion Metamorphic Complexes
by Igor S. Peretyazhko and Elena A. Savina
Crystals 2024, 14(12), 1052; https://doi.org/10.3390/cryst14121052 - 3 Dec 2024
Cited by 4 | Viewed by 2005
Abstract
New data, including Raman spectroscopy, characterize unusual mineral assemblages from rocks of the Naylga and Khamaryn–Khyral–Khiid combustion metamorphic complexes in Mongolia. Several samples of melilite–nepheline paralava and other thermally altered (metamorphosed) sedimentary rocks contain troilite (FeS), metallic iron Fe0, kamacite α-(Fe,Ni) [...] Read more.
New data, including Raman spectroscopy, characterize unusual mineral assemblages from rocks of the Naylga and Khamaryn–Khyral–Khiid combustion metamorphic complexes in Mongolia. Several samples of melilite–nepheline paralava and other thermally altered (metamorphosed) sedimentary rocks contain troilite (FeS), metallic iron Fe0, kamacite α-(Fe,Ni) or Ni-bearing Fe0, taenite γ-(Fe,Ni) or Ni-rich Fe0, barringerite or allabogdanite Fe2P, schreibersite Fe3P, steadite Fe4P = eutectic α-Fe + Fe3P, wüstite FeO, and cohenite Fe3C. The paralava matrix includes a fragment composed of magnesiowüstite–ferropericlase (FeO–MgO solid solution), as well as of spinel (Mg,Fe)Al2O4 and forsterite. The highest-temperature mineral assemblage belongs to a xenolithic remnant, possibly Fe-rich sinter, which is molten ash left after underground combustion of coal seams. The crystallization temperatures of the observed iron phases were estimated using phase diagrams for the respective systems: Fe–S for iron sulfides and Fe–P ± C for iron phosphides. Iron monosulfides (high-temperature pyrrhotite) with inclusions of Fe0 underwent solid-state conversion into troilite at 140 °C. Iron phosphides in inclusions from the early growth zone of anorthite–bytownite in melilite–nepheline paralava crystallized from <1370 to 1165 °C (Fe2P), 1165–1048 °C (Fe3P), and <1048 °C (Fe4P). Phase relations in zoned spherules consisting of troilite +Fe0 (or kamacite + taenite) +Fe3P ± (Fe3C, Fe4P) reveal the potential presence of a homogeneous Fe–S–P–C melt at T~1350 °C, which separated into two immiscible melts in the 1350–1250 °C range; namely, a dense Fe–P–C melt in the core and a less dense Fe–S melt in the rim. The melts evolved in accordance with cooling paths in the Fe–S and Fe–P–C phase diagrams. Cohenite and schreibersite in the spherules crystallized between 988 °C and 959 °C. The crystallization temperatures of minerals were used to reconstruct redox patterns with respect to the CCO, IW, IM, and MW buffer equilibria during melting of marly limestone and subsequent crystallization and cooling of melilite–nepheline paralava melts. The origin of the studied CM rocks was explained in a model implying thermal alteration of low-permeable overburden domains in reducing conditions during wild subsurface coal fires, while heating was transferred conductively from adjacent parts of ignited coal seams. The fluid (gas) regime in the zones of combustion was controlled by the CCO buffer at excess atomic carbon. Paralava melts exposed to high-temperature extremely reducing conditions contained droplets of immiscible Fe–S–P–C, Fe–S, Fe–P, and Fe–P–C melts, which then crystallized into reduced mineral assemblages. Full article
(This article belongs to the Collection Topic Collection: Mineralogical Crystallography)
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23 pages, 7242 KB  
Article
A Multiphysics Simulation Study of the Thermomechanical Coupling Response of Energy Piles
by Chang Xu, Yawen Wang, Xiaolin Meng, Qihang Lv, Hui Chen and Qingdong Wu
Buildings 2024, 14(5), 1440; https://doi.org/10.3390/buildings14051440 - 16 May 2024
Cited by 2 | Viewed by 2365
Abstract
The global demand for energy is on the rise, accompanied by increasing requirements for low-carbon environmental protection. In recent years, China’s “double carbon action” initiative has brought about new development opportunities across various sectors. The concept of energy pile foundation aims to harness [...] Read more.
The global demand for energy is on the rise, accompanied by increasing requirements for low-carbon environmental protection. In recent years, China’s “double carbon action” initiative has brought about new development opportunities across various sectors. The concept of energy pile foundation aims to harness geothermal energy, aligning well with green, low-carbon, and sustainable development principles, thus offering extensive application prospects in engineering. Drawing from existing research globally, this paper delves into four key aspects impacting the thermodynamic properties of energy piles: the design of buried pipes, pile structure, heat storage materials within the pipe core, and soil treatment around the pile using carbon fiber urease mineralization. Leveraging the innovative mineralization technique known as urease-induced carbonate mineralization precipitation (EICP), this study employs COMSOL Multiphysics simulation software to analyze heat transfer dynamics and establish twelve sets of numerical models for energy piles. The buried pipe design encompasses two types, U-shaped and spiral, while the pile structure includes concrete solid energy piles and tubular energy piles. Soil conditions around the pile are classified into undisturbed sand and carbon fiber-infused EICP mineralized sand. Different inner core heat storage materials such as air, water, unaltered sand, and carbon fiber-based EICP mineralized sand are examined within tubular piles. Key findings indicate that spiral buried pipes outperform U-shaped ones, especially when filled with liquid thermal energy storage (TES) materials, enhancing temperature control of energy piles. The carbon fiber urease mineralization technique significantly improves heat exchange between energy piles and surrounding soil, reducing soil porosity to 4.9%. With a carbon fiber content of 1.2%, the ultimate compressive strength reaches 1419.4 kPa. Tubular energy piles mitigate pile stress during summer temperature fluctuations. Pile stress distribution varies under load and temperature stresses, with downward and upward friction observed at different points along the pile length. Overall, this research underscores the efficacy of energy pile technologies in optimizing energy efficiency while aligning with sustainable development goals. Full article
(This article belongs to the Special Issue Trends and Prospects in Civil Engineering Structures)
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19 pages, 3797 KB  
Article
Crystal Phase Ionic Liquids for Energy Applications: Heat Capacity Prediction via a Hybrid Group Contribution Approach
by Moh’d Basel Shahin, Shehzad Liaqat, Paul Nancarrow and Sarah J. McCormack
Molecules 2024, 29(9), 2130; https://doi.org/10.3390/molecules29092130 - 3 May 2024
Cited by 1 | Viewed by 2077
Abstract
In the selection and design of ionic liquids (ILs) for various applications, including heat transfer fluids, thermal energy storage materials, fuel cells, and solvents for chemical processes, heat capacity is a key thermodynamic property. While several attempts have been made to develop predictive [...] Read more.
In the selection and design of ionic liquids (ILs) for various applications, including heat transfer fluids, thermal energy storage materials, fuel cells, and solvents for chemical processes, heat capacity is a key thermodynamic property. While several attempts have been made to develop predictive models for the estimation of the heat capacity of ILs in their liquid phase, none so far have been reported for the ILs’ solid crystal phase. This is particularly important for applications where ILs will be used for thermal energy storage in the solid phase. For the first time, a model has been developed and used for the prediction of crystal phase heat capacity based on extending and modifying a previously developed hybrid group contribution model (GCM) for liquid phase heat capacity. A comprehensive database of over 5000 data points with 71 unique crystal phase ILs, comprising 42 different cations and 23 different anions, was used for parameterization and testing. This hybrid model takes into account the effect of the anion core, cation core, and subgroups within cations and anions, in addition to the derived indirect parameters that reflect the effects of branching and distribution around the core of the IL. According to the results, the developed GCM can reliably predict the crystal phase heat capacity with a mean absolute percentage error of 6.78%. This study aims to fill this current gap in the literature and to enable the design of ILs for thermal energy storage and other solid phase applications. Full article
(This article belongs to the Special Issue Properties and Applications of Ionic Liquids-Based Advanced Materials)
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8 pages, 2119 KB  
Article
Three-Dimensional Numerical Simulation of Pyrolysis of Polymethyl Methacrylate under Non-Uniform Radiative Heating
by Yujia Sun
Polymers 2022, 14(24), 5360; https://doi.org/10.3390/polym14245360 - 7 Dec 2022
Cited by 3 | Viewed by 2130
Abstract
PMMA material is widely used in the building and household industries, and its pyrolysis behavior is important for fire safety. In real fire conditions, polymethyl methacrylate (PMMA) material will receive non-uniform distributed radiative heat flux from heat sources (such as fire). However, most [...] Read more.
PMMA material is widely used in the building and household industries, and its pyrolysis behavior is important for fire safety. In real fire conditions, polymethyl methacrylate (PMMA) material will receive non-uniform distributed radiative heat flux from heat sources (such as fire). However, most of the existing work on this subject is limited to one dimensional geometry with uniform heat flux. This paper investigates the heat transfer and pyrolysis mechanism of PMMA material under non-uniform radiative heat flux. A three-dimensional model is developed to this end with a consideration of in-depth radiation and surface heat loss. The results show that temperature and density contours are highly non-uniform inside the solid and there is both a high-temperature core and low-density core beneath the surface. The maximum temperature occurs at a location under the top surface. Full article
(This article belongs to the Special Issue Polymer Combustion and Pyrolysis Kinetics)
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23 pages, 2074 KB  
Article
Group Combustion of Dispersed Spherical Core–Shell Nanothermite Particles
by Mustafa Mutiur Rahman, Ahmed Saieed, Muhammad Fasahat Khan and Jean-Pierre Hickey
Thermo 2022, 2(3), 209-231; https://doi.org/10.3390/thermo2030016 - 8 Aug 2022
Cited by 4 | Viewed by 3463
Abstract
The group combustion characteristics of core–shell nanothermite particles differ from other dispersed solid or liquid fuels. In a core–shell structure, each discrete nanothermite particle can undergo an exothermic reaction as the oxygen atoms in the metal oxide shell undergo a solid state diffusion [...] Read more.
The group combustion characteristics of core–shell nanothermite particles differ from other dispersed solid or liquid fuels. In a core–shell structure, each discrete nanothermite particle can undergo an exothermic reaction as the oxygen atoms in the metal oxide shell undergo a solid state diffusion to oxidize the metal core. This feature allows the spherical core–shell nanothermites to react in the absence of gaseous oxygen, thus modifying their group combustion characteristics compared to char or liquid fuels. Using a number of simplifying assumptions, a theoretical framework was established—based on existing group combustion theory—to examine the characteristics of mass and heat diffusion in nanothermite combustion. First, a model for the quasi-steady state single-particle combustion, in quiescent air, was established. The isolated particle combustion theory serves as the basis for the combustion interaction and mass transfer in a spherical cloud of dispersed nanothermite particles. The type of group combustion is strongly dependent on the diffusion of vapour products, i.e., the interaction is more pronounced when the diffusion of vapour products is higher. The group combustion regimes in dispersed nanothermites were identified and delineated. Full article
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23 pages, 7186 KB  
Article
Numerical Simulation Study of Gas-Solid Heat Transfer and Decomposition Processes of Limestone Calcined with Blast Furnace Gas in a Parallel Flow Regenerative Lime Kiln
by Shaopei Duan, Baokuan Li and Wenjie Rong
Materials 2022, 15(11), 4024; https://doi.org/10.3390/ma15114024 - 6 Jun 2022
Cited by 14 | Viewed by 5645
Abstract
Quicklime is an essential reducing agent in the steel smelting process and its calcination from limestone is accompanied by considerable energy consumption. As a relatively economical lime kiln, the Parallel Flow Regenerative (PFR) lime kiln is used as the main equipment for the [...] Read more.
Quicklime is an essential reducing agent in the steel smelting process and its calcination from limestone is accompanied by considerable energy consumption. As a relatively economical lime kiln, the Parallel Flow Regenerative (PFR) lime kiln is used as the main equipment for the production of quicklime by various steel industries. PFR lime kilns generally use natural gas as the fuel gas. Although natural gas has a high calorific value and is effective in calcination, with the increasing price of natural gas and the pressure saves energy and protect the environment, it makes sense of exploring the use of cleaner energy sources or other sub-products as fuel gas. The use of blast furnace gas (BFG) as a low calorific value fuel gas produced in the steel smelting process has been of interest. This paper therefore develops a set of mathematical models for gas-solid heat transfer and limestone decomposition based on a Porous Medium Model (PMM) and a Shrinking Core Model (SCM) to numerically simulate a PFR lime kiln using BFG in order to investigate the feasibility of calcining limestone with low calorific fuel gas and to provide a valuable reference for future development of such processes and the kiln structure improvement. Full article
(This article belongs to the Special Issue Metallurgical Process Simulation and Optimization)
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22 pages, 6145 KB  
Article
Improvement and Validation of the System Analysis Model and Code for Heat-Pipe-Cooled Microreactor
by Li Ge, Huaqi Li, Xiaoyan Tian, Zeyu Ouyang, Xiaoya Kang, Da Li, Jianqiang Shan and Xinbiao Jiang
Energies 2022, 15(7), 2586; https://doi.org/10.3390/en15072586 - 1 Apr 2022
Cited by 17 | Viewed by 5041
Abstract
Heat-pipe-cooled microreactors (HPMR) use a passive high-temperature alkali metal heat pipe to directly transfer the heat of solid core to the hot end of the intermediate heat exchanger or thermoelectric conversion device, thus avoiding a single point failure. To analyze and evaluate the [...] Read more.
Heat-pipe-cooled microreactors (HPMR) use a passive high-temperature alkali metal heat pipe to directly transfer the heat of solid core to the hot end of the intermediate heat exchanger or thermoelectric conversion device, thus avoiding a single point failure. To analyze and evaluate the transient safety characteristics of an HPMR system under accident conditions, such as heat pipe failure in the core or a loss of system heat sink and other accidents, a previously developed model for transient analysis of a heat-pipe-cooled space nuclear reactor power system (HPSR) was improved and validated in this study. The models improved mainly comprise: (1) An entire 2-D solid-core heat transfer model is established to analyze the accident conditions of core heat pipe failure and system heat sink loss. In this model, radial and axial Fourier heat conduction equations are used to divide the core into r-θ direction control volumes. The physical parameters of the material in the control volume are calculated according to the volume-weighted average. (2) By coupling the heat transfer limit model and the two-dimensional thermal resistance network model, the transient model of a heat pipe for HPMR system analysis is improved. (3) Conversion system models are established to simulate the system characteristics of the advanced HPMR concept, such as thermoelectric conversion, Stirling conversion, and the open Brayton conversion analysis model. Based on the improved models, the HPMR system analysis program TAPIRSD was developed, which was verified by experimental data of the separated conversion components and the ground nuclear test device KRUSTY. The maximum deviation of the power output predicted by the energy conversion model is less than 8%. The accident conditions of the KRUSTY tests, such as load change, core heat pipe failure, and heat sink loss accident, were studied by using TAPIRSD. The results show that the simulation results of the TAPIRSD code agree well with the experimental data of the KRUSTY prototype reactor. The maximum error between the TAPIRSD code prediction and the measured value of the core temperature under accident conditions is less than 10 K, and the maximum deviation is less than 2%. The results show that the developed code can predict the transient response process of the HPMR system well. At the same time, the accuracy and reliability of the improved model are proved. The TAPIRSD is suitable for system transient analysis of different types of HPMRs and provides an optional tool for the system safety characteristics analysis of HPMR. Full article
(This article belongs to the Special Issue Advanced Numerical Modelling Techniques for Nuclear Reactors)
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