Search Results (197)

Space cooling is one of the fastest-growing end uses in the building sector, and reflective (“cool”) coatings have emerged as a low-cost passive strategy to limit solar heat gain through the envelope. This study evaluates the summer thermal behaviour of three building-envelope materials commonly used in flat roofing—self-protected asphalt sheet, steel sheet, and ceramic tile—under outdoor conditions in Valencia, Spain. Sealed cubic prototypes were monitored to compare uncoated reference specimens with specimens coated with a conventional high-performance white acrylic paint produced by SOETAM and with an advanced reflective coating based on a laminar TiO₂ nanostructure produced by Q+TERMIK. External surface temperatures were assessed by infrared thermography and internal air temperatures by autonomous data loggers. External white coatings significantly reduced surface temperatures across all substrates, with the effect most pronounced in low-thermal-inertia materials: the advanced reflective coating achieved peak surface-temperature reductions of 21.0 °C (33.2%) for asphalt and 17.4 °C (28.8%) for steel, outperforming the high-performance coating, with corresponding internal reductions of up to 9.7 °C (22.0%) and 8.1 °C (18.6%). The results indicate that the advanced reflective coating produced greater thermal mitigation than the conventional coating under the tested outdoor conditions, despite both coatings being applied with similar thicknesses. The advanced reflective coating generally produced the greatest thermal mitigation, particularly for low-thermal-inertia substrates, while the ceramic tile exhibited a different internal thermal response, highlighting the influence of substrate properties on coating performance. Full article

Building-integrated photovoltaics (BIPV) have achieved a high level of technical maturity. In spite of that, the installed capacity remains limited. To stimulate the integration of solar panels in the built environment, aesthetical features like color and freedom in size and shape are of key importance for architects and building owners. Multilayer interference coatings are an attractive coloring technique for solar panels, as they are known for their high solar transmission and tuneable reflection peak. The latter gives rise to an intense metallic reflection color. In this study, the outdoor performance of colored versus non-colored BIPV panels was investigated, and a method has been developed to measure the color variation of the solar panels with respect to outdoor conditions, viewing angles and tilt angles of the setup. A limited performance loss of 15% was measured for colored solar panels compared to their black counterparts, caused by a reduction in generated photocurrent due to light loss. Outdoor color measurements showed that the cloudiness of the sky and the tilt angle of the setup are key parameters causing a color variation from yellow-green to blue-green. In addition, the developed method and tailored measurement setup have proven their value in quantifying color appearance of colored BIPV in realistic and varying outdoor conditions. Full article

Buildings account for a significant share of global energy consumption and carbon emissions, creating an urgent need for advanced energy retrofit technologies. This review critically examines the role of plasma-modified textile polymer materials in improving the energy efficiency and durability of building retrofit systems. Various textile polymers, including polyester (polyethylene terephthalate, PET), polypropylene (PP), polytetrafluoroethylene (PTFE), polyamide (PA), and fiber-reinforced composites, are evaluated in relation to plasma surface engineering approaches, including atmospheric plasma, dielectric barrier discharge (DBD), and plasma jet treatment. Reported studies demonstrate that plasma treatment significantly alters surface morphology and chemistry, resulting in increased surface roughness, enhanced wettability, improved coating adhesion, and superior hydrophobic behavior. Water contact angles increased from approximately 70° to 145° depending on polymer type and plasma conditions, while reflective coating performance improved with solar reflectance enhancements of approximately 10–15%. Plasma-treated reflective roofing and shading textiles also showed reductions in building cooling energy demand of approximately 18–25% and roof temperature decreases of 10–15 °C. Furthermore, plasma-induced surface activation improved durability, ultraviolet (UV) resistance, and weather stability of textile membranes used in facade and roofing applications. The review also discusses industrial challenges related to scalability, plasma aging effects, energy consumption, and long-term performance. Plasma-modified systems demonstrate strong potential for multifunctional, lightweight, and sustainable building envelope technologies for future energy-efficient construction. Full article

Solar-driven NiTi alloy wire rotary engines are promising for lightweight actuation, but their performance is often restricted by insufficient light absorption of the alloy wire and unstable wheel–wire transmission. In this work, a collaborative surface-modification strategy was developed by combining a CNT/PDA-based photothermal coating on the NiTi alloy wire with a CNT/PDMS-based coating on the wheel surface. To establish a controllable wire-coating process, electrophoretic deposition parameters were first screened on titanium plates using an orthogonal design involving voltage, duty ratio, water content, treatment time, and electrode distance. Among the tested conditions, an electrode distance of 10 mm provided the most favorable balance between coating thickness and microstructural uniformity, while water content and electrode distance were identified as the main factors affecting coating variation. After transfer to the alloy wire, the coating greatly reduced reflectance in the 300–1400 nm range and significantly enhanced photothermal heating, increasing the maximum irradiation temperature by about 30 °C. On the wheel side, PDMS-based surface modification further improved rotational output, and the 1.5 wt% + 10 wt% formulation showed the best performance. In coupled rotation tests, the system with simultaneous wire and wheel modification exhibited the fastest startup and the highest angular velocity, reaching about five times that of the slowest rotating modified group. These results demonstrate that coordinated surface modification of the alloy wire and wheel is an effective route to improving the photothermal response and rotational performance of NiTi alloy wire rotary engines. Full article

Chalcopyrite-based thin-film solar cells have great potential for various applications, such as top or bottom cells in tandem devices, in addition to their use as standard single-junction modules due to their tuneable bandgap energy. A bandgap energy E_g > 1.5 eV should be targeted to realize a wide-bandgap top cell, e.g., by increasing the [Ga]/([Ga] + [In]) (GGI) ratio in Cu(In,Ga)Se₂ (CIGS) cells to the range of 0.7–1. A second approach is targeting the second theoretical efficiency maximum at a little lower E_g = 1.34 eV with a GGI around 0.6 for high-efficiency single-junction applications with reduced electrical losses. An industry-relevant (Ag,Cu)(In,Ga)Se₂ (ACIGS) co-evaporation process for wide-bandgap cells fabricated with GGI ratios above 0.6, with moderate [Ag]/([Ag] + [Cu]) (AAC) ratios < 0.1 and in-line RbF-PDT, was established on molybdenum-coated soda-lime glass substrates. Both measures, Ag alloying and RbF-PDT, can increase power conversion efficiency (PCE) mainly due to improved open-circuit voltage (V_OC). In addition, Ag addition can increase fill factor (FF)_, leading to an increase in the PCE for cells with GGI > 0.6 compared to Ag-free reference cells. (Zn,Mg)O, either with a [Mg]/([Mg] + [Zn]) ratio of 0.15 or 0.25, is a good option as high-resistive layer replacing the commonly used i-ZnO in combination with a CdS buffer. Our best ACIGS wide-bandgap solar cells with RbF-PDT and Zn_0.85Mg_0.15O (without anti-reflective coating (ARC)) from various experimental campaigns show a PCE of 12.7% (E_g = 1.50 eV), and with a slightly reduced E_g of 1.45 eV a PCE of 15.5%, with V_OC of 933 mV (V_OC deficit of 517 mV), and a good FF of 73.2%. In the case when the bandgap is significantly lowered to 1.34 eV (GGI = 0.61), to the second theoretical efficiency maximum, we achieved a PCE of 18.2% with ARC for an Ag-free CIGS cell with RbF-PDT. For this cell with a CdS/i-ZnO buffer system the V_OC deficit is 480 mV, and the FF is 78.1%. Full article

This article focuses on aspects related to the physical and thermal parameters of so-called thermal-insulating paints. These materials and systems are used in two different situations: first, as agents reducing surface temperature due to solar radiation, and second, as so-called “thermal-insulating” coatings. The paper focuses on the second aspect of the applications described by the manufacturers and presents the results of the author’s laboratory tests (using an insulated heating box with two different heat sources) and field tests (in situ) on a building façade. The research methodology focuses on contact and thermal imaging measurements to assess the effectiveness and properties of reflective thermal-insulating paints, as well as analyzing their impact on the surface temperature and heat transfer coefficient of building envelopes. The conducted research showed that the use of reflective thermal-insulating paints does not significantly improve the thermal insulation of building envelopes. Measurements of the heat transfer coefficient showed a reduction of 1–7% compared to the reference wall tested. In situ measurements using temperature sensors and thermographic studies confirmed the insignificant impact of reflective thermal insulation paints on the thermal protection of external walls. Full article

The escalating energy crisis and global warming drive the demand for all-season self-regulating functional textiles. This study presents a Janus smart textile that combines phase change energy storage with active and passive heating modes, electromagnetic interference shielding, and self-cleaning capabilities. The front surface incorporates phase change temperature regulation and thermochromic properties, while the back surface is spray-coated with a transition metal carbide to establish a continuous conductive network. In the low-temperature state, the black surface enhances solar absorption for efficient heating; as the temperature rises, the surface turns white to increase solar reflection and suppress overheating. This mechanism, combined with phase change energy storage, enables the textile to mitigate environmental temperature fluctuations. The MXene layer on the back provides efficient Joule heating and cycling stability under driving voltages of 3 to 5 volts, along with electromagnetic interference shielding dominated by absorption loss. The front hybrid coating further imparts hydrophobic self-cleaning performance. This study offers a strategy for synergistic active and passive thermal management, demonstrating application potential in intelligent outdoor gear and specialized protective outer layers. Full article

This research was motivated by the urgent need to address resource shortages and high energy costs in concrete production by replacing an energy-intensive traditional curing method with a new, more sustainable solution. By exploring solar heat treatment with composite binders and THACs, the study aimed to develop sustainable, cost-effective alternatives that harness renewable energy sources and optimize natural cement hydration processes for accelerated hardening. This article explores the potential application of solar energy in the production of precast concrete products using a composite binder. The effectiveness of the composite binder in solar thermal treatment of concrete using translucent heat-accumulating coatings is tested. The results of laboratory studies are presented, and the feasibility of using concrete based on composite binder at the laboratory scale for the production of concrete and reinforced concrete products, both with steaming and with solar thermal treatment, is established. The study of the structural features and basic physical and mechanical properties of hardened concrete under various conditions indicates that, under the investigated laboratory conditions, solar-thermally treated concrete exhibits physical and mechanical properties comparable to those of normally cured concrete. Laboratory studies confirmed the effectiveness of both steaming and solar heat treatment methods under controlled experimental conditions. Within the scope of the performed laboratory tests, the structure and properties of these concretes were comparable to those of normally cured concretes and, in several aspects, superior to those obtained under conventional steam curing regimes, which indicates the effectiveness of the described method, not only from the point of view of significant savings in fuel and energy resources. When producing products based on composite binders using solar thermal treatment, the consumption of the clinker portion of the binder is reduced by 50% (composition of the composite binder itself) and the consumption of conventional fuel during heat and moisture treatment is reduced by 70–100 kg per 1 m³ of concrete (reflecting process-level comparisons), which is of significant value for external energy demand. These findings confirm the technical feasibility and environmental advantages of the proposed method at the laboratory scale and highlight its potential for broader industrial application in precast concrete production. Full article

The inefficient utilization of industrial by-product phosphogypsum, coupled with the increasing global demand for cooling, has spurred the development of sustainable radiative cooling materials. Compared with conventional cooling coatings that primarily rely on expensive synthetic materials or complex fabrication processes, this study provides a promising cost-effective and sustainable route for integrating industrial solid waste valorization with zero-energy cooling technologies. In this study, we fabricated a composite coating (β-HPG@CA/SiO₂@OTS) consisting of β-hemihydrate phosphogypsum (β-HPG), a derivative product of phosphogypsum, cellulose acetate (CA), SiO₂ particles and octadecyltrichlorosilane (OTS) by a facile combination of blade coating and spraying, which exhibited strong solar reflectivity (90.9%), high mid-infrared emissivity (98.7%) and satisfactory superhydrophobicity (157°). The as-prepared composite achieved an ambient temperature drop of 18.7 °C under direct sunlight during sunny weather, achieving a net cooling power of 92.23 W/m². Meanwhile, the composite coating exhibits excellent durability after prolonged immersion in strongly acidic and alkaline solutions, ultraviolet radiation and outdoor testing. Owing to its simple fabrication process and robust cooling performance, this coating shows promise for scalable production and practical outdoor applications, such as building envelopes and equipment enclosures. Full article

In this study, a non-typical luminescent organosilicone was synthesized through a click reaction and used as a cross-linker to cure hydroxyl-terminated dimethylsilicone oil at room temperature via the sol–gel process, followed by application as a coating on a glass surface. This organosilicone film functions effectively as a luminescent down-shifting (LDS) material. Additionally, the presence of methyl groups and voids in the structure imparts a low refractive index, allowing it to serve as an anti-reflective (AR) layer. Optical and structural analyses on organosilicone-coated glass samples were conducted, and the dual-functional layer was applied to the glass cover of a perovskite solar panel to evaluate its performance. The coating not only enhanced light transmission as an AR layer but also converted UV light into blue light, which was absorbed by the solar cell. The results indicated improved solar panel performance, particularly in short-circuit current (Isc), external quantum efficiency (EQE) in the UV wavelength range, and overall efficiency. Overall, this material is a promising candidate for solar panel applications owing to maximized UV absorption for LDS, preserved transparency of the top cover glass, and room-temperature gelation, which facilitates repair of the dual-functional coating. Full article

Passive daytime radiative cooling (PDRC) is a promising thermal management technology, yet its widespread application is hindered by the high production costs and poor durability of traditional organic-based materials. Here, we presented a hierarchically porous, all-inorganic PDRC coating synthesized from industrial waste glass and alumina microparticles via low-temperature (600 °C) processing. Rather than serving merely as a cheap substitute, the alkali oxides inherent in waste glass act as natural fluxes, enabling partial melting. Concurrently, the steric hindrance of alumina restricts full densification, spontaneously constructing a highly scattering random photonic network. The optimized composite (50 wt.% waste glass/50 wt.% alumina) achieves 96% solar reflectance and 95% atmospheric window emittance. Field tests confirmed sub-ambient cooling of ~4.0 °C (day) and ~4.5 °C (night), yielding a peak net cooling power of 108.1 W/m². Accelerated weathering and thermal shock (1000 °C) tests demonstrated sustained optical stability under extreme environmental stress. Full article

Interdigitated back-contact solar cells were fabricated entirely with inkjet printing. poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS), TiO₂, and metal lines were printed on a textured silicon substrate with only one inkjet printer. No vacuum deposition or diffusion of a back surface field is needed for the printed IBC solar cell. Adding co-solvent to the PEDOT:PSS and passivation of the Si surface significantly reduced the losses and enhanced the short-circuit current, Jsc, and, as a result, improved the fill factor and efficiency of the devices. The thickness of the PEDOT:PSS layer is approximately half a micrometer measured by profilometer, which is thicker than the optimal range typically reported; there is still a best short-circuit current, Jsc, of 19.2 mA/cm². To further improve the performance of the devices, an anti-reflective coating on the front side is required. Also, an improved metal contact ink is needed to improve the contact resistance between the PEDOT:PSS layer and the metal contact. The initial performance of all printed cells are compared to conventionally fabricated devices. Full article

The design of broadband, high-efficiency solar absorbers remains challenging due to the complex and ill-posed inverse mapping from the target optical responses to the physical structures in inverse design optimization. To address this, we propose a joint forward–inverse deep learning framework that enables the rapid and accurate optimization of multilayer metamaterial absorbers. This method integrates an inverse network based on a Modified Swin Transformer with a Multilayer Perceptron forward proxy and performs end-to-end training in a consistency-driven cycle. This strategy reduces the one-to-many ambiguity in inverse design and improves the prediction accuracy, with normalized test mean squared errors of 7.2 × 10⁻⁵ (inverse) and 6.8 × 10⁻⁵ (forward). Using this framework, we optimized an absorber comprising W/SiO₂ hyperbolic metamaterial stacks and TiO₂/SiO₂ anti-reflection coatings, achieving 97.4% average absorptivity across the 400–1750 nm solar spectrum, along with polarization insensitivity and robust wide-angle performance up to 60° incidence. The outdoor solar heating tests showed that the fabricated absorber reaches a peak temperature of 86.3 °C under natural sunlight, with an irradiance peak of about 850 W/m² at noon. This work shows that combining forward and reverse deep learning provides a powerful and scalable paradigm for accelerating the intelligent design of high-performance solar thermal metamaterials. Full article

This study investigates the effects of deposition angle and arc current on the surface morphology and optical response of Ti coatings obtained by unfiltered cathodic arc evaporation for spectrally selective solar-thermal applications. 100 nm-thick Ti films were deposited at normal (0°) and oblique (80°) angles of incidence, with arc currents of 65 A and 90 A, respectively. The SEM measurements revealed the characteristic arc-generated microdroplet population. At normal incidence (0°), droplets are predominantly spherical and relatively uniformly distributed, whereas at 80° incidence, many droplets exhibit elongated footprints aligned with the incoming flux from the Ti cathode. This behavior is consistent with oblique-angle deposition (OAD), where the arrival geometry can promote self-shadowing and transient droplet spreading before solidification. AFM confirms an increase in nanoscale roughness, whereas GIXRD indicates nanocrystalline α-Ti and cubic TiO, with maximum crystallinity for 0°/65 A. Contact-angle measurements demonstrate a transition from hydrophobic 316L (~103°) to moderately hydrophilic Ti-coated surfaces (~68–72°), with only minor dependence on deposition geometry. Optical reflectance in the 400–800 nm range is significantly lower for Ti-coated glass and is further reduced for OAD films, indicating enhanced solar absorptance. Full article

Silica-based multifunctional coatings hold great promise for applications in optical devices, lenses, and solar panels. Herein, we report a facile, low-temperature route to integrate super-hydrophobicity with high transparency and low haze. By precisely controlling particle gradation and applying fluorine passivation, a multi-scale structure with micro-scale uniformity and nano-scale asperity was constructed. This unique architecture, combined with low surface energy, effectively reduces light scattering and enhances air trapping. Consequently, the coated glass achieves a high optical transmittance of 95.24% with a low haze of 0.97%, alongside a water contact angle of 153° and a sliding angle of 3°. The coating also exhibits distinct anti-reflection (an improvement of ~5.0% relative to the bare substrate) and self-cleaning properties. Furthermore, it demonstrates impressive robustness and durability, withstanding extreme conditions including cryogenic temperatures (−50 °C), hygrothermal environments, and long-term outdoor exposure. This work demonstrates the versatile potential of our strategy for fabricating highly transparent and superhydrophobic surfaces. Full article