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Keywords = short fiber printing

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29 pages, 15691 KiB  
Article
Mechanical Behavior and Response Mechanism of Short Fiber-Reinforced Polymer Structures Under Low-Speed Impact
by Xinke Xiao, Penglei Wang, Anxiao Guo, Linzhuang Han, Yunhao Yang, Yalin He and Xuanming Cai
Materials 2025, 18(15), 3686; https://doi.org/10.3390/ma18153686 - 6 Aug 2025
Viewed by 287
Abstract
Short fiber-reinforced polymer (SFRP) has been extensively applied in structural engineering due to its exceptional specific strength and superior mechanical properties. Its mechanical behavior under medium strain rate conditions has become a key focus of ongoing research. A comprehensive understanding of the response [...] Read more.
Short fiber-reinforced polymer (SFRP) has been extensively applied in structural engineering due to its exceptional specific strength and superior mechanical properties. Its mechanical behavior under medium strain rate conditions has become a key focus of ongoing research. A comprehensive understanding of the response characteristics and underlying mechanisms under such conditions is of critical importance for both theoretical development and practical engineering applications. This study proposes an innovative three-dimensional (3D) multiscale constitutive model that comprehensively integrates mesoscopic fiber–matrix interface effects and pore characteristics. To systematically investigate the dynamic response and damage evolution of SFRP under medium strain rate conditions, 3D-printed SFRP porous structures with volume fractions of 25%, 35%, and 45% are designed and subjected to drop hammer impact experiments combined with multiscale numerical simulations. The experimental and simulation results demonstrate that, for specimens with a 25% volume fraction, the strain rate strengthening effect is the primary contributor to the increase in peak stress. In contrast, for specimens with a 45% volume fraction, the interaction between damage evolution and strain rate strengthening leads to a more complex stress–strain response. The specific energy absorption (SEA) of 25% volume fraction specimens increases markedly with increasing strain rate. However, for specimens with 35% and 45% volume fractions, the competition between these two mechanisms results in non-monotonic variations in energy absorption efficiency (EAE). The dominant failure mode under impact loading is shear-dominated compression, with damage evolution becoming increasingly complex as the fiber volume fraction increases. Furthermore, the damage characteristics transition from fiber pullout and matrix folding at lower volume fractions to the coexistence of brittle and ductile behaviors at higher volume fractions. The numerical simulations exhibit strong agreement with the experimental data. Multi-directional cross-sectional analysis further indicates that the initiation and propagation of shear bands are the principal drivers of structural instability. This study offers a robust theoretical foundation for the impact-resistant design and dynamic performance optimization of 3D-printed short fiber-reinforced polymer (SFRP) porous structures. Full article
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16 pages, 10388 KiB  
Article
Highly-Oriented Polylactic Acid Fiber Reinforced Polycaprolactone Composite Produced by Infused Fiber Mat Process for 3D Printed Tissue Engineering Technology
by Zhipeng Deng, Chen Rao, Simin Han, Qungui Wei, Yichen Liang, Jialong Liu and Dazhi Jiang
Polymers 2025, 17(15), 2138; https://doi.org/10.3390/polym17152138 - 5 Aug 2025
Viewed by 497
Abstract
Three-dimensional printed polycaprolactone (PCL) tissue engineering scaffolds have drawn increasing interest from the medical industry due to their excellent biocompatibility and biodegradability, yet PCL’s poor mechanical performance has limited their applications. This study introduces a biocompatible and biodegradable polylactic acid (PLA) fiber reinforced [...] Read more.
Three-dimensional printed polycaprolactone (PCL) tissue engineering scaffolds have drawn increasing interest from the medical industry due to their excellent biocompatibility and biodegradability, yet PCL’s poor mechanical performance has limited their applications. This study introduces a biocompatible and biodegradable polylactic acid (PLA) fiber reinforced PCL (PLA/PCL) composite as the filament for 3D printed scaffolds to significantly enhance their mechanical performance: Special-made PLA short fiber mat was infused with PCL matrix and rolled into PLA/PCL filaments through a “Vacuum Assisted Resin Infusion” (VARI) process. The investigation revealed that the PLA fibers are highly oriented along the printing direction when using this filament for 3D printing due to the unique microstructure formed during the VARI process. At the same PLA fiber content, the percentage increase in Young’s modulus of the 3D printed strands using the filaments produced by the VARI process is 127.6% higher than the 3D printed strands using the filaments produced by the conventional melt blending process. The 3D printed tissue engineering scaffolds using the PLA/PCL composite filament with 11 wt% PLA fiber content also achieved an exceptional 84.2% and 143.3% increase in peak load and stiffness compared to the neat PCL counterpart. Full article
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20 pages, 3145 KiB  
Article
Determination of Dynamic Elastic Properties of 3D-Printed Nylon 12CF Using Impulse Excitation of Vibration
by Pedro F. Garcia, Armando Ramalho, Joel C. Vasco, Rui B. Ruben and Carlos Capela
Polymers 2025, 17(15), 2135; https://doi.org/10.3390/polym17152135 - 4 Aug 2025
Viewed by 408
Abstract
Material Extrusion (MEX) process is increasingly used to fabricate components for structural applications, driven by the availability of advanced materials and greater industrial adoption. In these contexts, understanding the mechanical performance of printed parts is crucial. However, conventional methods for assessing anisotropic elastic [...] Read more.
Material Extrusion (MEX) process is increasingly used to fabricate components for structural applications, driven by the availability of advanced materials and greater industrial adoption. In these contexts, understanding the mechanical performance of printed parts is crucial. However, conventional methods for assessing anisotropic elastic behavior often rely on expensive equipment and time-consuming procedures. The aim of this study is to evaluate the applicability of the impulse excitation of vibration (IEV) in characterizing the dynamic mechanical properties of a 3D-printed composite material. Tensile tests were also performed to compare quasi-static properties with the dynamic ones obtained through IEV. The tested material, Nylon 12CF, contains 35% short carbon fibers by weight and is commercially available from Stratasys. It is used in the fused deposition modeling (FDM) process, a Material Extrusion technology, and exhibits anisotropic mechanical properties. This is further reinforced by the filament deposition process, which affects the mechanical response of printed parts. Young’s modulus obtained in the direction perpendicular to the deposition plane (E33), obtained via IEV, was 14.77% higher than the value in the technical datasheet. Comparing methods, the Young’s modulus obtained in the deposition plane, in an inclined direction of 45 degrees in relation to the deposition direction (E45), showed a 22.95% difference between IEV and tensile tests, while Poisson’s ratio in the deposition plane (v12) differed by 6.78%. This data is critical for designing parts subject to demanding service conditions, and the results obtained (orthotropic elastic properties) can be used in finite element simulation software. Ultimately, this work reinforces the potential of the IEV method as an accessible and consistent alternative for characterizing the anisotropic properties of components produced through additive manufacturing (AM). Full article
(This article belongs to the Special Issue Mechanical Characterization of Polymer Composites)
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12 pages, 6639 KiB  
Article
Study of Space Micro Solid Thruster Using 3D-Printed Short Glass Fiber Reinforced Polyamide
by Haibo Yang, Zhongcan Chen, Xudong Yang, Chang Xu and Hanyu Deng
Aerospace 2025, 12(8), 663; https://doi.org/10.3390/aerospace12080663 - 26 Jul 2025
Viewed by 254
Abstract
To meet the rapid maneuverability and lightweight demands of micro-nano satellites, a space micro solid thruster using 3D-printed short glass fiber reinforced polyamide 6 (PA6GF) composites was developed. Thruster shells with wall thicknesses of 4, 3, and 2.5 mm were designed, and ground [...] Read more.
To meet the rapid maneuverability and lightweight demands of micro-nano satellites, a space micro solid thruster using 3D-printed short glass fiber reinforced polyamide 6 (PA6GF) composites was developed. Thruster shells with wall thicknesses of 4, 3, and 2.5 mm were designed, and ground ignition tests were conducted to monitor chamber pressure and shell temperature. Compared with conventional metallic thrusters, PA6GF composites have exhibited excellent thermal insulation and sufficient mechanical strength. Under 8 MPa and 2773 K ignition conditions, the shell thickness was reduced to 2.5 mm and could withstand pressures up to 10.37 MPa. These results indicate that PA6GF composites are well-suited for space micro solid thrusters with inner diameters of 15–70 mm, offering new possibilities for lightweight space propulsion system design. Full article
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18 pages, 2724 KiB  
Article
Projection-Based Simulation Method for Robotic 3D Printing of Large-Scale Polymer Composite Structures
by Yuen Xia, Kil-Sung Lee and Sung Kyu Ha
Polymers 2025, 17(11), 1564; https://doi.org/10.3390/polym17111564 - 4 Jun 2025
Viewed by 643
Abstract
As large-scale additive manufacturing advances, the reliable prediction of the structural behavior of FDM-printed composites is becoming increasingly important. However, existing finite element methods often oversimplify the material anisotropy introduced by the printing path. This study proposes a projection-based method that maps toolpath-defined [...] Read more.
As large-scale additive manufacturing advances, the reliable prediction of the structural behavior of FDM-printed composites is becoming increasingly important. However, existing finite element methods often oversimplify the material anisotropy introduced by the printing path. This study proposes a projection-based method that maps toolpath-defined fiber orientations directly into a finite element model to represent anisotropic mechanical behavior. The mechanical properties of printed carbon fiber-reinforced ABS were experimentally characterized in three directions (UDL, UDT, and UD10). The results confirmed strong anisotropy, with elastic moduli ranging from 3.2 to 9.8 GPa and tensile strengths from 20 to 81 MPa. The shear modulus and strength obtained from the 10° off-axis tensile tests were 1.17 GPa and 10.9 MPa, respectively. This directional data enabled the implementation of the FE model of a 20 m-long printed ship structure. The predicted mid-span deflection (2.19 mm) differed by only 5% from the experimental measurement (2.08 mm). While effective, this method may face challenges with highly irregular geometries. Nevertheless, it offers a scalable approach for the accurate simulation of FDM-printed composites. Full article
(This article belongs to the Special Issue Sustainable Cost-Effective Lightweight Polymer Composites)
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16 pages, 4064 KiB  
Article
The Importance of Fiber Orientation for the Performance of High-Performance Polymer-Based Hybrid Materials in Sliding Contact with Steel
by Alois K. Schlarb, Miaozi Huang, Yao Xu, Chi Hua and Leyu Lin
Lubricants 2025, 13(6), 234; https://doi.org/10.3390/lubricants13060234 - 24 May 2025
Viewed by 674
Abstract
The properties of composite materials depend not only on the composition but also on the distribution and orientation of the fillers, i.e., on the internal material architecture. Using the example of two differently composed PEEK-based hybrid materials, the influence of fiber orientation on [...] Read more.
The properties of composite materials depend not only on the composition but also on the distribution and orientation of the fillers, i.e., on the internal material architecture. Using the example of two differently composed PEEK-based hybrid materials, the influence of fiber orientation on the tribological behavior of these materials in sliding contact with steel was investigated. The tribological performance of these composites was assessed using a pin-on-disc (PoD) tribometer, testing in a pv range from 0.25 to 32 MPa·m/s. The findings indicate that the printed specimens exhibit a high degree of fiber orientation aligned parallel to the printing paths. Conversely, the injection-molded samples display a three-layered structure across the thickness, with fibers in the skin layers aligned parallel to the injection direction but perpendicular to it in the core. These variations in morphology are evident in both the mechanical properties and the tribological behavior. To describe the influence of the fiber orientation on tribological properties, a model is proposed that allows the prediction of tribological properties for any fiber orientation. Although fiber orientation appears to be the dominant factor in tribological behavior, there is also a clear influence of additional fillers. Full article
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20 pages, 1483 KiB  
Article
The Effect of Synthesis Conditions and Chemical Structure of Thermoplastic Polyimides on Their Thermomechanical Properties and Short-Term Electrical Strength
by Victor M. Nazarychev, Andrey A. Pavlov, Almaz M. Kamalov, Margarita E. Borisova, Andrei L. Didenko, Elena M. Ivan’kova, Vadim E. Kraft, Gleb V. Vaganov, Alexandra L. Nikolaeva, Anna S. Ivanova, Victor K. Lavrentiev, Elena N. Popova, Ivan V. Abalov, Aleksey N. Blokhin, Alexander N. Bugrov and Vladislav V. Kudryavtsev
Polymers 2025, 17(10), 1385; https://doi.org/10.3390/polym17101385 - 18 May 2025
Viewed by 684
Abstract
Polyimides (PIs) are materials that are resistant to high temperatures and crucial for the manufacturing of films, fibers, coatings, and 3D-printed items. PIs are widely used as electrically insulating materials in electronics and electrical engineering. This study investigated how the chemical structure (i.e., [...] Read more.
Polyimides (PIs) are materials that are resistant to high temperatures and crucial for the manufacturing of films, fibers, coatings, and 3D-printed items. PIs are widely used as electrically insulating materials in electronics and electrical engineering. This study investigated how the chemical structure (i.e., choice of initial monomers), the synthesis conditions of the prepolymer (i.e., choice of amide solvent), and the conditions for forming polyimide films (i.e., final curing temperature) affect the thermophysical properties and short-term electrical strength of obtained polyimide films of different chemical structures. In this work, we varied the compositions of the dianhydrides used for synthesizing polyamic acids—pyromellitic acid (PMDA), tetracarboxylic acid diphenyl oxide (ODPA) and 1,3-bis(3′,4-dicarboxyphenoxy)benzene acid (R)—with a constant diamine: 4,4′-oxydianiline (ODA). Additionally, we varied the amide solvents employed: N,N-dimethylacetamide (DMAc), N,N-dimethylformamide (DMF), and N-methyl-2-pyrrolidone (NMP). This study represents the first investigation into how the choice of solvent in the synthesis of thermoplastic polyimide prepolymers affects their short-term electrical strength. The molecular weights of the polyamic acids were determined using gel permeation chromatography (GPC). The deformation and strength characteristics of the investigated films were also assessed. The thermophysical properties of the polyimides were evaluated via dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). X-ray diffraction analysis and infrared spectroscopy (IR) were conducted on the examined film samples. The short-term electrical strength was also evaluated. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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24 pages, 12478 KiB  
Article
Orthotropic Constitutive Modeling and Tsai–Wu Failure Criterion for Carbon Fiber-Reinforced PEEK Composites
by Yu Ye, Zixin Yang, Dianwei Qu, Bingyin Hu and Lei Li
Polymers 2025, 17(8), 1076; https://doi.org/10.3390/polym17081076 - 16 Apr 2025
Viewed by 633
Abstract
This paper performs orthotropic constitutive modeling for short carbon fiber-reinforced polyetheretherketone (CF-PEEK) composites fabricated using material extrusion 3D printing technology. A variety of specimens for tensile, compressive, and shear tests are 3D printed under different deposition path patterns. The related experimental results disclose [...] Read more.
This paper performs orthotropic constitutive modeling for short carbon fiber-reinforced polyetheretherketone (CF-PEEK) composites fabricated using material extrusion 3D printing technology. A variety of specimens for tensile, compressive, and shear tests are 3D printed under different deposition path patterns. The related experimental results disclose the strong directional mechanical properties, including tensile/compressive modulus and strength. The Tsai–Wu failure criterion is also developed based on the experimental data. The tensile–compressive behavior models of different orthotropic materials were constructed by importing the experimental data into COMSOL, followed by a compression simulation of the S-shaped specimen. The experimental results of the S-shaped compression test were compared with the COMSOL-based simulation analysis, which validated the effectiveness of the Tsai–Wu failure prediction. The predicted failure timings, locations and load–displacement curves all show a good agreement with experimental observations. Furthermore, the Tsai–Wu failure index is incorporated as a stress constraint in structural topology optimization, showing the effect of significantly reduced stress concentration. These findings and data will be supportive for the design and optimization of 3D printed CF-PEEK composites. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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34 pages, 11753 KiB  
Review
Fused Deposition Modeling of Polymer Composites: Development, Properties and Applications
by Aldobenedetto Zotti, Teresa Paduano, Francesco Napolitano, Simona Zuppolini, Mauro Zarrelli and Anna Borriello
Polymers 2025, 17(8), 1054; https://doi.org/10.3390/polym17081054 - 14 Apr 2025
Cited by 2 | Viewed by 1393
Abstract
This review summarizes recent research advancements in thermoplastic composites used in Fused Deposition Modeling (FDM) processes. Since its development in 1988, FDM has emerged as one of the primary emerging technologies of Industry 4.0, receiving attention in fields such as industrial manufacturing, automotive, [...] Read more.
This review summarizes recent research advancements in thermoplastic composites used in Fused Deposition Modeling (FDM) processes. Since its development in 1988, FDM has emerged as one of the primary emerging technologies of Industry 4.0, receiving attention in fields such as industrial manufacturing, automotive, aerospace, and others, particularly for rapid prototyping and customization. The intention is to make available a guideline for 3D printing researchers, analyzing the properties and performance characteristics of different polymers and polymeric composites. The review analysis covers various reinforcing agents, including particles/nanoparticles, short fibers, and long fibers, identifying critical parameters of the FDM process which affect printed part quality, integrity and final geometry. Major attention is devoted to the different techniques employed for composite filament fabrication, mostly for structural elements and parts. An extensive overview of various FDM composites and fiber-reinforced composites by polymer matrices such as PLA, ABS, and PEEK is presented, with their mechanical and thermal properties reported for specific applications. Current challenges and prospective future research directions are also outlined, mainly focusing on the enhancement of material performance and sustainability. Full article
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16 pages, 4629 KiB  
Article
Evaluation of Mechanical, Thermal, and Tribological Properties of 3D-Printed Nylon (PA6) Hybrid Composites Reinforced with MWCNTs and Carbon Fibers
by Palaiam Siddikali and P. S. Rama Sreekanth
J. Compos. Sci. 2025, 9(4), 155; https://doi.org/10.3390/jcs9040155 - 24 Mar 2025
Cited by 1 | Viewed by 910
Abstract
Three-dimensionally-printed carbonfiber-reinforced composites are increasingly replacing thermosetting polymers and metals due to their lightweight structure and enhanced mechanical performance. This investigation examines the mechanical, thermal and tribological characteristics of 3D-printed nylon (PA6) composites reinforced with 0.5 wt.% multi-walled carbon nanotubes (MWCNTs), 15 wt.% [...] Read more.
Three-dimensionally-printed carbonfiber-reinforced composites are increasingly replacing thermosetting polymers and metals due to their lightweight structure and enhanced mechanical performance. This investigation examines the mechanical, thermal and tribological characteristics of 3D-printed nylon (PA6) composites reinforced with 0.5 wt.% multi-walled carbon nanotubes (MWCNTs), 15 wt.% short carbon fibers (CF), and a hybrid combination of both, consisting of 0.5 wt.% MWCNTs and 15 wt.% CF. This study focuses on evaluating the individual and synergistic effects of these reinforcements on the performance of nylon-based composites. A series of characterizations, including mechanical, thermal, tribological, morphological and FTIR analyses, are conducted. The tensile and flexural strengths of the hybrid composite are improved by 35% and 42%, respectively, compared to pure nylon. The findings emphasize the substantial influence of hybrid reinforcement on enhancing mechanical, thermal, and tribological properties, providing useful information on the possible utilization of these composites in engineering applications requiring high-performance materials. Full article
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16 pages, 4374 KiB  
Article
Investigation of Short Carbon Fiber-Reinforced Polylactic Acid Composites Blades for Horizontal Axis Wind Turbines: Mechanical Strength and Energy Efficiency of Fused Filament Fabrication-Printed Blades
by Lotfi Ben Said, Sarhan Karray, Wissem Zghal, Hamdi Hentati, Badreddine Ayadi, Alaa Chabir and Muapper Alhadri
J. Compos. Sci. 2025, 9(3), 118; https://doi.org/10.3390/jcs9030118 - 4 Mar 2025
Cited by 3 | Viewed by 1168
Abstract
The use of 3D printing is expanding in manufacturing wind turbine blades for renewable energy. This study examines the relationship between geometric parameters, mechanical strength, and aerodynamic performance in blades made from short carbon fiber-reinforced PLA (SCFR-PLA) composites. To achieve this, it includes [...] Read more.
The use of 3D printing is expanding in manufacturing wind turbine blades for renewable energy. This study examines the relationship between geometric parameters, mechanical strength, and aerodynamic performance in blades made from short carbon fiber-reinforced PLA (SCFR-PLA) composites. To achieve this, it includes a comparative evaluation of innovative blade designs and materials, aiming to enhance both the energy efficiency and mechanical durability of horizontal axis wind turbines (HAWTs). The numerical model of the wind turbine blade is validated against experimental results, which employed a NACA geometry and ABS polymer. Building upon this validation, a design of experiments (DOE) analysis is employed to explore the influence of fused filament fabrication (FFF) parameters on the mechanical properties of SCFR-PLA composites. A novel blade design, referred to as HAWTSav, is numerically evaluated using 3D-printed SCFR-PLA composites. Numerical simulations are conducted to evaluate the energy efficiency and structural integrity of the HAWTSav blade. A comparative analysis is then performed, contrasting the performance of the conventional NACA blade in ABS with the HAWTSav blade in SCFR-PLA composites. The findings highlight the potential of SCFR-PLA composites in the development of efficient and durable wind turbine blades, highlighting their applicability, particularly in small-scale wind energy systems. Full article
(This article belongs to the Special Issue Application of Composite Materials in Additive Manufacturing)
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17 pages, 2935 KiB  
Article
Effect of Fiber Content on the Preparation and Mechanical Properties of 3D Printed Short Carbon Fiber Reinforced PA Composites
by Yesong Wang, Feilong Li, Zixuan Sun, Chenyu Gu, Kunkun Fu and Xiangming Zhao
Polymers 2025, 17(5), 671; https://doi.org/10.3390/polym17050671 - 2 Mar 2025
Cited by 2 | Viewed by 1817
Abstract
3D-printed short-carbon-fiber-reinforced thermoplastic composites have attracted significant attention from both the academic and industrial communities due to their remarkable advantages such as lightweight, high strength, and recyclability. However, in most of the current 3D-printing-related nylon composites, the content of short carbon fibers is [...] Read more.
3D-printed short-carbon-fiber-reinforced thermoplastic composites have attracted significant attention from both the academic and industrial communities due to their remarkable advantages such as lightweight, high strength, and recyclability. However, in most of the current 3D-printing-related nylon composites, the content of short carbon fibers is generally low, and the influence laws of short carbon fibers on the mechanical properties of the composites have not been fully explored. This paper focuses on short-carbon-fiber-reinforced nylon (SCF/PA) composites with short-carbon-fiber contents of 15 wt%, 25 wt%, and 35 wt%, respectively. It studies in depth their mechanical properties and related characteristics. The research results show that with the increase in the short-carbon-fiber content, the melt flow rate of the SCF/PA composites shows a downward trend. In terms of mechanical properties, when the short-carbon-fiber content is 25 wt%, the tensile strength and flexural strength of the composite reach their maximum values, which are 101.43 MPa and 173.16 MPa, respectively. Compared with pure nylon, the improvement ranges are 17.01% and 21.4%, respectively. When the short-carbon-fiber content is 35 wt%, the impact resistance of the material reaches its optimal value, which is 6.02 KJ/m2, an increase of 38.1% compared with pure nylon. At the same time, when the short-carbon-fiber content is 35 wt%, the thermal deformation temperature of the material also shows a certain degree of slight increase. In summary, the research results of this paper will provide more abundant and detailed experimental data support for 3D-printed short-carbon-fiber-reinforced nylon composites in various different application scenarios, facilitating further exploration and application in related fields. Full article
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15 pages, 2050 KiB  
Article
Novel Treatment of 3D-Printed Short-Carbon-Fiber-Reinforced Polyamide (3D-SCFRPA66) Using Homogeneous Low-Potential Electron Beam Irradiation (HLEBI) and Ductility Enhancement
by Eiichi Miura, Helmut Takahiro Uchida, Taisuke Okazaki, Kohei Sagawa, Michael C. Faudree, Michelle Salvia, Hideki Kimura and Yoshitake Nishi
Polymers 2024, 16(23), 3408; https://doi.org/10.3390/polym16233408 - 3 Dec 2024
Cited by 1 | Viewed by 1647
Abstract
In short-carbon-fiber-reinforced polyamide 66 articles shaped by 3D printing (3D-SCFRPA66), the interfaces between printed layers are often susceptible to damage, and the composite is excessively brittle. Therefore, a novel treatment for 3D-printed short-carbon-fiber-reinforced polyamide (3D-SCFRPA66) using homogeneous low-potential electron beam irradiation (HLEBI) to [...] Read more.
In short-carbon-fiber-reinforced polyamide 66 articles shaped by 3D printing (3D-SCFRPA66), the interfaces between printed layers are often susceptible to damage, and the composite is excessively brittle. Therefore, a novel treatment for 3D-printed short-carbon-fiber-reinforced polyamide (3D-SCFRPA66) using homogeneous low-potential electron beam irradiation (HLEBI) to enhance tensile properties was investigated. In 3D-SCFRPA66 samples, ductility was measured based on the following parameters: strain at tensile strength (corresponding to homogeneous deformation) (εts) and resistance energy to homogeneous deformation, a measure of toughness (Ehd), which were both substantially increased. An HLEBI dose of 43.2 kGy at an acceleration potential of 210 kV for the finished 3D-SCFRPA66 samples increased the εts and Ehd values from 0.031 and 1.20 MPa·m for the untreated samples to 0.270 and 6.05 MPa·m for the treated samples, increases of 771% and 504%, respectively. Higher HLEBI doses of 86, 129, or 215 kGy also increased the εts and Ehd values to lesser degrees. Electron spin resonance (ESR) data in the literature show that HLEBI creates dangling bonds in Nylon 6. Since PA66 and Nylon 6 are constructed of C, N, and O and have similar molecular structures, HLEBI apparently severs the (-C-N-) bonds in the backbone of PA66, which have the lowest bond-dissociation energy (BDE) of ~326 to 335 kJ mol−1. This shortens the PA66 chains for higher ductility. In addition, for Nylon 6, X-ray photoelectron spectroscopy (XPS) data in the literature show that HLEBI reduces the N peak while increasing the C peak, indicating the occurrence of shortening chains via dangling bond formation accompanied by increases in crosslinking with carbon bonds. However, caution is advised, since HLEBI was found to decrease the tensile strength (σts) and initial elasticity ([dσ/dε]i) of 3D-SCFRPA66. This tradeoff can possibly allow the HLEBI dose to be adjusted for the desired ductility and strength while minimizing energy consumption. Full article
(This article belongs to the Special Issue Mechanical Characterization of Polymer Composites)
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21 pages, 8351 KiB  
Review
Application of Poly(lactic Acid) Composites in the Automotive Sector: A Critical Review
by Valentina Giammaria, Monica Capretti, Giulia Del Bianco, Simonetta Boria and Carlo Santulli
Polymers 2024, 16(21), 3059; https://doi.org/10.3390/polym16213059 - 30 Oct 2024
Cited by 15 | Viewed by 3410
Abstract
The introduction of bio-based matrices in automotive applications would, in principle, increase their sustainability and, in case the use of secondary raw materials is also involved, even result in reduced resource depletion. The bio-based polymer composite matrix that has been mainly brought forward [...] Read more.
The introduction of bio-based matrices in automotive applications would, in principle, increase their sustainability and, in case the use of secondary raw materials is also involved, even result in reduced resource depletion. The bio-based polymer composite matrix that has been mainly brought forward towards industrial application is poly(lactic acid) (PLA), which has often been proposed as the replacement for matrices based on polyolefins in fields such as packaging and short-term commodities since, in general, it matches the needs for conventional thermoplastic production processes. The passage to the automotive sector is not obvious, though: problems affecting durability, the relation with water and the environment, together with the requirement for outstanding mechanical and impact performance appear very stringent. On the other hand, PLA has obtained durable success in additive manufacturing as a competitor for acrylonitrile butadiene styrene (ABS). Also, the perspective for 3D and 4D printing does not appear to be confined to bare prototyping. These contrasting pieces of evidence indicate the necessity to provide more insight into the possible development of PLA use in the automotive industry, also considering the pressure for the combined use of more sustainable reinforcement types in automotive composites, such as natural fibers. Full article
(This article belongs to the Section Polymer Applications)
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23 pages, 10289 KiB  
Article
Optimization of Production Parameters for Impact Strength of 3D-Printed Carbon/Glass Fiber-Reinforced Nylon Composite in Critical ZX Printing Orientation
by Selim Hartomacioğlu
Polymers 2024, 16(21), 3006; https://doi.org/10.3390/polym16213006 - 26 Oct 2024
Cited by 4 | Viewed by 2437
Abstract
Additive manufacturing (AM) methods are increasingly being adopted as an alternative for mass production. In particular, Fused Deposition Modeling (FDM) technology is leading the way in this field. However, the adhesion of the layers in products produced using FDM technology is an important [...] Read more.
Additive manufacturing (AM) methods are increasingly being adopted as an alternative for mass production. In particular, Fused Deposition Modeling (FDM) technology is leading the way in this field. However, the adhesion of the layers in products produced using FDM technology is an important issue. These products are particularly vulnerable to forces acting parallel to the layers and especially to impact strength. Most products used in the industry have complex geometries and thin walls. Therefore, solid infill is often required in production, and this production must take place in the ZX orientation. This study aims to optimize the impact strength against loads acting parallel to the layers (ZX orientation) of PA6, one of the most widely used materials in the industry. This orientation is critical in terms of mechanical properties, and the mechanical characteristics are significantly lower compared to other orientations. In this study, filaments containing pure PA6 with 15% short carbon fiber and 30% glass fiber were utilized. Additionally, the printing temperature, layer thickness and heat treatment duration were used as independent variables. An L9 orthogonal array was employed for experimental design and then each experiment was repeated three times to conduct impact strength tests. Characterization, Taguchi optimization, and factor analyses were performed, followed by fracture surface characterization by SEM. As a result, the highest impact strength was achieved with pure PA6 at 8.9 kJ/m2, followed by PA6 GF30 at 8.1 kJ/m2, and the lowest impact strength was obtained with PA6 CF15 at 6.258 kJ/m2. Compared to the literature and manufacturer datasheets, it was concluded that the impact strength values had significantly increased and the chosen experimental factors and their levels, particularly nozzle temperature, were effective. Full article
(This article belongs to the Special Issue 3D Printing of Polymer Composite Materials)
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