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Keywords = sawdust

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13 pages, 1674 KiB  
Article
Impact of Substrate Amount and Fruiting Induction Methods in Lentinula edodes Cultivation
by Bruno de Souza Rocha, Wagner Gonçalves Vieira Junior, Adriano Taffarel Camargo de Paula, Asser Botelho Santana, Marcos Antônio da Silva Freitas, Milton Mineo Hirai, Lucas da Silva Alves and Diego Cunha Zied
Horticulturae 2025, 11(8), 915; https://doi.org/10.3390/horticulturae11080915 (registering DOI) - 4 Aug 2025
Abstract
Mushroom production is a sustainable practice but requires improvements, such as in Lentinula edodes (Berk) Pegler cultivation, which has high water and labor demands. In this context, this study proposed replacing the traditional primordia induction method by submersion with a water injection method. [...] Read more.
Mushroom production is a sustainable practice but requires improvements, such as in Lentinula edodes (Berk) Pegler cultivation, which has high water and labor demands. In this context, this study proposed replacing the traditional primordia induction method by submersion with a water injection method. Two primordia induction methods (submersion and injection) and two cultivation block formats were compared: rectangular cube (2 kg) and cylindrical (3.5 kg). The substrate, composed of eucalyptus sawdust (72%), wheat bran (12.5%), rice bran (12.5%), CaCO3 (1%), and CaSO4 (2%), was inoculated with strain LED 19/11 and incubated for 80 days at 26 ± 5 °C and 85 ± 15% humidity. After this period, the blocks were washed and transferred to the production environment. Fruiting was induced either by submersion or water injection, and production was evaluated over four harvest flushes. The 2 kg blocks had higher yields with submersion (16.62%), while the 3.5 kg blocks responded better to injection (13.01%), showing more homogeneous production. Increasing the substrate quantity contributes to greater harvest stability across production cycles. Water injections proved to be a viable alternative, reducing handling and facilitating large-scale production. The use of this technique demonstrates great importance in reducing water use and also the need for labor in cultivation. Full article
(This article belongs to the Section Vegetable Production Systems)
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13 pages, 1267 KiB  
Article
Toward Green Substitutes: Electrochemical Properties of Conductive Inks Containing Biochar
by Gordana Stevanović, Jovan Parlić, Marija Ajduković, Nataša Jović-Jovičić, Vojkan Radonjić and Zorica Mojović
Sustain. Chem. 2025, 6(3), 21; https://doi.org/10.3390/suschem6030021 - 31 Jul 2025
Viewed by 121
Abstract
Dry Turkish oak (Quercus cerris) sawdust, untreated and treated with three activators, (H3PO4, NaOH and H2O2) was pyrolyzed under limited-oxygen conditions to obtain biochar samples. The electrochemical properties of these samples were tested [...] Read more.
Dry Turkish oak (Quercus cerris) sawdust, untreated and treated with three activators, (H3PO4, NaOH and H2O2) was pyrolyzed under limited-oxygen conditions to obtain biochar samples. The electrochemical properties of these samples were tested and compared to the properties of several commercial carbon blacks. The electrochemical characterization was performed via cyclic voltammetry, analyzing the response toward two commonly used redox probes, [Fe(CN)6]3−/−4− and [Ru(NH3)6]2+/3+. The influence of the scan rate on this response was investigated, and the resulting data were used to obtain the values of the heterogenous charge transfer constant, k0. Higher k0 values were observed for carbon blacks than for investigated biochar samples. The detection of 4-nitrophenol and heavy metal ions was used to assess the applicability of biochars for electroanalytical purposes. The response of untreated biochar was comparable with the response of Vulcan carbon black, which showed the best response of all analyzed carbon blacks. Full article
18 pages, 3972 KiB  
Article
The Influence of Halloysite Clay on the Properties of the Polybutylene Succinate (PBS)/Sawdust, PBS/Sugarcane Bagasse, and PBS/Sawdust/Sugarcane Bagasse Hybrid Composites
by Tlholohelo Sylvia Sikhosana, Ntsoaki Joyce Malebo, Mpho Phillip Motloung, Tladi Gideon Mofokeng and Mokgaotsa Jonas Mochane
Polymers 2025, 17(15), 2120; https://doi.org/10.3390/polym17152120 - 31 Jul 2025
Viewed by 233
Abstract
In this study, the influences of natural fibres (sugarcane bagasse (SB) and sawdust (SD)) on the material properties of polybutylene succinate (PBS) prepared through melt compounding were investigated. The study further evaluated the effects of incorporating halloysite nanotubes (HS) and expandable graphite (EG) [...] Read more.
In this study, the influences of natural fibres (sugarcane bagasse (SB) and sawdust (SD)) on the material properties of polybutylene succinate (PBS) prepared through melt compounding were investigated. The study further evaluated the effects of incorporating halloysite nanotubes (HS) and expandable graphite (EG) on the properties of PBS/SD and PBS/SB binary and PBS/SB/SD hybrid composites. The morphological analysis indicated poor interfacial adhesion between PBS and the fibres. The obtained findings indicated enhancements in the complex viscosity of PBS in the presence of natural fibres, and further improvements in the presence of HS and EG. The stiffness of PBS hybrid composites also increased upon the addition of HS and EG. Moreover, the crystallization temperatures of PBS increased in the presence of fillers, with EG showing better nucleation efficiency. However, the mechanical properties (toughness and impact resilience) decreased due to the increased stiffness of the composites and the poor interfacial adhesion between the matrix and the fillers, indicating the need to pre-treat the fibres to enhance compatibility. Overall, the material properties of PBS/SD/SB hybrid composites were enhanced by incorporating HS and EG at low concentrations. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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18 pages, 2688 KiB  
Article
Acid-Modified Biochar Derived from Agricultural Waste for Efficiently Capturing Low-Concentration Nitrous Oxide (N2O): Mechanisms and Environmental Implications
by Mingming Fu, Yingdi Ma, Fengrui Yang, Ziyu Xiao, Mei Wang, Shaoyuan Bai, Qin Zhang, Huili Liu, Dandan Xu and Yanan Zhang
Toxics 2025, 13(8), 623; https://doi.org/10.3390/toxics13080623 - 25 Jul 2025
Viewed by 381
Abstract
Low-concentration N2O (≤5%) emissions from agricultural fields and waste treatment facilities in China reach 7.333 × 105 t annually, making them a significant but inadequately controlled contributor to global warming. Agricultural wastes were selected as precursors to prepare biochar, including [...] Read more.
Low-concentration N2O (≤5%) emissions from agricultural fields and waste treatment facilities in China reach 7.333 × 105 t annually, making them a significant but inadequately controlled contributor to global warming. Agricultural wastes were selected as precursors to prepare biochar, including pecan shell (SH), poplar sawdust (JM), wheat straw (XM), and corn straw (YM), which were subsequently acid-modified with 0.1 mol L−1 HCl. The objectives were (i) to quantify the enhancement in N2O capture achievable by acid treatment, (ii) to elucidate the underlying chemisorption mechanism, and (iii) to identify the most efficient feedstock for practical deployment. Acid modification increased the oxygen content, specific surface area, and the number of hydroxyl and carboxyl groups on the biochar surface. Both modified and unmodified biochar followed the pseudo-second-order kinetic model (R2 ≥ 0.960), indicating chemisorption-dominated processes. The adsorption performance ranked as XM > JM > SH > YM, with XM exhibiting the highest adsorption capacity (26.000 mol/kg unmodified, 43.088 mol/kg modified, 65.72% increase). The Langmuir model provided a better fit for N2O adsorption, suggesting dynamic multilayer heterogeneous adsorption. The findings demonstrate that acid-modified biochar derived from agricultural waste is a scalable, economical, and environmentally friendly adsorbent for mitigating low-concentration N2O emissions. Full article
(This article belongs to the Section Toxicity Reduction and Environmental Remediation)
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23 pages, 737 KiB  
Article
Influence of Plant-Based Substrate Composition and Extraction Method on Accumulation of Bioactive Compounds in Hericium erinaceus (Bull.) Pers. Fruiting Bodies
by Katarzyna Kała, Małgorzata Cicha-Jeleń, Katarzyna Sułkowska-Ziaja, Beata Ostachowicz, Ewa Węgrzynowicz, Jan Lazur, Agnieszka Szewczyk and Bożena Muszyńska
Molecules 2025, 30(15), 3094; https://doi.org/10.3390/molecules30153094 - 24 Jul 2025
Viewed by 342
Abstract
The selection of plant-based substrates for mushroom cultivation is a key factor influencing their growth and metabolism. The aim of this study was to demonstrate, in an innovative approach, differences in the content of biologically active compounds, bioelements, and antioxidant properties of Hericium [...] Read more.
The selection of plant-based substrates for mushroom cultivation is a key factor influencing their growth and metabolism. The aim of this study was to demonstrate, in an innovative approach, differences in the content of biologically active compounds, bioelements, and antioxidant properties of Hericium erinaceus (Bull.) Pers. cultivated on various plant-based substrates derived from waste materials, specifically hemp straw and beech sawdust. Another objective was to compare various extraction methods in terms of their impact on the concentration of these compounds. Elemental analysis was performed using the TXRF method, while bioactive constituents were determined using the DAD/UV RP-HPLC technique. The plant-based substrate and extraction method influenced the levels of obtained metabolites. Dual extraction with moderate ethanol concentrations was most effective for isolating key bioactive compounds from H. erinaceus—notably ergothioneine, lovastatin, L-phenylalanine, and ergosterol—while antioxidant activity did not correlate with the concentration of the solvent used. Although dual extracts enhanced certain antioxidants and metabolites, whole fruiting bodies contained higher levels of bioelements. Overall, fruiting bodies grown on beech sawdust had greater amounts of most bioactive compounds compared to those cultivated on hemp straw, emphasizing that both substrate choice and extraction method critically influence the mushroom’s bioactive profile and its potential health benefits. Full article
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15 pages, 2168 KiB  
Article
Utilization of Giant Mimosa Stalk to Produce Effective Stick Spawn for Reducing Inoculum Costs in Economic Mushroom Farming Systems
by Orlavanh Xayyavong, Worawoot Aiduang, Kritsana Jatuwong and Saisamorn Lumyong
Agriculture 2025, 15(15), 1584; https://doi.org/10.3390/agriculture15151584 - 23 Jul 2025
Viewed by 248
Abstract
The high cost of mushroom spawn remains a critical constraint to economically viable mushroom cultivation, particularly for small-scale farmers. This study investigated four spawn types, including stick (giant mimosa stalks, GMS), sawdust, sorghum, and liquid culture as inoculum sources for 10 edible mushroom [...] Read more.
The high cost of mushroom spawn remains a critical constraint to economically viable mushroom cultivation, particularly for small-scale farmers. This study investigated four spawn types, including stick (giant mimosa stalks, GMS), sawdust, sorghum, and liquid culture as inoculum sources for 10 edible mushroom species. The results indicated that GMS stick spawn provides excellent conditions for the mycelial growth of seven species, outperforming other spawn types in terms of colonization rate and pinhead formation. Mushrooms grown on GMS substrate demonstrated rapid development, with full colonization occurring within 11 to 26 days and pinhead initiation between 18 and 47 days, depending on the species. Among the mushroom species tested, Schizophyllum commune exhibited the fastest growth, reaching full colonization in 11 days and forming pinheads after 18 days of inoculation. In comparison, Auricularia polytricha showed the slowest development. Economically, GMS spawn was the most cost-effective at 0.074 USD per unit, significantly lower than sawdust (0.24 USD), sorghum (0.29 USD), and potato dextrose broth (PDB; 2.80 USD). The conversion from PDB with GMS could reduce industrial inoculum costs from 35,000 USD to 600 USD annually. These findings demonstrate the potential of GMS as an effective, low-cost, and sustainable spawn option that can enhance mycelial growth and support eco-friendly farming practices. Full article
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17 pages, 2649 KiB  
Article
Effect of Low-Temperature Preheating on the Physicochemical Properties and Energy Quality of Pine Sawdust
by Tingzhou Lei, Yang Mei, Yuanna Li, Yunbo Wang, Suyang Liu and Yantao Yang
Energies 2025, 18(14), 3875; https://doi.org/10.3390/en18143875 - 21 Jul 2025
Cited by 1 | Viewed by 257
Abstract
The advantages of torrefaction preheating, including the production of a hydrophobic solid product, improved particle size distribution, enhanced fuel properties with fewer environmental issues, decreased moisture content, and reduced volatile content. In order to meet the technical requirements of biomass oriented value-added and [...] Read more.
The advantages of torrefaction preheating, including the production of a hydrophobic solid product, improved particle size distribution, enhanced fuel properties with fewer environmental issues, decreased moisture content, and reduced volatile content. In order to meet the technical requirements of biomass oriented value-added and energy saving and emission reduction, pine sawdust (PS) was taken as the research object, and the physicochemical properties of the PS samples preheated at a low temperature were analyzed by synchronous thermal analysis (TG-DSC), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), and organic element analyzer (EA). The effect of preheating at a lower temperature on the physicochemical properties of PS was discussed. The results showed that, under the preheating condition of 200 °C, compared with PS, the water content of PS-200 decreased by 3.23%, the volatile content decreased by 3.69%, the fixed carbon increased by 6.81%, the calorific value increased by 6.90%, the equilibrium water content decreases from 7.06% to 4.46%, and the hydrophobicity increases. This research, based on the improvement of the quality of agricultural and forestry waste and the promotion of the strategy of converting waste into energy, has contributed to the advancement of sustainable energy production. Full article
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13 pages, 1873 KiB  
Article
Effect of Thickness Swelling and Termite Attack Resistance in Wood–Plastic Composites Produced with Pine Wood and Recycled Thermoplastics
by Emilly Silva, Yonny Lopez, Juarez Paes, Fernanda Maffioletti, Gabrielly Souza and Fabricio Gonçalves
Biomass 2025, 5(3), 43; https://doi.org/10.3390/biomass5030043 - 21 Jul 2025
Viewed by 427
Abstract
This research aimed to evaluate the biological resistance to xylophagous organisms and the dimensional stability related to water absorption in plastic wood panels manufactured by compression molding and produced with pine wood and recycled thermoplastics. The wood–plastic composites (WPCs) were prepared from 50% [...] Read more.
This research aimed to evaluate the biological resistance to xylophagous organisms and the dimensional stability related to water absorption in plastic wood panels manufactured by compression molding and produced with pine wood and recycled thermoplastics. The wood–plastic composites (WPCs) were prepared from 50% pine sawdust and 50% recycled plastics (polyethylene terephthalate-PET, high-density polyethylene-HDPE, and polypropylene-PP). The thickness swelling test was carried out by immersing of the WPC samples in water at room temperature (25–30 °C) and evaluating the total change in WPC thickness after 1500 h (≈9 weeks or two months). In addition, the coefficient of initial swelling was evaluated to verify the variability of the swelling. For the biological resistance evaluation of the WPCs, tests were carried out with soil or arboreal termites (Nasutitermes corniger) and drywood termites (Cryptotermes brevis). The WPC loss of mass and termite mortality were evaluated. The use of PP promoted the best response to thickness swelling. The simple mathematical model adopted offers real predictions to evaluate the thickness of the swelling of the compounds in a given time. For some variables there were no statistical differences. It was shown that treatment 3 (T3) presented visual damage values between 0.4 for drywood termites and 9.4 for soil termites, in addition to 26% termite mortality, represented by the lowest survival time of 12 days. The developed treatments have resistance to termite attacks; these properties can be an important starting point for its use on a larger scale by the panel industries. Full article
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14 pages, 3622 KiB  
Article
Surface Moisture Control for Sustainable Manure Management: Reducing Ammonia Emissions and Preserving Nutrients
by Ieva Knoknerienė, Rolandas Bleizgys and Vilma Naujokienė
Sustainability 2025, 17(14), 6617; https://doi.org/10.3390/su17146617 - 20 Jul 2025
Viewed by 334
Abstract
Researchers increasingly agree that livestock farming is the leading cause of air pollution with ammonia (NH3) gas. The existing research suggests that 30–80% of nitrogen is lost from slurry and liquid manure in the gaseous form of ammonia. Most studies have [...] Read more.
Researchers increasingly agree that livestock farming is the leading cause of air pollution with ammonia (NH3) gas. The existing research suggests that 30–80% of nitrogen is lost from slurry and liquid manure in the gaseous form of ammonia. Most studies have focused on environmental factors influencing ammonia volatilization and manure composition but not on controlling the moisture level on the surface of the excreta. Applying the principles of convective mass exchange, this study was undertaken to compare different types of organic covers that mitigate NH3 emissions and offer recommendations on how to properly apply organic covers on the surface of manure. Data was obtained from research in laboratory conditions comparing well-known coatings (chopped straw) with less commonly used organic materials (peat) or waste generated in other industries (sawdust, hemp chaff). This research demonstrated that applying bio-coatings can reduce ammonia (NH3) emissions at coating thicknesses of ≥5 cm for sawdust, ≥3 cm for peat, ≥10 cm for hemp chaff, and 8–12 cm for straw. These reductions are linked to the ability of the coatings to lower manure surface moisture evaporation, a key driver of ammonia volatilization, highlighting the role of surface moisture control in emission mitigation. Full article
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14 pages, 1686 KiB  
Article
Analysis of Sewage Sludge Drying Parameters Using Different Additives
by Małgorzata Makowska, Sebastian Kujawiak, Damian Janczak, Patryk Miler and Wojciech Czekała
Sustainability 2025, 17(14), 6500; https://doi.org/10.3390/su17146500 - 16 Jul 2025
Viewed by 268
Abstract
This paper describes the process of drying sewage sludge mixtures with the addition of various components: straw chaff, wood sawdust, ash, bark, wood chips, and walnut shells. The tests were conducted in two series: summer and autumn (with maximum insolation of 24.1 and [...] Read more.
This paper describes the process of drying sewage sludge mixtures with the addition of various components: straw chaff, wood sawdust, ash, bark, wood chips, and walnut shells. The tests were conducted in two series: summer and autumn (with maximum insolation of 24.1 and 29.8 MJ∙m−2, respectively). Using a set of sensors with which the experimental station was equipped, the parameters of the environment (temperature, humidity, and insolation) and the parameters of the dried mixtures (temperature and humidity) were measured. Based on the results obtained, the influence of external factors on the parameters, time, and drying effect of the respective mixtures was analyzed. With the initial moisture content of the mixtures ranging from 41 to 79%, a final moisture content of 6 to 49% was obtained, depending on the components and drying conditions. It was found that the drying rate was most influenced by the amount of solar energy and the associated outdoor (maximum 29 °C and 19 °C) and indoor (maximum 33 °C and 24 °C) air temperatures, and in the second series, there was an additional effect of the temperature of the mixtures (maximum 30 °C), upon which the intensity of water evaporation depended. Straw chaff and walnut shells proved to be the best additives, for which the highest drying rates were obtained (max. 50 to 60% humidity drop). The possibility of using dried materials for agricultural and energy purposes was indicated. This approach is in line with the principles of sustainable development. Full article
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6 pages, 657 KiB  
Proceeding Paper
Extraction of Lignin from Sawdust (Chlorophora excelsa)
by Abraham Thomas, Fadimatu N. Dabai, Benjamin O. Aderemi and Yahaya M. Sani
Chem. Proc. 2025, 17(1), 2; https://doi.org/10.3390/chemproc2025017002 - 16 Jul 2025
Viewed by 204
Abstract
Sawdust is an abundant source of lignocellulosic biomass, presenting a sustainable alternative to fossil fuels for producing aromatics, fuels, and chemicals. Lignin, a crucial component, can be depolymerized into valuable aromatics or used for polymer synthesis due to its multiple hydroxyl groups. This [...] Read more.
Sawdust is an abundant source of lignocellulosic biomass, presenting a sustainable alternative to fossil fuels for producing aromatics, fuels, and chemicals. Lignin, a crucial component, can be depolymerized into valuable aromatics or used for polymer synthesis due to its multiple hydroxyl groups. This study focuses on extracting lignin from Chlorophora excelsa sawdust via organosolv technology. The characterization of sawdust revealed 41.15% cellulose, 28.63% hemicellulose, and 26.13% lignin. The extraction process involved treating sawdust at varying temperatures (100–200 °C) with an ethanol–water solution and sulfuric acid. The optimal yield of 49.81% lignin occurred at 160 °C, confirming the chemical properties and composition of the extracted lignin. Full article
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17 pages, 504 KiB  
Article
Yield, Phytonutritional and Essential Mineral Element Profiles of Selected Aromatic Herbs: A Comparative Study of Hydroponics, Soilless and In-Soil Production Systems
by Beverly M. Mampholo, Mariette Truter and Martin M. Maboko
Plants 2025, 14(14), 2179; https://doi.org/10.3390/plants14142179 - 14 Jul 2025
Viewed by 243
Abstract
Increased market demand for plant herbs has prompted growers to ensure a continuous and assured supply of superior nutritional quality over the years. Apart from the nutritional value, culinary herbs contain phytochemical benefits that can improve human health. However, a significant amount of [...] Read more.
Increased market demand for plant herbs has prompted growers to ensure a continuous and assured supply of superior nutritional quality over the years. Apart from the nutritional value, culinary herbs contain phytochemical benefits that can improve human health. However, a significant amount of research has focused on enhancing yield, frequently overlooking the impact of production practices on the antioxidant and phytonutritional content of the produce. Thus, the study aimed to evaluate the yield, phytonutrients, and essential mineral profiling in selected aromatic herbs and their intricate role in nutritional quality when grown under different production systems. Five selected aromatic herbs (coriander, rocket, fennel, basil, and moss-curled parsley) were evaluated at harvest when grown under three production systems: in a gravel-film technique (GFT) hydroponic system and in soil, both under the 40% white shade-net structure, as well as in a soilless medium using sawdust under a non-temperature-controlled plastic tunnel (NTC). The phytonutritional quality properties (total phenolic, flavonoids, β-carotene-linoleic acid, and condensed tannins contents) as well as 1,1-diphenyl-2-picrylhydrazyl (DPPH) were assessed using spectrophotometry, while vitamin C and β-carotene were analyzed using HPLC-PDA, and leaf mineral content was evaluated using ICP-OES (Inductively Coupled Plasma Optical Emission Spectrometry). The results show that the health benefits vary greatly owing to the particular culinary herb. The fresh leaf mass (yield) of coriander, parsley, and rocket was not significantly affected by the production system, whereas basil was high in soil cultivation, followed by GFT. Fennel had a high yield in the GFT system compared to in-soil and in-soilless cultivation. The highest levels of vitamin C were found in basil leaves grown in GFT and in soil compared to the soilless medium. The amount of total phenolic and flavonoid compounds, β-carotene, β-carotene-linoleic acid, and DPPH, were considerably high in soil cultivation, except on condensed tannins compared to the GFT and soilless medium, which could be a result of Photosynthetic Active Radiation (PAR) values (683 μmol/m2/s) and not favoring the accumulation of tannins. Overall, the mineral content was greatly influenced by the production system. Leaf calcium and magnesium contents were highly accumulated in rockets grown in the soilless medium and the GFT hydroponic system. The results have highlighted that growing environmental conditions significantly impact the accumulation of health-promoting phytonutrients in aromatic herbs. Some have positive ramifications, while others have negative ramifications. As a result, growers should prioritize in-soil production systems over GFT (under the shade-net) and soilless cultivation (under NTC) to produce aromatic herbs to improve the functional benefits and customer health. Full article
(This article belongs to the Topic Nutritional and Phytochemical Composition of Plants)
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17 pages, 4964 KiB  
Article
Sustainable Development of Sawdust Biochar as a Green and Promising Material for CO2 Capture Technologies
by Ki-Seok Kwon and Han-Seung Lee
Materials 2025, 18(14), 3243; https://doi.org/10.3390/ma18143243 - 9 Jul 2025
Viewed by 309
Abstract
This study investigates the synthesis of highly porous ZnCl2-activated biochars derived from sawdust through controlled pyrolysis at 300 °C and 500 °C, aiming to enhance CO2 adsorption performance. The effects of pyrolysis temperature and chemical activation on particle size distribution, [...] Read more.
This study investigates the synthesis of highly porous ZnCl2-activated biochars derived from sawdust through controlled pyrolysis at 300 °C and 500 °C, aiming to enhance CO2 adsorption performance. The effects of pyrolysis temperature and chemical activation on particle size distribution, surface area, and pore structure are systematically analyzed. Particle size analysis reveals that higher pyrolysis temperature and ZnCl2 activation significantly reduce both median and mean particle sizes, resulting in finer and more uniform biochar morphology. BET analysis demonstrates a substantial increase in specific surface area and micropore volume upon ZnCl2 activation, particularly at 500 °C, where the activated biochar (S500ZC) exhibits a high surface area of 717.60 m2/g and a micropore area of 616.60 m2/g. CO2 adsorption isotherms recorded at 25 °C confirm that both thermal treatment and activation markedly enhance adsorption capacity, with the highest uptake of 35.34 cm3/g achieved by S500ZC. The adsorption performance follows the order: S300NZC < S300ZC < S500NZC < S500ZC, closely correlating with microporosity and surface textural development. The findings highlight the potential of ZnCl2-activated biochars as cost-effective, environmentally friendly, and efficient sorbents for scalable CO2 mitigation technologies. Full article
(This article belongs to the Section Green Materials)
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18 pages, 781 KiB  
Article
Technical Lignins Antibacterial Effects Against Environmental Mastitis Pathogens Across Various Levels of Bedding Cleanliness In Vitro
by Godloves M. Oppong, Diana C. Reyes, Zhengxin Ma, Santiago A. Rivera, Marjorie A. Killerby, Diego Zamudio, Anne B. Lichtenwalner and Juan J. Romero
Molecules 2025, 30(14), 2904; https://doi.org/10.3390/molecules30142904 - 9 Jul 2025
Viewed by 293
Abstract
This study aimed to evaluate the antibacterial activity of several technical lignins against major environmental bacteria that cause mastitis in dairy cattle. The efficacy of four types of technical lignins against environmental mastitis pathogens was evaluated using MIC and MBC assays. The best [...] Read more.
This study aimed to evaluate the antibacterial activity of several technical lignins against major environmental bacteria that cause mastitis in dairy cattle. The efficacy of four types of technical lignins against environmental mastitis pathogens was evaluated using MIC and MBC assays. The best candidate, sodium lignosulfonate (NaL-O), was further tested using sawdust bedding substrates. Substrates were prepared in different cleanliness conditions: sawdust only, sawdust plus urine, sawdust plus feces, or sawdust plus a combination of both. The antimicrobial activity of NaL-O against the mixture of environmental mastitis-causing pathogens was determined on days 0, 2, and 6 of incubation. In addition, the components of bedding substrates were analyzed to help understand the dynamics of pathogen loads. In the MIC and MBC assays, NaL-O showed the best antimicrobial performance against all pathogens except Escherichia coli. When testing in the bedding substrates, the addition of NaL-O decreased the concentration of Staphylococcus chromogenes, Streptococcus uberis, and Pseudomonas aeruginosa across all bedding cleanliness levels at d 0, 2, and 6 of incubation. As the incubation time increased, the antimicrobial effect decreased. NaL-O also lowered the counts of E. coli and Klebsiella pneumoniae across all incubation times, but to a lesser extent. The presence of feces significantly reduced the antibacterial effects of NaL-O for these two bacteria. Among the technical lignins tested, NaL-O showed the broadest antibacterial activity against the mastitis pathogens tested. This study suggests that NaL-O has promising potential as a bedding conditioner to control environmental pathogens on dairies due to its low cost, ready availability, and compatibility with sustainable livestock practices. Combined with bedding cleanliness, bedding conditioner application may play a crucial role in reducing the growth of EM pathogens and subsequent mastitis incidence. Full article
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20 pages, 9960 KiB  
Article
A Preliminary Investigation on the Adsorption of Cu2+ by Sawdust/Foamed Geopolymer Composites
by Shuang Wang, Hongqiang Li and Xiaofeng Zhang
Buildings 2025, 15(13), 2251; https://doi.org/10.3390/buildings15132251 - 26 Jun 2025
Viewed by 266
Abstract
Sawdust is receiving increasing attention as a promising green adsorbent. However, due to its powder nature, it is difficult to recover after adsorbing heavy metals and may even cause secondary pollution. To solve this problem, a novel sawdust/foamed geopolymer (SFG) adsorbent was prepared [...] Read more.
Sawdust is receiving increasing attention as a promising green adsorbent. However, due to its powder nature, it is difficult to recover after adsorbing heavy metals and may even cause secondary pollution. To solve this problem, a novel sawdust/foamed geopolymer (SFG) adsorbent was prepared by using sawdust as a raw material, geopolymer as a binder, and hydrogen peroxide as a foaming agent. This study discussed the effect of SFG dosage, solution temperature, solution pH, contact time, and initial Cu2+ solution concentration on the adsorption capacity and removal rate. The results showed that a desirable SFG adsorbent with the SFG dosage of 0.5 g, temperature of 25 °C, pH of 5, contact time of 720 min, and initial Cu2+ solution concentrations of 90 mg/L is recommended, of which the adsorption capacity is 31.5 mg/g with the removal rate being 92.76%. In addition, the adsorption performance of the SFG adsorbent is superior to that of pure sawdust and similar to that of the foamed geopolymer adsorbent, and it has the characteristics of higher strength, lower cost, and more environmental friendliness. This study indicated that the SFG adsorbents are feasible as adsorbents; meanwhile, this work can provide a scientific reference for the development of new bio-composite adsorbent materials, especially in the field of the treatment of heavy metal ions in wastewater. Full article
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