Search Results (472)

Saturable absorbers (SAs) are critical for passive mode-locking in ultrafast fiber lasers. Although many materials have been studied as SAs, new candidates with broadband and stable performance are still needed. In this work, we report the synthesis and fabrication of Ti₂O-based SAs and present the first systematic investigation of their performance in broadband ultrafast fiber lasers. Specifically, phase-pure Ti₂O crystals were synthesized via solid-state sintering. High-performance Ti₂O SAs were then fabricated through a photodeposition method. The balanced synchronous twin-detector measurement method demonstrated that Ti₂O exhibited obvious and stable saturable absorption behavior. To validate their broadband mode-locking capability, the as-prepared Ti₂O SAs were integrated into the Yb-doped and Er-doped fiber lasers, respectively. Experimental results show that both laser systems deliver stable pulsed output, with pulse durations of 441.7 ps at 1 μm and 522.5 fs at 1.5 μm. This work pioneers the application of Ti₂O in ultrafast photonics, and provides an important reference and novel research insights for the design and development of advanced broadband optical devices and systems. Full article

Tellurene has a wide bandwidth and low propagation loss at near-infrared wavelengths due to its nonlinear absorption coefficient. Therefore, we prepared tellurene–polyvinyl alcohol (Te-PVA) film as a saturable absorber in an Er-doped fiber laser by liquid phase exfoliation and spin-coating. The modulation depth was 5.25% and the saturation intensity was 17.02 MW/cm. The nonlinear optical properties of the film and its application in high-stability mode-locked operation were studied. A mode-locked pulse with a fundamental frequency of 8.48 MHz and a central wavelength of 1560.10 nm was obtained, with a signal-to-noise ratio which was greater than 75 dB. A traditional soliton mode-locked operation with a pulse width of 1.41 ps was achieved. In addition, eighth- and 19^th-harmonic mode-locked operations were obtained by adjusting the pump power and polarization controller. Our results show that Te-PVA film functioned as a saturable absorber which enabled harmonic mode-locking with an SNR of 75 dB in an Er-doped fiber laser. It is thus an excellent ultra-fast photonics material. Full article

Passively mode-locked lasers, as essential tools for generating ultrashort pulses, have found widespread applications in industrial manufacturing, optical communications, biomedical imaging, and fundamental scientific research. Saturable absorbers serve as the key components governing the performance of such laser systems. Conventional saturable absorber materials, including semiconductor saturable absorber mirrors, carbon nanotubes, and graphene, however, suffer from inherent limitations in operational wavelength range, damage threshold, and environmental stability. In recent years, two-dimensional transition metal carbides and nitrides, known as MXenes, have emerged as a promising class of materials to address these challenges. Their unique metallic conductivity, broadband saturable absorption, ultrafast carrier dynamics, excellent thermal management capability, and versatile chemical tunability offer unprecedented opportunities for advanced saturable absorber applications. This review systematically summarizes the recent progress of MXene-based saturable absorbers, with an emphasis on their distinctive advantages in extending the mode-locked wavelength range, enhancing output pulse stability, and increasing the optical damage threshold. Furthermore, strategies for performance optimization through surface terminal group engineering, defect modulation, and heterostructure design are discussed in depth. Finally, the future prospects and key challenges toward industrial implementation of MXenes in ultrafast photonics are outlined, aiming to stimulate further advancements in high-performance ultrafast laser technology. Full article

To address the common drawbacks of polyamine-based CO₂ absorbents, such as high viscosity and precipitation at high CO₂ loading, a novel liquid–liquid biphasic absorbent composed of triethylenetetramine (TETA), 1-(2-aminoethyl)piperazine (AEP), N,N-dimethylacetamide (DMAC), and H₂O was developed in this study. By comprehensively evaluating CO₂ saturation loading, phase separation behavior, rheological properties of the CO₂-rich phase, precipitation suppression, and desorption–regeneration performance, the optimal absorbent formulation was identified as 20 wt% TETA + 10 wt% AEP + 40 wt% DMAC + 30 wt% H₂O. The optimized system enabled more than 98% of the CO₂ absorption products to be concentrated in the lower phase, which accounted for only 56% of the total liquid volume. Compared with the AEP-free TETA/DMAC/H₂O system, the optimized AEP-modified absorbent effectively eliminated precipitation and reduced the viscosity of the CO₂-rich phase to 62.3 mPa·s, while also improving the desorption behavior and cyclic stability of the system. In addition, ¹³C NMR analysis suggested that the salting-out effect is the main driving force for phase separation, with ionic products preferentially enriched in the aqueous phase to form the CO₂-rich lower phase. AEP contributes to viscosity reduction, precipitation suppression, and enhanced regeneration by weakening carbamate aggregation through steric hindrance and promoting bicarbonate formation. Full article

Plasma polymerization offers a solvent-free route to functional polymer materials, but the structural integrity and accessibility of functional groups in plasma-derived networks remain insufficiently validated. Herein, N-vinylimidazole (NVI) was polymerized using atmospheric-pressure dielectric barrier discharge (DBD) plasma in a liquid-film configuration to generate a chemically heterogeneous poly(N-vinylimidazole)-like material that could be recovered and evaluated in aqueous solution. ATR–FTIR and ¹H NMR spectroscopy indicate substantial vinyl-group consumption with retention of imidazole functionality. Functional behavior was probed using chromium(III) (Cr³⁺) as a model metal ion. UV–Vis spectroscopy revealed systematic changes in the Cr³⁺ d–d transition region (~580–600 nm) with increasing polymer concentration, consistent with ligand-field perturbation arising from interactions with imidazole donor sites. A monotonic increase in absorbance with an increasing ligand-to-metal ratio was observed, followed by plateau behavior at higher ratios, indicating saturation of accessible coordination environments. These results demonstrate that plasma-polymerized material retains chemically accessible imidazole functionalities capable of coordinating transition-metal ions in solution, establishing atmospheric-pressure plasma polymerization as a viable route to functional imidazole-containing materials. Full article

Dual-loss-modulated Q-switched lasers at 1.3 μm are achieved by using both electro-optic modulators (EOMs) and different saturable absorbers (SAs). Laser pulses with a width of 7.75 ns at 60 kHz and a peak power of 4.07 kW at 20 kHz can be obtained in lasers with both an EOM and a MoS₂/WS₂ heterostructure SA. Compared with those generated in lasers with a MoS₂ SA under the same repetition rates, the pulse width is compressed by 37.7% (at 60 kHz), and the peak power is increased by 80.9% (at 20 kHz). The results show that dual-loss-modulated technology makes it easier to achieve pulses with a duration of several nanoseconds. Meanwhile, compared to single-material SAs, the heterostructure SA helps to generate pulses with a short duration and high peak power in 1.3 μm lasers. Full article

The development of cost-effective and resource-rich materials is crucial for the practical application of microwave absorbers. This study demonstrates the successful fabrication of core-shell Fe and TiC nanoparticles encapsulated within carbon shells using the arc discharge method. The samples are designated as Fe3Ti1 and Fe1Ti3, where the numbers indicate the Fe-to-Ti mass ratio in the precursor (e.g., Fe1Ti3 = 1:3 by mass). In the arc discharge synthesis mechanism, the mass ratio of Fe to Ti in the raw material was adjusted from 3:1 to 1:3 to optimize the Fe/TiC/C interfaces under a CH₄ forming gas atmosphere. TEM analysis reveals spherical and polyhedral nanoparticles with diameters of 30–50 nm and a uniform carbon shell thickness of 3–4 nm. Raman spectroscopy shows that the Fe1Ti3 sample has a higher defect density (I_D/I_G = 1.13) compared to Fe3Ti1 (0.87), indicating a more disordered carbon structure. Magnetic measurements yield saturation magnetization values of 87 emu/g for Fe3Ti1 and 50 emu/g for Fe1Ti3, with coercivities of 190.72 Oe and 203.65 Oe, respectively. When composited with paraffin at 50 wt% loading, the Fe1Ti3 sample exhibits superior microwave absorption performance, achieving a minimum reflection loss (RL) of −25.22 dB at 8.23 GHz and an effective absorption bandwidth (RL ≤ −10 dB) of 4 GHz (6.5–10.5 GHz) at a thickness of 2.5 mm. This enhanced performance is attributed to the synergistic effect of multiple loss mechanisms, including conduction loss within the three-dimensional core-shell architecture, interfacial polarization at the heterojunctions between the core and the carbon shell, and magnetic loss induced by ferromagnetic behavior associated with defects in both the shell and carbon atomic layers. The magnetic loss in the (Fe/TiC)@C nanocomposites primarily arises from the natural resonance (at ~6.5 GHz) and exchange resonance (at ~12 GHz) of the Fe cores. The dielectric loss is primarily attributed to dipole, interfacial, and space charge polarization from TiC and the carbon shell, as well as multiple scattering effects between nanoparticles. Furthermore, far-field radar cross-section simulations substantiate that the Fe/TiC@C nanocomposite demonstrates excellent radar wave attenuation capability. Further, first principles simulations reveal that introducing Fe at the C/TiC interface induces strong charge redistribution and orbital hybridization, transforming a localized dielectric interface into a highly conductive and electronically coupled C/Fe/TiC system. This interfacial modulation enhances both dielectric loss (via charge transport and polarization) and magnetic loss (via Fe-induced magnetic interactions), thereby enabling optimized dielectric-magnetic synergy for broadband microwave absorption in (Fe/TiC)@C nanocomposites. Full article

Stray-current corrosion from DC-electrified railways drives premature failure of buried metallic infrastructure (pipelines, foundations, tunnel reinforcement), causing resource waste, repair-driven carbon emissions and service disruptions that undermine the sustainability of urban transit corridors. Conventional impressed-current cathodic protection (ICCP) design relies on uniform-anode rules of thumb or closed commercial codes that cannot quantify the trade-off between protection uniformity, energy use and hardware cost. We present an open MATLAB framework that couples a custom 3D finite element method (FEM) solver with multi-objective particle swarm optimisation (MOPSO) and minimises three competing objectives simultaneously: total impressed current, RMS deviation from the protection target, and number of active anodes. A laboratory-calibrated coupling factor ($\mathrm{CF}=1.98$, consistent with the image-method prediction of 2 for a highly conductive pipe inclusion) absorbs the pipe–soil interface kinetics into a single direct FEM solve, and a pre-computed Green’s-function basis accelerates each MOPSO evaluation by more than two orders of magnitude. The solver is validated against an instrumented prototype with RMSE $=14.9$ mV across ten Cu/CuSO₄ saturated reference electrode (CSE) measurements, and applied to a 500 m DC traction line. At an identical total current of 20.30 A across five anodes, the optimised design achieves an RMSE of 86.6 mV against the $-850$ mV NACE target, whereas a conventional uniform layout produces severe over-protection (RMSE $=1107$ mV)—a twelve-fold reduction. The framework is recommended as a transparent, reproducible engineering tool that simultaneously extends pipeline service life and reduces rectifier energy demand, supporting UN Sustainable Development Goals 9 and 11 for sustainable urban-rail infrastructure. Full article

A relative humidity (RH) of 30–40% was considered optimal for the ‘sick’ glasses of the Veste Coburg Art Collections to prevent further corrosion at higher humidity values and crizzling on drying of the gel layer at lower levels. This has been achieved since 1993 by using saturated solutions of magnesium chloride in display cases, providing a constant humidity of 33%. These solutions also absorb volatile harmful ‘carbonyl’ and other pollutants. A visual survey of the glasses and recent ion chromatographic measurements of alkalis on their surfaces confirmed their stable condition after three decades: no crystals, no new haze, no tears, no fragmentation, and no further growth of crizzling. Full article

Graphene oxide (GO) has been widely investigated as a nanoreinforcement for cementitious composites; however, its effectiveness depends on stable dispersion within the highly alkaline, calcium-rich environment of fresh cement paste. This study evaluates the dispersion behaviour of GO in deionised (DI) water and saturated calcium hydroxide (Ca(OH)₂) under controlled conditions and assesses the effectiveness of anionic and cationic surfactants in both environments. GO was synthesised using the modified Hummers method and verified by comprehensive physicochemical characterisation. Dispersion stability was assessed using UV-Vis spectroscopy at GO concentrations of 0.04–0.08 mg/mL in DI water, and the 0.08 mg/mL system was further studied in saturated Ca(OH)₂ with and without sodium dodecylbenzene sulphonate (SDBS) and cetyltrimethylammonium bromide (CTAB) at a 1:1 mass ratio. Zeta potential and dynamic light scattering measurements were performed to understand the relation between the surface charge and agglomeration of GO. In DI water, GO retained close to 70% of its initial absorbance after 60 min, and both surfactants improved retention to above 90%. In saturated Ca(OH)₂, retention fell to approximately 40%, and neither surfactant restored stability despite producing zeta values that would conventionally support stable dispersion. The findings indicate that GO aggregation in calcium ion (Ca²⁺)-rich alkaline environments is not governed by net surface charge alone, consistent with the established mechanism of Ca²⁺ chemical cross-linking with GO carboxyl groups. Full article

Magnetorheological elastomers (MREs) have recently attracted significant attention for the development of adaptive vibration isolators and absorbers. Their ability to tune mechanical properties in response to external excitations makes them promising candidates for semi-active control applications. In this study, the Generalized Maxwell model with three Maxwell branches is employed to predict variations in storage and loss moduli of isotropic MREs operating in shear mode under varying excitation frequencies and magnetic flux densities. A practical semi-active MRE-based seat vibration isolator is proposed, and a multidisciplinary design optimization problem is subsequently formulated to determine the optimal geometrical parameters of the isolator. The objective is to maximize the frequency bandwidth while satisfying constraints on weight, material magnetic saturation, and total volume. The optimization results demonstrate that the proposed adaptive isolator can achieve a significant relative increase in its natural frequency by adjusting the applied magnetic flux density, while maintaining a practical total mass. A post-optimality analysis is also conducted to investigate the influence of the upper bound on the isolator’s mass. The findings reveal a nonlinear relationship between the optimal frequency ratio and the total mass of the isolator. Finally, closed-loop control strategies based on on–off skyhook and PID control are implemented and compared to evaluate the capability of the proposed adaptive isolator to mitigate vibration and shock under varying disturbances. Full article

Against the global carbon neutrality backdrop, amine-based CO₂ capture technology is critical for industrial greenhouse gas emission reduction. However, mixed amine absorbents can cause severe corrosion of Q235B carbon steel, restricting the stable operation of carbon capture, utilization, and storage (CCUS) projects. This study systematically investigated the corrosion behavior of Q235B carbon steel in a novel mixed amine system under simulated industrial conditions using weight loss tests, electrochemical measurements (EIS, potentiodynamic polarization), and advanced characterizations (FT-IR, ¹³C NMR, SEM-EDS, XRD). The temperature was the dominant factor: corrosion rate increased significantly with rising temperature. Under CO₂-saturated conditions, 15–30% absorbent concentrations showed no significant effect on corrosion rate owing to similar molar loading and pH. At 60 °C and 30% concentration, the corrosion rate peaked at 30 L/L CO₂ loading. Carbamate accumulation promoted corrosion at low loading, while increased bicarbonate inhibited corrosion at high loading. The main corrosion products (Fe₃O₄, Fe₂O₃) formed loose, porous films with poor protectiveness. This work clarifies the electrochemical corrosion mechanism and provides data support for corrosion prevention in CCUS equipment. Full article

Speech produced in helium–oxygen (heliox) environments in deep saturation diving exhibits pronounced spectral shifts and temporal distortions, which severely degrade automatic speech recognition (ASR) systems trained on normal-air corpora. Existing studies often adopt a restoration-then-recognition paradigm by training waveform mapping networks on paired heliox/air recordings. However, in realistic low-resource data collection, paired recordings are typically obtained by independent re-reading and are therefore not strictly time-aligned, which makes regression-style restoration more sensitive to pairing errors and increases the risk of front-end distortions. This paper proposes a robust recognition framework for heliox speech, termed PRL-DAS (Physics-informed Resampling and LoRA with Duration-Adaptive Speed). The framework consists of a physics-inspired linear resampling warm start (PhysSpeed), parameter-efficient Low-Rank Adaptation (LoRA), and duration-adaptive speed (DAS) inference enhancement. Specifically, we first apply physics-motivated linear resampling as a coarse warm start, and then perform mixed-domain LoRA fine-tuning of a Whisper foundation model to absorb residual non-linear differences. On a corpus of 1048 paired Chinese heliox utterances under leave-one-speaker-out (LOSO) evaluation, using Whisper-Medium as the base model, PhysSpeed followed by mixed-domain LoRA reduces the overall character error rate (CER) from 49.33% with PhysSpeed preprocessing only to 25.79%, while also improving performance on the normal domain. Furthermore, the full PRL-DAS framework applies Soft-DAS, a lightweight smooth schedule motivated by duration-dependent variation in the optimal resampling factor, and further reduces the overall CER to 24.37% without additional training cost. Full article

Herein, we report a simple procedure regarding the photodynamic therapy (PDT) treatment as a minimally invasive modality for treating superficial bladder cancer that utilizes a photosensitizer, light, and oxygen to generate cytotoxic reactive oxygen species (ROS). This study evaluates the histopathological and morphological changes induced by PDT in an ex vivo model of low-grade (LG) pTa non-muscle-invasive bladder cancer (NMIBC). We investigated the efficacy of exogenous protoporphyrin IX (PpIX) and Rose Bengal (RB) by incubating tissue samples (n = 30) with an oxygen-saturated solution of PpIX (1–3 mM) or RB (0.3–0.5 mM) for one hour. Since the criticism of using frozen tissue in research already exists, this framing explains how to mitigate those limitations. Thus, we use oxygen-saturated solutions PpIX and oxygen-saturated solutions of RB. We discussed a few aspects related to the use of frozen tissue in PDT. Frozen tissue preserves lipids critical for assessing membrane damage and maintains higher levels of metabolic markers like antioxidant molecules like glutathione and more likely lack factors such as metabolic activity, intact cell membranes, and oxygenation. It is critical to differentiate between “artifactual” changes and the “pathological” death of cells. Thus, we used histopathological microscopy observation typically used in daily clinical investigations to characterize cells before and after PDT. Following irradiation with the light dose of 72 J/cm² (410 nm or 532 nm at 300 mW for 15 min), hematoxylin–eosin staining revealed concentration-dependent apoptotic changes, including chromatin condensation, pyknosis, and nuclear fragmentation. While both agents induced cell death, RB demonstrated faster and more intense cytotoxicity than PpIX. These findings provide microscopic evidence of PDT-induced tumor destruction and suggest that RB is a potent candidate for further preclinical evaluation. At 410 nm (deep blue/violet), light penetration in biological tissue is very shallow, typically only around 0.3 to 1 mm; therefore, in a 2 mm thick tissue sample, most of the light would be absorbed within the first millimeter, with minimal light reaching the full depth of tissues. In this protocol, the generated ROS is used to destroy tumor tissue by attacking the cellular microenvironment directly. This led to immediate membrane disruption and lipid peroxidation. The proof-of-concept is an early-stage study designed to verify that a PDT treatment is feasible, safe, and biologically active in an ex vivo model of LG pTa NMIBC. Full article

The integrating sphere with sample inside (ISSI) method is useful for absorption spectroscopy of scattering samples, but the measured absorbance ($A_{\mathit{meas}}$) becomes nonlinear with dye concentration (c) because the sample is placed inside the sphere. This study modeled the $A_{\mathit{meas}}-c$ relationship for ISSI using a cylindrical cell (CC) and a Brewster cell (BC) with simple analytical expressions based on the fraction of light not passing through the sample and the effective weights of light passing through it multiple times. Four aqueous dye solutions—Trypan Blue, Brilliant Blue FCF, Tartrazine, and New Coccine—were used as non-scattering samples. For CC, a single-pass model reproduced the measured relationship well for all dyes, and linearity was maintained in the low-absorbance region (up to approximately half of the saturation absorbance, $A_{\max }/2\approx 0.67$ Abs). For BC, the same low-absorbance region (up to approximately $A_{\max }/2\approx 1.21$ Abs) also exhibited practical linearity, but the full relationship including saturation required a multiple-pass model. Model selection based on adjusted RMSE and AICc identified the 3-pass model as the minimum sufficient model for BC. The saturation absorbance $A_{\mathit{max}}$ was on average 1.81 times higher for BC than for CC (corresponding to an approximately 12-fold expansion in linear intensity ratio), and the upper concentration limit of the linear approximation was on average 1.85 times higher. These results demonstrate that BC extends the measurable concentration range while preserving practical low-absorbance linearity. In addition, the wavelength dependence of $A_{\mathit{max}}$ observed at short wavelengths is attributed primarily to the reduced reflectance of the BaSO₄ integrating-sphere wall rather than to the refractive-index dispersion of the quartz cell. Full article