Search Results (44)

With rising global temperatures and increasing sustainability demands, the need for advanced pavement solutions has never been greater. This study breaks new ground by integrating phase change materials (PCMs), including paraffin-based wax (Rubitherm RT55), hydrated salt (Climator Salt S10), and fatty acid (lauric acid), as binder modifiers within warm mix asphalt (WMA) mixtures. Moving beyond the traditional focus on binder-only modifications, this research utilizes recycled cigarette filters (CFs) as a dual-purpose fiber additive, directly reinforcing the asphalt mixture while simultaneously transforming a major urban waste stream into valuable infrastructure. The performance of the developed WMA mixture has been evaluated in terms of stiffness behavior using an Indirect Tensile Strength Modulus (ITSM) test, permanent deformation using a static creep strain test, and rutting resistance using the Hamburg wheel-track test. Laboratory tests demonstrated that the incorporation of PCMs and recycled CFs into WMA mixtures led to remarkable improvements in stiffness, deformation resistance, and rutting performance. Modified mixes consistently outperformed the control, achieving up to 15% higher stiffness after 7 days of curing, 36% lower creep strain after 4000 s, and 64% reduction in rut depth at 20,000 passes. Cost–benefit analysis and service life prediction show that, despite costing USD 0.71 more per square meter with 5 cm thickness, the modified WMA mixture delivers much greater durability and rutting resistance, extending service life to 19–29 years compared to 10–15 years for the control. This highlights the value of these modifications for durable, sustainable pavements. Full article

While crumb rubber powder has demonstrated effectiveness in enhancing the mechanical properties of asphalt binders, its viscoelastic behavior under freeze–thaw conditions in clean water and de-icing salt, typically urban road conditions in winter, remains insufficiently explored. This study systematically investigated the microstructural evolution, compositional changes, and mechanical behavior of asphalt modified with rubber under the influence of freeze–thaw conditions in clean water and de-icing salt. The findings revealed that rubber powder incorporation accelerates the precipitation of oil, enhancing material stability in both aqueous and saline environments. Notably, asphalt containing 10% crumb rubber powder (Asphalt-10% RP) and 20% crumb rubber powder (Asphalt-20% RP) exhibit creep recovery rates 50.53% and 28.94% higher, respectively, under de-icing salt freeze–thaw cycles than under clean water freeze–thaw cycles. Therefore, in regions with extremely low temperatures and frequent snowfall, rubber powder exhibits significant research potential, providing theoretical support for the design of asphalt pavements in cold climates. Full article

Energy storage systems are gaining increasing attention as a solution to the inherent intermittency of renewable energy sources such as solar and wind power. Among large-scale energy storage technologies, compressed air energy storage (CAES) stands out for its natural sealing properties and cost-efficiency. Having abundant salt resources, the thick and regionally extensive salt deposits in Unit B of Southern Ontario, Canada, demonstrate significant potential for CAES development. In this study, optimization for essential CAES salt cavern parameters are conducted using geological data from Unit B salt deposit. Cylinder-shaped and ellipsoid-shaped caverns with varying diameters are first simulated to determine the optimal geometry. To optimize the best operating pressure range, stationary simulations are first conducted, followed by tightness evaluation and long-term stability simulation that assess plastic and creep deformation. The results indicate that a cylinder-shaped cavern with a diameter 1.5 times its height provides the best balance between storage capacity and structural stability. While ellipsoid shape reduces stress concentration significantly, it also leads to increased deformation in the shale interlayers, making them more susceptible to failure. Additionally, the findings suggest that the optimal operating pressure lies between 0.4 and 0.7 times the vertical stress, maintaining large capacity and minor gas leakage, and developing the least creep deformation. Full article

The time-dependent deformation control of weakly cemented soft rock in deep underground engineering is a critical scientific issue that directly affects the long-term stability of roadways. Traditional Nishihsara models encounter limitations in accurately capturing the weakening effects of material parameters during rock creep failure and in describing the accelerated creep stage, making them insufficient for analyzing the creep failure mechanisms of weakly cemented surrounding rock. To address these limitations, this study integrates SEM and X-ray scanning results to reveal the microscopic degradation process during creep: under external forces, clay minerals, primarily bonded face-to-face or through cementation, gradually fracture, leading to continuous microcrack propagation and progressive parameter degradation. Based on damage theory, an enhanced Nishihara creep model is proposed, incorporating a time-dependent damage factor to characterize the attenuation of the elastic modulus and a nonlinear winding element connected in series to represent the accelerated creep stage. The corresponding three-dimensional constitutive equations are derived. Using the Levenberg–Marquardt (L-M) algorithm for parameter inversion, the model achieves over 98% fitting accuracy across the full creep stages of weakly cemented soft rock, validating its applicability to other rock types such as salt rock and anthracite. The damage creep model is numerically implemented through secondary development in FLAC3D 6.0, with simulation results showing less than 5% deviation from experimental data and the failure mode is similar. These findings provide a solid theoretical foundation for further understanding the creep behavior of weakly cemented soft rocks. Full article

Salt caverns serve as underground storage for crude oil, natural gas, compressed air, carbon dioxide, and hydrogen. Key stages of cavern development for storage purposes include design, construction, storage, and abandonment. The design phase addresses optimal cavern shape, size, pillar dimensions, number of caverns, the impact of interbeds, and cyclic loading while considering the creep behavior of salt and the mechanical behavior of surrounding layers. During this phase, geological factors such as depth, thickness, and the quality of salt are considered. For construction, two main methods—direct leaching and reverse leaching—are chosen based on design specifications. The storage stage includes the injection and withdrawal of gases in a cyclic manner with specific injection rates and pressures. After 30 to 50 years, the caverns are plugged and abandoned. The geological limitation of salt domes makes it essential to look for more bedded evaporites. This study provides a comprehensive review of bedded evaporites, including their origin and depositional environment. The stability of caverns in all these stages heavily relies on geomechanical analysis. Factors affecting the geomechanics of bedded salts such as mineralogy, physical properties, and mechanical properties are reviewed. A list of bedded evaporites in the U.S. and Canada, including their depth, thickness, and existing caverns, is provided. Additionally, this study discusses the main geomechanical considerations influencing design, solution mining, cyclic loading, and abandonment of caverns in bedded salt caverns. Full article

The salt layer serves as an excellent caprock for oil and gas resources, with its underlying strata often containing abundant hydrocarbon reserves. However, the strong creep characteristics of the salt layer frequently lead to damage issues. Therefore, research on the wellbore integrity of salt layers holds significant practical value. This study focuses on the wellbore integrity of high-pressure salt layers. Based on the Heard time-hardening creep model, a numerical simulation model of composite salt-layered wellbores incorporating a saline water seepage field was established. This study analyzed the mechanical influence of factors such as well inclination angle, azimuth angle, brine density, and liquid column density on the wellbore. The results indicate that high formation pressure, salt creep, and saline water seepage in high-pressure salt layers are the main causes of wellbore stress and deformation. These conditions pose a high risk of damage to the casing and cement sheath. When designing directional well trajectories within high-pressure salt layers, the inclination angle should be controlled between 45° and 60°, and the azimuth angle should be kept below 30°. Full article

This study investigates the mesostructural damage evolution and creep deformation mechanisms in bedded rock salt through integrated scanning electron microscopy (SEM) and multistage creep experiments. Utilizing a self-developed in situ observation system coupled with digital image correlation (DIC) analysis, the microstructural heterogeneity, strain localization, and damage propagation patterns in the rock were systematically characterized. The results revealed distinct microstructural contrasts between rock salt and argillaceous interlayers, with interfacial regions exhibiting pore-rich, interconnected structures due to crystal gradation disparities. Creep damage initiation predominantly occurred in pure rock salt domains, manifesting as transgranular fractures and intercrystalline slip, followed by crack propagation into salt–mudstone interfaces governed by shear dilatancy. The integration of mesoscale structural characterization with macroscopic mechanical behavior establishes a framework for predicting the long-term stability of bedded salt formations under operational loads. Full article

Salt formations are commonly encountered during oil and gas drilling. Due to the rheological properties of salt rocks, casing collapse accidents happen frequently. Under action of nonuniform geostress, casing failure has become an important influencing factor that restricts the exploration and development benefits of deep and ultra-deep wells. Casing stress in a period after well cementation in the salt formation of Brazilian deepwater fields was analyzed. Results show that the nonuniform geostress is instantaneously applied on the cement sheath when well cementation is completed in the salt formation and then transferred to the casing. Stress on the inner wall grows with an increase in the angle with the direction of the maximum horizontal principal stress and it reaches the maximum in the direction of the minimum horizontal principal stress. As the creep continues, stress on the inner wall of casings gradually enlarges and the circumferential stress in inner rings tends to be uniform, which means that creep of the formation weakens the nonuniformity of casing deformation. The collapse pressure on the outer wall of casings tends to increase at first and then decrease as the angle with the direction of maximum horizontal principal stress enlarges. Stress on the inner wall of casings in the salt formation reduces with the increasing thickness of casings selected, and the casing strength is improved as the wall thickness increases. The research results provide certain theoretical guidance for the strength check of casings in well cementation engineering in salt formations. Full article

Molten carbonate salts are a promising candidate for next-generation concentrated solar power technology owing to their excellent heat storage and heat transfer properties. This represents overcoming several problems that structural materials exhibit, including severe corrosion and high-temperature creep. Alloys with an aluminum element are alternatives in this regard as they are highly resistant to corrosive environments. In this paper, the corrosion behavior in molten carbonates (Li₂CO₃-Na₂CO₃-K₂CO₃) and creep properties of TP347H with different aluminum contents at 650 °C were studied. The results demonstrated that the alloy corrosion rate was reduced via Al addition. The alloy with 2.5 wt.% Al exhibited the lowest corrosion rate: ~25% lower than that without Al after 1000 h of corrosion. With increasing Al content, the inner corrosion layer of the alloys transformed from a Cr-containing oxide layer to a Cr–Al-containing composite oxide layer. The addition of Al promoted the formation of a layer of continuous and dense LiFeO₂ product on the alloy surface during early corrosion stages, which prevented the carbonate from coming into direct contact with the substrate. After 1000 h of corrosion, the surface of the alloy is mainly composed of LiFeO₂ and LiCrO₂. Compared to TP347H, the added Al element enhanced the strength and elongation of TP347H at 650 °C. The TP347H containing 2 wt.% Al exhibited the best high-temperature tensile properties. When the stress was 110 MPa, the lowest steady-state creep rate of the alloy containing 2 wt.% Al was 3.61 × 10⁻⁶, and the true stress index was 5.791. This indicates that the creep mechanism was a dislocation climb assisted by lattice diffusion. Full article

In this paper, we study the creep phenomena for self-similar models of viscoelastic materials and derive a generalization of the Kelvin–Voigt model in the framework of fractal continuum calculus. Creep compliance for the Kelvin–Voigt model is extended to fractal manifolds through local fractal-continuum differential operators. Generalized fractal creep compliance is obtained, taking into account the intrinsic time $\tau$ and the fractal dimension of time-scale $\beta$. The model obtained is validated with experimental data obtained for resin samples with the fractal structure of a Sierpinski carpet and experimental data on rock salt. Comparisons of the model predictions with the experimental data are presented as the curves of slow continuous deformations. Full article

With the development of salt cavern gas storage technology, the construction of large-scale salt cavern gas storage using sediment voids is expected to solve the problems of low effective volume formation rate and poor construction economy of high-impurity salt mines. At present, there are few studies on the long-term operational mechanical behavior of salt cavern gas storage under the influence of sediment accumulation. The present paper studies the influence of sediment height, particle gradation, and operating pressure on the stability of salt caverns by constructing a coupling model of sediment particle discontinuous medium and surrounding rock continuous medium. The continuous–discontinuous coupling algorithm is suitable for analyzing the influence of sediment height and particle gradation on the creep shrinkage of salt caverns. The increase in sediment height slows down the creep shrinkage of the cavern bottom, which strengthens the restraining effect on the surrounding rock of the cavern. As a result, the position of the maximum displacement of the surrounding rock moves to the upper part of the cavern. The sediment particle gradation has little effect on the cavern volume shrinkage rate. The greater the coarse particle content, the smaller the cavern volume shrinkage rate. The greater the operating pressure, the more conducive to maintaining the stability of the cavern. This situation slows down the upward movement of the sediment accumulation and increases the gas storage space in the upper part of the cavern. The obtained results can provide a reference for evaluating the long-term operational stability of sediment-type high-impurity salt cavern gas storage. Full article

Underground hydrogen storage (UHS) in salt caverns is a sustainable energy solution to reduce global warming. Salt rocks provide an exceptional insulator to store natural hydrogen, as they have low porosity and permeability. Nevertheless, the salt creeping nature and hydrogen-induced impact on the operational infrastructure threaten the integrity of the injection/production wells. Furthermore, the scarcity of global UHS initiatives indicates that investigations on well integrity remain insufficient. This study strives to profoundly detect the research gap and imperative considerations for well integrity preservation in UHS projects. The research integrates the salt critical characteristics, the geomechanical and geochemical risks, and the necessary measurements to maintain well integrity. The casing mechanical failure was found as the most challenging threat. Furthermore, the corrosive and erosive effects of hydrogen atoms on cement and casing may critically put the well integrity at risk. The research also indicated that the simultaneous impact of temperature on the salt creep behavior and hydrogen-induced corrosion is an unexplored area that has scope for further research. This inclusive research is an up-to-date source for analysis of the previous advancements, current shortcomings, and future requirements to preserve well integrity in UHS initiatives implemented within salt caverns. Full article

The aim of this paper is to investigate the aging mechanism of asphalt in the sea salt erosion environment from a rheological point of view. In order to simulate the real pavement aging process in the sea salt erosion environment, base asphalt and Styrene−Butadiene−Styrene (SBS)-modified asphalt were selected for salt environment aging tests. The asphalt samples were aged via a thin film oven test (TFOT) and a pressure aging vessel (PAV) test. Then, thermo-oxidizing conditions were created after the samples were immersed in salt solution, mixed with four different concentrations of sodium chloride (NaCl) and sodium sulphate (Na₂SO₄), to investigate the aging state of asphalt. Temperature scan (TS), frequency scan (FS), and multiple stress creep and recovery (MSCR) tests performed using a Dynamic Shear Rheometer (DSR) were used to investigate the effects on the rheological properties of aged asphalt in a salt environment. The results showed that both base asphalt and SBS-modified asphalt were aged to different degrees under mixed salt solutions. The two asphalt samples aged in a salt environment showed increased hardness. SBS-modified asphalt exhibited higher aging resistance compared with base asphalt in the sea salt environment. However, due to the degradation of the SBS modifier and the aging of base asphalt, the properties of the SBS-modified asphalt showed more obvious complexity with changes in salt solution concentrations. Full article

Nuclear graphite plays a crucial role in thermal-spectrum thorium molten salt reactors (TMSRs) as both the neutron moderator and the construct for the coolant flowing channel. When subjected to irradiation and elevated temperatures, graphite components experience considerable deformation due to a combination of dimensional changes, thermal expansion, irradiation creep, elastic deformation, and changes in thermomechanical characteristics. The lifespan of the graphite component is a limiting factor in TMSR designs as it strongly correlates with the dimensional changes of the graphite. To evaluate the thermal and mechanical reactions of graphite component under TMSR core conditions, it is necessary to couple models of thermal-hydraulics, neutronics, and thermal-mechanics. This paper presents an enhanced methodology for analyzing the deformation of graphite components using the finite element method. Then, this method was applied to analyze a 10-year deformation history of a hexagonal prism assembly (HPA) and it was compared with the traditional hexagonal round channel assembly (RCA). The results demonstrate that the stress–strain field of both types of graphite components undergo significant variations with the increasing neutron fluence from irradiation. HPA graphite exhibits a slower deformation as compared to RCA graphite when subjected to identical operating conditions. In this case, HPA graphite has a lifespan of approximately 10 years, while RCA graphite lasts only 8.8 years. Full article

Maintaining the integrity of the cement sheath is essential for the sealing of underground gas storage. The formation creep, temperature changes, and operating pressure changes during the operation of underground gas storage can cause changes in the stress of the cement sheath, which probably induces the failure of the cement sheath’s integrity. A creep model taking the effects of stress and temperature into account is developed to study the cement sheath’s integrity in creep formation, and the feasibility of creep simulation via finite element method is verified. The finite element method is used to analyze the effects of formation creep, temperature, operating pressure, and the cement sheath’s elastic modulus on the cement sheath’s integrity. The result shows that the coupling effect of formation creep and temperature increases the cement sheath’s failure risk; both the formation creep and the decrease in cement sheath temperature increase the Von Mises stress on the cement sheath, increasing the risk of the cement sheath’s shear failure. The decrease in cement sheath temperature decreases the circumferential compressive stress on the cement sheath and raises the risk of the cement sheath’s tensile failure. Shear failure of the cement sheath occurs at high operating pressure upper limits. The operating pressure is less than 70 MPa, or the cement sheath’s elastic modulus is less than 3 GPa, which can prevent the failure of the cement sheath’s integrity during the operation of underground gas storage. Full article