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23 pages, 36264 KB  
Article
A Mesoscopic Study on the Constraint Mechanism of Existing Pavement Rutting on the Mechanical Behavior of Sealcoat Based on Highways in China
by Zhanwei Zhao, Wenruo Fan, Hui Wang, You Zhou and Zhoucong Xu
Appl. Sci. 2026, 16(9), 4126; https://doi.org/10.3390/app16094126 - 23 Apr 2026
Abstract
Conventional maintenance models often neglect the impact of pre-existing rutting on sealcoat performance, particularly in high-temperature regions like Chongqing in China, where rut-related failures are common. Existing ruts impose geometric constraints that significantly alter stress redistribution within the new sealcoat layer, yet this [...] Read more.
Conventional maintenance models often neglect the impact of pre-existing rutting on sealcoat performance, particularly in high-temperature regions like Chongqing in China, where rut-related failures are common. Existing ruts impose geometric constraints that significantly alter stress redistribution within the new sealcoat layer, yet this constraint mechanism remains poorly understood due to limitations in laboratory observation. This study developed a mesoscopic AC16 + MS3 composite discrete element model to simulate the mechanical behavior of a sealcoat applied over a rutted pavement. To replicate real-world conditions, a constant pressure of 0.7 MPa, representing the standard tire ground pressure in JTG E20-2011, was applied at a temperature of 70 °C, reflecting extreme high-temperature stability limits. Virtual rutting tests and contact force chain analyses were conducted across varying existing pavement rut depths, including 0 mm, 3 mm, 6 mm, and 10 mm. The results indicate that existing ruts redirect stress transfer paths, causing vertical compressive force chains to densify within the rutted zone and tensile stress to concentrate at rut edges. Mastic-mastic contacts transmit over 65% of the load, identifying asphalt mortar as the primary load-transfer phase. Notably, a 10 mm existing rut depth induces a tensile vacuum zone at depths of 15–40 mm, disrupting the standard U-shaped stress distribution. These findings clarify how pre-existing geometries govern structural degradation, suggesting that maintenance in high-temperature regions must prioritize asphalt mortar performance to mitigate edge cracking and deformation. Full article
(This article belongs to the Special Issue New Trends in Road Materials and Pavement Design)
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18 pages, 8761 KB  
Article
Research on the Multiscale Characterization and Performance of Basalt Fiber Powder-Modified Sasobit Warm-Mix Asphalt
by Yuhan Li, Zhaoyang Chen, Junwei Bi and Meisheng Shi
Materials 2026, 19(9), 1708; https://doi.org/10.3390/ma19091708 - 23 Apr 2026
Abstract
Warm-mix asphalt (WMA) technology and basalt fiber modification have been increasingly applied in road engineering. However, conventional basalt fibers often disperse unevenly and tend to agglomerate. In this study, basalt fiber powder (BFP) was incorporated into a Sasobit-based WMA system and systematically compared [...] Read more.
Warm-mix asphalt (WMA) technology and basalt fiber modification have been increasingly applied in road engineering. However, conventional basalt fibers often disperse unevenly and tend to agglomerate. In this study, basalt fiber powder (BFP) was incorporated into a Sasobit-based WMA system and systematically compared with matrix asphalt, Sasobit-modified WMA, conventional basalt fiber-modified WMA, and styrene butadiene styrene (SBS)-modified asphalt. Multiscale characterization—including dynamic shear rheometry (DSR), bending beam rheometry (BBR), scanning electron microscopy (SEM), and nanoindentation—was conducted to elucidate rheological behavior and interfacial micromechanical responses. The corresponding Asphalt Concrete-13 (AC-13) mixtures were further evaluated through rutting tests, low-temperature bending tests, and moisture susceptibility tests. Results demonstrate that micronized BFP achieves more homogeneous dispersion within the asphalt matrix and may promote a more effective reinforcing morphology, significantly enhancing high-temperature deformation resistance while partially mitigating the low-temperature stiffness increase induced by Sasobit. Compared with conventional basalt fiber systems, BFP shows better stress relaxation capacity and interfacial mechanical response under the tested conditions. At the mixture level, the BFP–Sasobit system showed the best overall performance, with the dynamic stability increasing by 242.2% relative to the base asphalt mixture and the residual Marshall stability reaching 92.3%, while the low-temperature flexural strain increased by 33.3%. Overall, the findings suggest that morphology-controlled micronization provides a morphology-guided enhancement strategy for Sasobit-based warm-mix asphalt by promoting coordinated improvements across the rheological, micromechanical, and mixture scales. Full article
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30 pages, 989 KB  
Article
Rheological Performance of Asphalt Modified with Coal–Oil Co-Processing Residue
by Ruofei Qi, Jiuguang Geng, Pengju Huo, Yajie Guo, Wenhui Zhao, Yong Huang and Xiaoqian Zhang
Materials 2026, 19(9), 1707; https://doi.org/10.3390/ma19091707 - 23 Apr 2026
Abstract
To address high-temperature stability demands and promote resource utilization, this study investigates coal–oil co-processing residue (COCR) as an asphalt modifier. Penetration, softening point, ductility, rheological, and aging/storage evaluations were conducted on asphalt with varying COCR contents. Modification mechanisms were analyzed using FTIR, GPC, [...] Read more.
To address high-temperature stability demands and promote resource utilization, this study investigates coal–oil co-processing residue (COCR) as an asphalt modifier. Penetration, softening point, ductility, rheological, and aging/storage evaluations were conducted on asphalt with varying COCR contents. Modification mechanisms were analyzed using FTIR, GPC, and SARA fractionation. The results revealed that COCR significantly enhanced high-temperature performance while slightly reducing low-temperature performance, showing good storage stability. At a 10% COCR content, the rutting factors of 70# and 90# asphalt increased by 44.8% and 46.2%, respectively, at 52 °C. Increased asphaltene content indicated that COCR reinforced the colloidal structure, thus improving the deformation resistance. At a 15% COCR content in mixture, the dynamic stability of asphalt mixtures increased by approximately 53.5% and 59.7% for 70# and 90# base asphalt, respectively. Considering overall performance balance, 10% COCR in 90# base asphalt would be recommended for regions with hot summers and warm winters. Full article
(This article belongs to the Special Issue Sustainable Recycling Techniques of Pavement Materials (3rd Edition))
16 pages, 1546 KB  
Article
Sensor-Based and VR-Assisted Visual Training Enhances Visuomotor Reaction Metrics in Youth Handball Players
by Ricardo Bernárdez-Vilaboa, Juan E. Cedrún-Sánchez, Silvia Burgos-Postigo, Rut González-Jiménez, Carla Otero-Currás and F. Javier Povedano-Montero
Sensors 2026, 26(8), 2555; https://doi.org/10.3390/s26082555 - 21 Apr 2026
Viewed by 188
Abstract
Background: Sensor-based systems and virtual reality (VR) technologies provide new opportunities for the objective, technology-driven assessment and training of visuomotor performance in applied contexts such as sport. Methods: This study examined the effects of an integrated visual training program combining stroboscopic stimulation, VR-based [...] Read more.
Background: Sensor-based systems and virtual reality (VR) technologies provide new opportunities for the objective, technology-driven assessment and training of visuomotor performance in applied contexts such as sport. Methods: This study examined the effects of an integrated visual training program combining stroboscopic stimulation, VR-based vergence exercises, and instrumented reaction-light tasks in adolescent handball players. Twenty-eight adolescent handball players (under-18 competitive level) completed two baseline assessments separated by six weeks, followed by a six-session training program (approximately 15 min per session) integrated into regular team practice. The intervention targeted visuomotor reaction speed, accommodative dynamics, and peripheral visual responsiveness using sensor-based and virtual reality–assisted stimuli. Results: Compared with both baseline measurements, the intervention produced selective improvements in accommodative facility (cycles per minute, cpm)—particularly near–far focusing speed—and in multiple reaction-time conditions (milliseconds, ms) involving manual and decision-based responses. Specific peripheral-field locations showed increased response scores, whereas binocular alignment, AC/A ratio, near phoria, and stereoscopic acuity remained unchanged. Conclusions: These findings indicate that technology-supported visual training protocols incorporating sensor-based reaction systems and VR stimuli were associated with measurable adaptations in dynamic visuomotor processing while preserving fundamental binocular vision parameters. Full article
(This article belongs to the Special Issue Virtual Reality and Sensing Techniques for Human: 2nd Edition)
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22 pages, 5365 KB  
Article
Design, Performance and Mechanisms of Asphalt Modified with Polyurethane and Hydroxylated Crumb Rubber
by Jun Xie, Junpeng Lin, Shaopeng Wu, Quantao Liu, Chao Li, Shibo Zhang, Huan Wang, Fusong Wang and Zoujun Wan
Materials 2026, 19(8), 1654; https://doi.org/10.3390/ma19081654 - 21 Apr 2026
Viewed by 189
Abstract
Under long-term heavy load and complex service environments, polyurethane-modified asphalt (PUMA) struggles to simultaneously satisfy the requirements of rutting and cracking resistance of asphalt pavements, as cyclic stress loading reduces the elastic recovery and low-temperature toughness of polyurethane (PU). To address this issue, [...] Read more.
Under long-term heavy load and complex service environments, polyurethane-modified asphalt (PUMA) struggles to simultaneously satisfy the requirements of rutting and cracking resistance of asphalt pavements, as cyclic stress loading reduces the elastic recovery and low-temperature toughness of polyurethane (PU). To address this issue, this study employed hydroxylated crumb rubber (HCR), which is obtained by activating the surface of crumb rubber (CR) and can chemically crosslink with PU in asphalt to form a crosslinked network structure. The aim was to enhance the rutting and cracking resistance of PUMA by utilizing the elasticity and low-temperature toughness of CR. An orthogonal design was employed to systematically design a modified asphalt formulation with PU and HCR (PU/HCRMA) by controlling the isocyanate index and the contents of PU and HCR. The basic properties, rheological properties, and viscoelastic properties of PU/HCRMA were systematically investigated. The results demonstrate that the rutting and cracking resistance of PU/HCRMA are substantially enhanced, with an improvement of 28.91% in the rutting factor at 64 °C compared to PUMA and a reduction of 49.93 MPa in the stiffness modulus at −24 °C. Simultaneously, incorporating HCR in PUMA enhances its viscosity and flow resistance while reducing temperature susceptibility. Furthermore, by providing load-bearing sites, HCR endows PU/HCRMA with exceptional elastic recovery and deformation resistance. Results from FTIR and FM confirm the reaction between isocyanate groups in the PU prepolymer and the hydroxyl groups on the surface of HCR and the formation of HCR-PU crosslinked networks. Finally, PU/HCRMA asphalt mixtures demonstrate significant improvements in both rutting and cracking resistance. This research outcome provides a new direction for the development of high-performance road asphalt materials. Full article
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24 pages, 11089 KB  
Article
The Design and Engineering Application of Recycled Asphalt Mixture Based on Waste Engine Oil
by Guangyu Men, Fangyuan Han, Yanlin Chen, Yu Cui, Jialong Yan, Juanqi Liang and Zichao Wu
Infrastructures 2026, 11(4), 142; https://doi.org/10.3390/infrastructures11040142 - 20 Apr 2026
Viewed by 181
Abstract
To address the growing demand for sustainable road infrastructure development and resolve technical bottlenecks in reclaimed asphalt pavement (RAP) recycling, this study optimized the performance of recycled asphalt mixtures (RAMs) and validated their engineering applicability for field construction. RAM specimens were prepared using [...] Read more.
To address the growing demand for sustainable road infrastructure development and resolve technical bottlenecks in reclaimed asphalt pavement (RAP) recycling, this study optimized the performance of recycled asphalt mixtures (RAMs) and validated their engineering applicability for field construction. RAM specimens were prepared using 5-year and 10-year aged RAP from Ningxia, with a constant RAP content of 30%. Laboratory tests including high-temperature rutting, moisture susceptibility, low-temperature cracking, dynamic modulus, and four-point bending fatigue were performed to determine the optimal mix proportion. Fourier Transform Infrared Spectroscopy (FTIR) and Thin-Layer Chromatography-Flame Ionization Detection (TLC-FID) were employed to reveal the regeneration mechanism of waste engine oil (WEO). Results showed that WEO modified the functional groups and four fractions of asphalt, optimizing its colloidal structure, while excessive WEO compromised high-temperature stability. The optimal WEO contents were 4% for RAP (5Y) and 8% for RAP (10Y), which significantly enhanced the overall performance of RAM to adapt to Ningxia’s climate. This study provides technical support for sustainable road infrastructure in arid and semi-arid regions. Full article
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19 pages, 2980 KB  
Article
Development of a Soft Asphalt Mix for Pedestrian Pavements Using Crumb Rubber from Recycled Tires
by Beatriz Ribeiro, Josias Breda, Francisco Machado and Jorge Pais
Infrastructures 2026, 11(4), 141; https://doi.org/10.3390/infrastructures11040141 - 19 Apr 2026
Viewed by 138
Abstract
This paper develops a shock-absorbing asphalt mixture for pedestrian pavements that mitigates the impact of normal walking on pedestrians’ bodies by incorporating crumb rubber from recycled tires to produce a soft mixture. This aims to reduce injuries to vulnerable road users, enable the [...] Read more.
This paper develops a shock-absorbing asphalt mixture for pedestrian pavements that mitigates the impact of normal walking on pedestrians’ bodies by incorporating crumb rubber from recycled tires to produce a soft mixture. This aims to reduce injuries to vulnerable road users, enable the rethinking of urban pavement designs, and address the major challenges facing societies, ultimately achieving more sustainable, resilient, and safer cities. To promote land sustainability, the designed asphalt mixture should be pervious, allowing water to infiltrate into the underlying soil. The development of the asphalt mixture followed an experimental methodology that involved formulating asphalt mixtures with conventional bitumen, polymer-modified bitumen, and bituminous emulsion. The shock-absorbing capability was evaluated by measuring the deformation of the asphalt mixture over time in response to a falling weight from a Light Falling Weight Deflectometer. Permeability capabilities were assessed through the permeability test. Subsequently, the asphalt mixture was characterized according to its macrotexture, friction, air void content, rutting resistance, and stiffness to assess its suitability as a walking surface material. Results indicate that increasing rubber content enhances deformation capacity and improves cushioning but reduces stiffness. Among the solutions, mixtures with polymer-modified bitumen and intermediate rubber content achieved the balance between impact attenuation and mechanical performance. Full article
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33 pages, 1058 KB  
Review
Sustainable Asphalt Mixtures: A Review of Recycling and Low-Temperature Technologies for an Integrated Sustainability Assessment
by Caroline F. N. Moura, Hugo M. R. D. Silva and Joel R. M. Oliveira
Infrastructures 2026, 11(4), 139; https://doi.org/10.3390/infrastructures11040139 - 17 Apr 2026
Viewed by 358
Abstract
Asphalt pavements are essential to modern transport infrastructure but remain highly dependent on virgin aggregates and petroleum-based binders, resulting in high energy demand and significant greenhouse gas emissions. In response, research has advanced recycled-material solutions and low-temperature asphalt technologies. However, sustainability is still [...] Read more.
Asphalt pavements are essential to modern transport infrastructure but remain highly dependent on virgin aggregates and petroleum-based binders, resulting in high energy demand and significant greenhouse gas emissions. In response, research has advanced recycled-material solutions and low-temperature asphalt technologies. However, sustainability is still often inferred from isolated environmental indicators, without consistent consideration of mechanical durability or economic feasibility throughout the life cycle. This review provides an integrated synthesis of sustainable asphalt mixtures by jointly examining recycling strategies, temperature-reduction processes (warm-mix, half-warm-mix, and cold-mix asphalt technologies), and their combined applications through an integrated performance–cost–environment perspective. The literature reveals substantial methodological fragmentation, with limited harmonisation of functional units, system boundaries, and allocation rules, which constrains cross-study comparability. Evidence indicates that reclaimed asphalt, recycled concrete aggregates, and steel slag can maintain or improve rutting resistance, stiffness, and moisture durability while enabling material cost savings of approximately 5–68%. Temperature-reduction technologies further achieve significant energy and GHG reductions in the production phase (20–70%), with integrated recycling–temperature-reduction systems showing the most consistent combined benefits. Overall, this review demonstrates that asphalt sustainability cannot be established through single-dimensional assessments but requires harmonised life-cycle frameworks that explicitly link environmental gains to mechanical performance, durability, and economic viability. Full article
(This article belongs to the Special Issue Sustainable Road Design and Traffic Management)
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23 pages, 6460 KB  
Article
Performance Evaluation and Micro-Mechanisms of Composite Asphalt Modified by Desulfurized Rubber Powder and Distinct Waste Plastics
by Dongwei Cao, Mingming Zhang, Rui Zheng, Qidong Su and Wenbo Zhou
Polymers 2026, 18(8), 973; https://doi.org/10.3390/polym18080973 - 16 Apr 2026
Viewed by 191
Abstract
The synergistic utilization of waste plastics and tires in asphalt modification is a highly promising sustainable strategy. However, the differential impacts of distinct plastic molecular architectures on the performance and network evolution of rubber-modified asphalt remain fundamentally unclear. This study systematically investigated the [...] Read more.
The synergistic utilization of waste plastics and tires in asphalt modification is a highly promising sustainable strategy. However, the differential impacts of distinct plastic molecular architectures on the performance and network evolution of rubber-modified asphalt remain fundamentally unclear. This study systematically investigated the physical, rheological, and microstructural properties of composite asphalts modified with desulfurized rubber powder (DRP) and four representative plastics: polyethylene (PE), styrene–isoprene–styrene (SIS), styrene–ethylene–butylene–styrene (SEBS), and styrene–butadiene–styrene (SBS). Furthermore, the pavement performance of the asphalt mixtures prepared via dry and wet methods was comparatively evaluated. Microstructural and spectroscopic analyses revealed that the composite modification was primarily governed by physical blending and swelling. The non-polar, semi-crystalline PE resulted in severe phase separation and extreme low-temperature brittleness. Conversely, the saturated hydrogenated mid-blocks of SEBS endowed the asphalt with the highest high-temperature rutting resistance but severely compromised its low-temperature stress relaxation. Remarkably, SBS interacted synergistically with DRP to form a highly homogeneous and densely interwoven three-dimensional network, thereby achieving an optimal viscoelastic balance, outstanding storage stability, and superior low-temperature ductility. Pavement performance tests further demonstrated that the wet method significantly outperformed the dry method for block copolymers by facilitating sufficient pre-swelling. Overall, the SBS-DRP composite-modified asphalt prepared via the wet method exhibited the most exceptional and balanced comprehensive pavement performance, providing a robust theoretical foundation for the sustainable and high-value recycling of multi-source solid wastes in paving engineering. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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20 pages, 11369 KB  
Article
Asphalt Binder Modification with Hazelnut and Walnut Shells as Valued Antioxidant Sources: Effects on Rheological and Main Physicochemical Post-Oxidation Indicators
by Carlos Manterola-Barroso, Karina Godoy-Sánchez, Erick Scheuermann, Ivanka Netinger Grubeša, Dunja Šamec and Cristian Meriño-Gergichevich
Materials 2026, 19(8), 1560; https://doi.org/10.3390/ma19081560 - 14 Apr 2026
Viewed by 325
Abstract
Oxidative aging drives asphalt pavement degradation, causing critical structural failures. This study evaluated hazelnut (HS) and walnut shell (WS) powders (0–3% w/w; 10–12 μm) as sustainable antioxidants, from valued residues, to mitigate thermo-oxidative aging in CA-24 binders. After evaluating the [...] Read more.
Oxidative aging drives asphalt pavement degradation, causing critical structural failures. This study evaluated hazelnut (HS) and walnut shell (WS) powders (0–3% w/w; 10–12 μm) as sustainable antioxidants, from valued residues, to mitigate thermo-oxidative aging in CA-24 binders. After evaluating the antioxidant potential (ORAC; Oxygen radical absorbance capacity, and TPC; Total phenolic content), modified binders underwent RTFO (Rolling thin film oven) and PAV (Pressure aging vessel) aging, evaluated by Fraass fragility, Relative Aging Index (RAI), dynamic shear rheometry (G*/sin δ), and Multiple Stress Creep Recovery (MSCR). WS exhibited significantly higher antioxidant capacity (6000 μmol TE g DW−1) and TPC than HS. The 3% treatments demonstrated optimal antioxidant efficacy, reducing long-term RAI by 14% and improving low-temperature flexibility by 3.8 °C (Fraass point −12.3 °C). However, MSCR revealed initial plasticizing effects decreasing elastic recovery (70%) and increasing non-recoverable compliance (Jnr) compromising unaged rutting resistance. Principal component analysis confirmed progressive diversification of aging-induced properties, evidencing complex multivariate trajectories. Ultimately, while nutshell derived phenolic modifiers provide effective concentration-dependent antioxidant protection, practical application requires optimization through targeted phenolic extraction, particle engineering, or elastomeric co-modification. Balancing aging resistance with high temperature stability remains essential for advancing these sustainable biomodification strategies in road infrastructure. Full article
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31 pages, 3953 KB  
Article
Design and Construction Practices for Full-Depth Reclamation of Asphalt Mixtures with Bituminous and Cementitious Additives
by Swathi Malluru, Ahmed Saidi, Ayman Ali and Yusuf Mehta
Materials 2026, 19(8), 1540; https://doi.org/10.3390/ma19081540 - 12 Apr 2026
Viewed by 344
Abstract
Several highway agencies have implemented full-depth reclamation (FDR) as a sustainable technology for rehabilitating deteriorated asphalt pavements. However, the lack of standardized mix design procedures and limited field assessment, in terms of rutting and cracking resistance, pose challenges to the widespread implementation of [...] Read more.
Several highway agencies have implemented full-depth reclamation (FDR) as a sustainable technology for rehabilitating deteriorated asphalt pavements. However, the lack of standardized mix design procedures and limited field assessment, in terms of rutting and cracking resistance, pose challenges to the widespread implementation of FDR. This study addresses these challenges by synthesizing current FDR mix design and construction practices and validating highway agency-recommended practices through laboratory performance evaluation. The study objectives were achieved by (1) reviewing current FDR mix design and construction specifications of highway agencies across the US and internationally, (2) conducting surveys with highway agencies and interviews with subject matter experts (SMEs), and (3) evaluating the laboratory performance of FDR mixtures. Based on the findings from the literature, survey responses, and SME interviews, three FDR mixtures were designed in the lab: (i) cement-only, (ii) asphalt emulsion and cement, and (iii) foamed asphalt and cement. Each mix was then evaluated for rutting susceptibility using the Asphalt Pavement Analyzer (APA) and cracking resistance using the indirect tensile (IDT) test to identify optimum dosages of bituminous and cementitious additives. Laboratory results showed that FDR mixtures with 3% asphalt emulsion and 1% cement improved rutting resistance by 46% and cracking performance by 70% compared to cement-only mixtures with 4% cement. In contrast, foamed asphalt did not result in a significant improvement in FDR performance. Survey responses indicated that 89% of respondents reported good field performance of FDR, with Pennsylvania and North Dakota exhibiting excellent performance 10 years after construction. Full article
(This article belongs to the Section Construction and Building Materials)
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12 pages, 1100 KB  
Article
Assessment of Flexible Pavement Containing Rubberized Asphalt
by Noorance Al-Mukaram, Tariq Al-Mansoori, Ali M. Lafta, Karzan Ismael and Pooyan Ayar
Polymers 2026, 18(8), 927; https://doi.org/10.3390/polym18080927 - 10 Apr 2026
Viewed by 464
Abstract
This work deals with a practical method of using crumb rubber resulting from waste tires to produce modified bitumen via a wet mixing method for road construction in Iraq. Due to wide variation in temperatures and over-loading traffic in Iraq, rutting deformation is [...] Read more.
This work deals with a practical method of using crumb rubber resulting from waste tires to produce modified bitumen via a wet mixing method for road construction in Iraq. Due to wide variation in temperatures and over-loading traffic in Iraq, rutting deformation is the most observed structural pavement problem. Also, tire wear and tear are higher in Iraq than in other countries due to high temperature and dry weather most of the year, which makes considerable amounts of waste tire piles easily accessible. Utilizing this waste material could be crucial to the environment and economy of the country, as well as to the sustainability of resources. Using waste tire materials as bitumen modifiers in the production of hot mix asphalt is a widely practiced experiment, although it is applied differently depending on the weather, type of bitumen used, and its availability. In the methodology of this research, it is suggested to modify asphalt grades 60/70 by a certain amount of crumb rubber (5–20%). The modified asphalt and asphalt grade 40/50 were used in preparing two types of asphalt concretes to examine their volumetric properties and evaluate their rutting behavior. The results for both mixtures were compared to the Iraqi General Specifications for Roads and Bridges (SORB/R9). The findings showed significant improvements in Marshall stability and flow, as well as in the percentages of voids satisfied in the modified mixture. After using rubberized asphalt in the mixture, the rutting depth was recorded below 20 mm and decreased by 30% and 26% at temperatures of 40 °C and 60 °C, respectively, compared to the controlled mixture. Full article
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21 pages, 4125 KB  
Article
Rutting Resistance and Fatigue Performance of Crumb Rubber-Modified Asphalt Concrete: Experimental Investigation and Mechanistic–Empirical Modeling
by Udeme Udo Imoh, Daniel Akinmade and Majid Movahedi Rad
Infrastructures 2026, 11(4), 133; https://doi.org/10.3390/infrastructures11040133 - 8 Apr 2026
Viewed by 603
Abstract
Crumb rubber-modified asphalt concrete (CMAC) has gained increasing attention as a sustainable pavement material capable of improving mechanical performance while utilizing waste tire resources. This study investigates the rutting resistance and fatigue behavior of CMAC using a combined experimental and mechanistic–empirical modeling approach. [...] Read more.
Crumb rubber-modified asphalt concrete (CMAC) has gained increasing attention as a sustainable pavement material capable of improving mechanical performance while utilizing waste tire resources. This study investigates the rutting resistance and fatigue behavior of CMAC using a combined experimental and mechanistic–empirical modeling approach. Asphalt mixtures containing 0–25% crumb rubber by binder weight were prepared and evaluated through Marshall stability and indirect tensile fatigue tests, whereas Fourier-transform infrared spectroscopy (FTIR) was used to examine binder–rubber interactions. The results indicate that crumb rubber significantly influences both the volumetric and mechanical properties of asphalt mixtures. Mixtures containing 10–15% crumb rubber exhibited optimal performances, achieving up to 36% higher Marshall stability and improved fatigue life compared with conventional asphalt mixtures. FTIR analysis revealed that rubber particle swelling and limited chemical interactions enhanced binder elasticity and improved binder–aggregate compatibility. However, excessive rubber content (≥20%) resulted in reduced stability owing to increased binder absorption and decreased effective binder film thickness. A mechanistic–empirical model incorporating viscoelastic, viscoplastic, and fatigue damage parameters successfully reproduced the experimental trends and identified the same optimal rubber content range. The findings demonstrate that CMAC with a moderate rubber content can enhance pavement durability and structural performance while promoting environmentally sustainable road construction through the reuse of waste tires. Full article
(This article belongs to the Special Issue Sustainable Road Design and Traffic Management)
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24 pages, 3713 KB  
Article
Incorporation of Lignin Binder from Agricultural Waste to Enhance Sustainability and Performance of Asphalt Pavements
by Joan G. Lynam, Nazimuddin Wasiuddin, Mostafa A. Elseifi, Syed Ashik Ali, Musharraf Zaman, Md Reazul Islam, Nafisa Tarannum and Kenneth Hobson
Biomass 2026, 6(2), 28; https://doi.org/10.3390/biomass6020028 - 8 Apr 2026
Viewed by 248
Abstract
Utilizing lignin from agricultural wastes as a partial replacement for asphalt binder used in pavement presents a sustainable option, as it is abundant in nature. The effects of the addition of lignin on the properties and performance of asphalt binder and asphalt mixes [...] Read more.
Utilizing lignin from agricultural wastes as a partial replacement for asphalt binder used in pavement presents a sustainable option, as it is abundant in nature. The effects of the addition of lignin on the properties and performance of asphalt binder and asphalt mixes were studied. Lignin was produced from rice husks, using a hydrothermal carbonization (HTC) treatment process. The rice husk-derived lignin was then mixed with a PG 67-22 binder at 0%, 5% and 10% of the mass of the total binder. The HTC treatment of rice husks at 250 °C created a powdery substance with an increased acid-insoluble lignin content and a reduced cellulose and hemicellulose content. The addition of 10% lignin was found to produce an unstable modified binder due to phase separation between the lignin and binder, thus requiring continuous stirring before use. Asphalt mixes prepared with 5% lignin exhibited better moisture-induced damage resistance compared to the control mix. Also, an improved rutting resistance of asphalt mixes was observed with the use of a lignin-modified binder. Lignin from rice husks may constitute a sustainable partial substitute for a crude-oil-based binder. Full article
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22 pages, 2498 KB  
Article
Mn(II) Complex with Rutin—Spectral Characteristic, Quantum-Chemical Calculations, Antioxidant and α-Amylase Inhibitory Activity
by Maciej Kozłowski, Monika Kalinowska, Mariola Samsonowicz, Grzegorz Świderski and Beata Kalska-Szostko
Materials 2026, 19(7), 1466; https://doi.org/10.3390/ma19071466 - 6 Apr 2026
Viewed by 551
Abstract
Rutin is a naturally occurring flavonoid with well-documented antioxidant and pharmacological properties. In this study, a manganese(II) complex with rutin (Mn(II)-Rut) was synthesized in a solid state and characterized using FT-IR, Raman spectroscopy, thermogravimetric and elemental analysis, confirming its composition as C27 [...] Read more.
Rutin is a naturally occurring flavonoid with well-documented antioxidant and pharmacological properties. In this study, a manganese(II) complex with rutin (Mn(II)-Rut) was synthesized in a solid state and characterized using FT-IR, Raman spectroscopy, thermogravimetric and elemental analysis, confirming its composition as C27H27O16Mn2·5H2O. The IR spectra indicated that rutin coordinates manganese ions through the carbonyl group at the C4 position and the hydroxyl group at the C5 atom, as well as the catecholic system. The antioxidant potential of both Mn(II)-Rut and rutin was evaluated using several spectrophotometric assays. The Mn(II)-Rut complex showed stronger activity in most spectrophotometric assays than rutin, i.e., in ABTS assay, 50.37 ± 2.64% vs. 41.49 ± 1.38%; in CUPRAC assay, 0.468 ± 0.006 mM Trolox vs. 0.379 ± 0.007 mM Trolox; and FRAP assay, 0.201 ± 0.002 µM vs. 0.189 ± 0.003 µM. However, the DPPH assay complex showed a diminished effect compared with ligand (IC50 2.78 ± 0.13 µM vs. 0.98 ± 0.04 µM for rutin). Quantum-chemical calculations were also performed using the Gaussian09 program to determine the optimized geometric structures, electron charge distribution, and the energies of the HOMOs and LUMOs in the analyzed molecules in order to discuss the antioxidant mechanism of the molecules. Enzymatic assays demonstrated that the Mn(II) complex with rutin exhibited a stronger α-amylase inhibitory effect compared to free rutin, which showed the potential antidiabetic activity of the compound. The results suggest that the Mn(II) complex of rutin possesses better antioxidant and α-amylase inhibitory activity than the ligand alone. Full article
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