Search Results (5,351)

In this work, a flexible and sustainable radar-absorbing material (RAM) based on porous carbon derived from raw Kraft black liquor was developed. The porous carbon filler was synthesized through a simple, eco-friendly one-pot polymerization route, thereby avoiding lignin extraction, purification, and chemical activation steps. Macroporosity was introduced by using poly(methyl methacrylate) microspheres as a hard template, yielding a lightweight carbon material with a foam-like morphology, low density, and high porosity. The carbon filler was incorporated into a silicone rubber matrix at different loadings (5–25 wt.%) to produce flexible composites. The structural, morphological, and textural properties of porous carbon were investigated by SEM, EDX, Raman spectroscopy, nitrogen adsorption, and mercury porosimetry. The electromagnetic properties of composites were measured in the X-band (8.2–12.4 GHz) using a vector network analyzer. The mechanical behavior was evaluated through Young’s modulus. The results show that increasing filler content enhances dielectric losses and attenuation capability. Among all composites, the sample containing 20 wt.% of porous carbon exhibited the best electromagnetic performance, achieving a reflection loss of −42.3 dB at 10.97 GHz with a thickness of 2.43 mm, corresponding to an absorption efficiency of 99.99%. This performance is attributed to a favorable combination of impedance matching and quarter-wavelength cancellation effects. The developed sustainable, lightweight, and flexible composites demonstrate potential as low-cost RAM for aerospace and electromagnetic interference mitigation applications. Full article

To investigate the deterioration law of the mechanical properties of PVA-fiber-reinforced rubber concrete under the combined action of high-temperature and salt erosion, physical index tests, dynamic mechanical property experiments, and microstructural morphology observations were carried out on specimens subjected to different temperatures (ambient temperature, 100 °C, 300 °C) and various solution attacks (water, 5% NaCl, 5% Na₂SO₄, and 5% NaCl + 5% Na₂SO₄ mixture). The results show that, after exposure to 300 °C, the PVA fibers melt and the rubber pyrolyzes, since this temperature exceeds their melting points. A residual pore network is formed inside the matrix, and the damage degree of ultrasonic pulse velocity is about 2.3 times that of the 100 °C group. Although salt solution and its crystallization products can physically fill the pores and cause a partial recovery of pulse velocity, this change is mainly due to the alteration of the pore medium and does not represent a substantial restoration of the microstructure. The effects of different salt solutions on dynamic mechanical properties vary significantly: Sulfate erosion improves the dynamic performance significantly at ambient temperature by forming gypsum and ettringite to fill pores, but this strengthening effect disappears after 300 °C. Sodium chloride attack generates Friedel’s salt and consumes C₃A, leading to general strength deterioration. In composite salt erosion, the competitive and synergistic effects of Cl⁻ and SO₄²⁻ destabilize erosion products and weaken interfacial bonding, resulting in consistent decreases in dynamic compressive strength and elastic modulus under all temperatures and impact pressures. The strength reduction reaches 66.2% after 300 °C. Microscopic analysis confirms that composite salt erosion leads to the dissolution of ettringite and loose structure, which verifies the synergistic deterioration law of macroscopic properties. This study systematically reveals the damage evolution mechanism of PVA-fiber-reinforced rubber concrete under the coupled action of high-temperature and salt erosion, and provides a theoretical basis for the dynamic bearing capacity evaluation and durability design of concrete structures in such coupled environments. Full article

Taraxacum kok-saghyz (TK), the rubber dandelion, is an emerging crop offering potential for sustainable natural rubber production independent of tropical climates. Successful domestication of TK requires a mechanistic understanding of its reproductive biology, yet floral anatomy, sporogenesis, and gametogenesis remain poorly characterized. We hypothesized that TK’s reproductive development follows the general patterns of sexually reproducing diploid Taraxacum species and other Asteraceae, distinguishable from the irregular meiosis reported in apomictic taxa. Here, using light and scanning electron microscopy across multiple developmental stages, we describe the floral and inflorescence anatomy, as well as sporogenesis and gametogenesis in TK. Anther development in TK predominantly follows the simultaneous microsporogenesis pattern, typical of eudicots, producing regular tetrahedral tetrads. Notably, we also observed occasional successive-type events resulting in dyads and tetragonal tetrads, indicating a previously unreported developmental variation within the species, culminating in mature tricellular pollen. We detail key reproductive structures, including anther wall layers, ovary mesophyll differentiation, and the presence of a micropylar obturator. The meiotic behavior and gametophyte development observed in TK are consistent with those of diploid, sexually reproducing Taraxacum species and other members of the Asteraceae, in contrast to the irregular meiosis reported in Taraxacum apomictic taxa. These newly described morphoanatomical details on reproductive aspects will inform breeding strategies and advance our understanding of pollination, fertilization, and seed development in TK. Full article

The current paper aims to study the thermal stability of ethylene–propylene–diene monomer (EPDM) and styrene–ethylene–butylene–styrene (SEBS) block copolymer attained by radiation processing and evaluated by chemiluminescence (CL). Three blends with different weight ratios (1:3, 1:1 and 3:1), as well as individual rubbers, are γ-irradiated at 25, 50, 100 and 150 kGy. Their thermal stabilities are intercompared, and the activation energies required for oxidative degradation are calculated by using the values of oxidation induction times. Another investigation concerning the development of gel is in good agreement with the CL results. The aspects related to the mechanisms of the radiation fragmentation of blended components are discussed. The contributions of the blending components are evaluated based on the peculiar kinetic parameters, namely oxidation induction time (OIT) and onset oxidation temperatures (OOTs). It is clearly demonstrated that the EPDM component serves as the main source of radicals required for crosslinking, while the SEBS skeletons become the structural frames for the new crosslinked branches. The activation energies increase from 50 kJ mol⁻¹ to 59 kJ mol⁻¹ for unirradiated materials, but the increase for the blends exposed to 100 kGy is significantly larger from 41 kJ mol⁻¹ to 54 KJ mol⁻¹. The growth in the blending proportion of SEBS improves the thermal stability of the resulting materials. It is observed that the largest differences in the thermal resistances of γ-irradiated compounds are obtained for the samples exposed at 150 kGy, when the participation of each of the components is taken into account. This study highlights the research on and the productive methods of polymer processing, and the study of the irradiation of blends generates high-performance technical articles by the appropriate selection of technological parameters. Full article

To address the poor vertical vibration reduction in laminated rubber bearings, the high cost and low practicality of combined three-dimensional isolation bearings, and the low load-bearing capacity of thick-layer rubber bearings, this paper proposes a stiffness-reduced rubber isolation bearing. Based on the deformation coordination principle and the incompressibility of thick-layer rubber, theoretical formulas for the horizontal and vertical stiffness of the proposed bearing are established. Compression–shear tests and finite element simulations are then conducted to investigate its mechanical properties under vertical compressive stress. The results show that the theoretical predictions agree well with the simulation and experimental results. The maximum error of horizontal stiffness is no more than 5.6% relative to the finite element simulation and no more than 3.3% relative to the experimental results, while the maximum error of vertical stiffness is no more than 7.9% and 2.3%, respectively. Compared with the traditional laminated rubber bearing, the stiffness-reduced rubber isolation bearing reduces the average vertical stiffness by 35.8% while maintaining stable horizontal mechanical performance and overall integrity within the tested range. Furthermore, parametric analysis indicates that the stiffness can be effectively adjusted by changing the inner-diameter/outer-diameter ratio. A case study based on measured metro-induced vibration time-history curves further shows that the proposed bearing has potential for achieving the dual objective of horizontal isolation and vertical vibration reduction. Full article

Hydrogen is increasingly adopted as a clean energy carrier for storing and transporting low-carbon energy. Achieving a practical volumetric energy density for real-world deployment typically requires compression to several hundred bar, which in turn demands dedicated high-pressure infrastructure. Because valves are indispensable for isolation and flow control within this infrastructure, durable sealing valve materials become a key reliability and safety requirement. This assembly-level screening study compares two valve configurations with different polymer assemblies: EPDM O-rings with PEEK seats/bushing and NBR O-rings with POM seats/bushing. Four new identical 500-bar ball valves were tested (two EPDM/PEEK and two NBR/POM). For each seal configuration, one valve was cycled 5000 times at 500 bar in helium (inert baseline), and a second identical valve was cycled 5000 times at 500 bar in hydrogen to isolate hydrogen effects from mechanical/metallic wear. Leakage was tracked during cycling, and seals were analyzed by SEM/EDX after testing. The EPDM/PEEK configuration remained leak-tight in both gases, with no cracking observed in the elastomer or thermoplastic components. The NBR/POM configuration exhibited POM bushing fracture during cycling and minor external leakage at the stem during the hydrogen phase, accompanied by micro-fissures on the NBR O-ring surface. EDX indicated composition changes after cycling, including oxygen and fluorine enrichment and occasional metallic transfer species, consistent with surface films and deposits. Under the present valve geometry and cycling protocol, EPDM/PEEK provided robust sealing, whereas NBR/POM showed failure modes relevant to high-pressure service. These findings are intended as configuration-level screening evidence to be used in valves rather than as a full qualification of the individual materials. Full article

A sustainable way to recycle used tires and improve the functionality of asphalt pavements is through the use of crumb rubber modified asphalt (CRMA). However, its application during high-temperature construction raises environmental and occupational health concerns due to the release of significant quantities of odorous and potentially harmful gases. Therefore, this study selected α-Amyl cinnamic aldehyde (ACA) as a deodorant and added it to CRMA at proportions of 0.5%, 1.0%, 1.5%, and 2.0% to prepare DCRMA. A number of common tests, such as softening point, ductility, penetration, Brookfield rotational viscosity, and segregation analysis, were used to evaluate the basic characteristics of the modified asphalt. A self-developed asphalt fume monitoring device was used to quantitatively analyze the changes in VOCs, H₂S gas concentration, and solid particle content in the asphalt fumes to assess the deodorization effect of ACA on CRMA. Furthermore, the deodorization mechanism of ACA on CRMA was explored in depth using microscopic methods, such as fluorescence microscopy (FM) and Fourier transform infrared spectroscopy (FTIR). The findings demonstrated that ACA can increase the softening point and viscosity of CRMA while decreasing its penetration and ductility. The storage stability was optimal at a 1.0% ACA addition. Additionally, as the ACA content increased, the concentrations of VOCs, H₂S gas, and solid particles in the asphalt fumes continued to decrease. FM results indicated that when the ACA content did not exceed 1.0%, it promoted the swelling degree of CR in the asphalt. FTIR results showed that ACA can reduce the characteristic peak intensity of CRMA. This study offers important technical references and practical support for the environmentally friendly use of CRMA. Full article

The harvesting of energy from movements is one of the purposes of triboelectric nanogenerators (TENGs). Among the various devices designed to perform this function, floors are one of the primary ones, as they do not need to be individually fitted to each subject and can be manufactured and installed on a large scale. This work classifies previously published TENG-based floors based on their materials, electrical performance in terms of the voltage, current, and power they produce, and their application in different fields. The materials used have been correlated with other important aspects for floors, such as weather or flame resistance, sustainability, recyclability or biodegradability of materials, and price. The synthesis of the variety of TENG-based floor models, which incorporate novel materials, hybrid technologies, or various functionalities, among other characteristics, can enrich and inspire the reader to enhance the performance of future floor designs based on the triboelectric effect. In addition, a novel triboelectric floor design made of nitrile butadiene rubber (NBR) and fluorine kautschuk material is presented, along with the electrical power generated when tribolayers are in contact. For the three floor strips measuring 40 cm long × 4 cm wide and 1 mm thick, electrical current and voltage output was measured, achieving nearly 0.1 W (20 V & 4.5 mA) of electrical power generation. Full article

Noise pollution has become an increasingly discussed environmental problem in recent years. Developing a traffic infrastructure and recent sustainability goals require new solutions to mitigate noise pollution. This paper investigates the efficiency of the noise barrier made entirely of recycled materials. This solution would help achieve the United Nations sustainable development goals (SDGs). The proposed barrier target SDGs are: Good Health and Well-being (SDG 3); Industry, Innovation, and Infrastructure (SDG 9); Sustainable Cities and Communities (SDG 11); Climate Action (SDG 13). The changed barrier parameters were the parameters of the perforated panel and the air gap behind the porous material. To solve the optimisation problem, the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) method was used. The results showed that the proposed barrier configuration was the following: perforation shape—round, perforation diameter—5 mm, increment angle perforation—30°, thickness of the perforated panel—10 mm, porous absorbing material (composite rubber granule and hemp shive panel (RGHS))—50 mm thick, 20% of hemp shive content, air gap between absorbing material and the rigid backing—100 mm. The total thickness of the noise barrier was 180 mm. The acoustic parameters of the noise barrier structure were: α_avg. = 0.24, peaking at 0.51 (1250 Hz) and R_W = 39.7 ± 1.0 dB. These results indicate that the proposed barrier made of recycled materials could be a sustainable alternative for noise pollution mitigation and improving people’s quality of life. Full article

Floating roof seal integrity is critical for safety and emission control in petroleum storage tanks, yet current detection methods suffer from spark risks and operational inefficiencies. This study proposes an intrinsically safe, non-contact leakage detection system utilizing oil-swellable rubber actuators coupled with a linear magnetic transmission mechanism. By integrating quasi-static experiments with finite element simulations, we investigated the impact of permanent magnet geometry on transmission performance. The results establish a “thickness priority principle”, revealing that increasing magnet thickness nonlinearly enhances shear force and transmission efficiency, whereas increasing width yields diminishing returns due to magnetic flux leakage and added mass. Furthermore, comparative analysis demonstrates that optimized monolithic magnets significantly outperform arrayed configurations, achieving a 471% increase in shear force and a 3.7-fold improvement in transmission efficiency. Based on these findings, a practical detection device was designed and verified against API 650 standards. The proposed solution offers a reliable, electricity-free, and real-time monitoring method for early leakage detection in hazardous tank environments. Full article

The present theoretical study proposes and unravels chemical graft modification using a novel voltage stabilizer (3-amino-5-chlorophenyl 3-fluorophenyl methanone, ACFM) to ameliorate electrical insulation performance, oxygen-resistant characteristics, and thermal stability of addition-cure silicone rubber (SiR) used for cable accessory insulation in power transmission systems. First-principles calculations demonstrate that chemically grafted ACFM introduces shallow hole and electron traps into addition-cure SiR macromolecules to respectively impede hole transport and restrict hot electron production. Through molecular dynamics and Monte Carlo simulation, the chemically grafted ACFM is verified to enhance chain segment coalescence and decrease oxygen compatibility of addition-cure SiR macromolecules due to its higher dipole moment, leading to a reduction in oxygen permeation and improvement in thermal stability of the SiR crosslinked material. It is indicated from first-principles oxidation reaction paths that chemical grafting ACFM contributes positively to the oxidative stability of addition-cure SiR. The improved abilities of charge trapping and withstanding high temperatures together with enhanced resistance to both oxygen infiltration and oxidation of the addition-cure SiR material, as unraveled on a molecular scale in this research, open an avenue for developing advanced polymer dielectrics applied in harsh environments. Full article

In order to design a new type of long-life and reliable casing hanger, this paper studied the failure mechanisms of the rubber sealing structures of the slip hanger and the mandrel hanger. Through tensile and compressive tests, the tests and analyses of different rubber structures were completed, data fitting was carried out, and the constitutive relationship of the rubber material was obtained. A superior constitutive model was applied to the sealing materials of the hanger. Numerical calculations were used to obtain the strength and sealing performance variation laws of the rubber sealing components with different structures, and the reasons for the failure of the conventional hanger were found. The results show that the rubber components and the ball-shaped metal sealing components will lose their elastic deformation under high-pressure and large-load conditions, and the reliability will decrease. Finally, a new type of metal sealing structure was designed. Compared with the previous metal sealing structures, this paper conducts a more in-depth and detailed study, and further presents the superiority of metal sealing in terms of structural dimensions and working principles. Experiments were conducted, and the results showed that this sealing structure can meet the usage requirements of the casing hanger with large loads and high pressure. The research results provide theoretical and application guidance for the design of long-life and reliable performance hanger sealing structures. Full article

Background: Dental adhesive materials are important for achieving adequate adhesion results; however, they are not the only factor contributing to final bond strength, as improper operatory field isolation and contamination also significantly influence clinical outcomes. Objectives: This narrative review aims to provide a clinical perspective, supported by evidence-based arguments, to identify clinical procedures for optimizing adhesive protocols, including the execution of absolute isolation with a rubber dam, appropriate cleaning and preparation of the dental substrate, and protocols applicable to total-etch and self-etch techniques. Methods: The literature included in this review was selected through a structured search in PubMed, Scopus, and Web of Science, prioritizing systematic reviews, meta-analyses, long-term clinical studies, and foundational experimental investigations related to adhesive systems and substrate management. Results: A well-established clinical protocol that integrates proper adhesive selection, contamination-free operative field control, and adequate substrate preparation is essential for achieving predictable outcomes in adhesive dentistry. Conclusions: Although simplified adhesive systems offer acceptable bond strength results, established techniques continue to demonstrate consistent reliability, contributing to restorative longevity. Full article

To address the prominent problem of early rutting distress in asphalt pavements under heavy-load traffic in China, this study proposes a composite modifier consisting of direct coal liquefaction residue (DCLR), styrene–butadiene–styrene block copolymer (SBS), and styrene–butadiene rubber (SBR). The preparation process and formula were optimized through single-factor experiments and orthogonal tests. Systematic investigations were conducted on its conventional performance, water damage resistance, aging resistance, fatigue performance, rheological properties, and microscopic mechanism, with comparisons made against base asphalt, single DCLR-modified asphalt, SBS-modified asphalt, and SBS/SBR-modified asphalt. The results indicate that the optimal preparation process for the novel composite high-modulus modified asphalt is as follows: DCLR particle size of 0.3 mm, addition in molten state, shear temperature of 170 °C, shear rate of 5000 r·min⁻¹, shear time of 50 min. The optimal formula is 10% DCLR + 3% SBS + 2% SBR + 3% compatibilizer, with the addition sequence of “DCLR → SBS + compatibilizer → SBR”. This asphalt exhibits a softening point of 77.8 ± 2.1 °C, a Brookfield viscosity at 135 °C of 1.928 ± 0.105 Pa·s, and a grading of 5 for adhesion to aggregates; the rutting factor at 64 °C reaches 10.8 ± 0.9 kPa (6.43 times that of the base asphalt), the creep stiffness at −12 °C is 136 ± 12.5 MPa, and the low-temperature limit temperature is −17 °C; the freeze–thaw splitting strength ratio (TSR) is 94.6 ± 1.8%, and both aging resistance and water damage resistance are significantly superior to those of the control group asphalts (p < 0.05). The novel composite high-modulus modified asphalt showed improved overall laboratory performance and may be suitable for heavy-load traffic and complex climatic conditions, however, field validation is needed. Full article

Flood hazard mapping remains challenging in regions with limited hydrological and topographic data, despite increasing flood risk driven by climate change and land-use dynamics. This study aims to demonstrate that preliminary flood inundation maps can be developed under data-scarce conditions by integrating limited field observations with publicly available datasets and simplified hydrodynamic modeling. The Khlong Wat watershed in southern Thailand, where flood hazard maps had not previously existed despite recurrent flood events, was used as a case study. Flood simulations were conducted using the HEC-RAS model with a simplified terrain representation to approximate river bathymetry, acknowledging uncertainties in channel geometry. Hydrodynamic results show a systematic increase in flood extent and depth with increasing flood recurrence intervals, with inundated areas expanding from 1.43 km² for a 10-year flood to 4.02 km² and 5.97 km² for 100- and 500-year events, respectively. Agricultural land is consistently the most affected category, accounting for more than two-thirds of the flooded area across all scenarios, with rubber plantations being the dominant land use. Urban exposure increases with flood magnitude, although most buildings remain affected by shallow inundation below 0.5 m. The results confirm that meaningful flood hazard assessments can be achieved in data-limited regions and provide a transferable framework to support flood risk management and spatial planning in similar environments. Full article